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By Jerry W. Danni, R. Craig Ford, Kermit C. Benke, Jim B. Finley, Donald D. Runnells

Steady-state water balance models have historically been used in the management of acid drainage at mine sites. Such systems could be more realistically described by non-steady-state conditions. In addition, the evaluation of alternatives for closure and management of acid drainage must consider non-steady-state conditions. Dynamic systems modeling is a method for simulating water management systems, offering flexibility in: (1) simulating either steady-state or non-steady-state conditions, (2) allowing "what-if' scenario testing. and (3) optimization of operation and closure alternatives. A case study is given for acidic drainage management during closure at a heap leach facility that demonstrates the utility of dynamic systems models.

Jan 1, 2000

By M. S. Celik, A. Aslanbas, B. Pehlivanoglu, R. Asmatulu

The principal impurities in some feldspar ores are titanium and iron, which impart color and degrade the quality of the ore. Mineralogical investigations indicate that, while titanium originates mainly from rutile with small amounts of sphene, iron originates mainly from mica minerals. Fatty acids, particularly oleic acid, are extensively used, with reasonable success, in the flotation of colored minerals from feldspar ores. In this study, potassium oleate, oleoyl sarcosine and hydroxamate were used to float colored impurities both before and after magnetic separation. Oleoyl sarcosine is found to exhibit better results compared to other reagents. Magnetic separation followed by flotation is found to produce a feldspar concentrate of superior grade.

Jan 1, 2002

By J. P. Allen, D. A. Rice, H. L. Abercrombie

Cobalt, nickel and manganese can be recovered quickly, cleanly and selectively from cobalt-rich manganese ocean crust by leaching in dilute acid solutions in the presence of hydrogen peroxide. Common selective precipitation methods can then be used to recover these metals from the leach liquor. The leaching reaction produces only oxygen as a byproduct, and the waste residue from leaching was tested and found to be nonhazardous under existing EPA specifications. The leaching process is effective in either fresh water or seawater. This research is a part of the Bureau of Mines program to identify the mineral resources of the Exclusive Economic Zone and devise methods, for recovering their valuable components.

Jan 1, 1992

By John A. Lombardi

The HW Process Technologies Engineered Membrane Separation (EMS"') technology is a patented system for the removal of multivalent base metal cyanide complexes from cyanide process streams, and EMSni permeate, concentrate and recovery terminology is explained. Specifically, use of the EMS™ system for the removal of Cu(CN)i- and Cu(CN)43- cop­per from cyanide process streams is discussed. The historical "Copper-Gold" processing paradigm of copper related cyanide consumption and complexation and methods to recover copper and copper complexed cyanide from Cu-Au process solutions are summarized. An advanced stage R&D sequential Cu-Au leaching circuit is proposed wherein two PLS streams are generated, i.e., a high copper tenor "first flush" Cu-PLS and low Cu tenor "second flush" Au-PLS. Copper and cyanide recovery from the EMS"' concentrate generated by Cu-PLS EMSTI,f processing by well known acidification processes and lesser developed, but techni­cally feasible, electrowinning processes are projected to be lower cost than similar dilute solution treatments. Gold is described as Merrill-Crowe plant recoverable from the EMS™ permeate stream coming from the Cu-PLS EMS"' process. Gold is also recovered from the EMSTI,f permeate generated by the processing of an Au-PLS bleedstream. The economics of the proposed Cu-Au-EMS"' circuits are estimated as $2/ gpd capital cost for large systems and $1- $3/ l 000 gallons treated operating cost plus royalty.

Jan 1, 1998

By K. J. Stratford

The selection of a suitable mathematical function for the modelling of the partition curve for dense medium cyclones is discussed. Five alternative functional forms (based on three basic functions) are compared using data obtained in the course of an extensive experimental study of a 610mm dense medium cyclone. It is shown that, for adequately sampled tests, any of the functions may be used, although a function based on the Weibull distribution is shown to be most suitable. Where data are poor, all functional forms exhibit disadvantages, notably in terms of a reduction in precision of parameter estimation. This problem can be exacerbated by the complex numerical techniques required to estimate the parameters of a particular function. A set of ideal requirements for a performance function are presented.

Jan 1, 1986

By J de Cuyper, N. R. Tipman, G. E. Agar, L. Laré, W. Freyberger

The flotation chemistry of the commercial INCO matte separation process was investigated. The slow cooling of Bessemer converter matte forms discrete phases of Cu2S and Ni3S2 and a Cu-Ni alloy. After magnetically removing the alloy, the Cu2S and Ni3S2 are separated by flotation at pH 12.4 (saturated lime) using diphenyl guanidine (DPG) as both collector and frother. DPG has been used exclusively in this flotation process because of its unusual selectivity for copper minerals. The surface product resulting from chemisorption of DPG onto the Cu2S was identified as the double salt Cu(DPG)2SO4,.CU(DPG)2(OH)2. The adsorption followed Langmuir behaviour up to a monolayer coverage. In the absence of DPG, the rapid adsorption of oxygen by Cu2S in flotation pulps was observed. The surface product was identified as the insoluble basic copper sulfate CuSO4.3Cu(OH)2 with the production of sulfate ion. In the presence of DPG, the oxidation reaction appears to be suppressed. The frothing properties of DPG and commercial frothers were compared. DPG is not a powerful frother. Batch flotation tests confirmed that DPG is a highly selective collector when compared to most sulfhydryl collectors.

Jan 1, 1976

By Alfredo Menendez, Alberto Sarmentero

A B S T R A C T The Los Pijiguaos bauxite is one of the largest accumulations of trihydrate alumina ore recently discovered; it is a plateau type, with no overburden, relatively soft tertiary quartz-bearing bauxite developed on a pre-Cambrian Rapakivi Granite batholith. The deposits are found in the northwestern rim of the Guiana Shield, State of Bolivar, Venezuela, and were discovered in 1976 after a grass-roots exploration campaign. Target areas were mainly selected on the basis of geological and geo¬morpholigcal criteria, guided by correlation with known deposits elsewhere in the Guiana Shield. The vertical. lateritic profile consists of an upper concretionary zone, followed by a mottled zone, a palid zone and finally the weathered rock merging into fresh granite. The upper concretionary zone displays a cellular, pisolitic or spongy texture and contains the following minerals: gibbsite (60-90%),quartz (5-10%), hematite (5-10%), goethite (under 5%), boehmite (traces), kaolinite (traces). The gibbsite content decreases sharply downward from the lower limit of the concretionary zone and the kaolinite and quartz content increases in the underlying mottled zone. The mottled and palid zones display a pseudo rapakivi texture and quartz, kaolinite and mica are the. essential minerals.

Jan 1, 1984

By James A. Jones

The Doe Run Co. emerged from the depressed lead market of the mid-1980s as North America's leading lead producer. Doe Run was lean and mean but quickly recognized that technology had advanced while the company was held to the belt tightening slump. With the 1990s approaching, Doe Run moved quickly to update its technology and control equipment to ensure its position as an industry leader. Doe Run was formed in 1986 when Fluor Corp. and Homestake Mining Co. combined their lead-zinc-copper assets in Missouri to form a joint venture. Doe Run is now owned by Fluor Corp. A rich history of mining, milling and smelting started in Missouri in 1862 when the St. Joseph Lead Co. was founded. Subsequent acquisitions led to the formation of St. Joe Minerals, which was later purchased by Fluor Corp. Six mines, four concentrators and two smelters are presently being operated, and a secondary lead smelter was recently commissioned. The Viburnum, Buick and Fletcher operations are lead, zinc and copper flotation concentrators, while the Brushy Creek plant is set up to process high copper-low lead ores. This article looks primarily at the process control installation at the Fletcher concentrator.

Jan 1, 1991

By Erich U. Petersen

Discussion by Erich U. Petersen Harbuck et al. (1990) present results of research on sulfuric acid leaching of a germanium-gallium ore and shed considerable insight on possible extraction methods for gallium and germanium. However, the presentation does not give sufficient details to evaluate the research, so some of the conclusions may not be as applicable as stated. The objective of this communication is to indicate that relevant and easily obtainable geological and technical information was omitted. Consequently, on this basis, alternative explanations for some of the data are possible. Discussed below are the omission of: • pertinent geological, mineralogical and geochemical literature; • details regarding the determination of germanium concentration in quartz by electron microprobe; and • details on the calculation of the amount of germanium locked in quartz. "These topics are important since the determination of the amount and locus of "unrecoverable, locked germanium" may have an important impact on the economics and methods of germanium extraction and the directions of future research. Harbuck et al. state that "A key to increasing germanium extraction is understanding the mineralogy of the ore." However, only two studies are cited that in some manner describe the mineralogy of the ores. In addition, both of these studies were very preliminary, of limited scope and examined very few

Jan 1, 1993

By Shibo Zheng, Zhengxing Gu, Zhizhong Gao

In recent years, beneficiation tests were conducted on high dolomite phosphate samples from Florida by the authors from China Lianyungang Design and Research Institute (CLDRI). The research results indicated that flotation is the most effective process for recovering phosphate from Florida high dolomitic pebble. Other operations like scrubbing, desliming and selective grinding might work to some extent, but they could only be applied as supplementary approaches in some cases. Heavy media separation and calcination-digestion technologies are hard to produce satisfactory performance. This paper presents the results of both lab scale and pilot plant tests on Florida high dolomite phosphate pebble using the fine particle flotation technology developed by CLDRI. Some discussions are made on the concerns of Florida phosphate industry and further research.

Jan 1, 2002

By Donald P. Spitzer, Peter V. Avotins

The flow properties of thickener underflow slurries can be characterized by their rheological parameters. Most of these slurries exhibit Bingham plastic behavior, characterized by a yield stress, to, and a Bingham viscosity, nB. Red mud is generated as a leach residue in the Bayer process. The use of new Bayer process flocculants which contain hydroxamate functional groups leads to muds which are qua1itatively considerably more fluid than muds generated with conventional polyacrylates or acrylatefamide copolymers. A variety of rheological tests confirm lower yield stresses and less extended floc structures with the new flocculants, at the same solids levels. Conversely, under given viscosity restraints, the new polymers make it possible to operate at higher solids levels, which offers major benefits in processing red muds.

Jan 1, 1992

By A. E. Isaacson, T. H. Jeffers

The U.S. Bureau of Mines (USBM) is investigating arsenic removal from dilute waters using a biological precipitation/chemical adsorption system. The method includes (1) inoculating water with ferrous salts to increase hydrogen sulfide generation by indigenous sulfate-reducing bacteria, (2) utilizing the hydrogen sulfide to precipitate the bulk of the arsenic as arsenic sulfide, and (3) using beads containing ferric oxyhydroxide to remove the remaining arsenic. This approach was applied to a contaminated water containing 13 mg/L As. Arsenic extractions up to 99% were achieved. The use of sulfate-reducing bacteria is particularly warranted in this situation since most of the required nutrients are present in the water. Based on successful initial efforts, planning is underway to conduct a pilot-scale test at the site.

Jan 1, 1995

By Brian E. Davies, Bobby G. Wixson

INTRODUCTION The mining, extraction and refining of metals into useful materials is an honorable profession with an ancient and productive history. Civilizations have long depended upon metals for their implements, structures and machinery necessary for survival, growth, and development. Today, as in the future, metals and minerals are essential to the progress of mankind as we approach the 21st century with technologies and concepts that will require new concepts and production from the metal mining and processing industries. Today is the tomorrow we talked about yesterday and the implementation of new ideas is essential if we are to achieve "Frontier Technology in Mineral Processing". Unfortunately, the state-of-the-art mining, processing, smelting and refining methods historically employed were less than desirable environmentally, which has caused todays public to view the metal mining and processing industry with concern. Presently the ancient rock and chat tips connected with old Roman lead-zinc mines which were worked in Wales are causing stream contamination problems that must be corrected at considerable expense to the local governmental agencies (Firth, J.N.M., et al., 1981). However, improved progress has been made and the environmental control and clean-up procedures utilized by modern lead-zinc operations in the "Viburnum Trend" or "New Lead Belt" of South East Missouri may serve as a model to illustrate how alternative technologies, environmental concerns and cooperative efforts contribute to efficient mineral production within the confines of a U.S. National Forest region without significant environmental impacts. This area received international attention when it was opened within the boundaries of the Clark National Forest in the mid 1960's. By 1970 it ranked first in the world by producing 432,576 short tons of lead ore and has since continued in this position producing 451,153 short tons of lead ore in 1983 representing 91% of the total United States lead production (U.S. Bureau of idines, 1983). This production comes from a mining area approximately 40 miles long by 10 miles wide extending in a north-south direction. Geologically the lead is disseminated throughout the Cambrain age Bonneterre Formation, mostly a dolomite, at depths ranging from 700 to 1200 ft. (213.4 to 365.8 m). Galena (lead) is the principal ore mined with lesser quantities of sphalerite (zinc), chaleopyrite (copper) and silver being recovered as economic co-products. This new mining development in one of Missouri is most scenic areas could have led to a classic confrontation between industries and environmentalists. Instead, through the cooperation of industries, governmental agencies and university researchers, the Ozark environment has been protected, and may serve as a model for future coexistence of the mineral industry with the environment. Cooperative Program Development As early as 1965 five new mines and two lead smelters were being prepared for production and environmental concern was an essential part of that planning. All the mining companies became acquainted with representatives of the various federal and state agencies and scientists from the University of Missouri-Rolla (UMR). During the next six years, St. Joe Minerals Corporation, American Metal Climax, Inc., Cominco American Incorporated, Ozark Lead Company (Kennecott) and American Smelting and Refining Company participated in cooperative research efforts. The companies also participated in information exchange meetings, the development of improved analytical methods and the utilization of research findings in the modification or construction of pollution-abatement facilities. Early on research was carried out to determine background values and to establish natural baselines of trace metals in the surrounding environment. The unusual topography and drainage pattern of the mining area were helpful since it was possible to establish control sites and test sites below individual mine-mill operations to study waste-water effects on the receiving streams. The location of the ‘New Lead Belt', mines, mills,

Jan 1, 1985

By Steve Kral

It is agreed in mining and regulatory circles that a safe and healthy working environment for underground miners is the major challenge for mine operators. Underground mine ventilation is complex. And it is becoming even more difficult as mines become larger, deeper and more complicated. At the Seventh US Mine Ventilaton Symposium, a group of mine ventilation experts from industry, government and academia attempted to solve some of the problems in ventilating underground mines. The meeting, sponsored by the Underground Ventilation Committee of SME and the University of Kentucky, was held in Lexington, KY June 5-7, 1995. Andrzej M. Wala, symposium chairman, commented that previous mine ventilation symposiums have focused mainly on work in North America. The 1995 symposium, however, broadened its borders to include several international papers. Of the 77 papers presented and bound into the Proceedings volume, 25 are from operations and research centers outside of the United States and Canada.

Jan 1, 1995

By Xinyang Xu, Jirun Xu, Changlie Deng, Kang Yan, Luo Qian

Cake filtration is a complex process and the cake constructure is very difficult to describe in theory. Cake constructure parameters, such as the cake prosity, pore size shape and even its distribution, are main factors influencing the filtration results but have not been thoroughly understood yet. In this paper the fractal theory, an effective mathematical method in describing the self-similar phenomenon is used to investigate the filter cake constructure, and the scanning electron microscope and automatic image analyzer are used to measure the cake constructure. Cakes which formed in different condition are examined and the fractal dimension of the cake are calculated. The study shows that the constructure of the filter cake can be approximated by Sierpinski fractal geometry and that the fractal dimension of filter cake, related to the particle characteristics, slurry concentration and filtration pressure is a good parameter to describe the pore size distribution and the cake penetrability.

Jan 1, 1995

By Peter T. Luckie, Felicia F. Peng

INTRODUCTION The maximum recovery of cleaned coal at the required quality is of major concern to plant operators. However, the quantity and quality of products of coal cleaning, predicted by theoretical calculation based on washability studies and determined in the operation of actual commercial cleaning plants, will be different for each coal. Therefore, during the last half century, coal preparation engineers have repeatedly sought methods for evaluating the technical and economical efficiency of separating coal in coal cleaning equipment and for predicting the quantity and quality of cleaned coal produced, as well as profit- ability for the entire plant. Many formulas have been proposed by investigators to evaluate the efficiency of various coal cleaning operations. Performance criteria in use today are capable of defining all of the important aspects of a given concentrating operation; however, each criterion has certain restrictions or limitations. It is important, therefore, to understand how such formulas can be used and the problems involved in their construction. Technical Measures of Equipment/Plant Performance Conventional measures for evaluating the performance of a preparation plant are generally the same as those used to evaluate equipment performance. Measures involving separation efficiencies are influenced by the following three broadly encompassing primary factors: (1) density composition of the feed coal, (2) design characteristics of the cleaning unit, and (3) relative density of the separation. Since separation efficiencies are dependent on factors involving the nature of the coal, they are termed dependent criteria and represent a very broad technical indicator of an individual process or plant performance. Performance measures known as independent criteria are influenced mainly by quantitative errors inherent in the design and operation of the processing equipment. Economic Measures of Plant Performance True assessment of coal cleaning methods require reference to economic measures such as profitability. During the years in which technical efficiency criteria for characterizing plant performance were being improved, coal preparation engineers were also seeking appropriate economic criteria to assess plant performance. Technical and economic effectiveness of plant performance are important parameters for coal preparation flowsheet design. The relationship of the technical and economic parameters can be formulated in an economic model and mathematical model with the aid of computers. The computerized models

Jan 1, 1991

By Kerry Burns

Contrary to active subsidence, which occurs concurrently with mining operations, or is completed within a few days following coal extraction, delayed subsidence may take many years to appear at the surface after coal mines are abandoned. There are two principal morphological types of delayed subsidence: troughs, which are shallow depressions, and sinks, which are steep-sided crown pits. Both types are damaging to surface structures, and a variety of methods have been introduced to deal with the problem, ranging from subsidence insurance to site restitution. In planning insurance or restitution measures, a predictive model is of value in estimating the magnitude of the problem and the size of long-term budgetary commitments. Only one model is known, which was developed for the Bureau of Mines by GAI Consultants of Monroeville (l,2,3). The GAI model is presented in qualitative terms. This report develops a formal basis for the model and tests a numerical implementation on one of the best-described study areas, Allleqheny County in Pennsylvania.

Jan 1, 1982

By Victoria Vaccarezza, Corby Anderson

The demand for rare earth elements for everyday technology and applications has initiated much research into the extraction and recovery of these rare earth elements. An otherwise unknown group of minerals, eudialyte is a zircon silicate consisting of rare earth oxides (REO), contained in a unique mineral structure and represented by a complex chemical formula. Research into extraction and recovery of rare earth elements involves various beneficiation and hydrometallurgical techniques. The goal of beneficiation being to efficiently liberate and upgrade the REO content, followed by hydrometallurgy to extract the desired elements. This overview will discuss previous research on treating eudialyte group minerals via different mineral processing and extraction techniques.

By Andre Vien, Marc Grondin

For many years mill operator training was an informal process which involved senior operators training junior operators on an as-needed basis. The more rapid incorporation of new processing and information technologies, the goal to keep labour costs to a minimum by doing more with less, and the complexity of AG/SAG mill operation has forced companies to have a closer look at operator training. This paper describes a conceptual model of the charge of a AG/SAG mill that can be used for operator training. The conceptual model divides the charge into three regions: cascading, cataracting and toe. Mill behaviour is explained by the changes that occur in each region.

Jan 1, 1997

By Gus H. Goudarzi

The apatite deposits in east-central Bahia, Brazil, are about 50 km east of Serra do Jacobina, between lat. 11° and 12° S. and long. 39°40' and 40° W. Apatite was found and examined at 15 localities in a mineralized belt that strikes about N.25° - 30 W. over a distance of about 100 km, but the size of the deposits has not yet been determined. Rocks of the region consist of a sequence of Precambrian migmatites and quartz feldspar paragneisses containing units of pyroxene-rich rocks, lenses of sillimanite-bearing quartzite, amphibolite zones, and calc-silicate marble lenses. Pegmatites and granites of probable anatectic origin (anatexite) are abundant. Faults are numerous. Clastic sediments of Tertiary and Quaternary ages cover most of the area; thus, outcrops of the Precambrian rocks are sparse. Trenches and pits have exposed mineralized zones as much as 10 m wide at some localities within the region. A layer of apatite at least 1 ½ m thick is exposed in a trench at Lagoa do Mel. At Rio do Peixe, vertical shafts have penetrated a mineralized zone, to a depth of as much as 13 m, of which about 25 percent is apatite. Apatite is massive or forms minute crystals, stringers, and disseminated grains in alkalic host rocks. At Apolinario, euhedral crystals of apatite are as much as 50 cm long and 30 cm in diameter. Associated minerals include vermiculite, biotite, scapolite, opal, chalcedony, epidote, montmorillonite, chlorite, kaolinite, sericite, magnetite, and limonite. Apatite is everywhere intimately associated with pyroxene-rich rocks, alkalic syenite pegmatites, and alkalic granite pegmatites. At Panelas-Retiro, apatite is associated with pegmatites, crystalline calcite (vein calcite), vermiculite, and pyroxene-bearing rocks. Analyses of samples show that the apatite is radioactive and rare-earth-bearing. Traces of vanadium and titanium were detected by spectroscopic analysis. The apatite was probably derived from phosphatic zones in the original Precambrian sedimentary rocks and has been crystallized and some mobilized by high-temperature regional metamorphism (higher amphibolite facies) into veins, pegmatites, and along certain preferred beds and fractures. Radiometric and geophysical surveys, in addition to conventional geological investigations, are planned to further investigate the nature and economic potential of the deposits.

Jan 1, 1972