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By T. Bednarski, T. McCallum, L. Moya, B. Gay

"Molybdenum recovery by solvent extraction has gained interest partly due to advances in concentrate leach technology. Historically, both molybdenum and rhenium have been produced using amine-based extractants with the ability to co-extract both metals. Alternatively, a phosphinic acid-based extractant (CYANEX® 600) can be used depending on the flow sheet. CYANEX® 600 selectively extracts Mo leaving Re in the raffinate, which is a valuable feature in plants which require rejection of the rhenium from the molybdenum circuit. CYANEX® 600 piloting results are reviewed and compared to commercial experiences with an amine-based extractant. INTRODUCTION Molybdenum is most commonly found as molybdenite (MoS2) in primary porphyry deposits (about 59% of global reserves) and copper porphyries (about 39% of molybdenum reserves)[1]. Recovery from molybdenite traditionally involves flotation (concentrates typically containing 85 – 95% MoS2) followed by roasting to produce MoO3. Solvent extraction is also used to recover molybdenum from acidic aqueous solutions resulting from scrubbing of roaster and smelter off gasses and leaching of molybdenite (uranium ores). Molybdenum is also frequently found in low concentrations in copper leach inventories[2]. More recently, pressure oxidation has gained interest to treat molybdenite concentrates. Molybdenum Chemistry The chemistry of molybdenum is complex with a series of extractable species existing dependent on the pH and oxidation state as shown in Figure 1.Under strongly basic conditions, molybdenum primarily exists as MoO42- while under strongly acidic conditions MoO22+ becomes the predominant species. In between, a number of isopolymolybdates such as Mo7O246- and Mo8O264- are dominant. Equations (1) – (3) demonstrate some of the proposed molybdenum equilibrium reactions[1]."

Jan 1, 2017

By Vojtech Gall

Pre-support measures for urban tunneling have seen a substantial development in the recent past. Ground improvement techniques, pipe-arch and spiling methods now allow for non-disruptive tunneling at very shallow depths under sensitive structures, rail tracks and roadways. The paper presents experience gained on national and international projects built over the past decade that represent case histories and therefore may be used as guidance for the development of similar solutions for future tunneling projects at shallow depths. Reference projects include tunnels for the Washington, DC Metro, London Underground, Dulles Inter-national Airport, Busway tunnels in Boston and the Ft. Canning Tunnel in Singapore.

Jan 1, 2008

By E. H. Smith

St. Joe Minerals Corp., a subsidiary of Fluor Corp., treats high-grade gold, silver, and copper ore at its El Indio plant at an altitude of 4 km in the Chilean Andes. The ore is complex, being a mixture of massive pyrite-enargite and quartz, both containing very fine gold and silver. Treatment produces a copper flotation concentrate containing high levels of gold, silver, and arsenic, and also dore bullion. Part of the flotation concentrate is roasted to remove the arsenic content, and arsenic trioxide is collected as a by-product.

Jan 1, 1987

By E. J. Duggan

In the course of the grinding experiments conducted at Climax over the past twenty years one interesting phenomenon was discovered. This was that balls made of certain types of steel grind more ore than some others. The most significant variation was found in the results secured with a hard alloyed forged bail compared with the forged carbon ball supplied by most ball manufacturers These findings were confirmed in many repeated controlled tests. The value of these tests depends on the methods used, the facilities available and the care with which the investigations were conducted. These are described in the following. This testing has largely been done in eight 91 x 81 low discharge ball mills in closed circuit with 7811 duplex screw classifiers. The mills run at 20 RPM on a feed approximately minus 3/8 inch. The ore is ground through 28 - 35 mesh in one stage. Each mill and auxiliary classifier is in a separate, parallel grinding and flotation section The, ore to each: section is the same in every particular and is fed to each mill bin from a common conveyor tripper. The ore from the bin to the ball mill is weighed on a conveyor scale. The power input to each mill motor is determined with a watt hour meter which measures the power to the mill motor only. Both the scales and meters are checked periodically by standard methods and have been found to give consistent readings. Automatic samplers are employed on each section to obtain accurate measurement of the size reduction. A size analysis of the classifier overflow is made each shift and a composite size analysis is obtained from a weighted average of the various shift analyses. The mills are driven by 450 horsepower synchronous motors so that there is no speed variation and shell liner age is kept as nearly the same as possible in mills under test. The same set of operators is assigned to a mill under test as to the control mill. In all other particulars such as ball load, mill density, liner design, etc., the mills are operated in precisely the same manner. This is an ideal arrangement for plant testing. From observations of ball mill performance over the past twenty years, it is the opinion of the operating staff that variations of as little as one to two percent in mill capacities may be determined if sufficient operating hours are devoted, to a test. Relations between mill capacities, fineness of grinds and power consumptions have been established with a high degree of accuracy. In Table I are given the figures for one test. These show that while the grind with the hard ball was slightly coarser, the tons ground per hour was 5.4 percent greater with the soft ball, and 6.1 percent greater on the basis of minus 100 mesh produced. The power consumed per ton with the hard ball was 4.4 percent greater on a tons per hour basis. The soft ball was inferior in wearing qualities and steel consumption per ton of ore was 24 percent greater with it. In this test the mills were charged with the two different balls for a period of three months to allow the ball loads to come to equilibrium. In Table II are given the specifications of the two balls. The difference in grinding rates may be accounted for by the nature of the ball surfaces. The surfaces of the soft balls after being worn a while are rougher to the touch. Enlarged photographs of the worn-in surfaces of hard and soft balls are shown in Figure I. These show the presence of scratches or skid marks on the hard ball surface which indicates less nipping effect. The Climax ore pulp has a pH of 6.0 and is in a dispersed state. The viscosity is low compared with most ores especially those that are conditioned with lime. This would lower the tendency of the pulp to adhere to the balls with a lower grinding efficiency as a result. It was also thought that the relative rates of wear from surface to center might affect the make-up of an equilibrium ball charge. This probably has little effect on capacity as shown by the size analyses of the two ball charges in Table III. This hypothesis was subsequently investigated by the use of rationed charges. The rationed charge did not overcome the advantage in

Jan 1, 1958

By B. Slaker, M. M. Sears, G. Rashed

Ground falls represent a significant hazard at underground mines in the stone, sand and gravel (SSG) sector in the United States. Researchers from the U.S. National Institute for Occupational Safety and Health (NIOSH) are conducting detailed investigations into the complex loading conditions at underground stone mines operating in challenging conditions. This paper presents the application of numerical modeling to analyze pillar and roof stability at a dipping underground limestone mine.

By J. C. Adams

Although explosives constitute only a small portion of a mine's total cost, the relative success of each blast has a tremendous effect on subsequent activities such as excavation, crushing, and equipment maintenance. Beginning in January of 1993, tests were carried out to determine whether productivity could be improved by replacing standard ammonium nitrate fuel oil mixtures (ANFO) with a high density, high performance blasting agent. The study was carried out at gold mines, coal mines, and cement quarries in Nevada, California, Colorado, and New Mexico. A wide variety of rock types and blasting conditions were encountered. Results showed that at most operations productivity was sufficiently improved to more than offset the increase in explosives cost. This resulted in a net reduction in mining cost. This paper presents a summary of these results.

Jan 1, 1996

By Andres Salazar, Carlos Delgado Robles, Richard K. Preece

The paper discusses the evolution of the geometallurgical model at the Escondida mine in northern Chile, the world’s largest copper producer. It highlights the transition from early metallurgical forecasting methods to a comprehensive model that includes spatial distribution of metallurgical forecasts. This model helps in planning and adapting to the variability in ore characteristics, such as hardness and mineralogy, which affect processing performance.

Dec 1, 2023

By T. M. Sukel

Engelhard Corporation is one of the leading producers of kaolin based products in the world, having acquired the assets of Freeport Kaolin company in 1985. Much of the production technology used in the kaolin industry was pioneered by Engelhard and Freeport, including Ultraflotation for improving product brightness, delamination to produce kaolin platelet products, calcination to produce ANSILEX® high opacity titanium dioxide pigment extender and pipeline slurry operations to economically transport kaolin from the mine to beneficiation facilities. Engelhard traces its roots back to 1870 when the Edgar family discovered kaolin behind their property in Bonhamtown, New Jersey. Today the company produces the broadest line of premium coating pigments with extensive sales throughout the world. The international scope of the company's business has led Engelhard to evaluate kaolin deposits throughout the world as possible grass roots production sites. Most kaolin products are used in the paper industry -- the largest volume end-user 80% of the total market -- as filler and coating pigments. Lower volume specialized applications include fillers and reinforcements for plastics and TiO2 extender pigments for paints and coatings.

Jan 1, 1987

By M. E. Mellado

In this paper, we present an a posteriori validation of a heap leaching analytical model using sensitivity analysis. The model is suitable to represent the process of heap leaching of solid reactants from porous pellets and is based on a combination of the leaching kinetics at two levels: particle and heap. The validation is simple, and a sensitivity analysis can easily be performed. The simplicity of the analysis provides insight into the control and optimization of the heap leaching process without strong mathematical complexities. The model and the corresponding sensitivity analysis include the effects of heap height, particle sizes, flow rates and several operation-design variables. Using a case study, we discuss the importance of model validation based on sensitivity analysis. We also comment on several choices for optimizing the process. We had three goals in this work: a posteriori validation, highlighting the importance of model validation and providing insight into optimization choices. We can conclude that the model has good internal logic and there are no extra variables; i.e., all of the variables in the model are necessary.

May 1, 2012

By James Warner, Peggy Ganse, Glen Smoak, Raymond Henn, Sam Bandimere

Over the past several decades, cement-based grouts using ultrafine cement as are placement for portland cement have begun to gain acceptance as an alternative to chemical solution grouts, however the amount of information currently available on these grouts is limited. For this reason, the authors developed a field testing program to evaluate the penetration capabilities of various ultrafine cement grout mixes. The tests were conducted by injecting sand columns using different portland and ultrafine based grouts, the measuring penetration distances after applying equal injection pressure for the same time period. Results of tests performed in 1999 and 2000 are discussed herein.

Jan 1, 2001

By M. Yekeler

The critical surface tension of wetting values (Ye) of realgar (AsS), talc [Mg3si401o (OH) 2]' stibnite (Sb2S3), and sulfur (S) were determined by flotation in the absence of conventional flotation collectors as 38.7, 38.0, 35.5, and 30.0 dyne/cm, respectively. The surface tensions of flotation media were arranged by methanol. Separation of binary mixtures of these minerals was performed exploiting their Ye differences-which form the basis of the "ganuna flotation process". One step flotation test showed that sulfur floats preferentially from its mixtures with realgar and stibnite at recoveries of 73.6 and 70.7 % and grades of 81.7 and 91.2 %, respectively. The separation of stibnite from realgar gave a recovery of 4.1 % and a grade of 41.2 % for stibnite, indicate that a minimal Ye difference of 3.6±0.2 dyne/cm is essential for such separation when conventional flotation reagents are not used. This paper presents data and describes the approach employed in these separations.

Jan 1, 1994

By T. J. Smolik

The Golden Sunlight Mine started full-scale operations in February 1983, with a conventional open-pit mine supplying 4464 tonnes (5000 tons) per day of milling ore. After crushing and grinding, the ore is leached with cyanide solution in large agitation tanks. Soluble gold values are removed from the sand portion of the leached ore with five stages of countercurrent washing cyclones. After thickening of the cyclone-wash overflow slurry, the gold is recovered in activated carbon with a six-stage carbon-in-pulp circuit and a five-stage upflow carbon column circuit. Pressure stripping, carbon reactivation, electro-winning and refining complete the gold recovery process.

Jan 1, 1984

By Raul A. Deju

A theoretical and experimental study was made of the surface phenomena occurring in a silicate - sulfonate system and a silicate -amine system, Experiments were conducted varying the collector concentration to examine its effect both on the total surface sorption and the rate of sorption. The results were compared to a theoretical model based on a Langmuir-type isotherm, Finally, the flotation behavior of selected silicate minerals was predicted from the sorption results and an explanation for the flotation of silicates postulated on the basis of both the theoretical predictions and experimental data.

Jan 1, 1967

By Donald L. Everhart

Economic geologists faced with the task of evaluating phosphate rock deposits find it necessary to deal with a unique and a lengthy list of geologic, chemical, and economic factors before they can determine whether the deposit does, or does not, constitute "ore". The underlying fact is that phosphate rock concentrate sells at a price per ton that is among the lowest for all mineral commodities. A recent going price for a standard grade (i.e. 72% BPL) phosphate rock concentrate F.O.B. Tampa is $6.00 per long ton. This compares with sand and gravel's price of about $5.00 and $8.00, respectively, per ton. In the case of many, if not the great majority of mineral deposits, the evaluating geologist needs to concern himself principally with the fundamental and classic considerations of tonnage and grade. Barring some very unusual metallurgical problem any geologist that finds say 50 million tons of 1% copper rock, or substantial tonnages of 0.7% U308 sandstone, pretty well knows he has an ore body! Certainly the evaluation of phosphate rock starts with tonnage and grade. Any rock with less than about 10% P205 in the ground is generally ruled out as ore, on the basis of grade alone. Since nearly all phosphate rock operations must be of the large-tonnage, low-unit-value type, the tonnage of new reserves, to be considered as "ore", ought to be in the 100-million + class. But having outlined' a deposit of phosphate rock having acceptable

Jan 1, 1971

By Jamie Bonner, Ray Hutton, Taro Nonaka

The Nancy Creek Tunnel is a deep tunnel, designed to store and convey wastewater by diverting flows from trunk sewers currently at or near capacity in the northwest of the City of Atlanta. The tunnel, constructed in hard rock, has an overall length of 13,300 m (43,700 ft), and a finished diameter of 4.9 m (16 ft). The project is currently under construction by a joint venture of Obayashi/CJB for the City’s Department of Watershed Management. This paper describes the contractor’s techniques and equipment, as well as discussing challenges which were overcome. The project is scheduled to be complete in October 2005.

Jan 1, 2005

By Jeff LeBlanc, George Gutierrez, Carl Pitzer

The Bay Park Conveyance Project was one of the largest microtunneling and rehab projects in the United States at the time of completion. The completed project conveys treated water from the South Shore Water Reclamation Facility located in Nassau County, New York, which currently discharges an average of 50 million gallons per day (MGD) of treated water into Reynolds Channel, to the Cedar Creek Water Pollution Control Plant (WPCP) ocean outfall pipe. The pipe carrying treated wastewater was installed approximately 20–60 feet below the surface. The treated wastewater is conveyed via microtunnel construction of a 2-mile long force main from the South Shore Water Reclamation Facility to an existing aqueduct under the Sunrise Highway, the rehabilitation of an 7.3-mile stretch of the aqueduct via sliplining, and construction via microtunnel of a 1.6-mile-long force main to connect the rehabilitated aqueduct to the existing Cedar Creek Water Pollution Control Plant (WPCP) outfall, which discharges and diffuses treated water three miles offshore in the Atlantic Ocean. This paper will review the Design-Build requirements, the chosen innovative solutions during planning for the micro tunneling portion of the project and review the microtunnel construction on the project.

Jun 23, 2024

By I. H. Warren

Hydrometallurgy has a well-known and established role in the production of manganese metal (1) and manganese compounds, including battery grade manganese dioxide (2). Also, several leaching processes have been developed and applied at various times for the recovery of manganese from low grade ores (3). Recently, interest in the hydrometallurgy of manganese has been stimulated by the problems presented in the processing of sea nodules (4). Fumes and dusts from the ferro-manganese furnaces also offer a potential field for the application of manganese leaching techniques (5). In treating low grade manganese ores a major requirement of the leaching process is that it should dissolve manganese from a mixture of manganese and iron oxides. The most selective reagent for this purpose is ammonium carbamate applied after preliminary pyrometallurgical reduction of the ore (6). Since soluble carbamate complexes of the postulated type (7) are formed by both manganous and ferrous, but by neither manganic nor ferric, ions, selectivety of manganese leaching is achieved by control of the reduction operation to yield, essentially MnO and Fe304? A potential improvement to this two step process would be to simultaneously reduce and selectively leach the manganese in one hydrometallurgical operation. This possibility has been experimentally studied and the results are described below. During the preliminary study of the stability of solutions of ammonium, ferrous and manganous carbamates at elevated temperatures, it was observed, contrary to the observation of Welsh (8) at lower temperatures, that

Jan 1, 1971

By Gordon R. S. Smith

This paper is in two parts. The first part describes Membrane Back-Pulse Filtration and the effects of very short filter downtimes on cycle filtration rates. Part II describes the use of Membrane Back-Pulse Filtration for combined thickening and polishing soda ash thickener feed material followed by a description of computer modeling of CCD circuits by Iterative solver.

Jan 1, 1991

By E. J. Owen, S. Cherotich, V. T. McLemore

Breccia pipes are vertical pipe-like columns of rocks that provide conduits for fluid flow and open spaces for mineral precipitation, hence are focus areas for exploration. In the Gallinas Mountains, Lincoln County, New Mexico, there is recorded production of Cu, Pb, Ag, F, Fe, REE (as bastnäsite), and Au from 1902 to 1980, but no production reported from the breccia pipes. Previous studies described the occurrence of REE in breccia pipes, but their transportation and deposition controls are still unclear. The aim of this research is to characterize the magmatic-hydrothermal breccia pipes in order to understand the geochemical and physical conditions of deposition of REE and gold in the breccia pipes found in the Gallinas Mountains. There are more than 20 exposed breccia pipes that form a NE-trending belt about 3–5 kilometers, mostly gray-brown and consist of angular- to sub-rounded rock fragments, some host high concentrations of REE (80,500 ppm total REE) and Au (175 ppb). Preliminary studies suggest they are magmatic and intruded into the host rock and, subsequently, hydrothermal fluids precipitated F-REE and Au along the edges of some breccia pipes. More studies are underway to test this hypothesis.

Feb 1, 2023

By D. D. Murphy

The Bureau of Mines has studied the mechanism of shear-flocculation of silica with stearic acid. At pH 6 and 12, shear-flocculation of silica was not observed with up to 10-4M (5 lb/st) stearic acid. However, in the presence of 0.1 M NaCl at pH 6, shear-flocculation was observed at stearic acid concentrations 10-4 M (5 lb/st). Adsorption of stearic acid on silica was studied using stearic acids spin-labelled with a doxyl group. The presence of the spin-labelling group did not greatly affect the shear-flocculation properties of stearic acid. Adsorption of labelled stearic acid on silica was measured as a function of surfactant concentration with electron paramagnetic resonance (EPR) spectroscopy and gas chromatography (GC). The GC results indicate the stearic acid was predominately adsorbed on the surface at concentrations above 10-4 M. From the EPR spectra, the formation of aggregates of stearic acid was apparent at concentrations of approximately 10-414 (5 lb/st). The results are discussed in terms of a possible mechanism for shear-flocculation.

Jan 1, 1993