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By S. Usui

In a previous article1 the methyl stretching vibrations for a series of xanthates and amines were reported, and the frequency of the methyl stretching vibrations in a homologous series of the alkyl compounds were shown to decrease exponentially with chain length and approach a limiting value corresponding to that of saturated hydrocarbon beyond six or seven carbons. These observations were explained quantitatively by the theory of Goto and Takenaka2 who proposed an equation relating the frequency shifts to the inductive effect of polar groups. As a result, the alkyl groups in the shorter chain heteropolar compounds were interpreted as becoming somewhat polar, and a good correlation was observed between the CH3-stretching frequencies and such surface chemistry parameters as contact angle, surface tension lowering, solubility, and critical micelle concentration" The substitution of fluorine atoms, the most electronegative of all atoms, for the hydrogen atoms in alkyl groups was expected to reverse the direction of the inductive effect within a heteropolar molecule, and its effect on the C-F stretching frequency shifts and on some surface chemical properties became of interest. In a recent study the C-F stretching frequencies of a series of normal perfluorocarboxylic acids and a few 1,1' -dihydroperfluoro alcohols were determined as a function of chain length and the results were compared with the corresponding hydrocarbon analogs. Furthermore, the nature of the induced polarity in the hydrocarbon and fluorocarbon groups was investigated through surface potential measurements at the interfaces of air-aqueous solutions of normal butyl alcohol and of l,l'-dihydroperfluorobutyl alcohol and through differential capacity and electrocapillary measurements at the interfaces of mercury-aqueous solutions containing the above two alcohols. Experimental Normal perfluorocarboxylic acids and 1,1' -dihydroperfluoro alcohols were provided through the courtesy of the 3M Company, St. Paul, Minnesota. Normal butyl alcohol was purchased from Distillation Product Industries, Rochester, New York. A Perkin-Elmer Model 621 infrared spectrophotometer was used to investigate the spectra in the frequency region of 1200 to 1270 cm-l with frequency scale

Jan 1, 1971

By G. H. Sedahmed, S. A. Nosier, M. H. Abdel-Aziz, A. A. Mubarak, M. A. El-Naggar, E. G. Abdel-Aziz

The performance of a rotating fixed bed reactor in recovering copper from industrial waste solutions by cementation is studied under various conditions. The rotating fixed bed is made of stacked woven steel screens to take advantage of two features of screens: the ability to present large area per unit volume and their ability to promote high turbulence. Variables studied are initial CuSO4 concentration, bed rotation speed, mesh number of the screens and bed thickness. The presence of baffles was found to increase the rate of cementation. The data were correlated by a dimensionless mass transfer correlation suitable for the design and operation of large scale cementation reactors.

By Ebrahim Tarshizi, Livernois Ryan, Emily Sarver, Zoe Scopa, Robert Setterlind, Leah Frost

"The mines of the future present a host of challenges, which may appear exciting or daunting, depending on one’s perspective. Whether some sectors of the public recognize it or not, the demand for raw resources is not going away any time soon. In fact, it is rising, as the global population grows, urbanizes and attempts to steadily increase quality of life. Yet, at the same time that much of the highly developed world is calling for greener goods, reduced consumption and cleaner production, in other areas there are cries for clean water and sanitation, consistent energy supply, access to health care and education, personal security and support for basic human rights. The balancing act for sustainable development of our global society is, indeed, precarious and the mining community is a key player. Fortunately, many industry members have accepted this role and the responsibility to provide leadership and a solid foundation for progress. Looking ahead, we need new generations of leaders, including many mine engineers who are ready to tackle all sorts of complex problems.There are tremendous needs just for technological innovations. Increasingly tough deposits will require that the industry continues to expand scale toward “mega pits” and “super caves;” fully develop unconventional recovery techniques like in situ leaching and gasification or deep-sea extraction and seriously consider off-earth endeavors. Such work will take entirely autonomous equipment, novel separations, processing and recycling methods, and systems that can withstand extreme physical conditions, just to name a few. It will also take a level of systems integration never-before seen in the mining industry, complete with big data issues, sophisticated predecitve analytics and modeling efforts and cyber-security challenges.Moreover, increasingly complex environmental problems will require creative solutions. Addressing issues like pollution control across multiple media, emerging contaminants, optimal management of wastes, selective mining and shared use of resources between mine operations and surrounding communities and ecosystems are among the top priorities. Really, a complete paradigm shift must occur, such that the focus is on overall improvement of environmental conditions, rather than minimization of impacts. A similar shift will be required in the social realm. How can miners be safer and healthier on-site and off? How can the industry contribute to communities such that they are better off, now and longterm, for having a mine next door? How can artisanal mining practices be transformed to also contribute to sustainable development? How can the industry’s work be a factor in increasing economic and political stability? How can the public understanding of raw resources and the need for mining enterprises be improved?Given the coming challenges, there is no doubt that the mine engineers of the future will need highly diverse skillsets — meshing traditional and contemporary competencies to a degree not previously considered in mining, or most others fields. To be sure, the scope and scale of mining projects make them wholly different than most other engineering work, aside from perhaps the largest civil and urban development projects. While on-the-job experience will continue to be essential, formal education programs (i.e., at post-secondary institutions) must lay critical groundwork."

Jan 6, 2017

By I. H. Warren

The high temperature lubricant molybdenite, MoS2, is usually produced by a complex sequence of processes involving mineral dressing of molybdenite concentrates followed by leaching with hydrofluoric acid to remove abrasive impurities such as silica (1). Many attempts have been made, mostly by techniques involving, direct fusion of molybdenum compounds with sulphur, to produce synthetic molybdenite. However, apart from some experiments of geochemical interest (2) in which aqueous solutions of sodium sulphomolybdate, Nat MoS4, were decomposed under pressure at temperatures between 300°C and 700°C, no attempts to produce the mineral by hydrometallurgical procedures have been reported. Since molybdenite is nominally a compound of tetravalent molybdenum with sulphur, and the most common state of molybdenum is +6, production of molybdenite is likely to involve reduction and sulphidization. The present study, therefore, describes the reduction, with hydrogen and carbon monoxide, of molybdenum in the hexavalent state in alkaline aqueous solutions containing sulphide ion. In these

Jan 1, 1972

By James C. Gilliand

Leo-potpourri, was selected as the title to this paper for several reasons. First, it is a fascinating word--not looking like it sounds or sounding like it looks. It also allows for a great degree of flexibility in designing a presentation around it. Further, it has become popular to use this eco hyphen something pattern. We hear of eco-mania, eco-hysteria and the like. Lastly, in this era of intense environmental concern, two of the principle elements on which the integrity of our efforts must be equated are ecology and economics. Accordingly, the term "Eco-potpourris" allows me to roam at will through the great number of considerations that make up this environmental issue. Whereas only a few years ago the subject of environment and environmental control had low visibility with the public, today it competes as the focus of attention with the many other popular social issues of our time. The program content here at this meeting, for example, is liberally represented by papers dealing with one or more aspects of environmental concern. If one would look at the 1964 program, in contrast, I would expect that no more than possibly one or two papers covered this subject and even then that those papers dealt principally with the environmental aspect of occupational health. It is gratifying that the program at this meeting demonstrates a serious awareness to a broad spectrum of environmental concerns. It would be a mistake, of course, to believe that this clamor for a quality environment is a "flash in the pan" that will soon subside. The general public has been thoroughly aroused and even frightened into

Jan 1, 1972

By Sheldon P. Wimpfen

Back in 1970 Congress passed the National Mining and Minerals policy Act, which had as one of its basic tenets to rely on a strong and stable private minerals industry for the development and production of our mineral resources. Since then, a substantial amount of legislation has been introduced that impacts on the minerals industry. Although most of the bills proposed are not passed into law, each bill affecting minerals and mining is given careful review by the Bureau of Mines. Comment is forwarded with the object of being helpful to legislators by providing our assessment of the probable impact of each bill proposed along with suggestions to improve them. Actually few bills introduced become law. For example, in the 93rd Congress 4,260 bills were introduced in the Senate and 17,690 in the House. In the final accounting there were passed 123 private laws and 649 public, 3 percent of the bills introduced. There would be little merit here in attempting to analyze each mineral-related bill that was proposed. Many are similar and aim at making a certain aspect of our minerals activity fit needs. So, to simplify the task the many bills have been grouped by subjects. Slide 1 shows the principal topics and the number of related bills introduced. Putting it altogether, there are 26 principal subjects and almost 200 bills. And these numbers are probably off somewhat, as this accounting was made early in December.

Jan 1, 1976

By T. E. Wilson

In conjunction with experiments to improve the particle size preparation of coal bore cores prior to washability testing, discrete-event breakage of coal, shale and homogeneous low-strength concrete cores was studied. Breakage of individual size classes by drop-shatter and by incremental tumbling in an end-over-end hand-driven tumbling cylinder revealed systematic changes in the breakage function, namely, that breakage in any size class diminishes as the number of events increases. The effect of the fines removal enhances the breakage of harder material (having lower grindability indices), but appears to have less effect for softer material.

Jan 1, 1998

By M. J. Gula

In the solvent extraction -electrowinning recovery of copper from oxide or sulfide ores there is a continuous transfer of iron and other impurities from the primary leach solution to the copper electrowinning electrolyte via chemical transfer or mechanical entrainment. Iron is the principal impurity that has to be controlled in the electrolyte by a "bleeding" of the electrowinning solution. This bleeding transfers copper and sulfuric acid back to the primary leach circuit along with the iron. Copper is recovered via the solvent extraction process and generally the sulfuric acid is used as a reagent in leaching. Unfortunately, cobalt, which is added to the electrowinning solution to modify the anodic process, is irreversibly lost through the bleeding operation. This cobalt loss represents a significant operating cost to SX-EW copper producers. DiphonixTM ion exchange resin contains diphosphonic acid and sulfonic acid functional groups on a polystyrene-divinyl benzene matrix. This resin has been found to strongly and selectively extract ferric ion from copper sulfate -sulfuric acid solutions containing cobalt. Thus, an ion exchange process using DiphonixTM resin for the control of iron has been developed to replace the conventional bleed stream process. The new process minimizes the loss of cobalt from the electrowinning circuit and strips the iron into a sulfate based solution suitable for leach solution makeup. In addition, this process can effect a lowering of the total iron concentration in the electrolyte circuit with an associated increase in current efficiency. In this paper, data on the loading and elution of iron are presented. Laboratory and pilot scale data will be discussed along with information on process design and comparative economics.

Jan 1, 1996

By K. V. Raj, A. Miller

"Workers at mineral processing facilities are often exposed to high levels of dust generated when ores are processed. Crushing, grinding, screening, and other processes generate large quantities of dust, which can exceed the threshold VALUES (prescribed by the Mine Safety and Health Administration (MSHA). Many ores contain quartz (silica), which has been known to cause serious health problems in workers over time. Given the structure of mineral processing plants, the airflow regime is not coherent inside the building, which may lead to multiple recirculation zones. These recirculation zones can trap dust, and concentrations of dust can then rise over time. Therefore, there is a need to understand the airflow phenomenon that occur inside of mineral processing facilities and how these occurrences interact with the dust generation processes to identify zones of potentially high dust concentration. Computational fluid dynamics (CFD) modeling can give a better understanding of the airflow and help recommend designs and methods to mitigate the high dust concentrations in a mineral processing plant. This paper presents the CFD modeling of airflow inside of a mill building to demonstrate airflow patterns that will affect the generation and subsequent dispersion of dust due to crushing, grinding, and other activities. This study was conducted by researchers from the National Institute for Occupational Safety and Health (NIOSH). INTRODUCTION In a mineral processing facility, minerals go through various mechanical processes in order to reduce their size for separation of economic minerals from gangue minerals to produce a final marketable product. This research, conducted by the National Institute for Occupational Safety and Health (NIOSH), focuses on ore mills in metal and nonmetal mining (MNM) operations, but the applicability of the approach will be valid for any large structure where workers are exposed to airborne contaminants. The processes of crushing, grinding, cleaning, drying, and product sizing in these facilities generate a large amount of dust, creating hazardous conditions for the workers in these facilities. This is highlighted by the fact that MSHA sampling data for the years 1997–2012 indicate that 12.3% and 15.9% of the gathered samples were over 100 µg/m3 for silica for metal and nonmetal mills, respectively [1]. Mineral processing operations typically use some type of engineering control to address their most significant dust sources. Engineering controls include such approaches as bag-house-type dust collectors, scrubbers, and electrostatic precipitation [2]."

Jan 1, 2018

By Nilufer Kursunoglu

Despite being crucial for meeting the world’s energy demands, coal mining operations present considerable health risks, especially when it comes to exposure to coal dust. Longwall coal mining, an advanced technique, has considerably enhanced production but made dust control more difficult. Due to its explosive nature, coal dust continues to be a serious and dangerous concern in the industry despite developments in safety technology. This study aims to comprehensively assess the risk of coal dust explosions by integrating fuzzy risk matrix and Pareto analysis methodologies, offering precise risk ratings for various root causes. A fuzzy risk matrix was developed to assign exact risk ratings to identified root causes. Additionally, a Pareto chart was used to identify the main reasons and suggest particular preventive measures. 17 significant causes were determined for underground coal mines based on the study’s methodology, and some preventive measures were suggested. In accordance with fuzzy risk rating values, root causes were divided into six categories. The root hazard with the highest risk rating was identified as ‘accumulation of inflammable gas/gases’. The proposed approach was used to examine incidents caused by coal dust explosions in Turkish coal mines in order to demonstrate the effectiveness of combining the fuzzy risk matrix and Pareto analysis for assessing coal dust explosions. This study gives not only a solid framework for risk assessment but also critical information for classifying the risks associated with coal mine dust explosions. The results highlight the critical necessity for proactive and preventive actions to reduce the hazards of coal dust explosions and protect the safety of mining workers.

Nov 16, 2023

By E. Stone, R. Reagan

Risk of hand injury is very real for operators carrying out conventional bolting operations with power torque tools, reaction arms and backup wrenches. Bolting operations of this type are common today in the installation and maintenance of heavy mining machinery and equipment. Newer solutions have become available that have the potential to dramatically reduce the risk of hand injuries in mining applications. MINING APPLICATIONS Within the scope of mining operations, various types of equipment are used such as tunnel boring machines, bucket wheel excavators, draglines, material handlers, screens, pumps, crushers, continuous miners and longwall systems. Design of these machines typically includes larger diameter bolts for strength and durability. Due to rugged use all machines require frequent maintenance and service which requires the use of heavy industrial bolting tools and methods. Those engaged in bolting operations include technicians working for end-users, equipment manufacturers, general contractors and others who provide services in mining operations. Most all personnel involved with these activities are engaged with use of high power bolting tools and procedures. Training is essential to raise the awareness of bolting safety and to avoid accidents. However improved bolting tools and procedures can play an even more significant role in further improving the safety of all those engaged with bolting in the mining industry. SAFETY CONCERNS Professionals working in the mining industry are constantly looking for ways to further reduce risk to health and safety. Bolting operations which are fundamental to service and maintenance of mining equipment are often overlooked as a potential area for improvement. Several areas of bolting operations offer potential for improvement in safety and avoiding accidents during equipment maintenance. This paper addresses the safety concerns associated with reaction arms and backup wrenches in conventional bolting applications (Figure 1).

Jan 1, 2019

By M. J. Meulendyke

An extensive program of marked ball wear testing (MBWT), laboratory corrosion studies, and worn ball surface analyses has been used to gain insight about the role of corrosion in the overall wear process. In some environments, localized corrosion is observed; the actual wear mechanisms in such cases are pitting/spalling and abrasion. Factors affecting the occurrence of pitting include the abrasiveness of the ore, corrosivity of the slurry, corrosion resistance of the media, and galvanic coupling effects. Elimination of pitting substantially improves overall wear resistance. When pitting is not observed, the contributions of general corrosion are significantly less.

Jan 1, 1984

The strength of anchorage of various types of roof bolts in permafrost depends on the types of rock in which they are installed. Variation in the mine thermal regime results in weakening of the roof and walls, and at times total loss of ice cement bonds takes place in the surrounding rockmass. In mines with positive ventilation air temperature, the wedge or expansion types of bolts may become weakened due to the transfer of heat into the anchorage through the metal rod and subsequent thawing of rocks. Effective operation and evaluation of roof bolt systems for mine workings in permafrost require predictions of the dynamics of wall thawing by warm ventilation air. This paper presents an analysis of the temperature distribution in the frozen host ground surrounding roof bolts, the area of interest being the vicinity of the anchors for point anchored bolt and the entire length for split set bolt

Jan 1, 1994

By Guowen Dong, Qiyong Li, Qiang Li, Tiejun Chen, Zhihong Wu, Junying Wan

In order to search for a more economical and effective roasting additive for extracting vanadium from stone coal and solve the question of the disposal of PVC waste, PVC waste was proposed as a novel roasting additive to enhance extraction of vanadium from stone coal and realize the comprehensive utilization of resources. By adding this roasting additive, the leaching rate of vanadium reached 94.5% under the conditions that the PVC waste addition was 10 wt%, the roasting temperature was 800 °C, the roasting time was 1 h, the sulfuric acid concentration was 15 vol%, the liquid-to-solid ratio was 1.5 cm3 /g, the leaching temperature was 95 °C, and leaching time was 4 h, which increased by 8.4% compared with that of blank roasting. The thermodynamics calculation showed that the decomposition reaction of mica was performed easier with the participation of HCl produced by pyrolysis of PVC. Meanwhile, The SEM-EDS and aperture test analyses demonstrated that more cracks and voids appeared in the roasted sample by roasting with PVC waste, which could facilitate the release and extraction of vanadium. Additionally, the TG-DSC analyses indicated that PVC could provide large amounts of heat for the roasting process to promote the decarbonization and roasting efficiency of stone coal because of its high calorific value.

By J. Libaude

The Changement mine in French Guyana has, since 1983, processed gold ore by classical gravity methods. A large part of the gold is in the form of very small, free or enclosed grains. Recovery by gravity methods is thus limited (25-30%) and the present plant produces about 40,000 t annually of auriferous waste assaying about 6 git. The company therefore decided to retreat the waste by heap cyanidation. After laboratory tests which showed the feasibility of the method, a pilot test was set up on site. An experimental 3000 t heap, composed of waste of 0-8 mm grain size, was laid out by bucket loader on an impermeable pad covered by PVC and geotextile cloth. The upper layer of the heap was reworked by mechanical shovel to break up the area that had been compacted by the passage of the loader so as to restore adequate permeability.

Jan 1, 1998

By N. Rocco, G. Johnson

Implementation of post-closure draindown estimates for tailings facilities are important predictive tools for reclamation planning and often influence jurisdictional bonding. Simplified estimates of draindown have been proposed in the past but these methods are not able to capture many of the site-specific nuances as well as operational and material parameters that influence robust draindown estimates. This paper discusses an iterative approach that relies on unsaturated flow models to predict draindown rates and associated pond inventory water balances that track inputs into underdrain pond systems, solution storage volumes, implementation of active evaporation, and necessary recirculation of solution back to the tailings facilities. Specific design criteria such as climate, facility geometry, material properties, and initial conditions, as well as active closure operational considerations that can influence draindown estimate will be discussed. Concepts presented will be valuable for operators, designers, and regulators to guide closure planning and predictive analytical analyses that support draindown estimates.

Mar 2, 2022

By B. Pina

The conversion of maf coal to pyridine solubles and gas was investigated in a microautoclave batch reactor for two Kentucky washed coal samples (Ky. #9 and Ky. #11). Solvent hydrogen donor strength was controlled by the tetralin content of a mixed 1-methyl naphthalene-tetralin solvent. Primary liquefaction conversions greater than 90% in 10 minutes of reaction time at 427°C were achieved in liquefaction solvents with moderate hydrogen-donor strength (circa 40% tetralin). A modified irreversible first order rate expression, containing a parameter (a) to account for the intrinsic reactives of the maf coal, described the experimental kinetic data rather well. The integrated form of this rate expression is -k1e x = a (a- ß)e (eq. 1) Parameter ß in equation (I) is the pyridine solubility of the starting maf feed coal, x is the primary liquefaction fractional number of conversion, k1 is the specific reaction velocity constant and ? is reaction time. Primary liquefaction rate was found to be quite temperature sensitive and independent of coal when a liquefaction solvent containing 40% or more tetralin was employed. Primary liquefaction rate appears to depend on liquefaction solvent hydrogen donor strength for solvents containing = 40 wt.% tetralin. The intrinsic reactives in the maf feed coal or a appear to depend mainly on the inertinite group maceral content of the coal for the two coals studied in liquefaction solvents containing 3 40wt.% tetralin. In contrast, a appears to decrease in liquefaction solvents of low donor strength., i.e; solvents with less than 40wt.% tetralin.

Jan 1, 1984

By D. A. Stanley

Researchers at BCD Technologies and the University of Alabama have applied three statistical techniques to the information contained in a large database of measurements from a phosphate ore processing plant. The rust, Principal Components Analysis (PCA), replaces many measured variables with a few fundamental and un-correlated variables. The second technique, Projection to Latent Structures (PLS), is an extension of PCA that explores the relation between variables identified as either independent or dependent. The third technique, Cluster Analysis (CA), is applied to the results of the PCA or the PLS calculations, and identifies individual data clusters that represent uniform operating conditions in the plant. All three statistical methods can be seen as geometrical operations on the data viewed as points in space. A Viewer gives a corresponding graphical presentation of the data points. This paper describes the use of the above three techniques and the Viewer to explore part of the phosphate flotation database.

Jan 1, 1998

By Giorgio De Tomi, Rondinelli Sousa

Whilst all public mineral reporting codes require classification of mineral resource and reserves according to the level of geological knowledge and confidence of the estimates, companies are not required to disclose how mineral estimates and associated cashflow projections respond probabilistically to the incorporation of different types of risk events. As the level of expectations and scrutiny of investors and stakeholders continue to increase over the years, it will be essential for companies to adopt an integrated framework for sensitivity analysis to increase corporate value through better capital allocation and reduce potential losses associated with poor investment decisions. Failure in fully capturing the impact of unexpected incidents in mineral estimates and financial modeling could be extremely harmful to the business, affecting the company’s reputation, and negatively impacting the relationship with stakeholders.

Feb 22, 2026

By M. Guzman, S. B. Thais, M. F. Obispo, M. R. Arribasplata

One of the greatest environmental issues related to the development of the mining activity is the generation of Acid Mine Drainage (AMD). Many methods have been developed for AMD treatment, being wetlands a good option for heavy metal removal. In this sense, the implementation of artificial wetlands for the treatment of mining effluents would seem to be an environmentally friendly alternative. In this paper, we present the results on the elimination of heavy metals (Cu, Zn, Pb and Fe) using two Peruvian native species such as Schoenoplectus californicus (C.A. Mey.) and Phragmites australis (Cav.) Trin. Ex Steud. The results show that Schoenoplectus californicus preferentially removes copper (82 and 90%), lead (88 and 92%) and iron (28 and 69%), whereas Phragmites australis removes copper (68 and 87%) and zinc (53 and 95%). Likewise, it is observed that the Schoenoplectus californicus mainly retains the ions in its root, copper (89%), zinc (84%) and iron (76%). While the Phragmites australis accumulates iron (62%) and copper (74%) in the steam and root part respectively

Mar 2, 2022