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By Ewan Wingate, Ranjit Prasad, Yanjun Liu

The use of phosphorus by mankind is long established. From use in agriculture, foods, high tech electronics, and more recently in EV battery cathode production, one cannot escape its impact on today’s society. This paper will review and describe the circular journey of phosphorus through its value chain from the mining operation of phosphate ore through beneficiation into downstream chemicals production and finally into the EV battery cathode production space. This will include a review of phosphoric acid production from phosphate concentrate using wet process route and thermal route. The wet process route discussed will be via dissolution of phosphate concentrate by sulphuric acid. The thermal route will discuss thermal decomposition of phosphate concentrate using submerged arc furnace to produce yellow phosphorus followed by its combustion to produce phosphorus pentoxide and subsequent hydration to produce phosphoric acid. It will also discuss briefly other phosphate derivatives for specialty chemicals and recovery of phosphorus units from wastewater treatment plants, sewage sludge and incinerator ash. Finally, the paper will discuss the use of phosphorus in EV batteries in the form LFP cathode materials and its production. It will also briefly discuss the LFP battery recycle.

Sep 11, 2023

By A. K. Clarke

In any treatment process that requires a coarse feed material to be reduced to a fine size by crushing and/or grinding it must be determined whether a wet or dry comminution system should be utilized. All factors must be evaluated in reaching the decision. Among these factors are: 1) Ecology and Plant Environment: Unfortunately in many instances the decision on wet or dry is based on prejudice resulting from an unnecessary fear of dust. The writers submit that this fear, although once justified, is no longer valid because technology and equipment is now available to collect dust to meet any standard. When dry grinding is used it is very often possible to discard a portion of the waste product in a dry state. This will decrease the size of the tailing pond required. As pollution control standards increase it becomes increasingly difficult to clean up water from tailing ponds. 2) Operating Costs: Steel wear is often five or more times greater in wet grinding than in dry grinding. This is mainly due to corrosion. The evaluation of the economics of dry grinding must of course include the air system and dust collection; similarly in a wet grinding plant related pumping and material handling costs should be included. Pumping costs are often overlooked. This assumes water is made to flow for nothing. Pumping can account for 20 percent of the power consumption in the grinding plant. Large scale comparative tests were conducted in a wet and dry commercial plant in 1970. The same ore was used for both tests. With all factors included in both plants the dry system showed lower horsepower per ton.

Jan 1, 1971

By E. Kaya

Investigations of fine grinding of bituminous coal in a laboratory-scale pulverizer are described. The results indicate essentially "normal" breakage behavior at relatively coarse sizes (greater than about 20 µm) but show clear evidence for re-agglomeration in the fine size range (less than about 10 µm). A simplified population balance model for simultaneous growth and breakage has been formulated. Breakage rates and breakage distributions are assumed to follow the patterns typically observed in simple grinding systems. It is recognized, however, that solid particles and agglomerates may exhibit different breakage behavior. Agglomeration rates are assumed to be determined by contact probability, i.e. by the relative numbers of interacting particles. Based on comparisons of model simulations and experimental data, it appears that agglomerate re-breakage rates and fragment size distributions are quite different from those for solid particles. The result is that product size passes through a minimum and then increases with time as agglomeration begins to dominate.

Jan 1, 1996

By D. Brunner

System simulation is an increasingly popular technique for analyzing and improving existing as well as newly designed underground mining operations. An engineering firm that specializes in simulation helped a major metals producer build a long-range planning model of an existing underground mine. Subsequently the team adapted this model to assess technology alternatives in the design of a new mine. The two models differ in the level of detail used for modeling the development process. This paper discusses the differences in approach between the models along with the experiences gained and challenges faced during the construction and use of the models.

Jan 1, 1999

By Henry T. Mulryan

The philosophy, strategy and techniques of successful marketing of talc, differ sharply from those applied to most other mined products. Unlike non-ferrous metals, there are no commodity exchanges to facilitate the transfer of goods. Unlike iron ore and some non-metallics, assured markets by means of long term contracts are practically non-existent. Talc must be sold and sold and sold again. The normal channels of talc distribution are almost identical to those used, by the chemical industry. These consist of a blend of producer marketing staff, field technical service, and sales force; and independent chemical wholesalers. Like the term "chemicals", there is tremendous product diversity contained in the rather loose expression "commercial talc". Certain kinds of talc, processed in conventional ways, are regarded as commodities by the consumer. That is, that material from one source or supplier is considered to be effectively interchangeable with those available from a number of other areas and producers. Under such conditions, lowest delivered price, quickest delivery, and best, customer service, are the key factors in a successful sales effort.

Jan 1, 1965

By Peter Werner

Technological advances in mine equipment and milling processes have enabled mining companies to exploit ever lower grades of ore. The result has been larger disturbances, greater volumes of waste, a complex web of infrastructure, and an overall trend toward mega projects that can extend over several square kilometers. This explosive growth in a mining operation’s disturbance footprint provokes an obvious question: What is it going to cost to reclaim all of this? At face value, this can be an enormous financial liability for a company, but since the timing of reclamation may be years in the future for many operations, these costs can be heavily discounted, thereby limiting the burden on the corporate balance sheet. Nonetheless, mining companies are eager to remove these liabilities as quickly as possible; conversely, regulators want assurance reclamation will, in fact, occur. How might one bridge these competing interests? Navigating the practical and financial requirements of a post-closure landscape requires foresight, judgement and assumptions; however, companies that do not adequately plan for these future expenditures when there is no offsetting income stream will likely face some difficult decisions. Simple risk analysis tools and utilizing the time value of money can help bring some clarity to this end-of-mine life phase.

Dec 1, 2025

By T. Lupek, M. Buxton, A. de Jong

"With regard to the EU funded project ‘Real-Time Mining’ a sensor-based acquisition, collection and transmission of data for the resource extraction process will be developed. The key concept promotes the change in paradigm from a discontinuous to a continuous process monitoring. Especially concerning material characterization, machine performance and underground positioning ‘Real-Time Mining’ will provide sensor solutions as well as the interfaces for integration, management and visualization of the collected data for a permanent updating process of the resource model with the aim of near real-time optimization of decisions. On the basis of ‘Real-Time Mining’-Output a permanent monitoring of costs can be performed as well in both, the installation and the production process of a mine. Due to the collected data in terms of machine performance connected with the underground positioning information added with personnel tracking and mine surveys a comprehensive overview of process performance is available. By evaluating those information in a specific manner costs per unit will arise for monitoring and possibly controlling actions. INTRODUCTION By having a look into the future of mineral extraction projects, a new challenge for the Ore Mining Industry will arise in the short and medium term. Due to the depletion of currently mined mineral reserves in addition to the persistently high demand of mineral raw materials, the extraction of complex reserves will be necessary. By characterizing such deposits as not constantly graded and geometrically varying, the extraction process, especially concerning the requirement of a minimized zero-value material handling, will become economically ineffective by utilizing the traditional mineral resource management methods. Regarding the state-of-the-art mineral resource management process along the mining value chain, an intermitted, discontinuous sequence of actions is applied (Figure 1). Recently data will be collected from drill hole cores. These rock samples are analyzed in a laboratory. Based on those analyses a resource model is created whereby unknown data between drill holes is interpolated. This resource model is the basis for all mine planning actions including the selection of the mining method, extraction sequencing and the prediction of the expected performance. With the start of the production, real conditions (concentrations of elements, hardness, stability, etc.) can be observed and measured. As the production process is running accordingly to the above described mine plan, the verification of the initial assumptions happens at the earliest after processing of the extracted material. Even if deviations between the predicted and the actual performance are now recognized, the execution of corrective actions is not possible anymore."

Jan 1, 2016

By J. -B. C. Varnier, J. A. Cremeens, D. D. Overton

"Slope failures that occurred in 2008 and 2009 at the Pikeview Quarry in El Paso County in Colorado in the United States were investigated using three-dimensional discrete element modeling methods. Large-scale block sliding failures occurred along weak bedding planes that dip steeply into an excavation located at the toe of the slope. Several mining sequences at the toe of the slope were simulated to evaluate the effects of various degrees of extraction and backfill on slope stability. Slope stability back-analysis was conducted using prefailure and post-failure conditions to determine the joint shear strength properties. Laboratory testing was also conducted to determine intact rock properties. Three-dimensional discrete element analysis was uniquely applicable to this evaluation because it allowed representation of shear stress of the basal sliding surface and afforded evaluation of several scenarios of extraction and backfill at the toe of the slope. IntroductionThe Pikeview Quarry is an aggregate quarry located approximately 8 km (5 miles) northwest of Colorado Springs in El Paso County, CO, USA. The quarry has been operated by several owners since the early 1900s. According to the U.S. Mine Safety and Health Administration (MSHA, 1986), the quarry has been a major source of construction aggregate for the Colorado Springs area for many years. In the 1950s, the site was mined by Peter Kiewit and Sons to provide limestone for the construction of the nearby Air Force Academy.A large-scale slope failure occurred on Dec. 2, 2008, which stopped mining activity at the Pikeview Quarry. A second, related slope failure occurred on Sept. 13, 2009. The second slope failure was located immediately adjacent to the initial December 2008 failure.The objective of this paper is to discuss the three-dimensional slope stability evaluation. The causal relationships of slope instability are not within the scope of this publication. However, omitting the precursors to slope failure would limit understanding of the nature of the slope stability evaluation. The regional and local geology and the history of slope instability at the Pikeview Quarry aid in understanding these precursors. Two main failure mechanisms were hypothesized during the failure investigation to explain the triggering of the 2008 and 2009 large slope failures at the Pikeview Quarry, and both of these mechanisms were given equal credence in the present study. Quarry excavation and backfilling was a key factor in the slope instability for both failure mechanisms. The excavation was backfilled in stages in an effort to provide slope support. The objective of the three-dimensional model was to evaluate the effects of extraction and backfill at the toe of the slope with respect to slope stability."

Jan 3, 2018

By Ronald L. Wiegel

In a mineral processing plant there are a number of routine decisions which are based at least in part on the plant's metallurgical performance. Among these are those related to: 1) equipment functioning properly 2) suitable operating conditions 3) reagents achieving desired results 4} determining operating response to changes in ore 5) defining circuits offering potential for improvement A step beyond the routine, are the periodic management evaluations of operating supervision and technical assistance, which are based largely on profit -a direct function of are availability, metallurgical performance and operating costs. The "yardstick", excuse me -"meterstick", by which performance is best measured is the plant metallurgical balance, which tells not only what was produced but how it was produced. Since this metallurgical balance is directly related to both plant profits and individual rewards, it is only reasonable to make that "meterstick" as precise as humanly possible.

Jan 1, 1978

By J. A. Cremeens, D. D. Overton, J. C. Varnier

"Slope failures that occurred in 2008 and 2009 at the Pikeview Quarry in El Paso County, Colorado, USA were investigated using three-dimensional discrete element modeling methods. Large scale block sliding failures occurred along weak bedding planes that dip steeply into an excavation located at the toe of the slope. Several mining sequences at the toe of the slope were simulated to evaluate the effects of various degrees of extraction and backfill on slope stability. Slope stability back analysis was conducted using pre-failure and post-failure conditions to determine the joint shear strength properties. Laboratory testing was also conducted to determine intact rock properties. Three-dimensional discrete element analysis was uniquely applicable to this evaluation because it allowed representation of shear stress of the basal sliding surface and it afforded evaluation of several scenarios of extraction and backfill at the toe of the slope. INTRODUCTION The Pikeview Quarry is an aggregate quarry located approximately five miles northwest of Colorado Springs in El Paso County, Colorado, USA. The quarry has been operated by several owners since the early 1900s. The Pikeview Quarry has been a major source of construction aggregate for the Colorado Springs area for many years (MSHA 1986). In the 1950s, the site was mined by Peter Kiewit and Sons to provide limestone for the construction of the nearby Air Force Academy. A large scale slope failure occurred on December 2, 2008, which stopped mining activity at the Pikeview Quarry. A second, related slope failure occurred on September 13, 2009. The second slope failure was located immediately adjacent to the initial December 2008 failure. The objective of this publication is to discuss the three-dimensional slope stability evaluation. The causal relationships of slope instability are not within the scope of this publication. However, omitting the precursors to slope failure would limit understanding of the nature of the slope stability evaluation. The regional and local geology and the history of slope instability at the Pikeview Quarry aid in understanding these precursors. Two main failure mechanisms were hypothesized during the failure investigation to explain the triggering of the 2008 and 2009 large slope failures at the Pikeview Quarry. Both mechanisms are given equal credence in this publication. Quarry excavation was a key factor in the slope instability for both failure mechanisms. The objective of the three-dimensional model was to evaluate the effects of extraction and backfill at the toe of the slope with respect to slope stability. GEOLOGY Regional and local geology are both important factors in slope instability at the Pikeview Quarry. Geologic structure at the quarry is related to regional mountain building and basin development associated with the Laramide Orogeny and the Rocky Mountains. Lithologies at the Pikeview Quarry are also related to regional trends. Localized geologic features, primarily related to weathering and erosion, have also been major contributing factors to slope instability at the Pikeview Quarry."

Jan 1, 2017

Experimentation was performed on the flotation of apatite and dolomite separately using anionic collectors in the presence of Mycobacterium phlei. Also, the flotation of mixtures of dolomite and apatite in the presence of anionic collectors and in the absence and presence of the bacterium were studied. It was found that M.phlei functions as a depressant for both minerals. However, it functions as a better depressant for dolomite than for apatite. Experimentation was extended to two different Florida dolomitic phosphate rocks. In this investigation a concentrate grade of less than 1.0% MgO was achieved.

Jan 1, 1997

By J. T. Carlson

Dolomite [CaMg(CO3)2] is an intolerable impurity in phosphate ores, due to its MgO content. The need to develop a cost-effective method for the removal of dolomite from high-MgO phosphate ores becomes increasingly important as high-grade reserves become depleted. The jigging process has been investigated as a method for the beneficiation of phosphate ores. A laboratory-scale jig was constructed and tested using a semicontinuous, ?through-the-screen? jigging process. Two types of sedimentary phosphate ore were used; a sample from Plant 1 in the 4.00 x 0.85-mm size range, containing 1.55% MgO, and a sample from Plant 2 in the 3.40 x 0.85-mm size range, containing 3.07% MgO. These were tested, using previously optimized jigging parameters, at high and low feed rates. For the Plant 1 phosphate ore, a phosphate concentrate that contained 0.89% MgO was achieved with a bone phosphate of lime (BPL) recovery of 32.0%. For the Plant 2 phosphate ore, a phosphate concentrate that contained 1.38% MgO was achieved, with a BPL recovery of 74.7%. Minimum achievable MgO grades were also determined by analyzing hand-separated phosphate samples.

Feb 1, 2012

By John B. Goddard

Crystallization of ammonium paratungstate (APT) is frequently the last effective purification step in producing high-purity tungsten. However, crystallizer mother liquors are often several times higher in tungsten than predicted by the solubility of APT. The formation of heteropoly anions, particularly those containing phosphorus and silicon, is largely responsible. Solubility of tungsten in APT mother liquor can be linearly correlated with the concentration of these and other impurities. The problem can be overcome by direct treatment of the crystallizer feed solution with alum. By appropriate treatment, the aluminum hydroxide flocculates and is easily filtered, resulting in a purified low-aluminum crystallizer feed from which high APT yields can be attained.

Jan 1, 1984

By James Parkes

"The proposed Baltimore Red Line light rail system includes a 3.4 mile downtown tunnel (DTT) with five underground stations. The design of the underground stations involved overcoming several challenges, including limited right-of-way, high groundwater and uplift pressures, and metamorphic rock within the station depths. An innovative design was developed to maximize the internal station space while minimizing cost. The station designs use slurry walls for temporary and permanent support and groundwater control. Depths within rock are supported with cast-in-place concrete walls, the thickness of which are minimized through the use of permanent rock anchors for support of the rock mass and slurry wall toes. Permanent tiedown anchors are used for uplift resistance, which minimizes the station depths, volume of rock excavation, and the volume of deadweight concrete. Design considerations regarding individual elements and overall integration of the slurry walls, CIP walls, and multiple anchor types are presented.INTRODUCTION The Baltimore Red Line (BRL) project is a proposed light rail transit line for the Maryland Transit Administration (MTA) that runs east to west through Baltimore City and County. The project includes the Downtown Tunnel (DTT) consisting of 3.0 miles of twin running tunnels, two portals, five underground stations, and a pedestrian tunnel, as shown in Figure 1. The tunnels have an outside diameter of 21.8 feet and are designed to be mined using pressurized face tunnel boring machines (TBMs). The stations, portals, and the pedestrian tunnel are designed as cut-and-cover structures using slurry walls (concrete diaphragm walls) for both temporary support of excavation (SOE) and permanent structural walls. The dimensions of the five underground stations are summarized in Table 1. Design challenges included limited right-of-way (ROW), challenging soils conditions, strong metamorphic rock within the station depths, and high groundwater conditions. The final station designs included innovative use of slurry walls, tieback anchors, rock anchors, and tiedown anchors."

Jan 1, 2016

By Shuchen Sun, Ganfeng Tu, Chuan Liu, Xiaoping Zhu

The hydrometallurgical residue generated during the hydrometallurgical processing of waste automotive catalysts is valuable as a secondary resource. In this study, a process of platinum recovery from the hydrometallurgical residue by high-temperature smelting process was proposed. Results of lab- and pilot-scale experiments show a high recovery of more than 98% of platinum and glass slag was successfully obtained by controlling the Fe3O4 addition, C/Fe3O4 mass ratio, CaO/SiO2 mass ratio, smelting temperature, and holding time at 15 wt%, 0.4, 0.6, 1500 °C, and 120 or 60 min, respectively. Results from the pilot-scale show that the platinum contents in the glass slag and alloys were less than 4 g/t and more than 0.6 wt%, respectively. Therefore, the process proposed in this study is a prospective and effective approach for reutilization of hydrometallurgical residue containing platinum.

Oct 12, 2020

By Tahereh Rostami, Behnam Khoshandam

In the present paper, the recovery of mixed spent cathodes is evaluated and performed through a hydrogen reduction process. Firstly, the lithium is isolated by the hydrogen reduction process as LiOH at 600 ◦C for 15 min with 10% H2 with a flow rate of 350 ml/min. In the second step, 98.37% Li is recovered through water-leaching of hydrogen reduction products at 100 ◦C for 90 min with 50 ml/g. The filtration residual is reduced by using a carbothermic reduction process and a hydrogen reduction method. The first one is performed under an Ar atmosphere at 900 ◦C for 210 min and the second one is conducted at 800 ◦C for 150 min. The purer products are achieved using the hydrogen reduction method at lower temperatures and shorter holding times compared to a carbothermic reduction process with recovery percentages of 100%, 99.06%, and 70% for Ni, Co, and Mn, respectively. Given the importance of reducing the emission of toxic gases, the hydrogen reduction process is also a promising method for metal recycling. The obtained results also demonstrated that Li, Co, Ni, and Mn can be effectively separated from the mixed cathode material through the hydrogen reduction process as a sustainable and environmentally friendly recycling process. This study provides an impressive understanding of the hydrogen reduction process and valuable guidance for a larger-scale hydrogen reduction process.

May 3, 2024

By P. Somasundaran

The use of chemical additives in ultrafine grinding will be reviewed in this paper for the case of grinding of quartz in solutions of surfactants and inorganic electrolytes including some dispersants under different conditions of pH and ionic strength. Mechanisms are examined by correlating the grinding effects with those obtained for the influence of these chemicals on zeta potential, pulp fluidity and flocculation/dispersion characteristics. The analysis suggests grinding depends mainly on the state of aggregation of the ground products in- side the mill and the pulp fluidity. Implications of the observed effects on ultrafine grinding in general are discussed.

Jan 1, 1983

By Ramon S. Pizarro

The Masbate Province, Philippines, has been a gold producer for many years. Several gold properties were profitably operating until the outbreak of World War II in 1941. One of these properties was the Masbate Consolidated Mining Company that at the time showed an impressive production rate of more than 4,000 metric tons of ore per day and one of the lowest milling costs on record in the country at that time. Interesting enough, t was the milling equipment left abandoned at Masbate that gave birth to one of the giant copper producers in ASIA. In 1955, Atlas Consolidated Mining and Development Corporation started a new operation at its copper property in Cebu with the seven 2.4m 0 x 3m long (8'0 x 10' long) ball mills left abandoned at the old Masbate Gold Mine. Now, 25 years later, Atlas is processing over 100,000 metric tons of copper ore per day through its three copper concentrators, and, the seven old mills are still grinding, copper ores now.

Jan 1, 1981

By D. K. Adjei, G. Ofori-Sarpong, R. K. Amankwah

"Mercury (Hg) is toxic and has long-term effect on the muscle tissues, the brain and the central nervous system functions due to its bioaccumulation and biotransformation effect. Hg pollution around the world is high and this has attracted much global concern such as the Minamata Convention on Mercury, held in 2013. For several years, mercury has been the chemical of choice for Artisanal and Small-Scale Mining (ASM) gold extraction, accounting for about one-third of the global mercury consumption. A greater percentage of this ends up in the environment through open burning of amalgam, spillage and indiscriminate disposal of waste. To break this wall of mercury pollution, it is very important for the mercury used to be recycled through the use of mercury retort units. This brings into the limelight, the Lantern Retort which tries to synergise the high conductivity of steel and the see-through effect of glass, thus, improving the amalgamation process. A research conducted on improving the original Lantern Retort arrived at an appropriate distillation length of 5.08 cm which was used in redesigning a more efficient retort. The improved Lantern Retort recovered about 98% of the mercury used. INTRODUCTION Artisanal and Small-scale mining (ASM) is an informal mining activities which employ quite simple tools such as pickaxes, sluice boxes, shovels, chisels, metal bars, mattocks and water pumps for mining and processing of gold ores. The artisanal and small-scale mining (ASM) sector has served as source of employment for many people in developing countries including Ghana (Aryee, 2001; Hilson and Potter, 2003; Amankwah and Anim-Sackey, 2004; Amankwah et al., 2010) and has provided a substantial amount of foreign exchange through its activities (Hilson, 2001; Styles et al., 2010). Hentschel et al. in 2003 estimated that about thirteen (13) million people are said to be engaged directly in the small-scale mining activities worldwide. However, an estimated 100 million people are said to depend on this sector for their livelihood mainly in developing countries. In China alone, a projected number between 3 and 15 million people are engaged in artisanal and small-scale mining activities (Hentschel et al., 2003), whilst in Ghana, it is estimated that more than 1,000,000 people are employed directly or indirectly in the artisanal and small-scale mining activities, with 10% being women (Amankwah and Anim-Sackey, 2004; Amankwah and Ofori-Sarpong, 2014). In Ghana, ASM gold production has grown from a low of 2.2% in 1989 to a high of 34% in 2014. This figure is estimated to increase with proper documentation. This indicates that the sector has made significant socioeconomic impact on many individuals and communities as a whole. Notwithstanding the above positive contributions, the sector has also contributed to negative impacts on human, aquatic life and the environment in general due to indiscriminate mercury emission. This ‘pollution wall’ needs to be broken, and several interventions have been put in place including the use of retort units like the lantern retort (Adjei et al., 2014; Amankwah and Ofori-Sarpong, 2014)."

Jan 1, 2017

By Jim Huerta

Diesel fuel usage in the mining industry continues to escalate. This is because approximately 60 percent of all mined materials are surface extracted by large equipment using diesel fuel, which continues to increase in cost per gallon. For example, coal mining uses large equipment such as wheel loaders, wheel dozers, draglines and [ ] dredgers. In one year, three of the largest U.S. coal mining operations consumed approximately 567 million to 852 million L (150 million to 225 million gal) of diesel. At an approximate cost average of $3.25/gal the expenditure on diesel is $487 million to $731 million per year. So, are there any solutions that could reduce this cost burden? Yes, there are. Coal mining companies can extract less ore; use more efficient extracting equipment that consumes less fuel; wait for a significant reduction in the cost of fuel; or find and use technology that would create efficiencies that would lower the cost. Nanotechnology is one such technology that might provide the means to create the efficiencies that will significantly lower diesel fuel costs.

Jan 1, 2011