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By Frank Ladwig, Stephen Gos

Tailings and/or wastewater generated from gold extraction plants employing cyanida­ tion must often be treated to remove the cyanides and heavy metals for environmental reasons and/or gold extraction inhibition reasons, due to the presence of heavy metals like copper, which have a detrimen­ tal effect during cyanidation. In recent years, the treatment of effluents contain­ ing cyanides and heavy metals has been widely studied, Among chemical treatment methods, the use of hydrogen peroxide has been universally employed as a viable option. However, in some cases, effluents containing high concentrations of heavy metals and/or solids decompose the hydrogen peroxide, an undesirable side reaction. The addition of stabilizers or other peroxygen compounds together with hydrogen peroxide can, however, considerably reduce the rate of decomposition and thus result in detoxi­ fication costs, which are considerably less than the standard detoxification process using hydrogen peroxide. In some cases, the reaction rate can also be increased, resul­ ting in lower investment costs for new detoxification plants. This paper deals with the results of developmental work performed in the recent past and introduces some new processes with the aim of optimizing reagent consumption and costs.

Jan 1, 1992

By Kenneth N. Han, Yichang Guan

The dissolution behavior of metals from Au/Ag/Cu-alloys has been studied using rotating disc electrodes in solutions containing acids, cyanide, and ammonia. Electrochemical methods as well as leaching tests were adopted in this study. The results showed that there was no galvanic effect on the dissolution of metals from homogeneous alloys. In aerated cyanide solutions, the dissolution of gold, silver, and copper from their alloys was partly controlled by surface chemical reaction, but largely by mass transfer. On the other hand, the galvanic coupling effect played a very important role in heterogeneous alloy systems.

Jan 1, 1995

By James Y. Oldshue, Paul M. Kubera

Most coillillercial processing applications employing mixers in various types of slurry systems are continuous flow. These applications may also be multiple stage, with the stage number varying anywhere from two or three to ten or more. Two questions that usually come up at the beginning of any proposed pilot plant study are (1) can the pilot plant unit be operated batch-wise, and the results extrapolated both on the basis of scale and fluid motion to the full-scale tank which will be continuous-flow (and probably multi-stage), or (2) does the pilot plant need to be operated in a continuous-flow fashion, and if so, does the exact number of tanks/stages that are proposed for the plant need to be used in the pilot plant? We will consider these possibilities in sequence and present the principles involved in running some of the various pilot-plant arrangements.

Jan 1, 1992

By Robert J. Ramsey, N. Finkelstein, Foster J. Witthauer

First mining operations in the Tyrone District, located just north of the Burro Mountains in Grant County, New Mexico, commenced in the 1870's. A major operation was undertaken by Phelps Dodge Corporation in the early 1900's when a 2,000 ton per day underground mine was developed and a gravity concentrator was built east of the mine and across the Continental Divide. It was during this time that the picturesque Tyrone townsite was built and occupied. In 1921, however, the underground operation was closed because of high operating costs and low demand for copper. The area was drilled extensively during the 1950's and in October 1966 Phelps Dodge announced the pending development of the new Tyrone with a large open-pit mine, a modern concentrator, suitable support facilities, and a new townsite to be located between the mine and Silver City. Stripping for the pit and construction of shop and milling facilities began in 1967. By the spring of 1969, ore was being stockpiled near the primary crusher. Operation of the concentrator on a 3-shift per day basis commenced on July 17, 1969. The concentrator as initially built had one primary, two secondary, and five tertiary cone crushers, two grinding sections of six ball mills each, two flotation sections, four filters, and four tailing thickeners. 'he capacity was about 30,000 tons per day. In 1971 and 1972, the capacity was increased to 48,000 tons per day by the addition of one secondary and two tertiary crushers, one section of eight ball mills, one flotation section, two filters, and four more tailing thickeners. Centralized automatic control was built into the original and expanded facilities to the greatest extent possible, considering the state of the art at that time. Installation of additional control

Jan 1, 1976

By Tuncel M. Yegulalp

In this paper we revisit the well known "Ultimate Pit Limit Problem" and suggest an alternative approach for fast and efficient solution. We follow the approach originally proposed by Johnson and Barnes (1988), but utilize the "Excess Scaling Algorithm" in solving the equivalent maximum flow problem. This algorithm provides significant increases in speed and reduction in memory requirements over the well known Labeling Algorithm of Ford and Fulkerson (1956), enabling one to solve large problems with relatively small computers. We present results of a series: of benchmark tests using this approach against the well known Lerchs Grossman algorithm as well as a brief description of the new algorithm.

Jan 1, 1992

By S. N. Groudev

Acid mine drainage waters generated in the uranium deposit Curilo, Bulgaria, were treated by means of a pilot-scale passive system consisting of an alkalizing limestone drain, a permeable multibarrier for microbial dissimilatory sulphate reduction, biosorption and chemical neutralization, and a natural wetland, connected in a series. The waters had pH in the range of about 2.5 ? 4.1 and contained radionuclides (uranium, radium), heavy metals (copper, zinc, cadmium, lead, nickel, cobalt, iron, manganese), arsenic and sulphates in concentrations usually much higher than the relevant permissible levels for waters intended for use in the agriculture and/or industry. The water flow rate through the passive system varied in the range of about 5 ? 15 m3/24 h, reflecting water residence times of about 60 to 20 hours. An efficient removal of pollutants was achieved by this system during the different climatic seasons, even during the cold winter days at external air and water temperatures close to 0°C. The removal was connected with different mechanisms but the microbial sulphate reduction played the main role during the warmer months of the year. However, during the cold winter days the removal of pollutants was due mainly to their sorption by the solid dead plant biomass (cow manure, plant compost, straw) present in the multibarrier as well as to their precipitation as a result of chemical neutralization caused by crushed limestone.

Jan 1, 2006

By Robert A. Jankowski, Natesa I. Jayaraman, Jay F. Colinet

The U.S. Bureau of Mines evaluated the dust control effectiveness of two-phase flow systems in a full-scale model mine using a mockup of a Joy 14CM continuous mining machine. In a two-phase flow system, air and water flow simultaneously through the nozzle. Air pressure varies from 10 to 60 psi, and water at 30 to 50 psi. Coal dust was introduced at the face, and dust concentrations were monitored at the operator locations and in the return. When compared with a conventional spray system, a symmetrical two-phase flow system reduced dust levels during the box cut by 43 pct at the operator location, and 30 pct in the face return. Dust levels, however, increased at the off-operator position during the slab cut. A directional two-phase flow system reduced dust levels at both operator locations by more than 90 pct in the box cut mode. While the use of two-phase flow systems will reduce respirable dust levels and water usage, it requires an air supply to the miner. Moreover, the ability of the two-phase flow system to redirect the dust cloud makes nozzle orientation a critical factor.

Jan 1, 1991

By Stephen R. Brown

The principles of quality management are well developed and, from a practical stand- point, thoroughly implemented in the process industries of Japan. Although these principles are now applied to the U.S. manufacturing industry, and as a result, the steel industry, they have been largely ignored in the non-ferrous and precious metals industries. This paper presents the concepts and practical approaches to implement a total quality management program. Contrary to the beliefs of many managers, such a program increases yields, recoveries and output while it decreases unit costs. In fact, quality management incorporating statistical process control will be an essential ingredient for metallurgical plants to effectively compete in the '90's.

Jan 1, 1991

By G. A. Rowell, T. M. Barczak, J. C. Zelanko

The US Bureau of Mines conducted a multifaceted geomechanics research project at a bump-prone longwall coal mine in eastern Kentucky. This mine presented a unique opportunity to study coal mine bumps because the problem appeared to be confined to areas beneath a sandstone channel of limited areal extent. The Bureau's research plan sought to exploit the uniqueness of the site by monitoring strata behavior and longwall support reactions as the longwall face approached and passed beneath a sandstone channel. The study incorporated static pillar stress and strata deformation measurements, shield support leg pressure measurements and microseismic monitoring, as well as geologic mapping and the collection of observational data. Data collection was underway when a major coal bump occurred on the longwall face at the mine. Pillar behavior (load and deformation), shield loading and microseismic activity were monitored prior to, during and after the bump. Observations in the tailgate indicated that these pillars were failing prior to and following the face bump. Shield load data, evaluated in an effort to identify trends that could be used to forecast coal bumps, appear to provide a measure of the effectiveness of destressing operations conducted on the face (e.g. shot firing). Analyses of microseismic data revealed anomalous values associated with microseismic "energy" prior to the face bump. In addition, microseismic source-location data and underground observations provided some insight as to the sequence of pillar and face bumps.

Jan 1, 1992

By J. B. Zachwieja, P. E. Richardson, G. W. Walker

The electrochemical nature of mineral-collector interactions and their relationship to flotation have been investigated to develop a better understanding of the factors controlling sulfide mineral beneficiation. Spectrophotometric and electrochemical techniques have been used to examine the reactions occurring on electrodes composed of a bed of bornite particles in the presence and absence of potassium ethylxanthate (KEtX) at a pH of 9.2. The combined techniques showed that KEtX sequentially reacts with bornite by (1) a chemisorption reaction forming ca hydrophobic species between --0.4 and -0.2 V (SCE), (2) an electrochemical oxidation reaction forming cuprous xanthate between -- 0.2 V and the xanthate/ dixanthogen redox potential, and (3) oxidation to dixanthogen when the potential exceeds the reversible value for the xanthate/dixanthogen couple. The flotation response of bornite closely parallels spectrophotometric and electrochemical evidence for adsorption of KEtX by the reactions listed above. The degree of surface oxidation resulting from the formation of iron oxides on the surface dictates the flotation response as evidenced by the fact that oxidized bornite floats at more anodic potentials than unoxidized bornite. The strong correlations between the flotation response, degree of oxidation, and potential indicate that chemisorbed xanthate produces a hydrophobic layer sufficient to float unoxidized bornite, but cuprous xanthate and dixanthogen arc required to float oxidized bornite.

Jan 1, 1988

By G. Deschênes

In an earlier study (Deschênes et al., 2009), gold and silver were shown to be efficiently extracted from samples taken from the Kupol Mine in Russia using lead nitrate in a cyanide leach system. In the current study, a com-parison of the technical and economic merits of a new technology called CANMET enhanced leaching process (CELP) was made with the cyanidation/acidification-volatilization-recycling (AVR) process using eight metal-lurgical variability samples, as well as a large composite sample, which was to represent the initial two years of Kupol mill feed. The composite sample leach feed assayed 33.4 g/t Au and 289 g/t Ag. The metallurgical results from the large composite sample demonstrated that CELP produced very similar gold and slightly higher silver leach extractions compared to the conventional cyanidation/AVR leach conditions at 1/2 the cyanide concentra-tion (1,000 ppm NaCN in CELP vs. 2,000 ppm for cyanidation/AVR leach conditions). It was estimated that the total cost per ton was approximately the same for the two technologies (total cost of CELP with the use of Merrill-Crowe at $46.48/t, with cyanidation/AVR at $46.13/t). However, the implementation of CELP would eliminate a capital expenditure of approximately $5 million for an AVR system based on a 2005 feasibility level cost estimate. Eight variability samples used to confirm the composite sample results showed that, on average, the gold leach extractions with CELP and the conventional leach conditions were very similar, but the average silver leach extraction was 2.1% higher for CELP. Furthermore, CELP silver leach extraction was 4.6% higher on average compared to conventional cyanidation for the four mid-grade variability samples evaluated. The decision was made to remove AVR cyanide recovery from the flowsheet and implement CELP at Kupol. The ability to use the conventional leach equipment with CELP and simplify the flowsheet was also a factor, given the remote location of the Kupol Mine.

Jan 1, 2010

By Richard R. Klimpel

This paper summarizes the author's laboratory and industrial experiences in designing and evaluating frothers for optimal coal flotation circuit performance. The key variables discussed are particle size distribution hydrocarbon addition rate, frother chemical structure, and frother dosage. A number of detailed examples will be used to illustrate the important rare/recovery/selectivity interactions that can occur.

Jan 1, 1995

By K. N. Han

The kinetics of gold dissolution in iodide solutions with oxygen in an autoclave was investigated. The leaching process was described by a gas-liquid-solid heterogeneous reaction. The effects of stirring speed, temperature, oxygen partial pressure and lixiviant, concentrations on the overall leaching rate was investigated. It was found that the dissolution of gold could be represented by a heterogeneous chemical reaction. Under the conditions studied, the apparent activation energy ranged from 34.7 to 54.3 kJ/mol. Experimental findings were in good agreement with the kinetic model proposed.

Jan 1, 1998

By P. V. R. Bhaskar Sarma, P. K. Sahoo, G. Roy Chaudhury

A process was developed to treat an ammoniacal leach liquor containing zinc using Di (2-ethyl hexyl) phosphoric acid (D2EHPA) as the extractant. The objective of this work was to develop a process package for the treatment of complex sulfide leach liquors. Zinc extraction could not be carried out directly from the ammoniacal solution in mixer-settler units because of crud formation and low extraction efficiency. After neutralizing the free ammonia with H2SO4, the extraction efficiency was only about 40%, due to the high concentration of (NH4)2SO4. To decrease the (NH4)2SO4 concentration, the free NH3 was steam stripped, and the resultant liquor was subjected to zinc solvent extraction. An extraction efficiency of 98% could be achieved by controlling the equilibrium pH. Stripping studies were also optimized after removing ammonia from the zinc-loaded organic. A continuous 100-hr operation that included extraction, scrubbing and stripping, was carried out successfully.

Jan 1, 1995

By James W. Griffith, Sarah A. Riling

Bituminous coal dust was repeatedly placed into one lung lobe of anesthetized Macaca nemestrina monkeys using a flexible fiberoptic bronchoscope. Radiographs taken at 15 day intervals showed a focal radiographic density after 90 days time when a total of 1 gram of dust had been instilled. The radiographic density progressed slightly in size until 12 months by which time 3 grams of dust had been instilled and the animals were euthanized. At necropsy, the only significant gross lesion detected was the focal black pulmonary lesion located at the dust instillation site. Histologically, the lesion was composed of coal dust laden macrophages located primarily within interstitial tissue and interspersed with a slight amount of reticulum and connective tissue fibers. The distribution of coal dust was limited to the instillation site in the right caudal lung lobe based on radiographic, gross and histologic examination. Bronchoalveolar lavage of both right and left caudal lung lobes was performed 8 times during the 12 month long experiments without significant complications. More macrophages were found in lavage fluid from the right lung than the left, and most macrophages from right lung contained coal dust particles. Based upon a limited physical examination and complete blood count at 15 day intervals the animals remained normal during the experiment. We conclude that the primate lung's response to focal experimental bituminous coal dust resulted in a marked focal increase in pulmonary alveolar macrophages, which can be recovered regularly in high numbers by bronchoalveolar lavage. The model described has significant potential for investigating the pathogenesis of various respirable dust-induced pneumoconioses, for evaluation of new therapeutic approaches, and for refining experimental and clinical diagnostic applications of bronchoalveolar lavage. Key words: Coal Workers Pneumoconiosis, Disease model; Primate, Lung Lavage Fluids

Jan 1, 1991

By Z. T. Bieniawski

In the past 15 years, rock mass classifications have experienced unprecedented development and have emerged as powerful practical methods for assessing ground conditions and tunnel support. Such methods as the RMR System (Geomechanics Classification) and the Q-System have provided many advantages over the classical Terzaghi rock-load method introduced in 1946. These new classifications have found wide applications all over the world but some doubts have been expressed and shortcomings pointed out. The author, who developed the RMR System, takes a penetrating look into the promises and the pitfalls of modern rock mass classifications. He dispels some misconceptions and shows how rock mass classifications can serve as effective and dependable design aids in tunneling.

Jan 1, 1987

By P. Somasundaran, S. E. El-Mofty

A comparison of the IMC Anionic Process and the CLDRI Process, based on pilot plant testing of waste pebble by Jacobs Engineering is presented. Estimated costs for constructing and operating a beneficiation plant utilizing dolomite flotation are given. Research to develop practical flotation processes for removing dolomite from low-grade phosphate rock has been a high priority for the Florida Institute of Phosphate Research. The Institute funded the above pilot plant programs in 1998 and 2000. The Florida Phosphate industry currently deals with the increasing dolomite content of ore reserves by practicing selective mining. Heavy media separation plants installed at two mines to remove dolomite from pebble are not being operated. The flotation separation of dolomite from waste pebble requires that the flotation feed be ground. Grinding liberates the mineral species and produces particle sizes small enough to be floated. Only two dolomite flotation processes, the IMC Anionic Process and the CLDRI Process, have been successfully demonstrated on flotation feed that has not been deslimed after grinding. Deslimed flotation feed, relative to undeslimed feed, has improved flotation performance and reduced reagent consumption. However, for the above mention processes, undeslimed ground feed increases the yield of concentrate because the phosphate desliming losses are avoided.

Jan 1, 2002

By J. D. Miller

Reaction kinetics for gold dissolution in acid thiourea solutions were investigated using formamidine disulfide as an oxidant. For the conditions studied it appears that a surface reaction limits the rate of gold dissolution. The rate was found to be first order with respect to thiourea concentration and half order with respect to the concentration of formamidine disulfide; the apparent activation energy for the reaction was 10.40 kcal/mol (43.40 kJ/mol); and the reaction rate was independent of pH for the pH range 1.0 to 3.0.

Jan 1, 1999

By R. Hogg, T. F. Dumm

Procedures for particle size analysis on respirable dust from coal mines have been evaluated. Using respirable dusts dispersed in a laboratory dust chamber, size distributions measured using cascade impactors have been com- pared with the results of a variety of laboratory sizing methods performed on samples collected on filters placed side-by-side with the impactors. The laboratory techniques included centrifugal sedimentation, laser diffraction/scattering and automatic particle counting. The general agreement among the various methods was very good, with systematic differences which can be attributed to the different definitions of size used. Simple conversion factors have been obtained which can be used to transform the laboratory data to equivalent aerodynamic sizes. Similar comparisons have been made on samples collected in underground coal mines. Again, the results are in quite good agreement although small discrepancies were observed in some cases. These have been attributed to some degree of agglomeration in the airborne dust, leading to slightly coarser apparent distributions in the impactor samples.

Jan 1, 1987

By P. H. Lu, M. J. DeMarco, J. R. Koehler

Beginning in late 1985 and continuing through 1987, US Bureau of Mines personnel investigated longwall chain pillar and entry design in two and three-entry gateroad systems at a deep underground coal mine in central Utah. To evaluate their respective stability characteristics, four chain pillars and two longwall panels within the two separate entry systems were instrumented with Bureau hydraulic borehole pressure cells to continuously monitor vertical and horizontal pillar and panel stresses through adjacent panel retreat. In addition, supplemental entry closure information was obtained from sites located in the vicinity of the instrumented pillars. The findings presented in this report demonstrate the practicality of evaluating mine pillar stability using in situ methods and support three significant conclusions regarding ground control aspects of the investigated two-entry system: (1) Total areal entry loading was considerably less for the two-entry system, as opposed to the three-entry system, (2) a smaller percentage of opened ground in the two-entry system contributed to a marked reduction in rooffalls, and (3) lower areal loading in the two-entry system suggests improved ground conditions when mining the underlying seam.

Jan 1, 1987