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By Rex E. Loesby

The dramatic increase in molybdenum prices from the low of less than $2.50/lb in 1999 to more than $40/lb in 2005 has caught the attention of molybdenum mine owners and exploration project developers. Between 2005 and early 2007, prices pulled back and stabilized within a trading range of $25/lb to $30/lb. This 1,000 percent price increase has motivated most existing producers to expand production and is motivating those with molybdenum prospects to accelerate the development process for earliest possible production. It is still unknown how much new production will come from existing mines, how much production will be needed from new mines if demand continues to grow and how many potential new mines might be available to meet future demand. And of course, the billion dollar question is whether molybdenum prices will remain high, or will they fall back to the low levels seen during the 1980s and 1990s? This article attempts to answer these questions in a way that will help molybdenum project developers and financiers plan for the future.

Jan 1, 2007

By A. P. Gentsch

Commercially mined calcium carbonate is normally found near the surface in the United States. It is nun& either by open pit or underground methods, depending upon its geologic setting. Processing ranges from simple crushing to the more sophisticated ultrafine processes. Intermediate steps are pulverizing, screening, beneficiation, classification, fine and ultrafine grinding, and surface treating. These processes are performed both dry and/or wet resulting in powdered or slurry end products.

Jan 1, 1986

By Alice Blount, F. Patrick Carr

The quantitative evaluation,of quartz and other minerals in acid-insoluble residues from carbonate rocks and other industrial mineral products derived from sedimentary and low-grade metamorphic rocks is difficult. Commonly there are a dozen or more minerals present, and the suites vary from sample to sample. Because of these factors, either the absorption coefficient must be determined on a sample to sample basis or an internal standard must be used. Internal standards in general use are unsatisfactory. For example, [A1203] is often present in product samples because of ceramic grinding elements used in their production; CaF and LiF have peaks which overlap or nearly overlap mineral peaks in the samples. A careful evaluation has shown that magnesium aluminate (synthetic spinel) works particularly well as an internal standard for these types of samples. Not only does it have few, strong diffraction peaks which do not overlap, the peaks are in the same 28 region as the minerals, usually quartz and silicates, for which quantification is desired. Spinel also consists of equidimensional particles without prominent cleavages; this promotes a random orientation of the minerals in X-ray diffraction mounts. In addition, spinel can be used to correct for loss of diffracted-beam intensity due to thin sample preparations which are often unavoidable.

Jan 1, 1991

By F. F. Aplan

Estimations have been made of the tonnage of raw ores and coal treated by various beneficiation processes. The amount treated by gravity concentration is substantially greater than that treated by flotation, with coal representing the bulk of the material treated by gravity means. A discussion is given of the trends and anticipated improvements in gravity methods. Except for the concentration of iron ores, magnetic and elec- trostatic separation processes find their greatest use in the beneficiation of non-sulfide ores. Exciting new developments in magnetic materials and separation process (and, to a lesser extent, in the electrostatic process) indicate a substantial increase in the application of such processes to ores and a broad variety of non-ore uses.

Jan 1, 1989

By F. B. Henderson, D. Bird, P. L. Hauff, E. C. Prosh

A National Aeronautics and Space Administration (NASA)-funded project (NASA Grant #NAG13-02026) is underway to determine the ability of hyperspectral remote sensing to map mineralogy that affects water quality within a watershed and to identify the relative contributions of natural and anthropogenic sources to that drainage. Natural sources, particularly areas of pyritic hydrothermal alteration, have been found by the Colorado Geological Survey to be a significant source, sometimes the only source, for acidity and/or metals in a number of areas of Colorado (Neubert, 2000). This situation undoubtedly occurs in many places in the Western United States and elsewhere where metallic mineralization occurs. Anthropogenic sources arise from mining and other human activities that increase the exposure of acid-generating materials to weathering processes, thereby increasing acidity and metal loading to drainages where that activity is occurring or has occurred. This project is attempting to determine if these sources can be differentiated through mineralogical analysis, in conjunction with surface water chemistry that controls the precipitated minerals, of the impacted drainages by remote sensing techniques.

Jan 1, 2003

By F. H. Muge

The problem of how to handle heterogeneous populations in an ore reserve global estimation arises in many geostatistical studies. In some cases it is possible to split data into different significant types of ore in such way that non-overlapping subpopulations are obtained, and a separate study is possible. In other cases the subpopulations are intermingled and a set of nested structures may model the spatial variability of the ore. Finally, one of the populations, consisting of a small proportion of high grade values of economical meaning, may disturb the structural analysis. In this paper, some methods are proposed to cope with these kind of problems and typical case studies are presented.

Jan 1, 1986

By Richard H. Adams

INTRODUCTION With the discovery and depletion over the years of near surface ore bodies, exploration targets are tending to be at greater depth or overlain by various types of overburden which in some cases extends to considerable depth or is heavily water bearing. Access to these types of deposits for exploration and development often requires vertical shafts. This paper discusses the concept of small shaft engineering and construction, primarily for underground exploration but also for use as a low tonnage production facility or for mine ventilation. The option of a small shaft may be attractive in a number of cases, some of which are: The underground exploration of a deposit at depth where minimal expenditure is desirable until the potential of the deposit has been determined. The exploration shaft in many cases later serves as a ventilation way and second means of egress. Production of ore in a small tonnage/high-grade operation where decline access is impractical. For ventilation where other types of openings are impractical or would delay start-up of mine operations.

Jan 1, 1987

By Ian J. Duckworth, Pierre F. X. Mousset-Jones

A detailed heat flow project was conducted at the Homestake Mine in Lead, South Dakota. This paper presents results obtained from a stope sensor system installed in the mine. The design and installation of the system are described in detail in a previous paper (Duckworth et al., 1992). The major project objective was the construction of a comprehensive heat flow data base to allow the design and testing of a new climate prediction model applicable to irregularly shaped underground excavations in non-homogeneous surrounding rock types. A mechanized cut-and-fill (MCF) stope contributes a substantial overall heat source in a mine, and the effect of this source on the working environment must be considered when planning future ventilation and refrigeration requirements. The relative magnitudes of the component heat sources encountered with the MCF mining technique are presented, having been computed from actual stope beat flow data collected over a one-month study period. The percentage of the overall heat load that is removed from the scope for each component heat sink is evaluated, and the overall energy balance is analyzed. A one-month study length was considered a sufficient period of time to allow stope monitoring for a complete range of mining conditions.

Jan 1, 1993

By T. B. Whitmoyer, J. E. Sneckenberger, M. A. Jerabek, C. F. Stanley

The measurement of acoustic impedance at frequencies up to 6,400 Hz has been proposed as a diagnostic tool to yield more detailed information about lung condition. A three generation branching system of plastic Y-tubes has been constructed. The impedance of the branched system is measured by an impedance tube using the two-microphone technique. The impedance spectrum is used to calculate the reflection coefficient spectrum, which is converted to an impulse response by an inverse FFT. The area function is extracted from the impulse response by the Ware-Aki algorithm. Measurements of acoustic impedance of the branched system were made for several different end conditions of the eight terminal outlets. The outlets were either blocked with modeling clay, plastic packing material, or aluminum blocks or were unblocked. Six measurements were made of each configuration. In general, the more outlets blocked, the larger the shift to the right of the impedance magnitude peaks for frequencies above 3000 Hz. The impedance magnitude peaks for the plastic packing material were shifted in frequency to the right relative to the peaks of the other system terminations. The impedance magnitude peaks for the clay and aluminum system terminations were significantly different in magnitude but not shifted in frequency. The area functions at the end of the branched system were significantly different (a > 99%) for most of the end conditions. Area functions for the modeled branched lung systems between the end of the impedance tube and the termination outlets of the branched system were similar but distinctively different for the various end conditions. These results indicate that the two-microphone technique can sense small changes in the terminating end conditions of a rigid system of branched tubes and thus may sense impedance changes due to lung disease in the conducting airways. Keywords: acoustic impedance, lung model, area function.

Jan 1, 1991

By J. R. Parga

Bacís mining is a young enterprise in Mexico that produces a pyrite concentrate rich in gold and silver. When gold and silver are associated to sulfide minerals, pre-treament such as: roasting, pressure oxidation and bioleching, is required to decompose the sulphides and thereby expose the gold and silver particles to the cyanide solution. A novel method demonstrates that the oxidation and dissolution of gold and silver in alka-line cyanide solution can be conducted simultaneously in the same autoclave in less than 90 minutes with a recovery that exceeds 96%. Factors affecting recovery efficiency such as pH, leaching time in the reactor, temperature, particle diameter, pressure, % of NaCN and pulp density were investigated.

Jan 1, 2007

By Jeffrey D. Swanson, Martin L. Smith

Smelterville Flats in Idaho's Silver Valley has been designated as a Superfund site due to metals contamination resulting from the use of the South Fork of the Coeur d'Alene river as a tailings impoundment earlier in this century. Tailings average in excess of 4% lead and zinc. Selective mining of highly contaminated zones is being studied as one of several possible remediation strategies. The first step towards remediation is the examination of the stratigraphic, geochemical and spatial characteristics of the site. These characteristics are related to appropriate sampling protocols and exploratory sample grid design. Special problems involved in the geostatistical analysis of tailings are emphasized.

Jan 1, 1992

By Fathi Habashi

THE UNIT process of adsorption involves two steps: 1) Loading of the adsorbent. 2) Recovery of metal values from the adsorbent. Charcoal is the adsorbent commonly used in extractive metallurgy. The discovery of the adsorptive power of charcoal from solutions is generally accredited to Lowitz (1785), who observed that several dissolved organic substances were precipitated on charcoal. Graham was the first to demonstrate that inorganic substances were also adsorbed on charcoal. In 1830, he reported that iodine dissolved in KI solution was adsorbed on charcoal. Also calcium ions were adsorbed from limewater, as were lead ions from lead nitrate solution. The use of charcoal in metallurgy was first applied

Jan 1, 1970

By H. EI-shall

Bench top centrifuge is used to study the consolidation behavior of phosphatic clays. A mathematical model (based on first order kinetics) is developed to describe the relationship between the void ratio (at any time) and the effective stress. Permeability of the sediment as a function of the void ratio is also described. The obtained data are compared with that obtained by other consolidation testing methods. Centrifuge results indicate that consolidation data may be developed in a short period of time (hours) as compared to days or weeks when other techniques are used.

Jan 1, 1995

By D. A. Rice, R. G. Swanton, A. May, O. C. Carter

As part of a cooperative effort between the US Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input from the phosphate industry, the conversion of phosphogypsum to sulfur is being investigated. The proposed process incorporates a thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to ammonium bisulfide (NH4SH), which is then oxidized using a catalyst to produce elemental sulfur. The paper summarizes the results of continuing laboratory studies using an activated carbon catalyst which was loaded with sulfur through oxidation of ammonium bisulfide solution. The extraction of the sulfur that forms in situ on the catalyst is a key area in the development of the sulfur recovery process. Two approaches for removing the sulfur are being investigated: (1) thermal treatment to volatilize sulfur. and (2) leaching the sulfur using liquid anhydrous ammonia. The research has shown that it is technically feasible to recover over 90% of the sulfur from the carbon by either volatilization or ammonia leaching. Locked cycle testing has demonstrated that the carbon has the potential to be recycled after ammonia leaching.

Jan 1, 1987

By J. G. Groppo

Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 pm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This study is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The main focus of the pilot plant study was on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process.

Jan 1, 1997

By BHAMIDIPATI S. SASTRY, KATTAMURI PAVAN KUMAR, ADITYA PANDEY

Several laboratory methods are available to determine the thermal conductivity of rocks, but most of them are complex and cumbersome. The present study explains the working principle of Lee’s apparatus, which is relatively simple, easy to fabricate and use, and provides consistent results. In the present study, thermal conductivities of sandstone cores obtained from an Indian coal mine are determined using Lee’s apparatus. An approach is discussed to determine the temperature gradient of sandstone specimens while cooling and is used to calculate thermal conductivity. The thermal conductivities of different sandstone specimens have values between 2.37 and 2.59 Wm−1°C−1. For different sandstone cores obtained from the field, properties including specific gravity, specific heat capacity, thermal diffusivity and porosity, along with thermal conductivity, were determined and highlighted in this study.

By Jan Wolski, Jack Barry

Ventilation ductlines with a single fan or with a series of fans are analyzed. The duct friction loss factors are discussed. Numerical solutions, presented in the paper, applies to any fan number and locations along a duct line. The findings are compared with formulas available in the technical literature. Values of the air leakage factors are presented in the SI, technical metric, and US unit systems. A method is shown of how to determine the leak- age factor for a given ductline. Optimum solutions for the sample duct lines with two and five fans in series are discussed and presented in a graphical form. Performance of fans in series is discussed in conjunction with both friction pressure loss and leak- age.

Jan 1, 1997

By R. Karl Zipf, Z. T. Bieniawski

Based on the premise that understanding the fundamental mechanics of fine fragment formation in coal will lead to reducing coal dust problems in mines, a thorough study of the mechanics of crack propagation in coal was undertaken. Two approaches were considered in an attempt to understand and quantify the fracture process as it relates to fine fragment formation. In one approach, theoretical models are used which describe the size of the fracture process zone which may relate to the amount of structural damage and fine fragment formation on the new crack surface. The other approach is based on the relationship between crack tip stress intensity and new surface appearance for mixed mode crack propagation. Preliminary observations with a scanning electron microscope support the premise that fine fragment formation is related to fracture surface appearance and fracture initiation conditions. An experimental program designed to supply the input parameters for these approaches is presently underway. The experimentation features mixed mode fracture toughness testing, using a special mixed mode testing rig, and fracture velocity measurements with a crack propagation gage. The interpretation of this data via the approaches discussed will provide further under- standing of the mechanics of fine fragment formation in coal.

Jan 1, 1986

By Charles Schmidt

Phalabonva (Figure 1) is situated in the northern province of South Africa adjacent to Kruger National Park, about 500 km from Johannesburg. The nearest South African port to Phalaborwa is Richards Bay about 700 km distant by rail.

Jan 1, 1999

By W. J. Miles

At the beginning of the 20th century, barite was a mineral of minor importance in the USA. Its primary use was to extend lead oxide in white paint. Barite also added the special qualities of hiding power and flatness to paint. Because white lead sometimes turns black or yellow and barite does not, ground barite became a pigment on its own merit. Barium chloride was added to bricks before firing to stop efflorescence when exposed to weather. Barium carbonate or nitrate added luster and brilliance to glass. Barium chemicals were added to refining sugar, enameling iron, making oilcloths and paper collars, and in the manufacture of paper, artificial ivory, rubber and lithopone. Lithopone became a major paint ingredient in the 1920s; its use lasted until the 1950s, peaking at 150,000 metric tons of barite in both 1937 and 1947 for the manufacture of lithopone. Later in the 20th century, titanium dioxide replaced lead oxide, barite and zinc oxide in the coatings industry. In the 21st century, barite is used as a filler, extender, or weighting agent in products such as paints, plastics, and rubber. Some specific uses include its use in brake and clutch pads for automobiles, automobile paint primer for metal protection and gloss, add weight to rubber mud flaps on trucks, and add weight to the cement jacket around petroleum pipelines under water. In the metals casting industry, barite is part of mold release compounds. Because barite significantly blocks X-ray and gamma ray emissions, it is used as aggregate in high density concrete for radiation shielding around x-ray units in hospitals, nuclear power plants, and university nuclear research facilities. Ultra-pure barite consumed as liquid is used as a contrast medium in medical X-ray examinations. Barite is the raw material for barium chemicals, such as barium carbonate, which is an ingredient in faceplate glass in the cathode-ray tubes of televisions and computer monitors. In the 21st century, barite industrial uses account for an estimated 78,000 tons per year in the United States. Another barite use was patented in 1926 by the oil industry. In this patent, barite is primarily used as a non-abrasive weighting agent for drilling for oil and gas exploration and production. As a weighting agent, it provides the downward force in a water based or oil based drilling fluid for cutting through rock with a tri-cone diamond drill bit. In order to minimize the wear on the drill bit and drill stem, minimum abrasion of the weighting agent is preferred. In recent years in the USA, 95% of the barite produced and about 80% on a world basis are used as a fluid weighting material during the search for oil and gas. During the latter part of the 20th century, barite was used in the drilling mud of oil and gas wells, particularly for wells deeper than 2000 meters, and petroleum well drilling demand for barite became the mineral?s major end use during economic expansions after World War II and subsequent increased use of oil and gas in the USA. The profitability of oil and gas production had a strong effect on the number of drill rigs and consumption of barite. The United States was the leading petroleum well drilling country starting in 1970, reaching 4,530 drill rigs in December 1981, and was the largest consumer of barite. In the USA, record highs of about 2.6 million tons of barite produced and 4.3 million tons consumed were reported in 1981. From 1997 to 2006, barite production declined from 662,000 to 589,000 metric tons. However, USA imports increased from 1,470,000 to 2,530,000 metric tons for lump barite. World production of barite increased from 6,780,000 to 7,960,000 metric tons during the same period. Table 1 (see Appendix) lists USA production, imports and exports and world production from 1997 to 2006. Major sources of imported barite include China, India and Morocco. Table 2 (see Appendix) lists the USA imports and price of barite by country. China, India and Morocco are the three largest exporters of barite to the USA and the world. Vietnam is a new producer, beginning in 2006. IMPACT OF CHINA ON DRILLING GRADE BARITE In the 1970s or before, China began supplying barite to the world drilling market in order to help develop their economy. When China first entered the barite export market, their high production volume, low pricing and low ocean transport expenses to the Gulf Coast forced barite producers in the USA to supply only regional markets, such as Battle Mountain Nevada barite for the western and Rocky Mountain states and Canada. Until recently, it was China?s government policy for domestic consumers to use barite below the API 4.20 specific gravity specification, leaving higher grades for export, but this is no longer the case. In recent years the internal demand for barite in China increased tremendously as their economy rapidly developed. China reduced their former 15% VAT tax rebates to 5% for Chinese barite producers, and then eliminated all VAT tax rebates on December 15, 2006. On the supply side, some high-grade barite deposits in China have been depleted. In particular, the low heavy metals sources are less plentiful. Additional mine capacity is being developed, but the new mines are underground and therefore costs will be higher. China?s appetite for other raw materials has tied up a large portion of the world?s bulk vessel fleet, including Panamax vessels (preferred for barite ore transport). Ocean transport freight rates have increased in recent years, and receiving ports in the USA are congested with imports of higher-added-value products. The Panamax Index, which tracks maritime shipping rates, more than doubled in 2006. China has also devalued its currency from RMB8.30 to RMB7.80 per dollar. These factors are driving up the import price of crude and ground barite for drilling. In addition, in the USA, rail congestion and high fuel prices led to higher trucking rates, increasing the delivered cost of ground barite to oil customers. India is the second largest supplier of crude barite to the USA and world drilling market. It produces all of its barite from a single deposit in the Cuddapah region of Andhra Pradesh State. More than 90% of production comes from the State-owned Andhra Pradesh Mineral Development Corp., and the government continues to closely control production, export volumes, and prices. India saw a dramatic increase in barite prices as a result of its last 3-year tender in 2004. However, in 2004 and 2005 their shipments of crude barite to the USA were not significant. In 2005, India began supplying barite pulverized to meet API specifications to the Gulf Coast. In 2006, Indian production was reduced owing to severe flooding in November 2005 that curtailed mining until mid-April 2006. Morocco has been the third largest supplier of crude barite to the USA and world drilling market. In 2003 and 2004 their shipments of crude barite to the USA were not significant. In 2005, Morocco resumed shipment of crude barite to the Gulf Coast and began supplying barite ground to meet API specifications to the Gulf Coast.

Jan 1, 2009