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By E. J. Beckman, R. M. Enick, C. Powell

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic platinum group metal complexes from an aqueous phase. However, because conventional extractant-metal complexes are not soluble in liquid carbon dioxide, this can be achieved only if highly carbon dioxide-soluble extractants are developed. For example, trioctylamine-gold chloride is not soluble in liquid carbon dioxide, although trioctylamine is CO2 soluble. The novel CO2-soluble extractants presented in this paper have a CO2-philic fluorinated tail to enhance solubility and a conventional amine head group for extraction of metals. Both the extractant and the extractant-metal complex are soluble at ambient temperature at pressures from 7 to 35 MPa. Efficiency factors as high as 2.23 have been measured using 1,1,2-trichlorotrifluoroethane (TCTFE), a low pressure screening liquid for carbon dioxide, indicating that these compounds will strongly bind the metal chloride. For example, 84% of Pt-chloride was extracted into TCTFE using a 3.5:1 ratio of a double¬tailed fluoroalkyl amine extractant: metal chloride. An 88% recovery of Pt-chloride into high-pressure liquid carbon dioxide was achieved using the same extractant at a 3.5:1 ratio. Therefore, it appears possible to replace organic solvents with liquid carbon dioxide during the extraction of platinum chlorides if highly carbon dioxide-soluble extractants agents are employed.

Jan 1, 2002

By C. H. Rawlins

The total amount of ferrous slag generated in the U.S. is about one-third the amount of iron ore mined, thus ferrous slag can be considered a significant mineral body for processing. Steelmaking slag contains up to 30 wt.% metal of which only the >25mm fraction is commonly recovered. A grinding study was conducted of BOF, EAF, and LMF slags using the Bond Work Index method to determine grindability to 106µm. Work Index values obtained were 13.8-24.9 kWh/ST, depending upon the slag type and composition. Steel particles were magnetically recovered from the crushed and ground samples for size-by-size analysis, yielding up to 18 wt.% of the slag weight recovered as magnetic. The recovered material, as characterized by inert gas melting, was found to be 61-96 wt.% metallic.

Jan 1, 2008

By G. Rinelli, Arthur F. Colombo, Donald W. Frommer

With the opening of the Tilden mine near Ishpeming, MI, a new era in iron ore beneficiation was begun. A description of a U. S. Bureau of Mines investigation is summarized to illustrate the selective flocculation-deslime-flotation process developed by the Bureau and used at the Tilden concentrator, which is also briefly described. The operating parameters for the selective flocculation-cationic flotation of an oxidized taconite from the Mesabi range are discussed. A water reclamation system using lime and a cationic flocculant was applied to reclaim the effluents from a 900-pound-per-hour flotation pilot plant. About 80 percent of water requirements were recovered, and the calcium content of the reclaimed water was found to be more important than clarity in influencing the selective flocculation and flotation processes. Although reclaimed waters with about 10 ppm calcium registered turbidities of approximately 5,000 ppm SiO2 equivalents, the concentrates produced using these waters contained 64 percent Fe and =5.0 percent SiO2 and had accompanying iron recoveries of 75 percent. Lower grade concentrates resulted from using reclaimed water with higher calcium contents and lower turbidities.

Jan 1, 1976

By Louis J. Trostel

Refractories, called the Hidden Industry by The Refractories Institute, provide the temperature and chemically resistant linings for the multitude of vessels that are used today in high temperature processes ranging from giant iron-making blast furnaces to industrial incinerators to petrochemical cracking units to the smallest furnaces used by the jewelry trade. While these refractory linings are absolutely essential to the proper functioning of these processes, the linings are almost always on the inside of the vessels and thus hidden from the eyes of the public. Refractories are defined in Standard C71 of the American Society for Testing and Materials (ASTM), titled "Standard Definitions of Terms Relating to Refractories," as "nonmetallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above 1 000°F (538°C)." This criterion of ability to withstand exposure to environments above 538OC is the critical distinction separating refractories from other ceramics, fibers, and coatings applicable only at lower temperatures. In addition to resisting temperature, the refractories must with- stand abrasion, chemical and slag attack, resist thermal shock, and carry sustained structural stresses at high operating temperatures for as long as years. The most common methods of classifying refractories are by forming method and composition. First are the traditional formed and fired bricks, batts, and the associated multitude of special shapes. These refractories are usually formed at room temperature, dried, and then fired to high temperatures to develop the final properties desired. Other formed refractories are chemically bonded or resin or tar bonded. To complete the formed refractory matrix, some fired refractory bricks and shapes are subsequently impregnated with resins or tars. Physical dimensions of these formed refractories are classified into two general categories: standard sizes and special shapes. The standard sizes are those in common usage in the United States described in ASTM Standard C909 "Dimensions of a Modular Series of Refractory Brick and Shapes" based on the 38 mm basic module as described in ASTM Standard C861 "Determining Metric Dimensions of Standard Series Refractory Brick and Shapes." The most common size is the "9-inch straight" 228 x 114 x 64 mm (9 x 4 ½ x 2 ½ in.) of the "2 ½ -inch" series or 228 x 114 x 76 mm (9 x 4 ½ x 3 in.) of the "3-inch" series. Bricks of nonstandard sizes are referred to as special shapes. Their use is required in specific furnaces for particular requirements or applications. In addition there is the large and growing group of refractories sold as unshaped mixtures that may be formed into their final shapes at the application site. These unshaped mixtures are sometimes referred to as specialties. The mixtures are prepared to be hydraulically cast, plastic or wet rammed, dry rammed, or dry vibrated into their final shapes. Some are designed to be projected through nozzles (or gunned) onto their forms. The refractory mortars used to lay up the shaped refractories fall into this group referred to as specialties. Prepared refractory grains also are sold. These are usually calcined or fused materials that are subsequently crushed and sized to a variety of specific carefully controlled grain sizes or size distributions. These grains include calcined fire clay, dead burned magnesite, periclase (fused magnesia), dead burned dolomite, kyanite, tabular and fused aluminas, fused zirconia, fused mullite, and calcined alumina-magnesia spinel. The primary composition groups of refractories are the 1) alumino-silicate refractories made largely from fire clay and high- alumina materials, 2) silica refractories made from quartzites and ganisters, and 3) basic refractories from magnesia (or magnesite) and chromia (also referred to as chrome ore), alone and in combination, and dolomite. Special refractories include carbon, zirconia, zircon, high purity alumina, mullite, silicon carbide, silicon nitride, and some borides. In addition there are groups of special insulating refractories.

Jan 1, 1994

By Eung Ha Cho, Olufemi Olajide

A laboratory study of dense-medium cycloning with Redstone seam coal has been conducted. The investigation was performed using a 203 mm (8 inch) Heyl-Patterson dense-medium cyclone. Two underflow orifices of 31.8 mm (1.25 inch) and 44.5 mm (1.75 inch) in diam were used. The effects of feed pressure and particle size were determined on the cycloning performance. In addition, the cyclone performances with coal-rich and refuse-rich samples were also investigated. The results of the experiments were analyzed using basic hydrodynamic principles. The increase in the feed pressure increases the specific gravity of separation (defined as the specific gravity of a particle which has an equal chance of reporting to either the overflow or underfow) for both underfow orifices. The specific gravity of separation increases as the particle size decreases with the smaller underflow orifice. However, an opposite relationship has been observed with the larger under flow orifice. The separation becomes sharper with the smaller under flow orifice than with the larger underflow orifice especially for fine material. Also, the separation becomes sharper with an increased feed pressure for a coal-rich sample. However, this effect is less significant for a refuse-rich sample. This means that a high feed pressure is required for a coal-rich sample to maintain a good separation. It also means that applying a high feed pressure provides a good separation regardless of the type of feed coal in terms of ash content in the solid.

Jan 1, 1990

By İlknur Erol

The abstract highlights that hearing loss is an occupational disease caused by noise exposure in the workplace. The study investigates noise-induced hearing loss among miners in underground coal mines in Turkey, considering factors like occupation, age, and exposure time. The research employs logistic regression analysis to reveal the relationship between hearing loss and these factors. The findings suggest that occupational groups and duration of noise exposure significantly affect hearing loss. Miners in production groups and those exposed to noise for 10-14 years have a higher risk. The study concludes that age does not significantly increase the probability of hearing loss.

Mar 24, 2022

By S. Vijayan

Despite the limited demand for rare-earth elements, as well as yttrium and scandium, in conventional applications, the emergence of ne~ high-technology applications such as supermagnets, lasers and superconductors is expected to result in significant demand for some of these elements. This paper examines the anticipated applications and demands for rare-earth elements over the next decade and their implications on the utilization of available resources. Process methods for the recovery of rare-earth elements from conventional and unconventional resources are reviewed in the context of their growing demand. Challenges facing the industries in meeting this opportunity are also discussed.

Jan 1, 1988

By W. Kuckshinrichs

Metallic raw material flows are characterized by a complex global network of producers and consumers, as well as by a multitude of ecological, economic and social impacts across national boundaries and on different scales. This leads to the need to develop methodologies, which allow identifying obstacles that prevent metallic raw material flows to contribute to sustainable development. From a scientific point of view CRC 525 (Martens 2003) has developed an holistic indicator set consisting of approximately 80 different indicators. This set is taking into account the multi-dimensional character of sustainable development. Moreover the indicators reflect different system boundaries according to different actor levels and decision contexts. The full indicator set is important in scientific considerations and suitable for scientific awareness creation. However, to fulfil the function of a decision support approach for political and economic decision-makers some modifications are of central concern. At first a reduction of the full indicator set by selection of core indicators enables decision-makers to deal with complex issues of contrary economic and societal protection targets. Secondly, as thresholds of indicators justify societal call for action, they are discussed against its political or scientific origin. The proposed methodology is exemplified by indicator-based studies of the material flow of aluminium.

Jan 1, 2003

By J. A. Hrabik

The feasibility of mining deep phosphate deposits by a borehole mining system was compared with mining by proven conventional techniques. An economic comparison of the borehole mining system with conventional dragline and bucket wheel excavator mining systems was completed at various mining depths and production rates. Hypothetical phosphate deposits, with various overburden thicknesses and reserve tonnages, were defined. Geologic conditions necessary for the application of the borehole system were identified. Discounted cash flow analyses based on derived capital and operating costs were used to generate rates of return and product prices. Borehole mining was found to be more economical where overburden thickness was 46 m (150 ft) or greater. However, at 15- and 30-m (50- and 100-ft) thicknesses, conventional surface mining was more economical. Overburden thickness has a great effect on the economic feasibility of the conventional mining systems but less effect on the economics of borehole mining. Economies of scale are only realized in conventional mining, since larger equipment is used to achieve greater production, whereas increased production from borehole mining is achieved using additional equipment units. A comparison of the environmental effects of borehole and conventional surface mining systems showed that borehole mining is environmentally more desirable.

Jan 1, 1987

By Kallam V. K. Reddy, VADAPALLI SANJANA, Veerendra Singh, Gajanan Kapure

This work describes a leaching process for the conversion of high-magnesium peridotite rock, which is a chromite ore overburden, into two valuable products: magnesium salts and micro silica. Under normal leaching conditions, residue remaining after leaching is of a gelatinous nature and thus hinders the filtration process. To address this issue, oxidative leaching with the addition of H2O2 was employed, and it significantly improved the filtration kinetics. Four different approaches for H2O2 addition were tried, and they all proved effective in controlling gelation. The optimum oxidative leaching condition was 70 °C, 2 h time, 2 M H2SO4, 0.5MH2O2 and 400 RPM; under these conditions, 92% magnesium leaching efficiency was achieved. After leaching, the leach liquor obtained was purified and dried into Mg(OH)2 and MgSO4 salts. The leach residue contained mainly silica particles, with size in the 10–30 μm range. This material thus represents an attractive candidate for the production of highperformance concrete for the construction industry. The oxidative leaching process described here enabled the complete conversion of peridotite into valuable products, magnesium salts and micro silica.

May 5, 2020

By P. R. A. Andrews

Magnesite, brucite and dolomite occur widely throughout Canada, but deposits of economic significance are found only in Quebec, Ontario and British Columbia. Magnesite occurs in all three provinces, brucite in Quebec and Ontario and dolomite in Ontario. Beneficiation of refractory magnesium minerals has been the subject of many investigations at CANMET and the former Mines Branch. Twenty-three magnesite, four brucite and nine dolomite evaluation studies were conducted between 1920 and 1974. A review of some of the more important studies is presented. The information includes mineralogy, beneficiation methods and flotation data.

Jan 1, 1995

By D. A. Barr

The Galore Creek copper deposits lie in the Stikine River district of northwest British Columbia, a largely undeveloped region which possesses rugged mountain terrain with deeply incised valleys which support dense undergrowth. Timberline is normally at about 1300 m (4265 ft) and the higher levels contain glacial systems and large ice fields with peaks rising to 3500 m (I 1,483 ft). A location map of the Galore Creek area is given in Fig. 1. In the late 1920s, field parties under the direction of F.A. Kerr (1948) of the Geological Survey of Canada completed geological surveys of the district. Primary access for this work was provided by riverboats on the Stikine and Iskut Rivers. Kerr's party had to contend with extremely difficult travel conditions that required considerable backpacking, augmented by pack dogs in certain cases. Absence of ground control led Kerr to establish his own topographic maps. Among the geological data established was the recognition [ ] that small bodies of orthoclase porphyry in the district are often well mineralized with base metal sulfides. Copper mineralization in the upper Galore Creek valley, a tributary of Scud River which flows into the Stikine River some 80 km (50 miles) south of the small settlement of Telegraph Creek, was originally discovered during aerial reconnaissance by M. Morrison and W. Buckholz while prospecting for Hudson Bay Exploration and Development Co. Ltd. in 1955. Malachite- and azurite-stained out- crops in several parts of the Galore Creek watershed are clearly visible from distances of 500 m ( 1640 ft) or more. Claims were staked in 1956 and the copper showings were partly mapped, trenched, and investigated by shallow diamond drilling. Because of the remoteness of the area and higher priorities for expenditures elsewhere, no further work was undertaken and most of the claims were allowed to expire.

Jan 1, 1991

By Y. J. Wang

Editor's Note: Y.J. Wang's paper appeared in the September Technical Papers section. There were some inadvertent editorial errors in it. So we are reprinting it here. Abstract - This paper examines the ventilation network problem from a view point of solving a system of B equations in B unknowns, where B is the number o f branches in the network. Based on Kirchhoff s current and voltage laws, the solution to the general ventilation network problem must satisfy B network equations. In this paper, the air quantities and control-device pressures are chosen as variables and are grouped into B dependent variables (unknowns) and B independent variables, resulting in a system of B equations in B unknowns. Based on whether their variables are dependent or independent, the network branches are classified into f our types: five d, non-fixed, p-fixed, and q fixed. The ventilation network problem may include all four types of branches. There are .some conditions under which the problem as defined in this manner does not have a unique solution. To have a unique solution, the Jocabian matrix of the equations m us! he nonsingular. It then follows that: • the number of branches with independent air quantities must be less than or equal to the number of chords with respect to a spanning tree; •the subnetwork of branches with independent air quantities must not contain any cutset; and •the suhnetwork of branches with dependent control-device pressures must not contain any cutset. These three conditions must be met regardless of the values for the variables. In addition to the problem formulation, a solution procedure applying the Newton (or Newton-Raphson) method is outlined and illustrated with an example problem.

Jan 1, 1991

By W. Hoecker, S. Watson

The use of oxygen (Goldox™) in gold leaching has emerged as a significant modification in the past nine years. The Goldox™ process was ori gi na 11 y developed by Afrox Ltd ( part of the BOC Group) and is currently used in South Africa, Australia, Canada and the United States. Although a variety of benefits have been observed with oxygen, this paper out 1 i nes the main ones with reference to Australian plant data. The case studies were categorised into the ore type: Oxide, blends and primary ore.

Jan 1, 1992

By Paul J. A. Lever, Robert H. King

Human operators, geological conditions, equipment changes, mining sequences, and roof conditions are some of the continually changing operating conditions that drive a dynamic mining environment. These dynamic characteristics make it difficult to automatically analyze mining data because attributes change as the mining environment changes. Mine monitoring systems could provide mine managers with much more useful information than they do presently, if automatic analysis were possible. Automatic analysis of sensor data is also key to autonomous mining systems. This paper describes artificial intelligence (AI) and sensor fusion based sensor data analysis techniques developed over the past four years. These techniques were used to classify machine operating events by continuously monitoring machine power usage in a continuous miner section at an under- ground coal mine. The result is a report similar to an industrial engineering time study. First, numerical pattern classification techniques broadly identify operating events. However, domain knowledge about inter-machine and intra-machine interactions is necessary to identify and refine dynamic event boundaries. By implementing AI and sensor fusion based techniques we are able to classify machine events more accurately and recognize more specific events. These techniques could easily be applied to many different mining sensor data applications

Jan 1, 1993

By Dwayne C. Kicker, Duk-Won Park

As the use of longwall mining increases in the U.S.. there is a need to better understand the stress redistribu- tions indicative of this method. To control high stress concentrations, the yield pillar concept has been developed. A physical longwall mine model has been designed to study the effect of yield pillars in deep mining. The model in- cludes sensitive stress measuring devices, a new excavating technique, and a new model material. This study includes the use of both regular and yield pillar systems and has successfully simulated the mode of stress change in chain pillars.

Jan 1, 1986

By J. A. M. Cano

Since the beginning of operations at the pellet plant at Ponta Ubu ES, Samarco Mineração SA has produced pellets for direct reduction and blast furnace processes. Of the total amount of pellets produced from 1977 through 1993, 55% are used in the blast furnace, about 45 Mt (49.6 million st). The principal components of pellet gangue are calcium oxide, magnesium oxide, silica and alumina. They should be added in adequate quantities to guarantee the mechanical resistance of the fired pellets under blast furnace conditions. Over the years, the pellets produced by Samarco had a silica content between 2.5% and 2.8% and varying binary basicity preferably between 0.8 and 0.85. On the other hand, the increasing amount of industrial waste in siderurgical plants caused by the increase of steel production has caused some countries to put into practice methods to reduce the volume of slag produced in the blast furnace. This paper’s goal is to find an alternative for decreasing the amount of slag produced in the blast furnace. It is possible to decrease pellet gangue by decreasing the silica content to about 2%, leaving the metallurgical properties and quality of pellets unaltered. For this work, Samarco pellets were used with SiO2between 2.5% and 2.8%, pellets with high silica and pellets with SiO2 between 2.0% and 2.3% low silica. Both were partially fluxed by the range of varying basicity CaO/SiO2from 0.8 to 0.95 during production.

Jan 1, 1995

By R. V. Ramani

In this paper, the application of the concepts of reliability engineering to the evaluation of longwall system performance is illustrated with data from an operating longwall face. A number of cases are analyzed to highlight the impacts of longwall equipment, geological conditions and outby haulage on systems reliability and availability.

Jan 1, 1988

By Delon Hampton, Francis K. Mensah-Dwumah

INTRODUCTION The state-of-the art in the area of soil-structure interaction is not sufficiently developed that one can accurately predict the earth load distribution on buried structures. This lack of knowledge has led to the use of high factors of safety in their design and conservative assumptions for the loading diagrams. As a step towards the improvement of the design methodology for buried structures, it is important to be able to apply new analytical techniques and monitor the performance data obtained on full-size buried structures. The performance data should preferably include: 1) the actual stress distribution on the buried structure, 2) stress distribution in the buried structure and surrounding soil media, 3) vertical and lateral movements in the soil adjacent to the buried structure, and 4) deflection of the buried structure. Brown (1967), Davis (1972), Krizek, et al (1974), Krizek and MacQuade (1978), and some few others have compared the performance of full-size culverts with finite element results. Despite all these efforts, a complete understanding of the soil-structure interaction problem has not yet been fully achieved. In an effort to make improvements in the existing design procedures for buried structures constructed in an open-cut, the Department of Environmental Services (DES), Washington, D.C., in conjunction with Howard University, undertook a detailed study of Section II of the Capitol Hill Relief Sewer (CHRS). Inclinometers were used to measure lateral movements of the excavation wall and the total normal interface stresses acting on the concrete sewer were obtained using glotzl total pressure cells. This paper describes the results of the field instrumentation program for acquisition of data, their comparison with the design assumptions, and the results of a series of post-construction finite element analyses of the CHRS project.

Jan 1, 1979

By Robert G. Moorhead

Fine-coal screening can be one of the most critical operations in a modern coal-cleaning plant. The yield and quality of clean coal produced in fine-coal circuits is controlled as much by how efficiently 0.15 mm (100 mesh) particles are sized as on the performance traits of the fine-coal cleaning device itself. In addition, the increased interest in effective fine-coal sizing operations indicates that many operators have also discovered its importance in affecting the quality and yield of clean coal produced in fine-coal circuits. This paper describes the three most prevalently used fine-coal screening technologies and discusses their sizing mechanism, performance, and application.

Jan 1, 1988