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By T. Tamagawa, I. Iwasaki, N. X. Fu, M. Kobayashi

A low-temperature-chlorination selective oxidation followed by aqueous chloride leaching and SX-EW for producing electrolytic copper, elemental sulfur and ferric oxide was investigated for hydrometallurgical processing of a chalcopyrite concentrate. In this article, the selective oxidation phase of the process is described. The selective oxidation requires a temperature well above the CuCl-FeCl3 eutectic points. The test procedure was developed with a batch reactor and then tested with a continuous reactor. The process was initiated by adding small amounts of chlorinated samples to a fluidizing bed of dead-roasted sulfide concentrate micropellets. The selectively oxidized samples thus prepared were shown to fully dissolve copper, while virtually all the iron remained undissolved.

Jan 1, 2000

By Milton E. Wadsworth, Ximeng Zhu

Impurity metals can markedly influence the anodic dissolution of gold in the presence of cyanide. Several important findings related to the influence of lead are reviewed and some new observations presented. Based on the effect of pH, the scan direction, and voltage, it may be shown there are three separate voltage regimes where lead influences the anodic dissolution of gold. These are related to Pb°/ HPbO2, Au-Pb /HPbO2, and HPbO2/PbC2; oxidation-reduction reactions which provide low resistance paths for electron exchange. The gold dissolution rate was determined by direct solution analysis and is compared to the rate implied by electrochemical measurements.

Jan 1, 2005

By R. K. Mehta, K. N. Han, P. B. Queneau, V. Dieudonne

A study based on a statistically designed sets of experiments (central composite design) was conducted to determine the optimum conditions for leaching a subbituminous coal (7.0 % ash) from the middle Wyodak seam in mild sulfuric acid solutions. The statistical analysis was conducted with the ash content and ash removal as the dependent variables and with the coal loading, acid concentration, ferric ion concentration, and temperature as the independent variables. Treatment of the experimental data via a simple genetic algorithm (GA) revealed that acid concentration and temperature are the two most critical variables. Unlike the case with bituminous coal, the ferric ions addition shows no beneficial effect. The optimum "macro response" predicted by GA was verified experimentally; the ash content was reduced to 2.7%, which is close to the value predicted by GA. The ash content was further reduced to 1.7% in a two-stage leaching process devised by incorporating the optimization results with that of leaching kinetic studies.

Jan 1, 1993

Surface characterization techniques, i.e. contact angle measurement, atomic force microscopy (AFM) surface force and surface imaging measurement, were applied to investigate the molybdenite surface in aqueous solution. It was shown that the cleaved basal surface of molybdenite was very hydrophobic with a 92 degree water contact angle. The non-polar component of the solid surface free energy is 50.52 mJ/m2 while the polar components are almost zero. The solid surface was not reactive and was only weakly charged at the pH 6. When the aqueous media changes from water to 1×10-4 M KEX solution, the measured contact angle, adhesion force and surface roughness all increase slightly. However, ethanol rinsing made the surface change back to the bare substrate. It was suggested that the hydrophobic chemical, i.e. dixanthogen, which was shown in the morphology of patches by the AFM image, physically adsorbed on the hydrophobic molybdenite surface through the hydrophobic interaction.

Jan 1, 2009

By W. K. Collins, C. L. Dahlin, D. C. Dahlin, W. K. O’Connor, G. E. Rush

Direct mineral carbonation has been investigated as a process to convert gaseous CO2 into a geologically stable final form. The process utilizes a slurry of water, with bicarbonate and salt additions, mixed with a mineral reactant, such as olivine (Mg2SiO4) or serpentine [Mg3Si2O5(OH)4]. Carbon dioxide is dissolved into this slurry, resulting in dissolution of the mineral and precipitation of magnesium carbonate (MgCO3). Optimum results have been achieved using heat pretreated serpentine feed material and high partial pressure of CO2 (PCO2). Specific conditions include: 155°C; P002=185 atm; 15% solids. Under these conditions, 78% conversion of the silicate to the carbonate was achieved in 30 minutes. Process mineralogy has been utilized to investigate the appropriate feed characteristics, identify the process products, and interpret the mineral dissolution and carbonate precipitation reaction paths.

Jan 1, 2001

By Zhang You-di

A comprehensive model has been set up for surface mine long range planning. It is a system simulation model based on the oriented graph theory. Via this model, a series of mining results such as mineral and waste volume, mineral quality, mining intensity, material haulage distances, dumping area parameters and mining coat for different mining alternatives, can be derived and optimized. This model has been applied to 37 mining alternatives in several surface coal mines and proved mathematically correct and results reliable.

Jan 1, 1986

By Terry Mudder

Long-term anaerobic biochemical treatment for draindown of residual solutions is a cost-effective way to close a heap-leach pad. This article presents a laboratory evaluation of anaerobic biochemical treatment of cyanide heap-leach pad solutions. The traditional approach to heap-leach pad closure is to rinse the pads with multiple pore volumes of fresh or recycled treated water. The effluent from an initial rinse is often treated and recirculated until the solutions passed through the heap meet the appropriate numeric and narrative water quality standards. Column rinsing tests are completed during project planning to determine the number of pore volumes of fresh or recycled treated water required to rinse the pad to meet long-term closure requirements. A traditional closure plan generally includes provisions to sample the rinse effluent and rinsed solids (the Meteoric Water Mobility, Procedure or USEPA 1312) to verify that chemical requirements are being met.

Jan 1, 1995

By S. C. Suboleski

Underground long-range planning and mine design is an iterative process beginning with a specified production level, quality criteria, and geology of the deposit. Given these factors, face equipment is selected, the number of units needed and production per unit are calculated, and the mine infrastructure needs are developed. The scheduling of units then follows, with the design of the various support systems coming next. The support systems needed to maintain production can be grouped as follows: (1) outby haulage of mined material, (2) supply and manpower haulage, (3) ventilation and associated environmental considerations, (4) drainage, fresh water, and related considerations, (5) rock mechanics, and (6) power, supply. Thus, long-range planning may be viewed as a three-tiered structure, with the data on required production, product quality, and geology at the upper level; the development of face production capacity and the scheduling of units sufficient to meet the needs of the first two at the second level; and the development of support operations for the production units at the third level. Changes at any level may affect not only the items on that tier but may also cause a change to the items on the tier above and below. For example, if the rock mechanics data indicate that desired opening sizes will not be stable, then this situation will affect not only the ventilation design but also the production rate and possibly the selection of equipment itself. These, in turn, may affect the scheduling of units and the number of units, ultimately influencing the entire third tier of systems.

Jan 1, 1979

The main goal of this paper is to present readers with recommendations for choosing coaxial cables appropriate for mining applications of Time Domain Ref 1 ectometry (TDR) to monitor rock mass movements. Prior to discussing the recommendations, mining applications are illustrated with examples and the operating principle of TDR is discussed briefly. Items that affect the result of the monitoring system performance include the coaxial cable selected, the grouting material used, and the installation procedure.

Jan 1, 1986

By Peikun Liu, Guangyu Sun, Raja V. Ramani, Shambhu Sharan, Raman Srikanth, Bharath K. Belle

The contribution of the various outby sources to the contamination of the panel intake air has been the subject of a relatively small number of studies. In this paper, after a brief review of past studies, results from recent experiments on rates of contamination of intake air by outby dust sources are presented. Present study indicates that each outby source by itself may not be a major contributor. The loading point in the continuous miner section did not appear to be of major concern from contamination point of view. Belt entry including transfer point contributes significantly to the intake air dust level, though reentrainment was not a major source of dust. In longwall panels, the stageloader-crusher was the most dominant source. The panel-to-main belt transfer point was not a major source. Taken collectively, the contribution of all outby sources can be significant. In one longwall section, at the beginning of the longwall face, the contribution of all the outby sources and the headgate cut-out operation was observed to be about 80% of the permissible exposure limit (2 mg/m3). In modem high production longwalls, the application of effective dust control measures to reduce the dust generated from the outby sources is essential to achieve compliance with the dust standards.

Jan 1, 1997

By C. H. Lee, F. Concha, L. G. Austin, P. T. Luckie

The Concha-Almendra batch-settling treatment for concentrated suspensions of single-diameter spheres has been modified. This modified version is used in the differential equations of simple batch settling of a particle size range of different density materials. The equations have been programmed for a finite difference solution, and a number of test cases have been analyzed. By cutting the settling column at a fixed fractional height, the material below this height can be treated as underflow and the material above as overflow. The predicted partition curves obtained from treating the settling in this way have Sharpness Indices in the range of 0.5 to 0.6, in the absence of dispersion effects. The Sharpness Indices decrease as dispersion increases. When the feed size distributions are of the Rosin-Rammler form, the partition curves (corrected for the bypass fraction) fit the Rosin-Rammler equation with reasonable accuracy. The predicted Sharpness Index of a component of a mixture of two materials of different densities was unchanged from that of the same materials settled alone. However, for the same, feed size distribution and volume fraction of solids in the feed, the heavier material settled faster, and the lighter settled slower, than when settled alone.

Jan 1, 1993

By Günter Strappler, Max John

When tunneling through karstic terrain, diverse and complex karst structures are to be expected. By means of drilling ahead of the face using drill jumbos, these structures can be detected to such a degree that by applying proper support measures both open karst cavities and karst holes surrounded by boulders embedded in soft rock can be mastered without causing any break-outs. Support measures such as spiles ahead of excavation, sealing off cavities, back?lling with sand, etc. have to be planned schematically and adapted to the dimensions and formations of the karst structures on site. An essential requirement for a smooth excavation procedure is the availablility of all necessary tunneling equipment for excavation by drill and blast as well as for excavation of soil, with experienced tunnel engineers being in charge of any adaptions on site.

Jan 1, 2003

By S. G. Tough, H. J. Hignett

The Transport and Road Research Laboratory is carrying out tunneling trials at Chinnor, Oxfordshire, with a 5-m-diam, full-face tunneling machine. The work, which is for research purposes only, involves driving the tunneling machine through chalk with most of the physical characteristics of the machine and its power consumption closely monitered. At the Conference a film was shown about this work, illustrating both the tunnel construction and the research program.

Jan 1, 1974

By Bernd Friedrich, Elif Emil‑Kaya, Merve Papakci

In the production of SmCo permanent magnets with excellent temperature stability, corrosion resistance, and oxidation resistance, samarium (Sm), one of the rare earth elements (REEs), and cobalt (Co) are employed. Cobalt (Co) is a crucial component in tool materials, nickel-based alloys, tablet and smartphone batteries, and electric car batteries. REEs and Co have been listed as critical raw materials by the European Union Commission for many years. Due to the ever-growing demand for Co and REEs in technological applications, the recovery of these elements from secondary sources has garnered significant interest. There are two types of SmCo magnets, one of which contains a high amount of iron, approximately 15.2%. This paper focuses on the recycling of Fe-bearing SmCo. In this study, an oxidative leaching process with nitric acid was developed to eliminate iron through in situ hydrolysis and to dissolve REEs and Co. The influence of experimental conditions on the formation of an amorphous iron compound through the hydrolysis of Fe3+ in a nitric acid environment was thoroughly examined based on a Taguchi orthogonal array. The optimal parameters for oxidative leaching were determined to be an acid concentration of 3 mol/L, a solid-to-liquid ratio of 1/10, and a process temperature of 60 °C.

Feb 15, 2024

By Y. M. Jiang, D. W. Park, S. M. Lee

A vast majority of longwall operations in the US use shield-type hydraulic supports to provide ground control along the longwall face. The three-dimensional, finite-element technique combined with a progressive failure approach was utilized to simulate interaction between shields and surrounding strata and determine various loading conditions. In addition, a separate finite-element model of the shield structure was made to study responses of each longwall shield to the different loading conditions. Shield responses under various loading conditions and the shield characteristics, such as shield stiffness, the ability of resisting horizontal forces, and the effect of shield height, were studied based on the results from finite-element analyses. The results can provide the basis of effective shield design and be used for evaluation of the shield performance. It is suggested that a technique incorporating the finite-element method be developed to evaluate real-time shield performance for the purpose of effective ground control.

Jan 1, 1993

By P. Mendoza, R. Siwale, H. Amini, R. Silva, M. Richards, V. Ngcoza, D. Rivera, C. Canaza, R. van Reenen

Development of a realistic flotation model to predict its performance is of paramount importance to the processing plant and operators, a model that accounts for predictive and no-predictive maintenance simulating individual equipment downtime and the effect of it in the metallurgical performance on the flotation bank with final recoveries and grades has a huge advantage on optimizing the flotation circuit/bank in terms of mechanical and metallurgical side. The Model was developed in a dynamic environment that allows for a better and more realistic simulation of the flotation bank. The maintenance model accounts for the Failure rate, Mean Time Between Failures (MTBF), Mean Time to Failure (MTTF) and Reliability (R(t)) those characteristics are combined to a multi-compartment process model that consists of a slurry recovery model, two options of froth recovery models, entrainment and carry capacity as a final check for the system. In addition to the maintenance and process model, a dynamic dart valve model was added to the simulation in order to have a realistic model to control the slurry level at the flotation cell. The paper goes over a study case for a current flotation operation trying to explore all the elements and the simulator to optimize the Rougher flotation bank.

Mar 2, 2022

By P. Somasundaran

Previous studies on semi-soluble minerals such as calcite (1) and apatite(2) and sparingly soluble minerals such as quartz (3,4) have given evidence for significant changes in their electrokinetic properties as a function of aging time. Such changes are relevant to mineral processing operations where the crushed ore particles might not have yet reached equili¬brium with the water that it is in contact with. In order that these changes be studied under controlled experimental conditions for long periods unattended or with fairly less intermittant attention, a streaming potential apparatus with an automatic streaming system was constructed. Also, a new streaming potential cell was incorporated into the system so that the effect of temperature, a variable coming into increasing usage in mineral processing operations(5), could also be studied. Conventional streaming cells(6) cannot be safely employed to conduct studies as a function of temperature since they have many glass joints that are prone to leakage, parti¬cularly under pressure, in the course of an experiment. This paper describes the new apparatus and some typical results that have been obtained with it far temperature effects.

Jan 1, 1973

By M. Zhang, H. Ni, F. Zheng, M. Guo

"In the present work, we investigate the effects of roasting temperature and time on the transformation of the titanium (Ti)-bearing phase and magnesium aluminate spinel (MgAl2O4) phase in Ti-bearing electric arc furnace molten slag during the molten sodium hydroxide (NaOH) treatment process. With applied temperature of 700 °C for 60 min, and a mass ratio of Ti-bearing electric arc furnace slag to NaOH, or Rslag/NaOH, of 1:1.2, the conversion ratios of the Ti-bearing phase and the MgAl2O4 phase reached about 98.3 percent and 88.1 percent, respectively. Moreover, investigation of the reaction kinetics indicate that the conversion of these phases during the molten NaOH treatment process is a typical solid-liquid reaction, and it can be theoretically described by the unreacted shrinking core model. The conversion ratio of the Ti-bearing phase was found to be controlled by the chemical reaction step, with an apparent activation energy of 41.76 kJ/mol. The decomposition of the MgAl2O4 phase was found to be controlled by the surface chemical reaction in the early stage of 0 to 20 min from start of reaction, changing to diffusion control in the later stage of 20 to 60 min. The apparent activation energies of the process were determined as 55.88 and 22.72 kJ/mol, respectively.IntroductionChina has rich mineral resources of vanadium–titanium magnetite ore deposits, and the iron and steel industry in the country produces millions of tons of titanium (Ti)-bearing slag every year. The problem of how to dispose of the Ti-bearing slag has attracted much attention, and various approaches have been developed, including the acid process (Li et al., 2007; Zhang et al., 2011; Zhang and Nicol, 2010; Li et al., 2011), alkali fusion process (Han et al., 2012; Middlemas, Fang and Fan, 2013; Nayl, Awwad and Aly, 2009; Lasheen, 2008; Zhang, Qi and Zhang, 2009), carbonization and chlorination process (Liu et al., 2008; Tao et al., 2012; Fu et al., 2012; Liu, 2009), selective crystallization process (Lei and Xue, 2008; Li et al., 2011; Zhang et al., 2007a, 2007b). However, these processes have been beset by various functional, economical and ecological problems (Yu and Chen, 2010). With environmental protection regulations becoming increasingly rigorous, and demand growing for the comprehensive utilization of resources, the focus is on methods to treat Ti-bearing slag with high efficiency and mild reaction conditions (Nazari and Riahi, 2011; Wu et al., 2013)."

Jan 1, 2017

The National Mining Association’s (NMA)MINExpo International ’96 is shaping up to be the organization’s largest. About 30,000 mining industry business and technical professionals are expected to descend on Las Vegas, NV Sept. 9-12 to take part in the 25 technical sessions and visit the more than 900 exhibitors who will be showing off their products and services. MINExpo will be the largest mining equipment and services exposition in the United States this year. Exhibits at MINExpo will fill the Las Vegas Convention Center, parking lots and part of the Hilton Center, located next door to the convention center. NMA estimates that this year’s show will cover more than 46,450m2 (500,000 sq ft) of exhibit space. Some of the exhibits on display will include haultrucks, hydraulic shovels and excavators, conveyors, continuous miners and tunneling machines. In addition, an array of computer equipment and software will be demonstrated. A new feature this year will be a helicopter pavilion, located in the Hilton Center. Helicopters and fixed-wing aircraft have become indispensable to many remote mining operations. NMA said that at least one full-size helicopter will be on display.

Jan 1, 1996

By P. R. Khangaonkar, G. Bhaskar Raju

Three types of flotation columns were developed with a column dia of 8.0 cm and a length of 160 cm. The first type consists of an ordinary column fitted with a porous plate at the bottom. The second type consists of two electrodes at the bottom to obtain very fine and uniform bubbles generated electrolytically and the third is a combination of first and second types, i.e. to get both electrolytic bubbles and air from the compressor through porous plate. Three different ores were tested-gold tailings for recovery of scheelite, copper tailings (chalcopyrite) and oxide copper ore. In the case of scheelite and copper oxides, good results were obtained with the first type of column itself, whereas the third type column was found fairly effective in the recovery of chalcopyrite. The variables like the effect of reagent concentration, column height above the feed point, feed flow rate, current density, air flow rate, particle size etc. were examined.

Jan 1, 1988