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By M. S. Klima

Coal gasification solid residue (slag) contains unconverted carbon (char), which is considered an impurity for utilization applications of slag. Under this study, table concentration was used to process approximately 24,000 pounds of a nominal-3.4 mm gasifier slag (-85% ash) to separate high (-100%) ash slag from low (-50%) ash char. The results indicated a nearly ideal separation of the slag from the char for sizes coarser than about 1 mm. An overall slag yield of 71 % was obtained. The slag was sufficiently clean to be used as feed material for the production of expanded lightweight aggregate. The recovered char had an ash content of about 47% and was a nominal -1mm in size.

Jan 1, 1997

By J. S. Orphanos

The requirements for controlling air and stream pollution are a most timely subject for all concerned people. The coal industry has taken great measures to reduce both types of pollution. Through the use of more efficient scrubbing equipment on their thermal dryers, pollution has been considerably reduced. In many cases, the complete elimination of thermal drying by using centrifugal dryers to dewater fine coal products and meet customer specifications has completely eliminated air pollution from this source. To help eliminate stream pollution and the hazards created by tailing ponds, the coal industry is using centrifugal dewatering equipment. Use of centrifugals to dewater fine refuse for disposal would eliminate refuse ponds or extend their life. In doing this effectively and economically, preparation plants have the option of recycling the clarified water to close the water circuit or of discharging the water into receiving streams with the assurance that it contains an acceptable amount of refuse solids.

Jan 1, 1974

By J. D. Miller, J. Hupka

Important aspects of kerosene penetration into tar sand have been investigated. The natural tar sand porosity was measured and used to analyze the performance of the hot water process. Subsequently, pretreatment experiments, using 20-kg tar sand samples (Asphalt Ridge and Whiterocks, Utah) and kerosene as a diluent were carried out at the expected summer temperature (26°C) and the expected winter temperature (-14°C). The natural tar sand porosity accessible by diluent has a crucial impact on the reduction of bitumen viscosity and influences the penetration time required for successful bitumen separation from tar sand by hot water processing. Thus, the tar sand porosity is a critical variable that determines appropriate operating conditions. Experimental results indicate that diluent penetration into the Asphalt Ridge tar sand (high porosity) is almost complete after 30 min, whereas for the Whiterocks tar sand (low porosity) the penetration process is much slower, being still incomplete after 15 hours regardless of the ambient temperature.

Jan 1, 1994

By Patrick A. Ley

Maintaining, managing and manipulating large quantities of geologic data can be a very costly and time-consuming process. The use of computer-based methods can provide some relief to the problems of editing, displaying, and interpreting spatial geological data. ENCORE is a system designed specifically for coal orebody modeling and reserve esitmation where the geologic data is stored on a large mainframe computer and is accessed from a local work station for editing, manipulating, and producing various reports and high-quality engineering maps. The ENCORE system was designed for use by the geologist or mining engineer with little or no computer background and, additionally, it was designed to provide the geologist or mining engineer enough flexibility to be able to select the appropriate methodology for the orebody being analyzed. The various analysis tools incorporated into ENCORE can significantly increase the professional's productivity without burdening he or she with the need to understand the details of the internal computer language.

Jan 1, 1982

By Mahesh C. Jha, Frank J. Smit

Column flotation and selective agglomeration are promising advanced physical cleaning processes that can be developed for preparing premium quality coal-water slurry fuel from coal fines. Such a fuel could either replace oil or natural gas in certain industrial and utility boilers or else could be burned in advanced combustors currently under development. These applications require coal cleaned to sulfur and ash contents below 258 g/GJ and 430 - 860 g/GJ (0.6 lb/million Btu and 1 - 2 lb/million Btu), respectively, to meet clean air emission requirements. A highly loaded slurry must be produced in order to avoid derating the boilers, and the total cost of the fuel must be below $2.37/GJ ($2.50/million Btu) in order to penetrate the market by the turn of the century. Achieving these technical and economic goals depend critically on the selection of suitable feed coals. This paper describes the identification and evaluation of 18 coals and final selection of six coals from different regions of the United States as potential feedstock for preparation of premium fuel. The work is being performed under a cost-shared DOE project.

Jan 1, 1995

By G. Whitney, J. Steiner

Introduction The Summitville Mine located in southwestern Colorado is an example of the potential impact that natural weathering and mining activities can have on environmental quality. Acid rock drainage and metals leaching from active and historic mine districts are a major environmental problem facing the mining industry today. Sulfide ore exposed naturally or during mining operations has the potential to produce leachates that contain high concentrations of dissolved metals. These leachates can affect the quality of plant and animal health in surface water used for agriculture, recreation and human consumption. Pintail Systems has developed biological processes for detoxification of cyanide in heap-leached spent ore and process solutions. During application of spent ore cyanide bio-detox processes we have also observed a substantial reduction in many of the leachable metals in biotreatment solutions. These field observations of soluble metal reduction led us to propose that metal bio-mineralization should be a secondary treatment goal of spent ore detox in Focused Feasibility Studies (FFS) for the Summitville Mine. In the FFS (described in a companion paper) for Summitville, spent ore from the heap leach pile (HLP) was loaded into PVC test columns (six inch X ten foot) and was leached with bacteria/nutrient solutions. Two treatment designs were studied: a standard percolation leach (aerobic) and a saturated leach design where the ore was saturated with the heap leach solution to which bacteria and nutrients were applied in a continuous biotreat leach. The bacteria for all column treatment tests were isolated from the spent ore at depth through the Heap Leach Pile (HLP) in the saturated and unsaturated zones. Bacteria isolated from the heap material were tested for cyanide oxidation capacity and were submitted to a bioaugmentation program to improve reaction kinetics and metals tolerance. The final treatment population consisted of several distinct species including aerobic heterotrophs, facultative anaerobes and sulfate-reducing bacteria. The remineralization of soluble metals was observed through a decrease in copper in column leachate solutions and the formation of observable mineral products on ore surfaces in the columns. Several of the tests were run in clear PVC columns to facilitate observation of mineral formation. The column ore contents were photographed before, during and after the biotreatment process which ranged from 10 to 20 days for each test column. Ores were collected from each column after the treatment was complete and were submitted for SEM and TEM study at two laboratories - the USGS SEM Laboratory in Denver, Colorado and the City College of New York SEM laboratory. Treatment Process Description Numerous species of bacteria, fungi and yeasts are capable of accumulating many times their weight in soluble metals. Both living and dead biomass are effective in removing soluble metals from waste streams containing gold, silver, chromium, cadmium, copper, lead, zinc, cobalt and others. Soluble metals may also be immobilized in soils by natural or engineered biomineralization reactions. Several commercial processes using biological reactions are being applied on an industrial scale for metal remediation. Bacteria found in natural and extreme environments have developed a wide variety of metabolic functions to adapt to these environments. These natural microbial functions contribute to global mineral cycling that continuously forms, transforms and degrades minerals and metals in the environment. Biomineralization is described as a surface process associated with microorganism cell walls where the remineralization occurs. The biogeochemical activities initiated by microorganisms in ores, soils, surface and groundwater environments can dominate the formation and transformation of those mineral environments.

Jan 1, 1995

By V. I. Kefeli

Public-private partnership efforts are working to create green landscapes from abandoned industrial sites. Fabricated soils, potentially an essential element of such landscapes, are designed to substitute for topsoil on the areas free from ground cover and plant community. The aluminosilicate matrix and humus form the soil micelle - the primary unit of any soil complex. Humus formation is a process based on carbon-nitrogen interaction. Sources of carbon can be materials rich in easily composted products like cellulose and polyphenols (plant leaves) or aged lignin polymers (saw dust from different woody plants). The pathways of carbon-nitrogen complexes are discussed. Properties of the fabricated soil components were examined by bio-tests and plant models.

Jan 1, 2002

By Kasimcan Koruk, Julian M. Ortiz

A geological model accounting for uncertainties possesses important advantages for resource estimation. Machine learning algorithms (MLAs) employed on multivariate geochemical datasets open up ways to new methodologies for such geological models with ease in comparison to traditional geostatistical methods. This article proposes a two-step MLA with an ensemble implementation to define geological domains and their uncertainties based on geochemical data. The proposed workflow is applied hierarchically on a dataset from a porphyry copper deposit to perform binary classification that can be attributed to alteration domains.

Mar 1, 2024

By R. Weinstein, R. Snoby

There are many advantages to upgrading coal with dry jigging technology. The most obvious is the lack of process water, which eliminates the need for fines dewatering and slurry confinement. Dry jigging eliminates the clean coal moisture penalty associated with wet processing. Particulate emissions are virtually nonexistent due to inclusions of fabric dust collectors on all modern dry jig plants. Due to the environmentally kind nature of dry jig plants, installation permits are often measured in days, not months. Coupled with all these advantages there has been a fundamental advance in dry jigging efficiency. All of these advantages have renewed the coal industry’s interest in dry jigging. But, air jigging isn’t right for every application. There are limitations due to particle size, particle shape, moisture, and near gravity content. This paper explores the evolution of dry jigging; reviews parameters important for determining the suitability of dry jigging; compares historical performance data as measured by imperfection, against results from modern dry jigging technology; and presents actual data from modern dry jig installations.

Jan 1, 2006

By Eli Curiel, Ingar F. Walder, Patrizia P. Schuster, Walt Keyes

Mansfield Canyon, of the Wrightson Mining District, Santa Cruz County, Coronado National Forest, Arizona, was actively mined in the late 1800's and early 19001s, with minor activity until 1953. The main products were lead, silver, copper, zinc, and gold occurring in polymetallic quartz veins. The canyon contains numerous adits and waste dumps, some of which generate metal-loaded acid. Samples of seeps, waste dumps and bedrock have been collected for various analyses: metal concentrations, acid base accounting (ABA), and water quality to evaluate the extent of oxidation and metal release from the start of mining until present, the potential impact, and reclamation options. Although the waste-rock piles within the canyon are small (2,000-10,000 tons), they have a high sulfide content with little or no neutralizing capacity. It is planned, therefore, to move the waste piles either to a constructed repository site within the canyon or to a copper leach facility to be used as an acid generator.

Jan 1, 2000

By Giin-Fa Fuh, Sally A. Shoop

An instrumentation program was developed based on the results of an analytical study of the geomechanical effects of longer longwall face lengths. Boundary element simulations showed that longer face lengths can cause in- creased face convergence and an increase in the shear stresses in the immediate roof. Empirical design methods predict that longer faces will cause little effect on abutment stresses as long as the roof caving is well behaved. On this basis, a longwall face instrumentation program was designed with emphasis on the interaction between face support and ground response for optimizing face conditions. At a 600-foot (183 m) face, five midface shields and two headgate shields were monitored with vary- ing hydraulic pump pressure. The instrumentation included six convergence rods with linear potentiometers to measure canopy-to-toe convergence; fourteen pressure transducers to monitor leg pressures; and two portable data loggers. Similar instrumentation will be in- stalled on a 750-foot (229 m) face for comparison. The results from the 600-foot (183 m) face indicate that a ground reaction curve, as determined from the relationship between the sup- port set pressure and the roof convergence, can be used to optimize the support pressure to control convergence, the key element to ground stability in the face area.

Jan 1, 1986

By A. Iordanidis

Fly ash samples were collected from two large lignite-fired power plants of Ptolemais region, northern Greece. Environmental Scanning Electron Microscopy (ESEM) was applied for the characterisation of the samples. ESEM coupled with Energy Dispersive System (EDS) provided fast and accurate results on the morphology, mineralogy and chemical composition of the fly ash particles. Fly ash consists mainly of aluminosilicate glass, silicates, oxides-hydroxides, sulphates, carbonates and char. Various types of chars, spheres (e.g. ferrospheres, cenosphers, plerospheres etc.), spheroids, agglomerates and mineral crystalls were observed. The size distribution of the fly ash particles was correlated with their mineralogical and chemical composition. Possible environmental impacts and potential utilization is also discussed in this study.

Jan 1, 2005

By K. C. Nathsarma

An attempt was made to extract niobium oxide from ~98.5% Nb2O5 using solvent extraction processes. Nb2O5 is used as the feed material in carbothermic reduction processes aimed at producing high-homogeneity, super-conductor-grade niobium on a laboratory scale. The Nb metal used for superconductor applications requires a residual resistivity ratio (RRR) > 300, which in turn needs a stringent purity of Nb and allows impurities (substitutional and interstitial) in ppm levels only. In this paper, solvent extraction of niobium was studied under various experimental conditions, such as effect of different extractants, concentration of methyl isobutyl ketone (MIBK) in the organic phase and concentration of various acids. The concentrate was digested with hydrofluoric acid, with ammonium fluoride (NH4F) as a stripping agent. The extraction of niobium from low hydrofluoric- (HF-) bearing solution was found to be low. Thus, various concentrations of hydrofluoric acid and sulfuric acid, as well as hydrofluoric acid and hydrochloric acid, were investigated towards obtaining a maximum amount of niobium in the filtrate and a minimum amount of niobium in the residue. A McCabe - Thiele plot for extraction of niobium from the aqueous phase, HF-bearing solution using HCl with 85% MIBK in kerosene has been constructed to determine the O:A ratio and the number of stages of the process.

Jan 1, 2011

By K. C. Nathsarma

An attempt was made to extract niobium oxide from ~98.5% Nb2O5 using solvent extraction processes. Nb2O5 is used as the feed material in carbothermic reduction processes aimed at producing high-homogeneity, superconductor-grade niobium on a laboratory scale. The Nb metal used for superconductor applications requires a residual resistivity ratio (RRR) > 300, which in turn needs a stringent purity of Nb and allows impurities (substitutional and interstitial) in ppm levels only. In this paper, solvent extraction of niobium was studied under various experimental conditions, such as effect of different extractants, concentration of methyl isobutyl ketone (MIBK) in the organic phase and concentration of various acids. The concentrate was digested with hydrofluoric acid, with ammonium fluoride (NH4F) as a stripping agent. The extraction of niobium from low hydrofluoric- (HF-) bearing solution was found to be low. Thus, various concentrations of hydrofluoric acid and sulfuric acid, as well as hydrofluoric acid and hydrochloric acid, were investigated towards obtaining a maximum amount of niobium in the filtrate and a minimum amount of niobium in the residue. A McCabe - Thiele plot for extraction of niobium from the aqueous phase, HF-bearing solution using HCl with 85% MIBK in kerosene has been constructed to determine the O:A ratio and the number of stages of the process.

Nov 1, 2011

By C. Villa Diniz, A. H. Martins, Fiona M. Doyle

It is proposed that battery grade MnO2 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By R. L. Grayson, J. R. Warneke

Environmental conflict between the public and private sectors, including mining, is highly visible and often based on deeply divergent environmental, social, and economic values. In order to achieve sound public policies by government, scientifically rigorous and objective analyses of mining’s impacts are demanded. Material flows accounting and analysis, linked with other data to generate indicators of environmental, social, and economic impacts of mining activity are means toward providing cogent input into public policy-making on key issues. This paper will present a material flows analysis scheme for the coal industry and recommend derived, objective indicators of coal mining’s impact on society.

Jan 1, 2004

By R. Larry Grayson

A menu-driven, linear-programming- based, user friendly computer program was developed to assist mine managers in determining optimal longwall panel dimensions for a given set of operating conditions. A sensitivity analysis must be performed by varying key mining and configurational parameters over an expected, practical range during the optimization process. Results from analysis of a base case mine indicated that no single combination of longwall panel length and face width is optimal for all operating situations. Each mine manager must therefore look closely at his operating situation and determine the proper dimensions to minimize total mining cost.

Jan 1, 1989

By S. R. Wardwell, M. J. Robison

INTRODUCTION The first phase of the Los Angeles Metro Rail Project consists of 7.1 km of subway and stations running through downtown Los Angeles from Union Station to MacArthur Park. Contract A146, Tunnels from 5th/HILL Station to 7th/Flower Station, involves tunnel construction through the heart of downtown Los Angeles. The alignment of the tunnels passes beneath twelve buildings, ranging from a 3-story below grade parking structure to numerous 12 to 14 story buildings. The soil along the alignment is alluvium, consisting of silts and clays, clean sands and gravels located above the ground water table. Because of unstable ground conditions, which led to excessive ground losses in several instances, and because of the potential for excessive building settlements, it became necessary to design and perform a program of chemical grouting. The chemical grouting program was designed such that tunneling could proceed on a one shift per day basis, with chemical grounting being performed on the remaining two shifts. Each day 21,000 to 31,000 liters of sodium silicate grout were injected through sleeveport grout pipes installed 18 m deep through the tunnel face. Tunnel advance rates of 12 m per day, 60 m per week, under full chemical grout cover were achieved. The chemical grouting program virtually eliminated both ground loss and settlement and permitted successful excavation of the tunnels. The purpose of this paper is to describe the chemical grouting program used to control ground losses and settlement on Los Angeles Metro Rail Contract A146. The paper begins with a description of

Jan 1, 1991

By Munson R. McKinney, Bryan A. Slim

To date some 1,000 exploration targets (by way of adits, mine dumps, shafts, outcrops and unstoped mine areas) have so far been identified using an interactive data base system to query a digital data base comprising topographic, cadastral geological and mine components developed as a compilation of old plans, records, surveys and recently flown aerial photography. The exploration targets are intended for early follow-up as part of a 1987 exploration programme to investigate the reserve potential of the former producing property located in southern Utah. Of further interest is the unscrambling of old mine plans to provide drill targets for investigation of unstoped reserves with one target being a possible 800,000 tons in part of the lower workings. The project site encompasses about 3,200 acres of mainly patented lode claims covering most of the claims and mines of the Gold Mountain mining district formed in 1889. Turn of the century mining saw several mines operating whose total production was at least 143,000 oz. gold and 460,000 oz. silver from steeply dipping veins up to 20 ft. or more in thickness.

Jan 1, 1987

By H. Singh

Principal source of rhenium is molybdenite. Depending on the mineral processing route, rhenium can be recovered by one of the several alternative solvent extraction processes. Extensive experimental work has been carried out on the development of tertiary amine extraction process for treating very dilute highly impure scrub solutions obtained during scrubbing flue-gases of molybdenite oxidative roasting. Equilibrium data has been obtained under various process conditions by tracer analysis using radioactive Re-186. Extraction with 1% solution of a high molecular weight tertiary amine in kerosene, followed by scrubbing of organic extract with a solution of sulphuric acid and stripping with ammoniacal ammonium sulphate yields high recovery, concentration, and purification.

Jan 1, 1982