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By J. B. Hiskey, P. H. Qi

Activated carbon loaded with gold from different halide solutions was characterized by thermal analysis (TA) techniques. The mechanism of gold uptake by carbon varies from predominately adsorption for gold iodide to predominately reduction for gold chloride. Thermogravimetry analysis (TGA) and differential thermal analysis (DTA) measurements confirm the existence of adsorbed gold-halide species within the micropore structure of carbon. These results suggest that the ratio of reduced to adsorbed gold increases for gold halides in the following order: Au-I < Au-Br < Au-Cl. In the case of Au-I, TA results for the loaded carbon were compared with pure compounds of 12, Aul and Aul3.

Jan 1, 1998

In 1988, at the request of members of the Society for Mining, Metallurgy, and Exploration (SME) Inc., the president of SME formed Working Party No. 79, Ore Reserve Definition. Its mission was to develop guidelines for the public reporting of exploration information, resources and reserves. These guidelines were published in the April 1991 issue of Mining Engineering,(pp. 379-384), and as a document entitled "A Guide for Reporting Exploration Information, continued on an ad-hoc basis until 1996. Working Party No. 79 was then renamed the SME Committee on Re¬sources and Reserves and became a standing committee. Since 1994, the Council of Mining and Metallurgical

Jan 1, 1999

By Hassan El-Shall, Abbas A. Zaman, Brij M. Moudgil

The addition of organic and inorganic dispersants to aqueous suspensions of heterogeneous particles (kaolin) was found to significantly affect the solubility of metal ions from kaolin particles and stability of the dispersion. In most of the industrial applications of kaolin, highly concentrated slurries of controlled stability and fluidity are required. The solubility of kaolin particles in terms of aluminum and silicon ions and its effect on the stability of the slurry was investigated. The main objectives of this study were (1) to study the effect of the extracted metals on the properties and performance of the slurry, (2) to understand the reaction mechanism of dissolution of metals from kaolin, and (3) to understand the interaction mechanism of dispersants with kaolin particles. The controlling variables were dispersant dosage, slurry pH, solids loading, and aging.

Jan 1, 2003

By S. C. Bandis, N. Barton

During drilling of deep boreholes, local mechanical failures of the wellbore walls may occur due to the inability of the incompetent overburden and reservoir rocks to withstand drilling-induced changes of the stress environment. At present, borehole failure mechanisms in three-dimensional stress fields are poorly understood. Our experimental investigations based on 3-D physical models demonstrate the stabilizing effect of the intermediate principal stress. The latter may play a dominant role in maintaining the integrity of the stress relieving failure zone around the borehole. However, this will depend on the stress anisotropy, the angle of hole deviation and on the angle of internal friction. Our tests also indicate that the failure zone can accomodate high extensional strains. Finally, relations between the physical models and closed-form elasto-plastic solutions are discussed.

Jan 1, 1986

By T. W. Oshnock

Pulverized coal (PC) and other injectants can be injected into the blowpipes of a blast furnace to decrease coke requirements. Throughout the history of blast-furnace development, there have been many attempts at injecting PC. In the 1960&apos;s a more serious effort was made to improve pulverized coal injection (PCI) technology. However, because of the additional capital requirements and the projected near-term inexpensive cost of other injectants, very few PC1 systems were installed. When the second oil crisis occurred around 1979, the shortage and high cost of fuel oil caused blast-furnace operators to operate without oil injection. It was soon discovered that blast- furnace operation without oil was not as smooth or efficient. Experiments with PC1 quickly showed that coal was a good replacement for oil which resulted in the rapid application of PC1 in both Europe and Japan. As a result, PC1 technology for blast-furnace operation has progressed rapidly during the 1980&apos;s. This paper will describe the worldwide status of PCI, characteristics of different PC1 systems, the effect of PC1 on blast-furnace process parameters, and the economic effects of using PCI. Results from the USS Blast-Furnace Thermochemical Projection Model comparing the effects of different coal properties and the effects of other tuyere injectants such as oil and natural gas will also be described.

Jan 1, 1988

By R. K. Mehta, C. W. Schultz, R. R. Mallepali

Stirred ball mill feeds used for ultrafine grinding applications require a fine size separation step to avoid overgrinding. This paper presents the selectivity curves obtained for oil shale and complex sulfide ore using a 460-mesh (30-µm) Derrick vibrating screen. The selectivity curves generated from the experimental data show increasing selectivity with larger size for the oil shale but not for the sulfide ore. These unusual selectivity curves are similar to the mechanical air separator, fishhook selectivity curves described by Luckie and Austin. A two-stage, in series, classification model describing the fishhook selectivity curve has been used in proposing the classification mechanism for fine vibrating screens when a heterogeneous, multicomponent sulfide ore undergoes size separation.

Jan 1, 1994

By Shuang Shuang Huang, John Fillos

Ozonation was evaluated as an alternative treatment process for leachates of municipal landfills. The study was carried out on leachate from the Fresh Kills Landfill, New York City. The leachate has strong tea color and BOD5 ranging between 90 mg/L and 130 mg/L. The average COD, TOC and NH3-N concentrations were 1800 mg/L , 550 mg/L, and 665 mg/L, respectively. The kinetics of the process were studied in a sparged batch reactor by developing concentration- time profiles for residual color and TOC. Continuous flow experiments were then carried out at two selected contact times. The process was found to be effective in the treatment of leachates for color and TOC removal.

Jan 1, 1992

By Martin Knights, Geoff Featherstone, John Flanagan, David Lawrence

The proposed paper will address specific transport, engineering, environmental and community related issues concerning the current construction and future operation of Europe’s biggest urban road tunnel project—the US$500m Dublin Port Tunnel. Situated in Ireland’s capital, the three mile long, 40 ft diameter twin tunnel project encounters a range of ground conditions using TBM, Shield, Cut & Cover with diaphragm walling and major slope stabilisation and Multi-jacked pipe techniques. Where possible units of measurement are given in feet and inches.

Jan 1, 2003

By J. A. Brierley, S. N. McIntosh, C. L. Brierley, E. G. Baglin, E. G. Noble, D. L. Lampshire

The U.S. Bureau of Mines investigated column bioleaching as a means of recovering manganese from a domestic low-grade oxide ore. Manganese was solubilized from the ore using indigenous heterotrophic microorganisms and molasses as the nutrient source. The effects of medium flow rate, molasses concentration, and frequency of medium replacement on the rate of manganese extraction were examined. Results showed that flow rates between 0.4 and 8.1 L/min/m2 had little impact on manganese extraction, while an increase in the total amount of molasses applied during leaching directly affected the extent and rate of manganese extraction. Manganese extractions of more than 90% were achieved in 12 weeks of bioleaching in column tests using 500 g charges of ore. Sugar utilization by the microorganisms and formation of organic acid metabolites were monitored by high performance liquid chromatography (HPLC). Two methods were evaluated to recover manganese from the sugar- depleted bioleaching medium: (1) adsorption onto weak cation exchange resin, followed by stripping and precipitation techniques; and (2) direct precipitation of the manganese as MnCO, using ammonium carbonate. Both recovery methods removed at least 95% of the solubilized manganese from the medium as a carbonate salt. The stripped molasses medium was replenished with fresh molasses and recycled back through the bioleach column, successfully leaching more manganese.

Jan 1, 1993

By Tim Wolf

The paper "Weld Notch Affects on Pulley and Belt Conveyor Reliability" has done an excellent job of describing theoretical fatigue and fracture mechanics methods used in modern weld design. From this foundation, we intend to further detail areas previously discussed and present new research in the application of these principles to pulley weldment life prediction. Affects of changes in alternating stress range, mean stress, and residual stress have been investigated using controlled laboratory fatigue tests on a pulley weldment. Comparisons between these results, weld codes, and theoretical fatigue predictions will be made and discussed.

Jan 1, 1998

By R. D. Begley, A. W. Khair

This paper presents an assessment of modeling techniques in predicting subsidence over longwall areas. Extensive instrumentation has been made, both at the surface and subsurface, at three longwall mines in northern West Virginia. Ground movements were monitored during a three- year period until subsidence ceased in these areas. A comparative analysis of empirical subsidence prediction techniques including graphical (NCB), profile function, influence functions (USBM, Bals&apos;, Knothe&apos;s, and zone area) will he presented. A brief geologic and topographic description of each site, along with the instrumentation and monitoring program, will also he presented.

Jan 1, 1990

By John A. Shuster

Case histories are reported for several soft ground shafts ranging from 6&apos; to 40&apos; in diameter and 50&apos; to 230&apos; in overburden depth for which ground freezing was employed to provide temporary ground support and groundwater control during shaft sinking through the overburden. Cases reported emphasize dealing with difficult site and ground conditions such as working within existing buildings, through very soft, running and bouldery soils, in the presence of substantial lateral groundwater flows, and into salt dome deposits requiring special considerations. Construction procedures, schedule, and relative costs are discussed for each case.

Jan 1, 1985

By P. R. McOllough

The Colorado Department of Highways awarded a contract to construct the Second Bore of the Eisenhower Tunnel in August, 1975. The contract was completed June 29, 1979, nine days ahead of schedule, with¬out major claims or delays. The tunneling involved complex construction through difficult ground conditions. The contract, plans and specifications were specifically planned to more equitably share the risks involved and to minimize adversary relationships. The Department produced a detailed tunnel design and maintained responsibility for the design. The contract employed some new provisions; e.g., a review board for settlement of claims and disputes; escrow documents (contractor&apos;s bid documents) to determine the contractor&apos;s basis of bid when determining adjustments. The tunnel contract, plans and administrative efforts employed by the owner and contractor were very successful in this project.

Jan 1, 1981

By Joseph Lynch, John DiPonio

This report refers to the Chicago Deep Tunnel Contract 13A, which was the first contract let in the City of Chicago requiring the construction of deep drop shafts for the transportation of high level sewage to the deep tunnel system. The basic contract required the contractor to construct certain drop shafts designed to deliver surface and high level sewage to the deep tunnel system approximately two hundred feet below. The design of the drop shafts was in a degree affected by their proximity to the existing deep tunnel. The tunnel, approximately three and one-half miles long, was to have five shafts dropping sewage at five locations. Four of the drops were approximately one-half mile apart and spaced from the dead end of the tunnel. One shaft divided the remaining two miles from the existing work shaft at the southeast end of the tunnel wherein a 220&apos; deep pumping station was to be built. The existing tunnel had been built some time previously and all dewatering had stopped, allowing the tunnel and main shaft to fill with water. According to the plans, the drop shafts were all between fifty and ninety feet north or south of tunnel center line, and located in heavily built-up residential and industrial property. This then defines the problems: How do we control the water. If we excavate from the top down, how do we handle the slurry and the muck from five locations. How shall we construct the connecting tunnel between

Jan 1, 1997

By Takashi Sakaguchi, Akira Nakajima

Some attempts were made to recover and remove heavy metal elements, such as uranium, copper and chromium, from aqueous systems by using several phosphate compounds. The phosphorylated derivatives of polysaccharides, chitin phosphate, chitosan phosphate and cellulose phosphate, have high abilities to accumulate heavy metals, such as uranium, copper, manganese, cobalt, cadmium, zinc, nickel and chromium, compared with non-phosphorylated polysaccharides. In order to obtain basic information on the recovery and removal of uranium that may be present in industrial effluents, mine waste water and seawater, the adsorption of uranium by chitin phosphate and chitosan phosphate was investigated in details. The adsorption of uranium by chitin phosphate and chitosan phosphate was much greater than copper, cadmium, manganese, zinc, cobalt, nickel, magnesium and calcium. The adsorption of uranium was very rapid and was affected by pH of the solution, temperature. granule radius and co-existence of carbonate ion. The amounts of uranium adsorbed on the adsorbents increased linearly as the external uranium concentration increased. Uranium adsorbed on chitin phosphate easily desorbed with diluted sodium carbonate solution. On the other hand, uranyl and cobalt ions were separated from each other by using chitin phosphate. Along with these fundamental research, some attempts were made to recover uranium from seawater.

Jan 1, 1993

By Allen J. Sobczak, Peter J. Peters

The five tunnel contracts of Milwaukee Northeast Side Relief Sewer System are about 80 percent complete. The tunnels are all excavated for 1.9 meter (6&apos;-0") finish diameter sewers in a variable rock, mixed face, and glacial soil environment. Different contracts were let under two primary types of specifications, performance and prescriptive, which treated aspects of construction, such as primary ground support and groundwater control, differently. Interfacing of design and construction through field personnel allowed the needs of all parties to be met and resulted in savings in time and money to the Milwaukee Metropolitan Sewerage District (MMSD). Interfacing, cooperation and risk sharing allowed resolution of problems such as line and grade variations and potential differing site conditions. It also allowed the parties to pursue constructive changes to construction activities. Thus on one contract prescribed use of compressed air was eliminated, but migration of fines into the tunnels was stopped with filter fabric. Use of an expensive primary support system was dropped, but concern about deterioration of lagging was alleviated by use of special materials.

Jan 1, 1983

By H. Soto, J. Jara, F. Nava, J. B. Hiskey, B. J. Scheiner

Laboratory tests showed that ozone can destroy free cyanide and weakly complexed cyanide (copper and zinc cyanides). The iron cyanide complexes were resilient to ozonation but they were effectively eliminated by precipitation with Fe (II) ions under controlled pH conditions. Tests carried out with effluents from a number of gold mills confirmed the results obtained previously in the laboratory. The industrial samples contained cyanide in the form of free cyanide and also complex copper, zinc and iron cyanides. Solutions that contained up to 184 mg/L total cyanide, after the ozone treatment analyzed only 2-3 mg/L dissociable cyanide and 50-90 mg/L CN(t) (accounted for by iron complexes). After precipitation with ferrous ions total cyanide was reduced below 1.5 mg/L. For most solutions ozone consumption ranges from 3 to 6 g per g of cyanide destroyed. However, certain impurities (such as SCN and S203 ), present in some effluents, increase ozone consumption and make it more difficult to reduce copper concentration to satisfactory levels.

Jan 1, 1993

By Yeonuk Choi, Patrick R. Taylor, Lyle Cunningham

Laboratory experiments have been performed to evaluate the potential for metal removal and recovery from river bed tailings by ferric chloride leaching. The lead, zinc, silver and other metals in the river bed occur due to the old method of dumping mill tailings into rivers. This was practiced prior to the introduction of tailings impoundments. The effects of the leaching method, leaching time, pulp density, ferric chloride concentration, and leaching temperature on the rates and recoveries of lead, zinc and silver were studied. The effects of pulp density and leaching temperature were significant on the extraction rates of lead, zinc and silver. The lead content in the leached tailing was reduced to 0.023 percent, when using an 353O K leaching temperature and 0.384 g of FeC13/1 g of sample.

Jan 1, 1992

By Regina N. Tempel, Timothy E. Eastep, R. Craig Ford, Bryce R. Roming, Geoff Clothier, Maggy F. Lengke

The Climax Mine, near Leadville, Colorado treats acid drainage in a lime neutralization chemical treatment system. Chemical treatment has been successful in reducing the concentration of metals to below surface water discharge effluent limits, but lime usage has not been optimized. A geochemical modeling approach has been developed to increase the efficiency of lime neutralization. The modeling approach incorporates two steps: (1) calibration, and (2) calculation of amount of lime needed to increase pH and remove metals. Results of our work quantify the lime treatment process and improve our ability to predict overall water quality.

Jan 1, 2000

By Vanessa M. Torres

Diagnostic leaching tests provide a good indication of gold deportation in its various occurrence phases. With the results of these tests, possible flowsheets for difficult ore treatment can be established for further evaluation and plant operation can be optimized. The use of this technique can be extended, including heap leach evaluation and complex copper-gold ores. The results on the use of diagnostic leaching tests in gold ores from Companhia Vale do Rio Doce (CVRD) are presented and discussed, as well as the methodology to select steps and interpret results used at CVRD Technology Center (Sutec).

Jan 1, 1998