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By L. Mao, R. Yoon

The thin film balance (TFB) technique was used to measure the equilibrium thicknesses of the water films formed between two oil phases. The measurements were conducted with dodecane at varying concentrations of dodecylammonium chloride, pH, and electrolyte concentration. The data obtained in the present work were used to calculate the surface forces acting between the two oil phases. The calculation was carried using the Extended-DLVO theory with the surface potentials calculated from the Gibbs adsorption isotherm. The results show that oil droplets suspended in water are hydrophobic and the hydrophobicity changes with surfactant and electrolyte concentrations.

Jan 1, 2004

By Jun Han

Coal has been mined in the Kailuan mining area for more than 130 years. The remaining reserves consist of, in large part, coals that would have been considered economically unminable or technically not feasible by the previous generations. Some of the current operations have to resort to overmining because the lower seams had been extracted in the past. This paper deals with the feasibility and proper layout of mining roadways of overmining carried out in the No. 5 seam of Qianjiaying coal mine of Kailuan mining area using numerical and physical simulation. FLAC2D was used to investigate the characteristics of stress and displacement in the overburden after extraction of the lower seams. It also analyzed the proper layouts of gateroads in the upper seams, i.e. locating them in the stress-relief zone of the gob so that their stability can be easily maintained. In addition, a two-dimensional physical model was constructed for investigation of damages to the upper seams due to mining of the lower seams. Finally, based on the results of investigations, proper gateroads layout was designed and successful extraction was implemented for panel 1357 in the No.5 seam.

Jan 1, 2009

By Ronald D. Mariani, Gregory E. Mahoski

BACKGROUND The steel and iron ore industry has had a long history of an adversarial relationship with its union and workforce. The Empire Mine during its first 40 years of existence was no exception. The "we-they" mentality went hand-in-hand with the normal by-product of an adversarial relationship, grievances and arbitration. This relationship was considered the norm and it was not until the late 1970s that consideration was given to changing this relationship. At this time the industry was involved in a fight for existence and the economic pressure demanded increasing productivity to lower cost. The challenge to survive highlighted the fact that an adversarial relationship was not conducive to attaining the needed gains in productivity. The first formal attempt to change the way we worked came in the 1980 Labor Agreement which provided for the opportunity to utilize Labor Management Participation Teams (LMPTs). LMPTs were established at the Empire Mine and they functioned for a couple of years. The teams spent most of their time working on creature-comfort issues and steered clear of dealing with productivity issues. Mine shutdowns had occurred in Michigan resulting in large layoffs, and the union was trying to add jobs and was not supporting teams that could increase productivity and eliminate jobs. When the 1986 labor negotiations began, the local union pulled their support of the LMPT process. Other initiatives were negotiated over the years to foster a change in the culture but, as with the LMPT program, they did not produce the desired culture change. It became abundantly clear: you cannot negotiate a culture change.

Jan 1, 2004

By R. A. Thomas, C. D. Litton

"The objective of this study was to develop a laboratory-scale method to rank the ignition and fire hazards of commonly used underground mine materials and to eliminate the need for expensive large-scale tests that are currently being used. A radiant panel apparatus was used to determine the relevant thermal characteristics of the materials: time to ignition, critical heat flux for ignition, heat of gasification, and mass loss rate. Three thermal parameters, TRP, TP1, and TP4, were derived from the data, then were developed and subsequently used to rank the combined ignition and fire hazards of the combustible materials from low hazard to high hazard. The results compared favorably with thermal and ignition hazards of similar materials reported in the literature and represent a simpler approach to quantifying these combustible hazards. INTRODUCTION The potential fire hazard from combustible mine materials is a major concern that can impact the safety of mine workers. Combustible materials tend to be solids and within this category there exist degrees of flammability and fire resistance. These materials may be readily ignitable or they may be able to withstand high temperatures and high heat fluxes. Presently, no simple methodology exists to assess these possible fire behaviors and quantify the resultant fire hazards. Thus, better knowledge of the thermal properties and chemical characteristics of combustible materials is of great importance to the safety of mine workers. Tewarson [1994] developed a methodology which he subsequently used to evaluate the ignition and fire resistant properties of combustible mine materials, but these efforts are more than 20 years old, and do not include many of the new materials used in mines today. The standard practice that has evolved for a combustible material to be approved by the Mine Safety and Health Administration for use in underground coal mines is to conduct extensive and costly large-scale experiments on each new material that is used in a particular mine operation. Results of such tests provide pass/fail answers to the questions of a material’s flammability or fire resistance, yet they provide little, if any, information that will lead to a better understanding of the basic mechanisms involved. Therefore, there is a need to quantify material flammability properties and to develop a methodology to rank the ignition and fire hazards of commonly used underground mine materials. During the heating and ignition stages of combustible materials, properties such as smolder susceptibility, minimum surface temperature for ignition, thermal conductivity, heat capacity, density, and heat of gasification are known to be important [Apte, 2006]. During the flaming stage, additional parameters, such as the heat of combustion, heat release rate, flame spread rate, yields of soot/smoke, and toxic gas production become more important as the flame is sustained and spreads. In very general terms, the heat flux incident on the surface of a solid combustible not only controls the rate of temperature increase of the local fuel surfaces, resulting in expulsion of fuel vapors that sustain the flaming process, but also the heating of other combustible surfaces that subsequently ignite and spread flame."

Jan 1, 2015

By Jorge Gutierrez C.

CODELCO-CHILE, the world's largest copper producer, began an integrated study of the informatics situation in the corporation at the end of 1980. As a result, a five years strategic Systems Plan was elaborated and approved by top Corporate management. Main points in this plan were: a systems architecture with information integration to the top level management; a higher degree of information technology in the production areas, an optional systems development resources utilization and a high profitability of the plan itself. During the study phase a series of theoretical definitions were fixed and used as a basis for the plan's design. A "common systems" approach was chosen as the development strategy instead of corporate systems or separate divisional efforts. Top management should be highly involved in the revisions of the plan, as well as qualified users should be chosen as project managers. The systems architecture should grant the information integration to the corporate level, in order to support an integrated planning and administration environment for the corporation. A total of 15 projects were defined, involving 570,000 man-hours and shifting the development efforts towards the production and production services areas. The paper presents a critical evaluation of the whole process, showing its good and bad aspects and a positive global balance. It also points some suggestions and hints to any corporation who wishes to get involved in a similar experience.

Jan 1, 1989

By P. Bottomley, M. Matthews

Maintaining an acceptable thermal environment in South African gold mines becomes increasingly difficult as mining progresses to greater depths where higher virgin rock temperatures are encountered. Current environmental practice offsets the resulting high heat loads by installing large refrigeration plants. However, with the continued escalation of refrigeration costs, it has become necessary to examine other methods for economically combatting the underground heat load. The Chamber of Mines Research Organization has recently been pursuing a programme to devise methods of reducing the flow of heat into underground workings at source. Although there are several sources of heat (such as machinery, men, and explosives), the most significant is that from the rock mass surrounding the workings (Bluhm et al., 1986a). The main thrust of the work has therefore been directed at predicting and devising methods of reducing this heat source. A great deal of theoretical work has been carried out on the prediction of underground heat flow. From a review of this work (Bluhm et al., 1986b) it became apparent that there are two major aspects which require attention, namely algorithms for predicting the heat flow around the advancing stope face, and a correlation of the theoretical work with accurate empirical data. In order to remedy this situation, new theoretical models have been developed (von Glehn and Bluhm, 1986), and heat flow measurements have been made in both a conventional stope (Bluhm et al, 1986a) and in a backfilled stope (Matthews u., 1987). A number of methods for reducing rock heat flow are being examined. These include the insulation of intake airways (Bottomley, 1985 ), backfilling with waste material of the worked out areas, and alternative approaches to the design of mining layouts, the mining method, and the choice of cooling strategy. This paper highlights the heat load reductions that can be achieved by backfilling the worked-out areas and by adopting concentrated mining. The first part of this paper summarizes the results of the measurements obtained in the conventional and backfilled stopes. The theoretical models are then described and comparisons are made with the measured values.

Jan 1, 1987

By R. J. Anderson, A. V. Castelli

In 1986, United States' barite production fell 48.9%, consumption - sold or used by grinding plants - was off 47.3%, and imports were down 63.8%. Meanwhile, world mine production decreased 29.6%, according to the US Bureau of Mines. However, value of US-produced barite FOB mine increased 46.51%, according to USBM figures. The declared value CIF US port of all imported unground barite decreased from $41.94/t ($46.23 per st) to $39.02/t ($43.01 per st). Nevada continued to be the leading US producer of barite with 69% of the total. It is followed by Georgia, Missouri, Tennessee, and California. The USBM estimates that 65% of the barite mined was used as a weighting agent in drilling fluids. The remaining 35% was used in the production of barium chemicals and as a filler. Most of the production from Missouri, Georgia, and Tennessee was used in the non-oilfield sector. This sector made up a larger percentage of the US produced barite in 1987 than it did in 1986, increasing the overall value per ton of barite. Barite consumption was at its lowest since 1963. It is estimated that 80% of the barite was consumed in the drilling fluid market. The remaining 20% was used in barium chemicals, glass, and as filler in plastics and paper. The decline of barite used in drilling fluid followed the decline in the average number rotary rigs operating - 964 versus 1968 in 1985. This was the lowest average number of rotary rigs operating since 1971. The non-oilfield market was up 5.3% in 1986. This increase can be attributed to the increased use as a filler in plastics. Imports of crude barite, though down nearly two-thirds, still made up 65% of the barite consumed in the US. China was the leading exporter to the US with 58%, followed by India, 15.4%; Morocco, 11%; Thailand, 5.4%; Mexico, 4.6%; Chile, 3.9%; and Ireland, 1.7%. Less than 1% of the imported ore was used in the nonoilfield sector. Imports of ground barite dropped from 64.4 kt (71,000 st) to 19.8 kt (21,800 st) in 1986. Of this amount, 14.1 kt (15,500 st) were used in drilling fluids in 1986 and the remainder for non-oilfield use. During 1986, more of the grinding plants supplying the drilling fluid market were closed. Dresser Magcobar and IMCO Services, a Halliburton company, formed M-I Drilling Fluids Co. Mine production in the US will probably decrease in 1987 due to the lower cost of imported ore. No significant change is expected in the drilling fluid market. The average number of operating rotary rigs is estimated at 950 in 1987 versus 965 in 1986. The nondrilling fluid markets (chemicals, glass, and filler) will follow the overall US economy. Bauxite and alumina R. J. Anderson, Ohio State University US bauxite production in 1986 dropped to a pre-World War II level, continuing a decline that began a decade ago. 1986 production totaled 450 kt (496,000 st), compared to 674 kt (743,000 st) in 1985. World production of bauxite also decreased in 1986. This reflected the soft market in alumina, aluminum, and related products. Total mine production worldwide came to 79 Mt (87 million st), down from 85 Mt (94 million st) in 1985. For the sixteenth consecutive year, Australian production of bauxite led all other sources. No other country approached the 28 Mt (31 million st) mined in Australia in 1986, despite a 4.4-Mt (4.9-million st) drop in its output from 1985. Other major producers in 1986 were: Guinea 11 Mt (12 million st), Brazil, 6.5 Mt (7 million st), Jamaica, 6.5 Mt (7 million st), and Suriname 2.8 Mt (3 million st). Despite weakness in world demand for bauxite, Venezuela, heretofore an alumina producer, is now pushing development of a new mining venture near the western border of the state of Bolivar. Plans call for barging bauxite down the Orinoco River to the Ciudad Guyana alumina plant, a distance of 650 km (400 miles).

Jan 5, 1987

By Greg P. Timms, John W. Bennett

Monitoring on Whites waste rock dump at Rum Jungle has provided a unique opportunity to assess the effectiveness of a cover in the medium term. Temperature and oxygen concentration profiles have been measured continuously, from some years before the cover was put in place in 1983 until the present. Lysimeters have been used to measure water infiltration rates. Heat and oxygen transport processes in the dump have been modelled and compared with field data, enabling oxidation rates to be quantified both before and after the cover was put in place. It has been found that the cover reduced the overall oxidation rate to between one third and one half of the uncovered rate. There is evidence that both the overall oxidation rate and water infiltration rate have increased in recent years.

Jan 1, 2000

By J. M. Cases

Diffuse - reflectance Fourier - transform infrared spectroscopy, Hallimond tube flotation and microelectrophoresis have been utilized to investigate the reactions involved in the adsorption-abstraction of K-amylxanthate on finely ground galena and pyrite. In order to work under well-controlled conditions both minerals were wet ground in a specially built laboratory stainless steel or iron mill. Four surface products were found to be formed on galena: monocoordinate lead xanthate, non-stoichiometric lead xanthate, dixanthogen, and amyl carbonate disulphide. Only dixanthogen was observed on pyrite after using stainless steel rods, while ferric iron xanthate was found when iron rods were utilized.

Jan 1, 1989

By J. E. Garlanger, R. K. Shrestha

During mining, the surficial aquifer and, in some cases, the top of the uppermost confining unit within the mined areas are excavated. Portions are removed from the area for resource recovery. Until the mined areas are reclaimed, the surrounding unmined area continues to dewater. The impact of mining and subsequent restoration of the surficial aquifer on the ground and surface water resources of the watershed affected by the mining will be described. This will be done in terms of ground water recharge, ground water levels, and base flow and runoff to surface streams. Data from actual mining situations will be used in analyses and discussion. Recommendations will be made for further research.

Jan 1, 1992

By David Akers, Clifford Raleigh, Glenn Shirey

Under a Cooperative Agreement with the U.S. Department of Energy’s National Energy Technology Laboratory (NETL) and the Mining Industry of the Future Program, CQ Inc. is demonstrating the GranuFlow™ process for improving the recovery of fine-sized coal in commercial coal preparation facilities. The State of Pennsylvania’s Energy Harvest Grant Program is also providing funding for this project. The GranuFlow technology involves the addition of an asphalt emulsion to a slurry of fine-sized coal (<100 mesh or 0.15 mm, typically froth flotation concentrate) before mechanical dewatering in screen-bowl centrifuges. The emulsion selectively agglomerates the carbon-rich particles, resulting in increased particle size and improved recovery of the coal fines during the dewatering process. This paper summarizes the test conditions and current results for both bench-scale investigations and full-scale commercial plant demonstrations.

Jan 1, 2005

By S. H. Advani, J. K. Lee, K. S. Chan, J. M. Avasthi

A summary of field equations governing the hygro-thermo-mechanical (coupled temperature, moisture, and stress) response of geological media is presented. The applicability of these equations, with appropriate boundary conditions, to the study of basic mechanisms associated with underground coal gasification (UCG) process is discussed. In particular, the phenomenon of stress-induced spalling resulting from intense drying near the gasified cavity and in situ effects is investigated by means of the finite element method. Some typical results from sample finite element model representations are presented for the evaluation of field experiments.

Jan 1, 1986

By V. R. Manukonda

Selective flocculation of iron ores is extremely sensitive to the type and the amount of soluble salts in pulp solutions. Chemical precipitation of alkaline earth ions combined with ultrasonic treatment deactivates their adverse effects without using any environmentally ill-defined reagents. The manner in which ultrasonic treatment affects starch adsorption on hematite, dissolution of quartz, and selective flocculation process was investigated. Selective flocculation tests were conducted in the presence of up to 400 ppm calcium ion on a quartz-hematite mixture by precipitation as calcium carbonate, and the role that silicate ion generated by ultrasonic treatment plays in achieving the selectivity of separation is discussed.

Jan 1, 1987

By B. V. Close

Surface mining regulations together with mine and reclamation planning require collection of large amounts of geologic and hydrologic data for both new and existing mines. Recently developed microcomputer software facilitates the integration of this information from computer databases into ground-water flow models. The databases are used to identify areas which require dewatering and/or depressurizing and for generating contour maps of aquifer parameters. Gridded versions of these contour maps are incorporated into finite difference ground-water flow models which are used to design dewatering and depressurizing well fields and to estimate the effects of ground-water pumping and pit progression on local ground-water levels.

Jan 1, 1988

By A. M. Marabini

Flotation of rutile with N-benzoyl-N-phenyl-hydroxylamine (N-BPHA) has been investigated. Initially, floatability tests were performed in a Hallimond tube. The results indicated that rutile was floatable in the pH range from 2 to 4 at N-BPHA concentration between 2x10-3 M and 2x10-2 M. Selectivity against hematite was recognized when operating at pH values below 2. Following the hypothesis of the formation of a surface chelate between N-BPHA and titanium ion, this compound was precipitated from a solution of Ti(SO4) to which N-BPHA was added. I.R. spectrometry oft the rutile before and after treatment with N-BPHA solution confirmed the presence on the rutile surface of the same compound. The absorption isotherm and kinetics were determined by analyzing N-BPHA in solution with an U.V. technique. A hypothesis for the mechanism of adsorption of N-BPHA on rutile is suggested.

Jan 1, 1982

By B. K. Sternberg

Since 1986, we have developed a series of electromagnetic (EM) sounding systems at the Laboratory for Advanced Subsurface Imaging (LASI). These may be categorized by their frequency ranges: low frequency (LF, 30 Hz to 30 kHz), medium frequency (MF, 1 kHz to 1 MHz), and high frequency (HF, 30 kHz to 30 MHz). We have applied these EM systems to a variety of targets, including: mapping of plumes of contaminated groundwater, tracing leachate for an in-situ leaching operation, locating buried hazardous waste, identifying subsidence-prone zones and detecting buried voids. These systems are also applicable to exploration for ore bodies. Currently, our sounding system uses a vertical magnetic field vector. Previous systems of this type required a slow and relatively inaccurate manual rotation of the sensing coils. The systems also used occasional calibrations of the measuring system. We have developed a 3-dimensional mathematical rotation procedure for the data, as well as a simultaneous, high-accuracy, calibration method. These new developments have greatly increased the speed of the measurements, as well as improving the accuracy of the ellipticity data. We use stepped-frequency measurements along with narrow-band filtering to allow accurate measurements, even in high-noise areas. We typically obtain ellipticity measurements at eleven frequencies and along densely sampled profile lines. We use neural networks to help interpret the measured ellipticity patterns. Neural networks can be trained to relate the measured ellipticity patterns to earth resistivities or to discrete targets buried in the earth. The neural network training may use theoretical EM responses calculated from computer codes for relatively simple structures. The theoretical EM response for many complex targets that are of interest cannot currently be reliably calculated, even with the largest supercomputers available. We have therefore chosen to do some of the training using theoretical EM responses generated in a full-scale modeling tank located at our Avra Valley Geophysical Test Site. We have also developed data-visualization software to help interpret the large data sets produced by this system.

Jan 1, 1997

The use of belt air in underground coal mines has been a continuous discussion since it was first introduced in the Federal Coal Mine Health and Safety Act (Coal Act) of 1969. Although the Coal Act prohibits the use of belt air to ventilate active workings, there were two exceptions prior to the 2004 Final Rule. There have been several major studies/rule-proposals by MSHA since 1985 and the most recent of which is the Technical Study Panel (TSP) established by the Mine Improvement and New Emergency Response (MINER) Act of 2006 to study the use of belt air and related issues. This paper reviews the history of belt air use, its associated controver-sies, and more specifically, the 20 recommendations unanimously approved by the TSP.

Jan 1, 2009

By M. Hancer, J. D. Miller

It is known from soluble salt flotation practice that the K, Mg double salts of kainite (KClMgSO43H2O), and carnallite (KClMgCl26H2O) are difficult to float and must be converted to other salts such as schoenite (K2SO4MgSO46H2O) and sylvite (KCl) in order to recover potash values. The flotation characteristics of these double salts have now been confirmed in some detail by carefully controlled laboratory experiments with both cationic and anionic collectors. The experimental results are discussed in view of recent experimental findings regarding the flotation characteristics of simple salts, in which the flotation response was shown to be determined by the interfacial water structure and whether the salt could be considered to be a water structure maker or a water structure breaker. The same approach can be use to explain the flotation response of the potassium double salts ; schoenite, kainite, and carnallite. In addition, the sign of the surface charge of schoenite (K2SO4MgSO46H2O), was determined as a function of pH from nonequilibrium electrophoretic mobility measurements. Schoenite appears to exhibit three charge reversals (CR) which can be explained based on surface hydrolysis reactions. The flotation behavior of schoenite is further considered based on solution chemistry calculations, electrophoretic mobility measurements, and microflotation results.

Jan 1, 2001

By M. A. Schimmelpfennig, A. D. S. Gillies

M.J. McPherson Having worked on the thermodynamics of air/liquid-water mixtures passing through the surface fans of deep mines, I find this paper of great interest and congratulate the authors on producing it. There are two matters, however, deserving discussion. First, the authors have described the classical theory of fog formation with fogging occurring at "supersaturation." In fact, the process of fog formation begins well below 100% humidity. The more strongly hygroscopic nuclei in the atmosphere will attract water molecules and begin to grow at a relative humidity perhaps as low as 70%. The process is a dynamic one with both condensation and evaporation taking place throughout the mixture on microscopic liquid surfaces. As saturation is approached, the rate of condensation accelerates rapidly producing the familiar reduction in visibility. Hygroscopic nuclei are present in all natural atmospheres and under the appropriate conditions of pressure and temperature, will produce clean fogs. However, if the air is polluted by particulates from combustion or other processes then the resultant coagulation with growing liquid particles may produce dense (and sometimes photochemical) smogs. It is this process that is likely to occur in underground mines when moist air is cooled below dew point. Second, the authors have summarized very well the individual measures that might alleviate the problem. In particular, I agree that neither heating nor refrigerating the air, by themselves, provides a satisfactory solution. However, there is a combination of these that provides a neat and effective control of fog formation. This involves a small, self-contained refrigeration unit within a duct but without the usual external heat rejection facility. The air is cooled below dew point and, hence, dehumidified on passing over the cold evaporator coils. The heat from the condenser is rejected back into the air downstream from the water eliminator, as shown in Fig. 1. The duct configuration can be designed to create good mixing at the outlet. I have used a climatic simulation program to illustrate the effect, assuming a 500-m (1,640 ft) long airway of cross section 60 m2 (645 sq ft), an airflow of 9 m3/s (318 cu ft per sec), inlet conditions of 19/19.25°C (66/67°F) wet bulb/dry bulb temperatures, a virgin rock temperature of 17°C (63°F) and typical rock thermal properties for a hard-rock mine. I have also assumed that 10% of the rock surface is wet. Figure 2 shows the variation in temperatures along the airway if no measures are taken. The relative humidity remains close to 100% and condensation will occur throughout the length of the airway. Before any such installation is designed, the exercise must, of course, be repeated for each location with accurate data. However, this example demonstrates the potential of the system. The idea is not new - the principle is sometimes used in air-conditioning plants for buildings. Figure 3 shows the effect of removing 30 kw of heat by evaporator coils sited 40 m (131 ft) along the airway and rejecting that heat (plus another 10 kw of compressor and fan power) into the air at 60 m (197 ft). Condensate water is produced, at a rate of 0.45 L/min (0.12 gpm). The result of this sequential cooling/dehumidification/heating process is to separate the wet and dry bulb temperatures along the length of the airway. The relative humidity increases from 80% at the duct outlet to 92% at 500 m (1,640 ft). The airway is maintained free from fog.

Jan 11, 1983

By Daniel P. Farjeat, Hector A. Canseco, Juan M. Schmitter

Since the early sixties, tunneling in the soft clay of Mexico City, has been done with the aid of open face shields and recently with compressed air. The use of pressurized shafts up to 1.5 kilograms per square centimeter, (147 kilo pascals) with vertical locks to launch the shields, have been used in two cases. After advancing almost 200 meters of tunnel, the same vertical locks were transformed into horizontal locks, to continue the work. Due to the high decompression times involved, it was necessary to install long locks, using the tunnel itself as part of the system. This article describes those cases.

Jan 1, 1981