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By Wang Zuoyu

The manuscript of this paper was not available for publication when the Proceedings went to press. Should the author elect, he may distribute copies to the time of the Symposium.

Jan 1, 1986

By Joe W. Cotton, Thomas A. Wheeler

This paper briefly covers theories behind caking of crystalline salt particles, and methods of its prevention. The main factors that influence the extent of caking are humidity, storage pressure, temperature variations, and length of storage time. Careful adherence to control- ling these variables are more critical than the addition of even the most efficient anticaking reagent. The principle characteristics that a successful anticaking reagent must possess are: high retention at the temperature of application, good coating of reagent on the particle surface, capability of in- creasing the hydrophobicity of the particle, reducing the surface tension of liquids, and/or creating of a barrier between particles that prevent contact between particles, and modifying the crystal structure of the salt between the particles. Methods to evaluate the reduction of caking tenacity with the application of various anticaking reagents, reagent volatility and reagent degradation in plant and laboratory scales are discussed. Various types of anticake reagents used today in industry are organic active and inactive reagents, inorganic inert and inorganic salt crystal modifying re- agents.

Jan 1, 1986

By K. Biswas, P. Tsang, S. S. Peng

A survey was undertaken in late 1993 and early 1994 to gain insight into the current status of pillar-design practice in underground coal mines in the United States. A total of 552 room-and-pillar mines and 75 longwall mines were surveyed to collect general, geological and mine-plan information. The collected information was critically analyzed with special emphasis on the pillar-design criteria adopted in these mines. A safety factor analysis was also carried out for the pillars in the room-and-pillar mines.

Jan 1, 1997

By R. M. Carland, F. F. Aplan

The ion-exchange capabilities of natural zeolites from the western United States, representing the species chabazite, clinoptilolite, erionite and mordenite, have been studied because of their potential use in environmental remediation and in hydrometallurgical processes. These raw zeolite samples were found to contain Na+, K+, Ca+2 and Mg+2 as exchangeable cations, and all of these, with the exception of Na+, were found to seriously interfere with the exchange of Cu+2 from solution. Placing these zeolites in the Na+ form was found to increase their cation-exchange capacity, often massively. In addition, the elution of Cu+2 from the Na+ pre-exchanged zeolite is greatly facilitated when the deleterious K+, Ca+2 and Mg+2 have been largely expelled. The relative influence of these deleterious ions on the uptake and elution of Cu+2 was determined.

Jan 1, 1996

By E. T. Balazs

Share of developing countries in world bauxite resources mining and processing. Technical assistance of the United Nations Industrial Development Organization to the developing world in the field of bauxite evaluation and processing. Review of selected projects of bauxite research and development aimed at creating indigenous capabilities in developing countries: "Assistance to the bauxite aluminium industry of the People's Republic of China". Project activities. UN inputs. Achievements. Follow-up. "Upgrading the scientific and technological capabilities of the Jamaica Bauxite Institute". Project activities. UN inputs. Achievements. Expected follow-up. Assistance to the establishment of an "Aluminium research, development and design centre" in India. Project activities. UN inputs. Achievements. Follow-up. "Establishment of an aluminium institute for research and development in Titograd, Yugoslavia". Project activities. UN inputs. Achievements expected. Second UNIDO group training on bauxite evaluation and processing to alumina October - November 1983 in Budapest, Hungary. Programme and coverage. Show of movie picture on organization and execution (15 minutes). Significance of UNIDO's assistance to the developing world in bauxite research and development. References.

Jan 1, 1984

By Michael Deutscher, Jozef F. Zurawski

Part of Capital Improvement Project SE-754 tendered by New York City Department of Design and Construction included installation of a 96-in. (2.47 m)diameter sewer by pipe jacking methods. The pipe selected by the Contractor, EIC Associates, Newark, New Jersey, was a glass-fiber-reinforced thermosetting resin pipe installed in two reaches: 72 m (235-ft.) and 222 m (728-ft.). The machine selected for the excavation was an open face shield. This paper describes the set up of the tunneling operations, subsurface conditions, progress of excavation, pipe performance and other details of the project including unexpected difficult ground conditions that were encountered during excavation and how these conditions were overcome.

Jan 1, 2003

By Howard J. Haselhuhn

The effectiveness of selective flocculation and dispersion processes for the concentration of hematite ore are strongly dependent on the ionic content of the process water. It has been noticed that magnesium ions are more detrimental to iron recoveries during gravity separation and flotation processes than calcium. This phenomenon was studied by measuring the zeta potential of hematite ore at various concentrations of sodium, magnesium, calcium, strontium and barium at a pH of 11. Results show that zeta potential inverts from negative to positive at concentrations as low as 0.16 mM of magnesium ions in the solution. It takes a significantly higher concentration (1.25 mM) of calcium ions to achieve the same effect. This difference is attributed to the ability of magnesium ions to adsorb to all surface hydroxyl groups, whereas calcium, due to its larger size, can only adsorb to every third hydroxyl group. This hypothesis was confirmed by results similar to those seen with calcium when this test was repeated with strontium and barium ions. The tendency for calcium ions to adsorb to every third surface hydroxyl group causes higher concentrations of calcium to be less detrimental to hematite concentration processes than magnesium.

May 1, 2012

By Barnaby J. Watten, Sibrell. Philip L., Brian J. Vinci, Andrew E. Friedrich

We evaluated a new process for remediation of acid rock drainage (ARD). The process treats ARD with intermittently fluidized beds of granular limestone maintained within a continuous flow reactor pressurized with CO2. Tests were performed over a thirty day period at the Toby Creek mine drainage treatment plant, Elk County, Pennsylvania in cooperation with the Pennsylvania Department of Environmental Protection. Equipment performance was established at operating pressures of 0,34,82, and 117 kPa using an ARD flow of 227 L/min. The ARD had the following characteristics: pH, 3.1; temperature, 10 OC; dissolved oxygen, 6.4 mg/L; acidity, 260 mg/5; total iron, 21 mg/L; aluminum, 22 mg/L; manganese, 7.5 mg/L; and conductivity, 1400 uS/cm. In all cases tested, processed ARD was net alkaline with mean pH and alkalinities of 6.7 and 59 mg/L at a CO2 pressure of 0 kPa, 6.6 and 158 mg/L at 34 kPa, 7.4 and 240 mg/L at 82 kPa, and 7.4 and 290 mg/L at 117 kPa Processed ARD alkalinities were correlated to the settled bed depth (p<0.001) and CO2 pressure (p<0.001). Iron, aluminum, and manganese removal efficiencies of 96%, 99%, and 5%, respectively, were achieved with filtration following treatment. No indications of metal hydroxide precipitation or armoring of the limestone were observed. The surplus alkalinity established at 82 kPa was successful in treating an equivalent of 1136 L/min (fivefold dilution) of the combined three ARD streams entering the Toby Creek Plant. This side-stream capability provides savings in treatment unit scale as well as flexibility in treatment effect. The capability of the system to handle higher influent acidity was tested by elevating the acidity to 5000 mg/L with sulfuric acid. Net alkaline effluent was produced, indicating applicability of the process to highly acidic ARD.

Jan 1, 2000

By D. R. Taylor, R. G. Goss

The use of clay granules as carriers for pesticides dates from the early 1940&apos;s and by the present day represents a business conservatively estimated at between 200 - 300 thousand tons / year in the U.S. alone. Aside from economic and specific target pest efficacy advantages, the use of clay granules as pesticide carriers also delivers a number of environmental benefits which will be reviewed. Topics to be discussed will include: 1) drift control (versus liquid sprays), 2) mobility (in the environment), 3) worker safety, and 4) transportation (spill) safety.

Jan 1, 1999

By Mark E. Smith

Large scale copper heap leaching in Chile began in November 1980 when the Lo Aguirre heap leach project was put into operation. At almost the same time, El Indio gold mine began production. While El Indio was not a heap leach project, it was Chile&apos;s first major bulk tonnage, open-pit gold deposit. This paved the way for the introduction of North American gold heap leach technology in the early 1980s. Heap leaching has become more popular in Chile during the past five years because it allows the exploitation of large but relatively low grade ore bodies at a reasonable cost. Pioneering research in hydrometallurgy carried out at some Chilean universities and at the Centro de Investigaciones Minero Metalurgicas (CIMM) played an important role. There are more than 10 large copper heap leach and solvent extraction/ electrowinning (SX/EW) process plants in different stages of development in Chile. Total production from these facilities will eventually increase Chile&apos;s present copper exports about 50%.

Jan 1, 1995

By P. Pal Roy, Ajit Raj Ostwal, M. M. Singh

Field investigations have revealed that sawdust can be used as an efficient additive to ANFO for carrying out production blasts in limestone mines. Sawdust can be used at a reasonably reduced cost without sacrificing fragmentation, muck profile and wall control. Such additives lower the detonation pressure of ANFO by acting as low-grade fuel that reacts or burns more slowly in the presence of ammonium nitrate than does fuel oil. On detonation, it eventually forms near-ideal oxygen balance that helps in liberating maximum energy to break the surrounding rock. It also forms a low-density stable mixture that helps in reducing loading density (kg/m) of explosive in the blasthole. Experiments performed at the Hirmi Limestone mine, M/s L&T, and at the Lambasta Limestone mine, M/s Jaypee Rewa Cements, showed the novel acceptance of the technique in a highly competitive market where cost reduction has been a major area of thrust.

Jan 1, 2003

By F. M. Doyle

Metal removal kinetics and metal ion selectivity in ion flotation were studied from a thermodynamic perspective. Surface tension data could be used with the Gibbs adsorption equation to quantitatively predict the metal-ion removal kinetics in alkylsulfate-Cu systems. However, surface tensions predicted cation selectivity coefficients in the sodium dodecylsulfate (SDS)-Cu-Ca and SDS-Cu-Pb systems rather poorly, although the predicted order of the selectivity (Cu2+ < Ca2+ < Pb2+) was correct. Another thermodynamic selectivity model, which used the Grahame adsorption equation and a geometrical analysis, predicted cation selectivity coefficients that agreed very well with experimentally measured values.

Jan 1, 2002

By Peter J. Tarkoy

The art of predicting rock excavating machine performance has become increasingly detailed and refined. Researchers using laboratory experiments and machine manufacturers using field observations have identified and defined mechanisms of failure, rock and tool interaction, and relevant design principles affecting them. Concurrently, practitioners have developed index tests which reflect rock properties relevant to machine performance. Empirical relationships between index properties and machine performance (penetration rate, cutter consumption, and machine utilization) have been established from past experience and are currently used throughout the industry. Contractors have used such relationships for estimating throughout the world. The detail in which geological, geotechnical, test, and project data, empirical relationships, and construction experience are utilized, is limited by time constraints imposed by the bidding period. To fully utilize all available data, methods of analysis, and construction experience, a simple computer program was developed for a microcomputer costing less than $7500. As a result, 1. machine performance predictions are detailed & reliable, 2. construction alternatives may be examined, 3. anticipated conditions & performance are graphically, documented & easily comparable to those encountered, and 4. results include a listing of assumptions & results of performance analyses & a graphic performance summary.

Jan 1, 1979

By R. J. Pindred

In his paper, Davis presents an overview of risk. He also introduces the Capital Asset Processing Model (CAPM) as a foundation for selecting the appropriate discount rate for a mining project. While applying portfolio theory is more defensible than the ad hoc adjustment of discount rates, the CAPM is not a panacea.

Jan 1, 1995

By M. H. Rauschkolb, J. A. Cremeens

Geotechnical solutions were developed for closure of two historic, remote underground mines in the deserts of southern California. Closure criteria included access closure, minimal site impact, and optimum use of native materials. The closure designs and construction activities incorporated techniques for protecting sensitive biota, particularly bats and desert tortoise. The types of mine openings that were closed include adits, declines, shafts, daylighted stopes, and dugout dwellings. The desert locations permitted implementation of cost-effective closure techniques that relied upon the use of native materials. The strategies and techniques developed for these desert closures are adaptable to other climates.

Jan 1, 2002

By Daniel W. Kappes

This paper examines the issue of heap leach cash flow based on some recent operational examples. After the first six months of operation, single-lift continuous heaps produce into salable bullion only 70% of the total recoverable gold stacked. This compares with "batch" heaps and lab columns which achieve 100% in two to three months. Multiple-lift heaps often experience a second cash flow depression as a result of the holdup of gold in the heap. Heap leach projects seldom fail based Oil technical pe1for111ance, but they often fail in the sense that they gmerate cash flow at a much slower rate than expected.

Jan 1, 2000

By Yiming Zhang, Yunpeng Li, Chun Feng, Ruyang Cao

In the past, the selection of the number of empty holes between blast holes heavily relied on the subjective experience of practitioners, leading to unsatisfactory blasting results. The number of empty holes between blast holes is particularly important for the perforation of explosive cracks. In order to determine the optimum number of empty holes for inducing the propagation of explosive cracks, a two-dimensional numerical model of two-hole blasting was established based on the continuous-discontinuous element method (CDEM) using polymethyl methacrylate (PMMA) as the medium, and numerical simulation of various working conditions was conducted; the simulation results are basically consistent with the PMMA model test. Through the analysis of blasting parameters, the optimal number of empty holes with a certain hole spacing is fitted. The following conclusions are drawn: (1) There is a threshold for variable x. When x exceeds 50, the presence of empty holes cannot lead to the perforation of explosive cracks between the blast holes. (2) When x is below 50, the optimal number of empty holes inducing the propagation of explosive cracks can be determined through fitting an empirical formula. By adjusting the number of empty holes between blast holes, a significant spacing between adjacent blast holes was achieved, allowing for effective penetration, so as to effectively “induce” the direction of the fracture zone and make full use of the energy of explosives. The research results of this paper are conducive to the research of directional blasting technology and provide certain references for the optimization of precision blasting parameters.

Dec 19, 2023

By C. G. Cunningham

The Marysvale volcanic field of west-central Utah contains large areas of argillically altered rocks (fig. 1) that, in turn, enclose smaller areas of fine-grained, medium-grade, replacement alunite deposits and coarsely crystalline, high-grade vein-type alunite deposits. The largest replacement alunite deposits are [ ] located peripheral to a 23-m.y.-old monzonite stock called the Central Intrusive (fig. 1). The deposits formed in near-surface, highly oxidizing environments at the tops of hydrothermal plumes that were spaced irregularly around the stock. The deposits are horizontally zoned from alunitic cores through kaolinitic to propylitic envelopes. Vertically, characteristic alteration minerals progress from a pyrite-propylitic alteration assemblage at the base, upward through alunitic, jarositic, and hematitic assemblages to a flooded silica cap as shown on figure 2. The silica caps are cut by hydrothermal explosion breccias. d34Sso4 values of + 11.5 to + 15.4 permil indicate that sulfur in the hydrothermal plume was derived from underlying Mesozoic evaporites. The sharp upward transition from pyrite- propylite to alunite probably marks the paleowater table, and the top of the flooded silica cap represents the paleoground surface. Basin-Range extensional tectonism began shortly after alteration, and buried the replacement alunite deposits in basins beneath sediments eroded from uplands. The deposits were only recently exhumed.

Jan 1, 2013

By R. J. Sweigard

One possible alternative for disposal of flue gas desulfurization (FGD) by-products is use as backfilling support material in highwall mine adits. The finite element method was used to analyze the variation of stresses and displacements within and around a highwall adit backfilled with FGD materials. The engineering properties of the rock material and the optimum mix proportioning of the FGD materials were obtained from laboratory tests. Finite element analyses show that, for the case in question, the roof displacement would decrease about 48 percent and the peak stress could be decreased about 58 percent. The study indicates that fairly weak FGD materials can eventually lead to stability of backfilled highwall adits.

Jan 1, 1996

By P. R. A. Andrews, G. Heinrlch, V. I. Lakshmanan

The paper describes a simplified method to chemically modify the surface of industrial mineral fillers. Four industrial mineral samples were taken from feedstock of commercial fine grinding operations. These samples were ground in bench scale ball mills and in the presence of various organic solvents. The ground products were measured for particle size distribution, surface area, surface chemistry by oil absorption and degree of organicJminera1 bonding. Where appropriate, the ground products were compared to commercially available surface modified, industrial mineral fillers.

Jan 1, 1990