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By T. D. Wheelock

The effect of various flotation depressants and surface treatments on the floatability of coal derived pyrites in the presence of XIBC was investigated with a modified Hallimond tube microflotation cell. The floatability of pyrite particles which had been cleaned with hot dilute (5%) hydrochloric acid was relatively large. However, the floatability of such particles was reduced greatly by the addition of specific depressants such as calcium hydroxide and also by treating the pyrite with an aerated warm alkaline solution. Although this treatment and these depressants also had some effect on the floatability of coal particles, the effect was much less than on the pyrite particles.

Jan 1, 1979

By Robert R. Dorfler

We ought not look back unless it is to de- rive from past errors, and for the purpose of profiting by dear bought experience. - George Washington During the mid 1960's, the application of automation was introduced to Climax by two process control companies. In 1969 Climax decided to seriously consider improved control of selected areas of their milling process after preliminary research had been completed on two rougher ball mill grinding circuits. In 1971 the Climax Mill Department developed a direct digital control scheme for rougher milling, designed a remote control center for handling process water, planned to automate the central steam heating facility for energy conservation, and convert other plant areas to automation. All twenty rougher grinding mills and the industrial water system were automated by 1977. The idea of automating central heating and other areas was abandoned although some fuel conservation items were installed at the heating plant. During this period from 1971 to 1978, the mill capacity was expanded from 39,000 metric tons per day to 43,000 metric tons per day and cyclone classification was introduced to rougher milling. Ore quality changes degraded the milling recovery from over 90% to less than 85%. This report describes the procedure the mill used in developing the automatic process and the occurances that affected the timing and fina1 control logic. The report deals primarily with the automation of the ball mill grinding, classification and flotation process as this was the bulk of the seven-year project.

Jan 1, 1979

By Isobel Clark

The problem of the estimation of ore reserves is essentially a simple one to describe. Given a set of sample data, at specified locations within a deposit, how can we estimate the value (or quantity) of ore in unsampled areas. The question may be posed of a whole deposit (global) or it may be more desirable to estimate smaller volumes within the planned mine area, e.g. stopes or blocks (local). Many methods have been evolved to tackle this problem, from hand-contouring of values by the mine geologist to extremely sophisticated geomathematical analysis. The main difficulty with any estimation method in this context is that it is almost impossible to check whether the "predicted" value bears a close relationship with the "actual" value. The only reliable way to decide if an estimation method has "worked" is to test the eventual value of ore against the predicted value. This is, more often than not, impossible - even allowing for the time factor involved. To know the "actual" value of a mined block it has to be sampled intensely, and these values with their positions recorded accurately. Alternatively, blocks may be passed through the concentration process individually and these results recorded. In most producing mines neither of these alternatives are practicable or seen to be-important. Another problem with comparing in-situ (so-called) mineable reserves with production figures is the introduction of many variables into the concentration process -- dilution, wastage, possible stockpiling, mill recoveries and so on.

Jan 1, 1979

By A. L. Mular

Optimization has been defined as the procedure of locating the best of something or the best way of doing something (Mular, 1971). Several texts (Himmelblau, 1972; Ray and Szekeley, 1973; Box and Draper, 1969; and Lee, Adams, and Gaines, 1968) on the subject are available. Such techniques have been placed in two categories, namely, off-line optimization and on-line optimization. For the former, an optimization model is employed; for the latter, a black box approach is involved. The essence of an optimization problem becomes obvious, when a response surface is considered. Suppose that a response (in this case, a criterion of improvement such as profit per day; grade of concentrate per day) denoted by Y, depends only on two variables, X1 and X2, which can be manipulated and controlled. The relationship between Y, X1 and X2 may be represented graphically as shown in Fig. 1. The diagram is called a response surface and its height, Y, is determined by X1 and X2. Points associated with equal responses constitute response contours. The shape is that of a hill, and optimization is the procedure of ascending the hill to reach the top (maximum). In practice, a response surface is subject to disturbances which distort its shape and shift its location from time to time, so that the exact location of a maximum is imprecise. Generally, constraints (restrictions of some sort) on responses and manipulable variables serve to define a region of permissible operation.

Jan 1, 1979

By H. Wesley Peirce

Although not generally recognized, Arizona has rock salt deposits unique in the United States. This uniqueness stems from a combination of two factors: (1) relatively youthful geologic age and (2) nonmarine origin. Although Arizona shares one deposit with Nevada (Figure 1, No. I) there are three others within the State (Nos. 2, 4, 5) that are believed to be both late Cenozoic in age (less than 15 million years) and nonmarine in origin. The only other recognized nonmarine salt deposits in the U.S. are much older, being in the early Cenozoic (Eocene) Green River Formation of Colorado and Wyoming. According to Johnson and Gonzales (1), the remaining rock salt deposits in the United States are marine and either Paleozoic or Mesozoic in age. Of the seven localities shown in Figure 1, six in the Basin and Range geologic province are believed to represent nomarine late Cenozoic phenomena and one (No. 7) in the Colorado Plateau geologic province is Paleozoic (Permian) in age and marine in origin. The following comments are intended to update the general geologic highlights of these deposits and to summarize the nature of their present utilization.

Jan 1, 1979

By Ken J. Richards

Industries dependent on pyrometallurgical processing generally find themselves facing a common set of problems, namely, serious environmental restrictions, heavy capital requirements for new facilities and for plant modernization, the certainty of rapidly escalating fuel costs, and the uncertainty of fuel availability. To remain competitive, it has become clear to industry that a new dimension of attention must be given to assuring the maximum performance from plant facilities already in place and from those that are built in the future. In the last decade or so, in response to these needs, there has been an acceleration in the development of new pyrometallurgical process concepts. Their application, though spotty, is increasing. A common factor in this developing base of technology is the need for effective process control. Digital control is an indispensable element of meeting the challenge. We cannot make the point, however, by looking to a general survey of instrumental control of pyrometallurgical processes. Computer control is in its awkward adolescence. Its application is so new that only isolated applications can highlight the trends. For this reason, the authors have chosen to focus on the nonferrous smelting industry to illustrate the status of pyrometallurgical processing and control. We believe this approach will best meet the interests of most readers of this edition and the background of the authors.

Jan 1, 1979

By Gregor de Ratmiroff

Field prospecting for bauxite in Venezuela has had a long but interrupted history having till now oferred but evidence of occurrences. The Venezuelan Government, trough the Corporación Venezolana de Guayana (C.V.G.), in 1974, formalized a major effort in prospection for bauxite in the Shield area and the Orinoco Delta in orden to establish the possibility of raw material supply to an upcoming and expanding aluminium industry. The Corporation, in turn, created and delegated to the Division of Geological Stu- dies, the formulation of the necessary infrastructure and execution of work in orden to determine the existence of economically exploitable bauxite deposits.

Jan 1, 1979

By Larry B. Bramlett

Regional radiometric, magnetic and geologic data point to Copper Mountain as an area of general uranium favorability. Sub-regional radiometric and magnetic data direct interest to a specific section of an overthrust Precambrian granite. Detailed magnetic and resistivity surveys in this area show local targets of interest, one of which corresponds to Rocky Mountain Energy's North Canning deposit. On the basis of these data a second and previously untested target was drilled resulting in the intersection of uranium horizons similar to those at North Canning. This integrated geophysical approach can be used for uranium exploration in geologically similar areas.

Jan 1, 1979

By J. A. Ryder

Compressed air is a relatively inefficient yet very convenient vehicle for transmitting mechanical energy. It is inefficient when compared to, say, hydraulic or electric energy systems since compressor and pneumatic machine efficiencies are quite low (in the range 20-65%) and reticulation losses can be quite high unless adequate pipe diameters are used to minimize friction drops. It is convenient in that capital and maintenance costs of pipes and machines are exceptionally low, the equipment is flexible and lightweight, the technological level is simple, the form of the energy supply is intrinsic- ally safe, and as an additional minor but psychologically important benefit, it provides a ready source of cooling and air supply for emergency use in deep hot mines. It is for these reasons that compressed air is a premier source of energy for many forms of underground equipment, in particular hand or rig-mounted rockdrills, some forms of rock- handling equipment, and a host of minor applications including agitators, small-lift pumps and temporary f am installations. In a typical S. African deep-level gold or platinum mine, compressed air generation accounts for 15% of the total mine electrical energy bill - more than is used for hoisting. In these mines it is not uncommon for over 100 km of underground compressed air piping to be installed, primarily to supply handheld rockdrills.

Jan 1, 1979

By E. Steel

The asbestifom habit is most commonly developed in certain amphiboles and chrysotile, but other minerals may also crystallize with this unususual habit, The habit may be characterized by 1) a fibril structure, single or twinned crystals of very small widths (generally less than 0.5 inn) which have gram with a common fiber axis direction but which are disoriented in the other crystallographic directions, 2) anomalous optical properties, primarily parallel extinction, 3) unusual tensile strength, 4) high aspect ratio, and 5) flexibility. In addition, there is evidence to indicate that some amphibole asbestos may have unusual surface properties.

Jan 1, 1979

By Stephen R. Hunt

This paper summarizes some preliminary results of the Illinois State Geological Surveys current investigation into surface subsidence resulting from coal mining in Illinois. The purpose of the study is to characterize-the vertical movements that may result from various types of underground coal mining. In general there is relatively little published information about subsidence from room-and-pillar mining as compared with longwall mining. The findings of this study, based on mining operations in a variety of geologic settings, delineate the magnitude, shape, and position of the subsidence profile. Comparisons of case histories of subsidence are based primarily on the extraction ratio and the general geometry of the mine (depth, panel width, and mining height).

Jan 1, 1979

By R. C. Troxell

Alternative methods of analyzing data acquired by the Morenci copper concentrator process control instrument-computer system are presented. Experimental measures of ore characteristics, for proposed feed forward control, are introduced. These include on-line indexes of ore hardness, ore density, ore dusting, and ore color. Comparison of metallurgical results before and after computerized process control implementation, allowing for differing ore grades, oxidation, hardness, and fineness of grind, also is described.

Jan 1, 1979

By Paul H. Earl

This paper discusses the evolution of a modeling methodology for explaining price behavior in the aluminum industry. Three generations are described, each utilizing as a foundation a microeconomic stages-of-processing approach. The second generation represents an improvement over the initial version, by incorporating more rigorous specifications of energy cost, and market strength (demand-supply balance) as well as endogenous treatment of market strength. International linkages across prices, costs, and markets, are the major extensions in the third generation. The discussion covers theoretical considerations, data problems and limitations, and model specifications. Simulation and forecasting properties of the models are also addressed.

Jan 1, 1979

By Paul M. Bommer

Abstract. This cater presents the development of and results from a computer model of in-situ uranium leaching. This model uses a streamline-concentration balance approach and is useful with a vide range of reservoirs. It can be used with any type of veil system, in a reservoir with or without boundaries, and with any form of descriptive kinetics. The model also includes the effects of dispersion and consumption of oxidant by minerals other than uranium. The effects of areal sweep, variable uranium concentrations, variable permeability, and the presence of oxidant consumers on uranium production are shown and discussed.

Jan 1, 1979

By R. B. Dunn

Whilst coalmining in the United Kingdom has been synonymous with longwall mining practice there have been changes in recent times which have enabled not only an extension in the length of the face to be worked but also in the ability to extract both thick and thinner seams. Additionally the industry has taken a positive view in the extension of retreat methods of extraction applied for different reasons both to particularly thick and specially thin seams. To permit development of a flexible programme to meet these diverse needs, it has been necessary to design machinery along with mining systems specially suited to these requirements. In reviewing current UK thinking special emphasis is made on the extraction of thinner seams generally of higher quality coal at moderate depths with a commentary on some recent results.

Jan 1, 1979

By D. C. McLean

One of the few innovations in hydrometallurgy in recent years has been the utilization of the chemistry of basic iron sulfates called jarosites. These have been used to make iron-zinc separations in the processing of zinc concentrates and are a very important factor in both the Duval and Cymet copper chloride processes as a means of preventing iron build-up in the closed leaching circuits. Copper oxychlorides are kindred compounds in that they are insoluble basic salts that form at low pH (1.5 to 3) and precipitate selectively from many base metal solutions. They have been reported in the chemical literature as far back as 1860, and a few of them are known in their mineralogical forms (particularly atacamite) usually as nuisance minerals because of their chloride content. Several patents describe their synthesis and use as fungicides and insecticides, and papers have discussed their formation as corrosion pro¬ducts on copper and brass piping (14).

Jan 1, 1979

By Rudolf Fahn

Bentonites are best suited for the preparation of acid activated clays with efficient adsorption properties. They are weathering products of acid volcanic ashes and their natural deposits are world-wide spread. The main constituent of bentonite is the aluminium hydrosilicate nontmorillonite with a high ability to swell. Süd-Chemie owns bentonite deposits in Germany and subsidiaries in Italy, Mexico and Arizona.

Jan 1, 1979

By J. A. Herbst

Grinding circuits employed in mineral processing operations are designed to produce feed materials for beneficiation steps such as flotation and magnetic separation, which are sufficiently fine to achieve good liberation of valuable minerals from gangue without over- grinding. In many respects, grinding is the most important unit operation in a mineral processing plant. If adequate liberation is not achieved during grinding, subsequent separation steps will yield low metallurgical recoveries and/or product grades. Grinding energy requirements and operating costs typically exceed 50% of the total expenditures of the entire plant. Because grinding is an inherently energy intensive process and grinding circuit capital and operating costs are high, it is essential that such circuits be run as efficiently as possible. In- creased efficiency in grinding usually translates to a decrease in the energy required to produce a metric ton (short ton) of product size material. It is generally accepted in the mineral industry that efficient grinding circuit performance can not be achieved without the use of some form of automatic control. This is true because all circuits are subject to random disturbances which, if left unchecked, will upset circuit performance and rob a plant of productivity. Such disturbances arise from a variety of sources including natural variations in ore characteristics (particularly hardness changes), uncontrolled water additions, feed-rate upsets, changes in crusher performance, and mechanical upsets such as blockages in pumps and classifiers. Many of these disturbances occur with a frequency which is too high for an operator to detect and react to efficiently. Disturbances which occur on a time scale of several minutes up to several hours can be effectively dealt with using automatic control.

Jan 1, 1979

By G. A. Kordosky

The control of pH in solvent extraction circuits is an old technique (1,2) but one which has a large potential for future use. The equilibrium position of any reaction which has hydrogen or hydroxide ions, either as products or as reactants, can be controlled by pH adjustment. Several examples of reaction types which are important in solvent extraction systems and which also show a pH dependence are shown in Figure 1. The examples were chosen to show the wide variety of reactions which fit the above criteria, but it is not meant to be a complete listing of all the possible reaction types, Some of the reactions are presented in a simplified form. It is the intent of this paper to discuss pH controlled solvent extraction reactions for some relatively simple systems through more complex ones.

Jan 1, 1979

By John W. Harshbarger

The Upper Santa Cruz Groundwater Basin lies in the drainage area of the Santa Cruz River in Arizona, and extends upstream from the community of Rillito to the international boundary, see Figure 1. The principal water use area lies between and includes the cities of Tucson and Nogales. A subsurface geologic barrier near Rillito provides a reasonable dividing line between the groundwaters of the Upper and Lower Santa Cruz Basins. The Upper Basin contains the Tucson and Sahuarita-Continental critical ground- water areas. The Tucson Water Use Area encompasses the Tucson metropolitan area and extends from the northern boundary of the Basin south to the boundary between the Tucson and Sahuarita- Continental critical groundwater areas near San Xavier. The San Xavier Use Area is the San Xavier Indian Reservation. The north and south boundaries of the Continental Use Area coincide with the limits of the Sahuarita-Continental critical groundwater area. The first study of groundwater in this valley was initiated by Dr. G. E. P. Smith in 1905 and the results were published in 1910, followed by a series of bulletins of the Arizona Agricultural Experiment Station, University of Arizona, covering the general field of groundwater development and utilization. Beginning in 1939, the Ground Water Branch of the United States Geologic Survey, in cooperation with the Arizona State Land Department and the Arizona Water Commission (AWC), have published a series of bulletins concerning groundwater occurrence and utilization in various areas of the state. In 1975 and 1977, the AWC published the "Arizona State Water Plan" (1), comprising a detailed inventory of water availability and use in the State of Arizona, and a study of alternative futures.

Jan 1, 1979