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By Nelson R. Shaffer

Glamorous, burgeoning biotechnology and mundane industrial minerals would at first glance seem to share little in common, but in truth, modern biotechnology depends on many minerals. Biotechnical processes also can be used in industrial mineral extraction and processing. Biotechnology is broadly defined as the application of biological organisms, systems, or processes to manufacturing and service industries. Genetic engineering has reinvigorated one of mankind's oldest sciences, biotechnology, into a booming business. Many modern processes depend on microorganisms cultivated under very stringent conditions in bioreactors. Minerals from carbonate, sulfate, chloride, nitrate, phosphate, and silicate families are used to provide essential nutrients and to regulate growth conditions (such as pH) in order to assure optimal growth of organisms. Certain cells or enzymes perform better when immobilized upon or within solids, and minerals are often used to immobilize cells, especially in continuous process. Minerals are also used extensively in separating and purifying products of biotechnology. Diatomite, zeolites, and silica are especially useful in purification processes. Industrial minerals also are commonly used to clean up large volumes of process water that must be treated. Biotechnology can be employed in exploration, extraction, and processing of geologic materials and in reducing mining or other environmental problems through bioremediation. Microbes have been shown to solubilize certain elements and so promote extraction of heavy metals, phosphate, aluminum, potassium, and even rare earth elements. In a related technique, unwanted materials such as pyrite impurities can be leached microbially to produce cleaner products in sand and clay industries. Microbial actions can modify surface characteristics and so enhance certain ceramic properties. Certain organisms can accumulate useful elements from dilute sources; others can transform unusable chemical species to more useful forms. Deterioration of stone, concrete, and even glass or brick, can be accelerated by microorganisms. Control of such biodeterioration could improve long-term performance of industrial mineral products. Microbial processes have shown promise in improving several mine-related problems. Certain bacteria help remove clays from phosphate slimes and other suspensions. Others are used to degrade cyanide or other organic chemicals such as floatation aids. Cells immobilized on clays have been especially efficacious in bioremediation. Biotechnology industries, like the industrial minerals industries, encompass huge ranges of materials and processes. Costs of products from these industries range from pennies to thousands of dollars per unit, and their products are vital for maintaining modern life styles. Many biotechnical processes depend upon industrial minerals and certain biological processes can be harnessed to do useful tasks in the minerals field. The interplay of industrial minerals and biotechnology is important today, and as biotechnology advances, its interaction with the industrial minerals industry can only increase.

Jan 1, 1995

By V. L. Jr. Davis, F. L. Stanley, P. J. Bethell

Fwe 3 m (10 ft) diameter Microcel™ flotation columns were installed at Clinchfield Coal Company's Middle Fork preparation facility in order to reduce product ash and increase recovery and plant capacity. The Middle Fork facility is utilized for the recovery of fine coal from a feed stream that consists primarily of 1 .5 mm x 0 material. The columns replaced conventional flotation cells for the treatment of the minus 150 pm fraction while spirals are used to upgrade the plus 150 pm material in the plant feed. The addition of the column flotation circuit resulted in an increase in plant capacity in excess of 20 percent while reducing the flotation product ash content by approximately 7 percentage points. Flotation circuit combustible recovery was increased by 17 percentage points. This paper discusses circuit design, commissioning, and sparging system design. Circuit instrumentation, level control, reagent system control, performance comparisons with conventional flotation, and general operating procedures are also discussed.

Jan 1, 1995

By S. Y. B. Subbarao, K. Ravindranath

Lead and Zinc concentrates are being recovered at Rajpura- Dariba (Distt. Rajsamand, Rajasthan, India) from a complex multi metal sulphide deposit since 1984 by selective flotation employing a large number of reagents. The cost of concentrates' production has been high. Due to the increased availability of concentrates world over and to be competitive, it is necessary to reduce cost of production. An effort has been made by the R.D. Department of Hindustan Zinc Limited to bring down the cost by resorting to production of Bulk Pb + Zn concentrate with enough Ag to make it attractive to the smelters. This paper gives an account of open cycle testing and locked cycle testing in the Dowa Continous Mini Flotation unit. The metallurgical data generated in the mini flotation unit indicate the possibility of obtaining smelter-acceptable bulk concentrates containing Pb+Zn 45%, Ag 400 ppm and graphite carbon about 3%. An in-plant trial in the 3000 TPD concentrator indicated that there would be savings through dispensing with and reduction in some reagents, lower power requirement, etc. Also, a substantial increase in revenue is expected due to higher recoveries by resorting to bulk concentrate production as against individual concentrates.

Jan 1, 1995

By M. T. Ityokumbul

Flotation columns and their variations are increasingly replacing conventional cells in mineral processing circuitry. While the operational characteristics of columns differ from those of conventional cells, the same scale-up methodologies are being employed in design. This practice may be attributed to poor understanding of the factors controlling throughput. The use of tall flotation columns is frequently justified on the requirement for increased particle residence time. It is shown that longer particle residence times in the column cell alone do not translate into increased recoveries. Throughput data from several industrial flotation column installations is presented. An attempt at using dimensional analysis to provide scale-up methodology for the factors controlling column throughput is made.

Jan 1, 1995

By G. F. Revey

Most commercial explosives contain 70 to 94% ammonium nitrate, by weight. When portions of these explosives end up in shot rock and ore, through spillage or incomplete detonation, ammonia and nitrates leach out of them and into ground water. In recent years, State and Federal regulators have been applying more stringent water quality standards, particularly at new mines and development projects. Bulk ANFO, a mixture of ammonium nitrate and fuel oil, is the explosive of choice at most mines, when mining conditions allow it. ANFO use is desired because it less costly than other explosives, but when spilled it dissolves readily in water. Several case histories in the United States and Canada show a clear connection between uncontrolled losses of bulk explosives and high nitrate levels in mine effluents. Mining companies have tried several approaches to reduce ammonia and nitrate levels in groundwater. They either control explosive losses, or they treat mine effluents at the end-of-pipe. This paper addresses the former solution --controlling explosive losses. For both packaged and bulk explosives, guidelines designed to limit losses during storage, handling and use, are described in detail.

Jan 1, 1995

By Cathleen J. Webb, Arden D. Davis

Begun in 1992, an abandoned and inactive mine inventory in the Black Hills National Forest has resulted in a hazard ranking of the most severely affected sites. For purposes of the inventory, the Black Hills were divided into three main regions: the northern Black Hills, with primarily gold mines; the central Black Hills, with pegmatite mines and some gold mines; and the southern Black Hills, with primarily uranium mines. A computerized data base has been developed along with standard forms for field crews. The forms were designed to provide maximum compatibility with other abandoned mine inventories on various federal and state lands. Measures recommended for the most hazardous and heavily affected sites include regrading of unstable slopes, fencing of open shafts, and remediation of the most severe acidic mine drainage problems. Specific examples are illustrated where remediation and safety measures were recommended or have been implemented. The vast majority of the sites, however, needed little or no remedial action.

Jan 1, 1995

By Kal V. S. Sastry

Mathematical and expert system models are being used extensively for mineral process engineering; nevertheless, standardized methodologies for their computer implementation do not exist. In meeting this need, this paper introduces the concept of a process software model, or more specifically an object-oriented software model, and presents a detailed methodology for its development involving software model specification and development. These software models provide a formal basis for the subsequent design and construction of software objects corresponding to the real world process objects.

Jan 1, 1995

By J. E. Urosek

The Mine safety and Health Administration (MSHA) formed the Mine Ventilation Bleeder and Gob Training Committee in 1993. This committee was charged with developing a training course designed to enhance the knowledge and understanding of practical bleeder ventilation systems. The course will probably include a discussion on the theory behind bleeder system design, an in-depth look at the strengths and weaknesses of the basic bleeder system types, case studies, and a review of the systems currently in use. A database on active underground bituminous coal mines, gob areas, and the bleeder systems presently used was developed from questionnaires distributed to nine Coal Mine Safety and Health (CMS&H) districts. Representative systems were selected for thorough investigation to develop case studies. This paper introduces some of the material to be included in the course, including a description of basic bleeder system designs, a review of a portion of the database, and facts about the gob areas and bleeder systems investigated for the development of case studies.

Jan 1, 1995

By I. K. Gilmore

Texasgulf Inc. currently operates an open pit phosphate mine in the central coastal plain of North Carolina. The area of phosphate deposition lies within the Aurora Phosphate district which consists of an embayment which is in the center of the Neogene phosphate deposition. A variety of solid and liquid fertilizer products are produced at the Texasgulf complex. One of these products is known as North Carolina Natural Phosphate (NCNP). New potential for use of unacidulated natural phosphate, now exists in regions with acid soils due to the discovery of the findings from recent research, cost advantages, and moves to reduce chemical inputs.

Jan 1, 1995

By P. O. Lindahl

The U.S. Bureau of Mines initiated research to improve the safety and efficiency of transporting coal from deep underground mines using a balanced air-lift hydrohoist. A 50-m-high pilot-scale model was constructed and tested to evaluate the feasibility of hydraulically hoisting a coal-water slurry in a U-tube pipeline from the mine level to the surface with the assistance of compressed air. A prototype screw feeder is used to continuously compact and inject 5-cm or less run-of-mine coal into a pressurized 20-cm-diam pipeline. Production rates up to 40 metric tph at an airflow of 1.5 m3/min were achieved with the model, and coal size degradation was relatively minor. Modifications are in progress to achieve 100 tph at an airflow of 2.8 standard m3/min injected into the riser pipe. Pilot-scale results indicate that an air-lift hydrohoist system is a feasible, cost-effective alternative to conventional skip hoisting that can be installed in existing shafts or surface-drilled holes closer to the face area. Air-lift hydrohoisting offers advantages of infinitely adjustable slurry flow rates, reduced pressure at the point of coal injection, and flexible design that can be combined with hydraulic pumping. Proposed design changes are discussed for coal transport, mine layouts, ventilation, fire control, and escapeways using this system.

Jan 1, 1995

By R. Bhaskar

Although the health effects of airborne dust in underground coal mines are well recognized, a lack of understanding remains about the fundamental mechanisms of dust generation, transportation, deposition and dust-lung reaction. This study was intended to contribute to the understanding of dust transportation and deposition mechanisms in underground mine airways. Data from in-mine experiments carried out under controlled conditions in a straight section of a longwall panel with three different airflow velocities and two different types of coal dust (bituminous and semi-anthracite) were used to determine the turbulent deposition rate of dust particles. Measurements of ambient dust concentrations and deposition along the mine airway were obtained and the total dust deposition velocity (rate) was calculated. The deposition velocity of turbulent diffusion was estimated based on the experimental data and theoretical equations. The effects of airflow velocity, particle size, particle density and distance from the dust source on gravitational, turbulent and total dust deposition are discussed along with related conclusions.

Jan 1, 1995

By Jacek Galas, Stanislaw Lenczowski

The image of the flotation froth surface in the mineral processing plant contains the information about its composition. This information can be very useful for a technological process automation. Images, captured in the optical part of the measurement system were read by the computer, then were transformed and analysed digitally. The set of image parameters, extracted from an image transforms, was evaluated by statistical analysis. The recognition algorithm constructed in this process allowed to estimate the froth composition.

Jan 1, 1995

By Taneomi Harada

Mine drainage has high acidity and sometimes contains more than the allowable concentration of ionized iron. In such a case, mine drainage is neutralized with calcium carbonate and calcium hydroxide to separate precipitates, such as the iron hydroxide and gypsum generated. Currently, most of these precipitates are not utilized and are accumulated in tailing dams. As a result, the service life of the tailing dams is reduced. This becomes a matter of concern, since securing sites for such dams is difficult. A most effective means of solving this problem would be to promote utilization of these neutralized precipitates. This paper reports on the results of studies on neutralized precipitates produced at the old Matsuo Mine (Iwate Prefecture), which has the largest neutralization treatment facility in Japan. As a result of the studies, the following was proposed regarding application of neutralized precipitates. Utilization as ferrite: Mix ferrous hydroxide and ferric hydroxide in water to synthesize magnetite-like ferrite, to be used in the manufacture of magnetic markers for a mobility support system for blind pedestrians, or in producing magnetic fluids for sink-and-float separation of nonmagnetic metals and nonmetals. Utilization as hematite: Bake ferric hydroxide to produce hematite, thereby extracting metallic iron for paint pigment as well as for the manufacture of ironware by local industry. Production of aluminum sulfate: Precipitate aluminum ions from water and add sulfuric acid to produce aluminum sulfate.

Jan 1, 1995

By L. Laage, R. Greur, W. Pomroy

MFIRE is a mine ventilation and fire interaction computer simulation program. It allows transient state ventilation simulation and features mass based flow rates, natural ventilation, air recirculation, fan curve fitting, airflow reversal and product of combustion tracking. MFIRE was designed to accommodate the needs of the mining industry, for routine ventilation calculations and mine emergency planning. This paper describes recent work by the US Bureau of Mines and Michigan Technological University to improve MFIRE by incorporating humidity in the mass flow and heat exchange calculations, a data file preparation program, and variable reference density in the network calculations. Recent bug fixes are also discussed.

Jan 1, 1995

By Terence H. Fisher

The use of more productive mining equipment, the tendency to longer development and the advent of new mining methods have introduced new challenges to the ventilation practitioner in Western Australia. These new and more productive mining methods have presented specific ventilation problems, that if not properly addressed, present additional hazards to miners. Factors influencing the increased hazards are larger diesel units, the use of series ventilation systems and an increasing incidences of long (single entry) development and production headings where miners could be trapped in a fire emergency. This paper discusses these new ventilation safety challenges, how they have been and are being addressed, and the legislation changes that take cognisance of technological developments.

Jan 1, 1995

By D. Hongjun

In this paper, the flotation rule and behaviors of kyanite-group polymerphous minerals were studied in modified Hallimond tube in detail. Furthermore, the energy change of collector/mineral systems before and after adsorption and the net charge densities of the atoms on the minerals surfaces were calculated by use of quantum chemistry. The flotabilities in minerals were successfully explained.

Jan 1, 1995

By Werner Stahl, Karsten Keller

Vibration screens are commonly used not only in classifying bulk material but also in dewatering it. The lack of a comprehensive physical theory of dewatering often leads to difficulties in the design and operation of the vibration screens. Firstly, the dewatering of bulk material will be shown, based on a physical model. Because of the oscillatory motion of the liquid in the bulk, the inertial force of the accelerated liquid and the dripping of water out of the bulk or screen must be taken into special consideration. The physical model put forward shows the effect of the various operations parameters of dewatering screens. The comparison between dewatering theory and practice will be shown by measurements using coal, limestone, etc. Dewatering measurements, which have been conducted on a vibration screen, demonstrate that different vibration frequencies and rates of acceleration lead to different residual moistures. Finally, the possibilities of improving vibration dewatering will be described.

Jan 1, 1995

By Liu Hanzhao, Jin Yongduo

Many gold ores which are not only submicroscopic but also rich in arsenic and organic carbon, for example Dongbeizhai Mine, have been found in china. These ores belong to the most refractory ores The key to the recovery of gold from these ores is preoxidation. Dongbeizhai ores have been tested with biooxidation, chlorination, double oxidation, acidic and alkaline pressure oxidation, catalytic oxidation, NITROX and roasting. To date it appears that either roasting or pressure oxidation is optimal. It is suggested that the flotation-roasting (or pressure oxidation)-CIL process should be used to treat this type of ore.

Jan 1, 1995

Along with kyanite and sillimanite, andalusite forms part of the sillimanite industrial minerals trimorphous alumina-silicate group. Theoretically, andalusite contains about 60% A1203 and 40% Si02, with a Mohs hardness of 7 to 7.5 and a specific gravity of 3.0-3.2. Andalusite generally occurs in the contact metamorphic zones of schists and shales, constituting about 10% of the ground mass ore body. The 5- to 20mm- (0.2- to 0.8-in.-) long crystals are usually liberated through crushing and magnetic/heavy-media separation. Relatively minor occurrences of andalusite are found in Andalusia, Spain (where it was first identified), Portugal, the former Soviet Union, Ghana, South Korea, California and North Carolina. It also occurs in China, France and South Africa. The latter two represent nearly all the andalusite that is exported. Andalusite is an inert refractory raw material that does not require calcining before use. It involves an internal conversion to mullite after heating to 1400° to 1600° C (2552° to 2912° F). At higher temperatures of about 1800° C (3272° F), the mullite converts to corundum and liquid silica.

Jan 1, 1995

By B. K. Parekh

Sludge obtained during production of magnesium (Mg) metal from electrolyzing of molten MgCl2 contains entrapped magnesium particles. The sludge material containing the magnesium particles is a friable, continuous matrix of frozen salt mixture which may also contain some oxides and impurities. A dry process was developed for recovery of magnesium metal from the sludge, utilizing minerals beneficiation unit operations. The steps included selective comminution, screening, attritioning and tabling. Recovery of the high grade (+90 percent) metal was in the 70 percent range. The process is being commercially used in the U.S. The novel process was also successfully applied to a magnesium-alloy for recovery of metal from the sludges.

Jan 1, 1995