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By D. M. Bodily, M. D. Deo, E. M. Whitney

Field data from coalbed methane wells indicate a significant variation in composition as a function of flow rate and time. In particular, San Juan Basin wells have displayed an increase in C02 concentration over time. Prediction of gas quality is critical to the economic evaluation of any coalbed project. Previous models have forecast only pressure and production profiles, ignoring compositional variations. In this study a multicomponent model that incorporates binary isotherms for methane and carbon dioxide has been developed. An extended Langmuir isotherm is used for the adsorption representation and a constant separation factor (similar to relative volatilities in distillation) describes the phase distribution of the species. This separation factor depends both on the surface characteristics of the coal and on the adsorbing species. The chromatographic separation equations have been superimposed on Darcy's law flow. The formulation allows decoupling of the pressure and compositional partial differential equations. The equations have been cast in dimensionless form and solved for pressures and compositions. It is observed that the composition of the preferentially adsorbed C02 increases at the wellbore as a function of dimensionless time. The dimensionless time is directly proportional to the real time and coalbed permeability and is inversely proportional to the gas viscosity, coal porosity and the square of the length of the reservoir. As the separation factor increases, the compositional variation increases. This variation in produced C02 concentration is also greater when the initial C02 concentration in the reservoir is higher. A sensitivity study has been performed to identify the effects of important parameters such as isotherm variables and reservoir characteristics on pressure and composition profiles.

Jan 1, 1993

By A. E. Hall, K. R. Mutama

The wind tunnel has been used extensively for mine ventilation research and continues to be a valuable tool. The advent of the powerful personal computer has reduced the use of wind tunnels because several flow problems car be simulated and investigated quickly. This paper describes the recent design and construction of a wind tunnel which is now being used for mine ventilation aerodynamic research and teaching purposes. The wind tunnel has a square cross section measuring 900 by 900 mm and is 8485 mm long from the entrance to where it joins the fan. The tunnel was designed as an open circuit suction type and is attached to a 7.5 kW variable pitch axial flow fan capable of producing over 6 m3/s of airflow. The entire length of the wind tunnel can be used for flow investigations and all activities are visible since the sides are made of plexiglass. Results are presented from the test program to show that even without honeycombs and screens air flow symmetry is achieved.

Jan 1, 1993

By B. R. Satio, P. G. West-Sells, D. B. Dreisinger, B. J. Y. Leong, G. A. Kordosky

Electrolytic techniques have historically been used to remove arsenic, antimony and bismuth from copper refining electrolytes. However, both solvent extraction and ion exchange techniques have been heavily researched and in a number of cases commercially introduced. In this study a large number of solvent extraction reagents and ion exchange resins were screened to determine the selectivity of the reagents for impurity removal. Solvating extractants were found to efficiently remove arsenic from electrolyte. The extent of arsenic extraction increased in the following order: TBP < DBBP < DPPP < Cyanex 925 < Cyanex 923. Antimony and bismuth extraction from electrolyte were demonstrated with the reagent 2EHAP04. The ion exchange resins UR-3300 and Duolite C-467 were found to strongly extract antimony and bismuth from electrolyte. C-467 appeared to be superior to UR-3300.

Jan 1, 1993

By S. K. Kawatra, T. C. Eisele

Under normal conditions, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. To reduce this pyrite recovery, it is first necessary to determine the primary recovery mechanism, because different measures are required for reducing entrainment, locked particle flotation or true hydrophobic flotation. In this paper, evidence is presented that suggests that hydrophobic flotation is not the major mechanism for recovery of liberated pyrite; instead, the bulk of the recovered pyrite results either from simple entrainment or from being physically locked with floatable coal particles.

Jan 1, 1993

By R. D. Grove

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and, therefore, only assist in recalibrating the operators&apos; vision when major deviations occur. An image analysis system was developed by IMC Fertilizer to improve the accuracy and precision of the composition estimation process. It still relies on the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. Background The search for a quick and inexpensive technique for estimating phosphate flotation stream composition continues. There have been attempts at using "wet chemistry," nuclearmagnetic resonance, neutron activation, X-ray diffraction and other techniques reported on in the past several years. None of these have yet found its permanent place in the flotation plants of the Florida phosphate industry. IMC attempted to use wet chemistry to provide 7.5-minute estimates of final concentrate insol and tailings BPL. This was aborted after 36 months of plant operation due to the high operating costs for chemicals and an operator. There was also no significant economic improvement in the plant&apos;s operation. Another factor was the necessity to limit these crude analyses to only a few process streams, which were insufficient to achieve improved plant operation.

Jan 1, 1993

By S. W. Cavender

The analysis of the results of metallurgical experiments is often complicated by experimental errors and uncertainty, the complexity of the system being studied, and the confusion of correlation with causation. Consequently, comparative statistics are used to determine if a difference exists between the outcomes of tests, an estimate of this difference, and the precision of the estimate. This paper reviews the use of significance tests and confidence intervals for the comparison of results from two tests, the use of reference distributions, and blocking and randomization techniques to reduce unavoidable sources of variability. These techniques are demonstrated using plant and laboratory data.

Jan 1, 1993

By S. Monette, D. B. Dreisinger, D. Vleeschhouwer, G. B. Harris, G. A. Kordosky

A new process for the recovery of pure (>99.95%) palladium and platinum is described. The process, which has been tested at the pilot scale, comprises (i) the simultaneous solvent extraction of palladium and platinum by a new Schering Berlin reagent, TN 1911, (ii) washing of the loaded extractant to remove co- extracted impurities, and (iii) differential stripping of first platinum at pH 3, and secondly palladium with strong hydrochloric acid, and (iv) precipitation of palladium and platinum salts, followed by reduction to metal. The process is, unusually, a non-ammonia one requiring only small amounts of ammonia at the end where final purification may be necessary for particularly complex feed solutions.

Jan 1, 1993

By R. J. Lambert

The purpose of this paper is to discuss the application of mine design to the North DeLamar pit of NERCO&apos;s DeLamar Mine. Many discussions on mine planning and design focus on computerized mine modeling but neglect the final step of operating design development. Mine planning and design criteria used for the final layback in the North DeLamar pit are included along with a comparison of designed and as-built tonnages, grades and topography.

Jan 1, 1993

By Bryan Morris

Quebrada Blanca (QB) is a copper project located in the semi-arid Andean highlands of northern Chile. The operation is situated 170 km ( 105 miles) southeast of the port of Iquique and 30 km (18 miles) west of the border with Bolivia, at an altitude of about 4300 m (14,000 ft) (Fig. 1). The QB ore body is a secondarily enriched porphyry copper deposit containing reserves of 85 Mt (93 million st) grading 1.3% copper. Underlying the enriched zone is a significant primary ore zone containing several hundred million tons grading about 0.5% copper. In the late 1970s and early 1980s Falconbridge and its affiliates spent $20- $30 million exploring the deposit and conducting feasibility studies. Falconbridge, however, decided not to develop the property. It was returned to its owners, Empresa National de Mineria (ENAMI), a Chilean state mining corporation. In 1988, ENAMI announced its intention to privatize the property through public bidding. Cominco Resources, then 61% owned by Cominco Ltd., examined the property and the extensive data base developed by Falconbridge. In conjunction with its parent company, Cominco Resources submitted a proposal to ENAMI to construct an open- pit mine, with heap leaching and solvent extraction/electrowinning (SX-EW) processing facilities. The plan would use patented heap leaching technology developed by Sociedad MineraPudahuel (SMP), a privately owned Chilean mining company. At that time, a $150-million project that would produce about 45 kt/a (50,000 stpy) of cathode copper was envisaged.

Jan 1, 1993

By S. G. Zahony

The Moris gold deposit resides in a massive ridge-forming sulfide-poor epithermal quartz and calcite vein system and consists of a mineable reserve of four million tons of 2.1gm Au/ton. Post-mineral normal faulting along the hanging wall of the main fissure has caused a hogback-like exposure of the vein, allowing for inexpensive opencut mining. The vein formed between pre-Cretaceous(?) phyllitic clastic sedimentary units in the footwall and Tertiary andesitic volcanic rocks in the hanging wall. Part of the ore reserve is hosted in a Tertiary conglomerate that rests unconformably atop the phyllitic footwall sequence. The original unoxidized vein material contained substantially less than 1 gram Au/ton. A four-fold upgrading of gold occurred by enrichment when gold recrystallization took place in the electric fields of oxidizing pyrite cubes.

Jan 1, 1993

By Karel SPIRKO

The one-dimensional mathematical model of unsteady-state heat conduction through semi-infinite homogeneous and isotropic airway walls with convective heat and moisture transfer between their wet or dry naked surfaces and mine air with time variable temperature and humidity has been developed on the basis of introduction of acceptable simplifications of description of heat and moisture transfer between rock mass and mine air. The analytical solutions for computation of the temperature distribution and surface temperature of the airway walls and floor and for calculation of water vapour pressure near the wet surfaces at given time are obtained by means of the model presented. The presented solutions are derived for general conditions and they could be easily adapted to the actual ones. Results of the model represent basis for balancing heat and moisture transfer between mine air and its surrounding in deep mines under time variable temperature and humidity of the air and enable us to solve complicated dynamic changes of mine air temperature and humidity in an airway system by relatively simple mathematical tools. INTRODUCTION The importance of unfavourable influences and the costs of condition arrangements increases with mine depth. Precision demands on the methods which predict the environmental condition changes and by which it is possible to optimize condition arragements are still increasing. Environmental conditions in deep mines are determined especially by flow velocity, barometric pressure, temperature, and humidity of mine air. Therefore new and more exact mathematical models of mine air flow through airway system and those of heat and moisture transfer between mine air and individual important sources of heat and moisture are developed. The paper presented deals with description and solution of problems of heat and moisture transfer between mine air and airway walls as the rock mass is one of the important heat and moisture sources in deep mines. There are several different approaches to the problem. In some models the moisture transfer between mine air and airway walls is not considered at all. In other models the moisture transfer is described only by certain empirical coefficients. Simultaneous heat and moisture transfer is described seldom. This paper tries to describe in a simple way simultaneous convective heat- and mass-transfer processes taking place on wet naked surface of airway walls by means of corresponding

Jan 1, 1993

By Paul C. Jones

Summitville is an old mining district located south of Wolf Creek Pass in the southern San Juan Mountains of Colorado at an elevation higher than 3500 m (11,500 ft). The Summitville mine site is about 40 km (25 miles) southwest of Del Norte. The current mine, developed by Galactic Resources Ltd. and its subsidiaries in the mid-1980s, is on the north facing side of South Mountain. The area is drained by Cropsy Creek to the east and Wightman Fork to the north, both tributaries to the Alamosa River. Mining in the Summitville area began in 1870 when James Wightman discovered placer gold on what is now known as Wightman Fork of the Alamosa River. The first vein-type deposits were located in 1873 on South Mountain near the current Summitville Mine. Mining began in the district in 1875 and continued sporadically through 1942. Major mining episodes occurred from 1875 to 1894 and from 1926 to 1942. Total gold production from the mining district through 1949 totaled 7.5 t (240,000 oz). An additional 7.7 t (249,000 oz) were produced during Galactic&apos;s tenure. Natural degradation of the outcropping sulfide-rich veins in the area and the early mining activity, including development of the Reynolds, Dexter and Iowa drainage tunnels in the late 1890s, have polluted the streams draining the area with heavy metals and acidic water. Names of the various tributaries to Wightman Fork, such as Iron, Alum and Bitter Creek, testify to this natural pollution. This degradation has reduced, or killed, aquatic life in several area creeks, including Wightman Fork, for many years before recent mining activity.

Jan 1, 1993

By F. M. Doyle, Jun Li, Milton E. Wadsworth, E. Peters

The Raman spectroscopic technique was used to study electrochernically oxidized pyrite in-situ. It was found that Raman-active sulfur oxidation products could be detected after a proper potential was applied to the pyrite electrode for a threshold period of time. There existed a minimum potential below which sulfur could not be observed. However, when the applied potential exceeded a certain limit, the intensity of the sulfur spectra decreased. The minimum potential at which sulfur could be observed changed with solution pH. For both acid (pH 2.7) and weak alkaline (pH 9.2) solutions, the minimum potential was 0.8 V/SCE, whereas for neutral (pH 6.5) solutions the value was 0.4 V/SCE. In strong alkaline solutions (pH 12.5) surface sulfur oxidation products could not be detected at any potential.

Jan 1, 1993

By Lane White

Ninety-seven papers were presented at the Mine Ventilation Symposium&apos;s technical sessions. Following are brief summaries of topics covered in this wide-ranging program.

Jan 1, 1993

By Stephen G. Hardcastle, Michel G. Grenier, Kevin C. Butler

Today there are numerous electronic rotating vane and thermal (hot-wire) anemometers, as well as vortex meters available to measure air velocity. Of these, a laboratory and field evaluation has found that certain instruments are better suited to routine airflow measurements in mine roadways and ventilation ducts. This paper concludes a study sponsored by the Atomic Energy Control Board of Canada, that was introduced at the 5th U.S. Symposium. The study investigated the suitability of currently available electronic anemometers as replacements for the traditional mechanical analog devices while maintaining standard methods such as the continuous traverse. Six electronic instruments were subjected to extensive tests under controlled conditions both in a wind-tunnel and in the field at an underground mine. The evaluation concluded that ergonomics and design were major considerations in unit preference as most of the instruments had very similar performance characteristics. Specific findings were: a) In the wind-tunnel the vane anemometers, especially the "micro" vanes, were more susceptible to misalignment or yaw effects but these were not noticeable in the field; b) Both the vortex and hot-wire anemometers were suitable for continuous traverses of mine roadways; c) Traversing ventilation ducts was more practical than a Pitot-tube multi-point assessments or discharge measurements; d) Yaw is a major concern in duct measurements; e) The continuous traversing method for roadways overestimates the average air velocity; f) Hot-wire anemometers can require significant air density corrections; and g) Hot-wire anemometers are better suited than rotating vanes to mine roadways of less than 1 m/s average air velocity. Based on research detailed in this paper, the ventilation engineer should be able to match the mine&apos;s requirements with the presented instrument performance characteristics, thereby optimizing the purchase of a new anemometer and the efficiency with which air velocities are measured.

Jan 1, 1993

By B. L. Gibbs

The mining industry is constantly in a state of flux -boom or bust; mine openings and closings. Part of the reason is the nature of ore deposits -they are there or they are not. Once they are mined, they are reclaimed and the move is on to the next deposit. Risks are usually high, and payoffs can be great or not so great. Many factors go into making a property payoff, and mining companies are continually searching for ways to remain profitable as long as possible. Computers and the people who can make them work are one of the ways available to improve productivity and ensure this happens. Computers have been used in the mining industry for the last 30 years (and more in a few cases). During the past 10 years, the explosion of micro-computing has changed how many mining companies do their work.

Jan 1, 1993

By Gordon C. ‘Bud’ Presley

The pumice and pumicite review arrived too late for the June issue. Estimated domestic production of pumice and pumicite in 1992 was up compared with 1991, according to US Bureau of Mines statistics. The Bureau estimate of domestic production of 400 kt (440,000 st) for 1991 turned out to be 401 kt (442,000 st) of actual production, the lowest since 1989. In 1992, the estimated the value of pumice and pumicite sold or used in the United States was $11.6 million, up only $200,000 from the 1991 value. There was an increase in the mine, or mill, average price from the five-year low of $11.44/t ($10.37/st) in 1986 to $26.42/t ($23.96/st) in 1992. Estimated tonnage produced in 1992 was 439 kt (484,000 st). Apparent domestic consumption was 642 kt (707,000 st), up 135 kt (149,000 st) from 1991. Imports for consumption were estimated to be 215 kt (237,000 st) last year. Domestic production supplied 68% of the demand in 1992, with net imports supplying the remaining 32%. This compares with domestic production sup¬plying 53% and net imports supplying 47% of the apparent consumption in 1988. Exports were about 900 t/a (1000 stpy) for the period 1984 to 1988. In 1989, exports rose sevenfold to 7 kt (7700 st) and to 20 kt (22,000 st) in 1990. The Bureau of Mines reported that the amount of pumice and pumicite exported in 1992 was 12 kt (13,200 st). It is assumed that these exports were from the Pacific Coast because imports, mainly from Greece, continued to be a market factor on the East Coast and the Gulf Coast States in the United States.

Jan 1, 1993

By D. C. Yang, J. Ye

A comprehensive flotation study has been conducted on a Chinese fluorspar ore using the packed flotation column developed at Michigan Technological University (MTU). The results are compared with those for a conventional mechanical flotation method on the same feedstocks. Key factors controlling flotation performance of both methods are evaluated based upon a simple statistic design. The flotation concentrate produced in one stage of the packed column has 4% to 5% higher recovery and much lower silica impurity than the concentrate produced by up to six stages using a conventional mechanical cell. The results also show that the packed-column flotation process is particularly suitable for the recovery of finer fluorspar particles.

Jan 1, 1993

By F. M. Doyle, Jun Li, Milton E. Wadsworth, Ximeng Zhu, E. Peters

The electrochemical behavior of pyrite in borate/sulfate solutions was investigated using cyclic voltammetry. Three anodic peaks at approximately -0.8 V, -0.1 V and +0.5 V (SCE) were detected along with their corresponding reduction peaks. The first two peaks correspond to the oxidation of surface products. The third peak corresponds to the direct oxidation of pyrite with reaction products FeO oxides. sulfate ion and partially oxidized sulfur intermediates present as a surface film of polysulfides and So. The Few oxides and sulfur intermediates were reduced to ferrous hydroxide and HS during the negative-going scan. The HS interacted preferentially with Fe(OH), on the surface to form FeS. Excess fenous hydroxide continued to reduce to metallic iron. During the return positive-going scan, metallic iron was oxidized to ferrous hydroxide and FeS was oxidized to pyrite. These reactions are characterized by a unique double peak observed in the region -0.8 to -0.65 V. The growth kinetics of the surface sulfur film formed during anodic oxidation were studied using chronoarnperomeay. Potentiostatic measurements were well correlated by a paralinear rate equation, suggesting the formation of an intermediate passive film, associated with the simultaneous dissolution of the outer layer of the film. The reaction rates were affected by applied potential, solution pH and temperature, but were independent of electrode rotation speed. A reaction kinetics model which fitted well with experimental results, was developed.

Jan 1, 1993

By P. M. Lin, P. Tsang, S. S. Peng

This paper presents an overall stabilization method to eliminate the potential of reoccurrence of subsidence over abandoned mine lands (AML). The method considers column grouting at specific locations, including the destressed and stress concentration zones, instead of grouting around and beneath damaged structures. The latter method is currently commonly used for AML subsidence abatement. The finite element method (FEM) can be used to calculate stress distribution in the strata before and after grouting. A grouting pattern is generated that includes the location and number of grouting holes. Stress concentration can be reduced or eliminated. A comparative analysis, including the number of grouting holes, area of grouting influence, stress level and potential of subsidence reoccurrence, is also presented.

Jan 1, 1993