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By Hans G. Machel

In low-temperature diagenetic environments (0 c T c 60 - 80°C), elemental sulfur forms by six common processes: via (1) inorganic oxidation of H2S by molecular oxygen, (2) inorganic oxidation of H2S by ferric iron compounds, (3) polysulfide disproportion- ation; and via the microbial metabolic actions of (4) colorless sulfur bacteria, (5) colored sulfur bacteria, and (6) some types of thiobacilli. Economically viable deposits of native sulfur usually are formed by only one process: inorganic oxidation of H2S by molecular oxygen. The amount of elemental sulfur is also limited by three common processes that destroy it in low- temperature diagenetic environments: bacterial reduction, bacterial oxidation, and inorganic oxidation. In high-temperature diagenetic environments (80 - 10o°C c T c 150 - 200°C), particularly in sour gas reservoirs, there are seven common processes forming elemental sulfur: (1) SOdH2S reaction, (2) H2S- hydrocarbon reaction, (3) polysulfide disproportionation, (4) catalytic H2S decomposition, (5) C02-H2S reaction, (6) chlorinification, and (7) exsolution of physically dissolved elemental sulfur. Natural processes that destroy or remove elemental sulfur in such settings are hydrocarbon sulfurization, polysulfide formation, and advection. In most sour gas reservoirs, relatively small quantities of elemental sulfur occur as a free phase (solid or liquid). However, elemental sulfur often precipitates in copious amounts from the reservoir fluids via exsolution and polysulfide disproportionation during production of sour gas reservoirs. By extension, elemental sulfur may precipitate from reservoir fluids in relatively large quantities upon uplift and erosion of deep sour gas reservoirs, or from advection of sulfurous fluids into shallower settings via faults or other high-permeability pathways.

Jan 1, 1992

By Zvonimir Jam?ek

In Rudarski Institut Ljubljana (RIL), i.e. Ljubljana Mining Institute, we have developed CADRIL, a smaller CAD package which purpose is to overcome the difficulties by introducing Computer Aided Design in our mines. Program CADRIL is a graphics shell for several computer applications in mining. With the basic version of CADRIL all 2D working maps for daily use can be produced. Inserting different program blocks into CADRIL we get versions MAPRIL, TAHRIL, SECRIL and so on. The main purpose of all versions is graphics design. The main and most innovative feature of CADRIL is the screen four-word command menu. Not having pull-down or tablet menus is the speciality of this program. CADRIL contains 500 achievable commands. Each of them can be composed by choosing two to four expressions stored and shown in a specific four- column menu, sorted as objects functions, parameters and modes. Thus all commands are immediately accessible. As a result of its plainness and adaptability to the present working methods of mining engineers, CADRIL quickly attained a good reputation in our mines.

Jan 1, 1992

By C. A. Roberts

What are the benefits and limitations of financial analysis software as a decision making tool in the mining industry? Traditionally, the assumptions and simplifications imposed by complex and uncertain information have been viewed as the main obstacle to reaching an optimum decision. Recently, however, phenomena such as corporate culture and power structure have received increasing attention as significant influences on organizational decision making processes. Studies of these phenomena have suggested an alternative way of understanding decision making processes and an alternative view of the role played by computer analysis in such processes. This paper presents these two views of decision making, and examines what each implies about the role of financial analysis software as a decision making tool in the mining industry.

Jan 1, 1992

By Louis W. Cope

INTRODUCTION Various methods for sampling placer deposits have been mentioned by Wojcik in Chapter 2. Here, a brief description and comparison of these methods will be given as related to bulk versus drill sampling. The advantages and disadvantages inherent to each will also be given. The means of sampling can be grouped into bulk or drill samples. As a generality, drill samples over a five-foot length will run from I/,, to 1 /, cubic yard, depending on the diameter of the drive shoe on the drill casing. Bulk samples can be expected to be in the range from one to many cubic yards each. SAMPLE METHODS Bulk Bulldozer-dug trenches and dozer or front-end loader pits are two methods to excavate large bulk samples. Smaller bulk samples can be obtained by digging small dimension shafts through the deposit, by hand or caisson-like drills. It is not recommended to split samples by alternate bucket-loads or by other means, as the effect of a nugget falling into one or the other fraction will seriously alter the sample.

Jan 1, 1992

By R. J. Reuss

Mina Maria is a high-grade, underground copper mine located in the Cananea district of Sonora, Mexico. The ore body is a massive sulfide breccia located in mountainous terrain. A major highway and an electric transmission line pass directly over the near-surface ore body. The mine is operated by Minera Maria SA de CV, a joint venture company that is 51 % owned by Empresas Frisco SA de CV and 49% by Cominco Resources International Ltd. Empresas Frisco is the operating partner. Production began in October 1990. The mining method used is undercut and fill. A continuous miner and a single-boom, hydraulic jumbo mine the ore. Backfill is a weakly cemented sand-gravel mixture that is pneumatically placed. The ore is treated by conventional crushing, milling and flotation. The Maria deposit is located about 40 km (25 miles) south of the Sonora-Arizona border and 11km (7 miles) northwest the city of Cananea and the Cananea Mine. The mine portal, at an elevation of 1780m (5840 ft), is on the east side of an important drainage divide. The mill site is situated about 800 m (2625 ft) northwest of the mine on the northwest side of the drainage divide where the drainage is more favorable. Its elevation is 1860 m (6100 ft) (Fig. 1).

Jan 1, 1992

By F. Bourgeois, J. A. Herbst, R. P. King

The ultrafast load cell (UFLC) has proved to be an exceptionally good device for the study of the fundamental processes associated with the impact fracture of particulate material. A new high- sensitivity UFLC has been commissioned at the Utah Comminution Center for the study of low-impact energy single-particle fracture. The force-time histories of individual fracture events have been measured. The force and energy absorbed at crack initiation have been measured at several particle sizes. The mass specific energy for fracture and the associated breakage function have been determined. The distributions of particle breakage energy and particle strength have been measured as a function of particle size.

Jan 1, 1992

By André Vervoort

The roof behaviour in room and pillar panels during the development of roadways and the subsequent pillar extraction was monitored underground and numerical simulations were conducted. For several underground sites, a satisfactory, correlation was found between underground measurements and three-dimensional numerical simulations using a boundary element code in the linear elastic domain. However, to simulate bed separation, and roof block collapses more complex models were required, of which examples are presented.

Jan 1, 1992

By M. R. Peterson

The U.S. Bureau of Mines has investigated new methods for increasing the selectivity in flotation by creating and regulating reagent concentration gradients within flotation columns at steady-state operation. Gradients were generated and traced in a water-only system with the use of fluorescent dyes, and the effects of various operating parameters on these gradients were investigated. From this investigation, it was found that both gradual and steep gradients could be generated in the froth cleaning zone, and that these gradients could be changed through the manipulation of both physical and chemical operating parameters. The application of reagent-gradient control to mineral systems could improve both flotation grade and recovery in commercial flotation operations without the use of additional flotation circuitry.

Jan 1, 1992

By Tuncel M. Yegulalp

In this paper we revisit the well known "Ultimate Pit Limit Problem" and suggest an alternative approach for fast and efficient solution. We follow the approach originally proposed by Johnson and Barnes (1988), but utilize the "Excess Scaling Algorithm" in solving the equivalent maximum flow problem. This algorithm provides significant increases in speed and reduction in memory requirements over the well known Labeling Algorithm of Ford and Fulkerson (1956), enabling one to solve large problems with relatively small computers. We present results of a series: of benchmark tests using this approach against the well known Lerchs Grossman algorithm as well as a brief description of the new algorithm.

Jan 1, 1992

By P. R. Taylor

This investigation (Bowles, 1990) involves consideration of technology utilized by three separate fields of metallurgy and materials science: 1) The recovery of metals employing the use of solvent extraction, 2) The fabrication of materials using powder metallurgy, and 3) The use of composite materials in fabrication of engineering materials. The research considers each of the processes in order to realize the benefits of each. In light of the fact that materials have an intended use -it does seem plausible to simplify the process required between "mother earth" and final use. For instance, a primary copper producer that already employs a solvent extraction and electrowinning process could produce value added products directly. Part of the existing extractant flow could be diverted into a pressurized hydrogen stripping process in order to produce specialty composite powders. Innumerable methods have been employed for the recovery of metals; solvent extraction, the one considered in this study, was used due to the possibility of it providing a pure powdered metal. The use of solvent extraction in the recovery of metals has gained wide acceptance and its use proves beneficial in many applications (Ritchey and Ashbrook, 1984). Pressure hydrogen stripping of solvent extractants may provide the benefit of flowsheet simplification compared to conventional solvent extraction followed by electrowinning. It may also provide the benefit of direct production of high purity metal powder (Demopoulos and Distin, 1985).

Jan 1, 1992

By Jorma Miettunen, Reijo Kalapudas, Pertti Koivistoinen

A new method for measuring the mill filling was developed by Outokumpu’s Pyhäsalmi concentrator during 1989-90. The method utilizes the power draw oscillation which is caused by the mill lifters. Each lifter bar causes a peak in the power draw and thus a continuous oscillation results. In a fixed time scale, the oscillation peaks will shift as the lifter bare hit the mill charge sooner or later depending on the volumetric filling of the mill. Thus the measuring method is based on the phase shift of the power oscillation. So far the measurement is utilized for maximizing throughput of the primary mills at Pyhäsalmi and Enonkoski concentrators and at Harjavalta slag concentrator. The paper describes the new method and the results achieved.

Jan 1, 1992

By J. M. Dean

The MANpower SUPport Program (MANSUPP), a part of the Mine Management Support System (MMSS), allows an underground coal mine site user to determine manpower requirements for production support work by considering ongoing operations and current mine conditions. The objective of MANSUPP is to plan a detailed manpower structure for a mine by incorporating a production schedule, condition-modified work standards and management preferences to predict required manhours for various activities, for example, belt moves. The program is written in Quattro Pro version 3.0 (Lotus 1-2-3 compatible) utilizing the command language, macro and formula capabilities.

Jan 1, 1992

By Paul J. A. Lever

The mine environment is dynamic and operating conditions change continually and are difficult to predict. New equipment, variable geological conditions, modified layouts, and different equipment operators make monitoring and control system difficult to apply without continual software maintenance. The paper reports on algorithms that were developed, encoded with Knowledge Craft Tools, and tested on underground coal mine data to adapt to the dynamic environment. The system receives data from sensors in near real time and then identifies patterns in the data. Using a set of mode features the data is automatically checked to determine the present operating mode. When the operating mode changes from the previous shifts, the system automatically learns the new mode characteristics and uses that mode context for further data analysis. The concepts presented in this paper are applicable to a wide variety of mining scenarios, not just underground coal mining.

Jan 1, 1992

By Daryl R. Tweeton

The Bureau of Mines has developed PC-based tomographic computer programs for geophysical applications, and is making them available to potential users as part of a Bureau plan to facilitate the transfer of technology to industry. These programs were initially developed for predicting and monitoring the flow pattern of leach solution during in situ mining. Seismic crosshole tomography has located fractured zones of low seismic velocity and saturated zones of high seismic velocit above the natural water table. The Bureau has applied tomography also to assessing high-wall blast damage, and examining the integrity of mine-related geological structures. The tomographic programs include the straight ray pro ram BOMTOM (Bureau of Mines Tomography? and the program BOMCRATR (Bureau of Mines Curved Ray Tomographic Reconstruction) that can be run with either curved or straight rays. Both programs provide optional mathematical constraints to help counteract the nonuniqueness of reconstructions that occurs with crosshole data. They are available from the Bureau free of charge. With typical data sets, they can be run on a 386 microcomputer with 640 Kb RAM. BOMTOM was described in the Bureau Report of Investigations 9159, so this report emphasizes BOMCRATR. Curved and straight ray reconstructions using seismic field data collected while simulating injection of leach solution were compared. The curved and straight ray tomograms were quite similar even with velocity variations of more than 50 percent.

Jan 1, 1992

By Menzhans Guo

A coal bunker basically acts as a buffer and regulator to reduce the interruptions between its proceeding production system and succeeding haulage system so as to maximize the availability of the whole system. Although such a role has long been recognized, quantitatively studying it is still rarely seen in the literatures. Its unique characteristics, coupled with numerous transitional states, make it very complex to describe the state transitional process in analytical models and, also very difficult to seek an analytical solution. Moreover, the analytical models inappropriately consider the state of bunker being full or empty as a kind of failure, therefore, by no means can they realistically describe the impact of the difference between rates of coal flowing to and from a bunker on the system availability. In light of this, Monte Carlo simulation methods are suggested to reach an approximate solution. In comparison, simulation methods are simpler and more effective than analytical approaches. Applications of simulation methods to a Northern colliery for determining bunker size from the viewpoint of maximizing system's availability are discussed. The results are satisfactory.

Jan 1, 1992

By A. S. Ibrado

Research investigations on the chemistry of the adsorption of gold cyanide on activated carbon have mostly reduced the role of activated carbon as the provider of the large surface area needed for adsorption. Most do not go beyond suggesting that oxygen functional groups on carbon play a key role in the adsorption process. Our research shows that the nature of the material, specifically its structure, is a crucial factor in the adsorption equation. To delineate the effect of adsorbent properties, gold cyanide was adsorbed on a series of carbonaceous adsorbents, including lignite, coals, anthracites, carbon blacks, graphite and activated carbon, which covers wide variations of composition, surface acid group content, and degree of graphitization. The results show that the adsorption of gold cyanide per unit area of adsorbent is not related to the amount of oxygen groups on the surface or even the total oxygen content of the material. However, they show very strong correlation with the degree of graphitization of the adsorbent, which indicates that the graphitic plates of activated carbon play the most important role. The findings suggest that majority of the adsorption occurs on the plate faces of the graphite crystallites of activated carbon.

Jan 1, 1992

By Jr. Zink

An economic and operational evaluation of the unrecovered metal, physical conditions, and chemical environment in a leach pad should be made prior to decommissioning. This evaluation will help determine the possibility and method of secondary and/or enhanced metal recovery and the method(s) to be used for detoxification and heap closure. The evaluation requires quantitative sample collection in a locally variable, yet grossly homogenous material. An assessment of a valley fill heap leach pad was made using a technique borrowed from placer technology called sonic drilling. The sonic drilling technique produced very satisfactory core recovery and sample quality. At this site, drilling results demonstrated that the method of heap construction produced expected features after extensive long term leaching. Rather than a uniformly homogenous pile of metallurgically depleted crushed ore, an assemblage of solution channels, un-oxidized sections, unleached areas, and compaction due to various factors, were found. These conditions are thought to represent a normal, rather than unique, situation for a valley fill heap leach. The lack of this information can have a significant impact on the economics and methods of heap re-handling and ultimate closure.

Jan 1, 1992

By J. A. Herbst, Y. C. Lo

An attempt has been made to parameterize the population balance model for a ball mill based on measurements of the elementary breakage process obtained using an ultrafast load cell device. Detailed insight obtained concerning the fragmentation of particle assemblies with the ultrafast load cell leads to a better understanding of ball mill grinding. The ball mill breakage function and specific selection function are derived from an average single event representing the multiple breakage events which occur in ball mill grinding. Since both the breakage function and the specific selection function depend on the loading mode in the mill, predictions of breakage mechanisms in ball mills are possible by using data obtained in various elementary loading modes. The application of this model to the description of batch ball milling behavior has resulted in reasonably accurate predictions of product size distributions for various energy inputs.

Jan 1, 1992

By S. Fairis Samuelson

Boling Dome. a piercement salt dome in the Texas Gulf Coast basin is (was) the single largest deposit of native sulfur in the Western world. Total sulfur production has been over 81.000,000 long tons and the mine is still in production. Data from over 60 years of operation and 8.000+ wells reveal a salt dome rich in history as well as minerals. Sulfur mineralization and production correlate well with caprock structure and morphology. The occurrence of Mississippi Valley-type deposits in fracture zones is notable in some areas and may warrant additional study. DISCOVERY AND PRODUCTION HISTORY Boling Dome is located in the south- east corner of Wharton County, Texas, 60 miles south-west of Houston. It is a piercement type dome in the Houston diapir province. It was discovered in 1922 when the county surveyor noticed sour gas seeps along the San Bernard River (Haynes. 1942). Several companies including Gulf Production Company. Humble, Texas Company, Sun and others quickly began drilling for oil and gas. Traces of native sulfur were reported in cuttings from many wells penetrating the caprock, but the first commercial quantities of sulfur were not found until Gulf Production's E.M. Chase 3 and 4 wells were drilled in 1927. Texas Gulf Sulphur, then mining sulfur at Gulf Dome in Matagorda County, secured the sulfur rights from Gulf for $3 million in cash and half of the profits after expenses for development and construction of plant and townsite were met (Haynes, 1942). The drilling results from 200 or so Wells revealed a massive deposit destined to become the largest single source of native sulfur in North America. Original reserves were estimated at just over 46 million long tons and were increased in later years. Production by the Frasch method was begun by Union Sulphur in 1928, and continued by Texas Gulf Sulphur Co. in 1929, and Duval Sulphur Co. and the Baker Williams Co. in 1935. Union produced 8,009 long tons, Duval produced 571,123 long tons, and Baker Williams produced 1,453 long tons. Through its deal with Gulf, Texasgulf acquired the largest and best mineralized portion of the dome and has produced 88,544,466 long tons through 1990, and production is planned for several more years. That amount of sulfur is equivalent to a cube measuring 1,152 feet on each side, or a sulfur highway 1 foot thick, 20 feet wide and 14,479 miles long. Peak production averaged 8,376 ltpd in 1948. A price war between North American sulfur producers and Mexican sulfur producers in 1956, followed by the recession of 1957 and 1958 (Haynes, 1959) coupled with a rapid increase in mining depth to below 700 feet began a gradual production decline that was never reversed (Figures 1 and 2).

Jan 1, 1992

By Henry Antwi

The decade of the 1990s promises to be one of increasing internationalization for domestic minerals producers as they scramble to enhance relative positions in highly competitive, international minerals markets. This "international mining rush" is fueled by developing countries seeking international investment capital to explore for, develop and exploit sizable mineral endowments in an attempt to support the increasingly popular, but expensive, wave of democracy and selfdetermination sweeping the world. This "fuel" typically takes the form of revised mining codes and, often, lucrative investment incentives. These incentives include favorable tax rates, royalty provisions, relaxation of import/ export constraints, depreciation schedules, profit repatriation and other variables that can positively impact mineral investment decision making. Concomitantly, in their attempts to address real and perceived short- and long-term woes associated with enhancing competitive positions internationally, many domestic explorers and producers are attracted to the prospect of finding high-grade deposits in relatively virgin areas. Combined with the investment incentives provided by foreign governments, these high-grade deposits promise lucrative potential returns from projects having short payback periods. Classic examples of this mutual desire to intensify international mining efforts by domestic producers are illustrated by activity levels in countries like Chile, Bolivia and Venezuela in Latin America and, more recently, in Eastern Europe and select locations in the former Soviet Union. As US corporations scurry to send fact-finding, technical, evaluation and financial teams to these presently popular locations, one area of the world has received little attention - Subsaharan Africa. Specifically, the country of Ghana (formerly the Gold Coast) deserves more attention than it appears to be receiving from North American mining companies.

Jan 1, 1992