Search Documents

By Gerson de Araújo Filho

This paper shows the use of tires as fuel to be employed into blast furnaces. The tires can substitute coal or even charcoal in the blast furnaces tuyeres. The injection into tuyeres, besides the contribution for energy generation, can also produce gas for iron oxide reduction. The tires, as powder to be injected into blast furnaces, contributes for an environmental use of this waste, which helps to obtain a high value product as well. So, the advantage of using such material is that it is waste and has lower cost for preparation. The obtained results showed that the tires have good combustibility. This one was obtained in a model that simulates the same conditions occurring in the blast furnaces tuyeres; these used raw materiais include tires and mixtures of tires with coal or even with charcoal.

Jan 1, 2006

By Jamil M. Khalifeh, Shadia J. Ikhmayies, Bothina A. Hamad

"We computed the optical properties of the cubic niobium nitride (o-NbN) compound using the full potential linearized augmented plane wave (FL-LAPW) method within density functional theory (DFT). The complex dielectric function and optical constants, such as optical absorption coefficient, refractive index, extinction coefficient, energy-loss spectrum, and reflectivity, are all calculated and compared with experimental results. The behavior of the computed quantities is similar to that obtained experimentally, but the optical positions are shifted to lower energies. This shift was related to the strong interband transitions, which are located at energies higher than 5 eV for NbN- as they are for IV B transition-metal mononitrides- and they appear in the computed spectra and not in the experimental spectra. These interband transitions simply shift the position of the reflectivity edge or the screened plasma frequency to the longer wavelength side.IntroductionIn recent years, NbN, as a transition metal nitride, has become a very popular material due to its high hardness, melting point, wear resistance, chemical inertness and temperature stability, which makes it suitable for use as emission cathodes in microelectronics and sensors, optical films and micro-mechanics etc [l]. Niobium nitride has long been known as highly polymorphic material, for which several crystalline structures have been reported in the literature [2]. These structures include the well known super-conducting rock-salt (Fm-3m, or Bl) structure (o-NbN), the hexagonal structure with space group p63/mmc and prototype Fe2N (18fuN), the hexagonalstructure with space group p63/mmc and prototype NiAs ~-NbN) and others.There has been a lot of computational studies for the structural and electronic properties ofNbN [3, 4-7], but according to our knowledge there is not any computational work that has been devoted to study the optical properties of this transition metal compound. At the same time a number of authors had performed experimental work in this direction. For example, Xin-kang et. al [l] studied the microstructure and optical properties of magnetron sputtered NbN thin films. Torche et. al [8] studied the composition, structure, electrical and optical properties of nonstoichiometric niobium nitrides. Newport et. al [9] investigated the reflection and transmission spectra of cubic niobium nitride films, and Tanabe et. al [10] had investigated the optical parameters and reflectivity of reactively sputtered NbN thin films by using in situ ellipsometry."

Jan 1, 2013

By G. N. Shannon

Keywords: inclusions, slag, modeling, interfacial energy, capillary force, particle flotation, particle separation A previously introduced model of inclusions separating across a steel-slag interface, developed by Nakajima/Okamura and Bouris/Bergeles, is expanded to include different inclusions shapes (octahedral and plate-like, besides spherical) as well as comparison between model ladle-, tundish-, and mold-slags. Investigation of the relation of these shapes with the interfacial capillary force ? which arises due to the dynamic interfacial energy during separation ? has shown that the force has a significant effect on whether the inclusion separates rapidly or settles at the interface. For the slags considered, the most significant physical property is found to be viscosity, which resulted in fast separation times for inclusions in the mold and ladle slags, relative to the more viscous tundish slag. Particle dissolution (using experimental data) is included in separation modeling.

Jan 1, 2005

By Thomas Gliick, Jianming Lu, David Dreisinger

"The recovery of manganese from the Boleo project of Baja Mining is via an acid oxidation and acid reduction process in seawater. Manganese as manganese dioxide is leached into solution as manganese sulphate with the addition of sulphur dioxide gas as a reductant and then precipitated as a manganese carbonate. The use of the manganese carbonate intermediate to produce electrolytic manganese metal (EMM) has been extensively studied. The manganese carbonate can be used in place of natural (MnC03) or reduced ores (MnO) of manganese as a feed to the EMM plant. Manganese carbonate can be dissolved in spent electrolyte from manganese plating, followed by purification using ammonium sulphide precipitation of minor elements and then electrowinning in a selenium free process. The results of small cell testing of manganese electrowinning are reported.IntroductionThe Boleo Project of Baja Mining is a greenfields development currently under construction approximately 5 km north of the town of Santa Rosalia, Baja California Sur, Mexico. The Boleo property is held by the Mexican company, Minera y Metalurgica del Boleo S.A. de C. V. (MMB). MMB is owned 70% by Baja Mining Corp. and 30% by a consortium of Korean companies consisting of KORES - Korea Resources Corporation, LS Nikko Copper, Hyundai Hysco, SK Networks and lljin Copper.The Boleo deposit has Measured and Indicated resources of264.7 million tonnes grading 1.50% copper equivalent (CuEq) & Inferred resources of 159.9 million tonnes grading 1.15% CuEq. The calculation of copper equivalent is based on a combination of metal prices and predicted metallurgical recoveries (Table I). The metallurgical recoveries have been confined by extensive bench and pilot plant testing. Proven and probable reserves are available at Boleo to provide for more than a 30 year mine life. Initially, 25 years of mine life and 23 years of process plant operation have been scheduled in the February 2010 Technical Report Update (www.sedar.com)"

Jan 1, 2012

By Esher Hsu

Keywords: Recycling, Consumer Battery, Fee rates On November 11, 1999, all types of spent consumer batteries are proclaimed to be collected in Taiwan. Under current recycling system, all producers and importers of consumer batteries have to pay a collection/recycling fee to the Recycling Management Fund (RMF) of EPA based upon the rate approved by EPA. Collectors and recycling plants receive subsidies from RMF according to the collected and treated amounts audited by an independent auditing organization. Collected spent consumer batteries only reached 923 tons in 2002 equivalent to 10% of the total quantity sold at the same year. How to increase the collection efficiency of used batteries becomes an important issue for EPA in Taiwan. The objective of this study is to explore current recycling system of spent consumer battery in increasing collection efficiency. Results provide some suggestions to Taiwan EPA regarding recycling route, recycling system, recycling rates, and recycling subsidies.

Jan 1, 2005

Four slag types covering the range of Fe-Ca-Si-O compositions and two iron blast furnace slags were melted at 1300 °C and doped with 1% of arsenic, antimony, cadmium, zinc and chromium. The melts were either slow cooled or quenched and the solidified slags were leached according to TCLP procedures. The morphology of the solidified slags was characterised using XRD, optical and electron microprobe techniques. Theoretical considerations showed that the capacity of the molten slag to hold the above toxic elements depended upon slag basicity and this was confirmed in practice. The experiments showed that the leaching of the toxic elements was a function of surface area and the phases present, both of which were affected by the mode of cooling. Iron silicate slags produced in nonferrous smelting operations and blast furnace slag from ferrous smelting operations both show promise of being suitable media for immobilising low levels of toxic elements and complying with current regulatory requirements.

Jan 1, 1994

By Torben L. Edens

Norddeutsche Affinerie is the largest copper producer in Europe. Two sites are in operation for the production of refined copper: primary copper production is located in Hamburg and secondary copper production in Lünen. A total of just under 560,000 tonnes of copper cathodes is produced annually at the two sites. Primary copper production using the flash smelter furnace has been in operation in Hamburg since 1972. Over the years, the capacity of the flash smelter has been increased in three expansion projects from 120,000 t to almost 500,000 t of anode copper p.a. The anode sector consisting of two anode furnaces and a 24 mould casting wheel still features just about the same equipment as in 1972. The paper describes the most important steps taken to optimise operation which have put NA in a position to cast meanwhile more than 500,000 t of anode copper annually with the two anode furnaces and 24 mould anode casting wheel.

Jan 1, 2006

By Tomas Astorga

APEC, the Asia Pacific Economic Cooperation is the forum of 21 countries having approximately 56% of the total world income, and over 45% of global trade. In 1997, APEC economies produced 67% of the world copper output, 55% of gold, and over 45% of other base metals. Mining in APEC captures more than 60% of the total mining investment in the world. New and emerging economies are now appearing in the demand scenery, such as China. New trends in the international environmental regulations are posing questions related to the use of copper in different industrial and consumption applications. These may have a strong impact on future trade of copper. New applications are also appearing based in new technology fields. The paper examines the growth potential of the copper market in main consumer ad highly populated economies of APEC, incorporating analysis of various interrelated factors. It also analyses the outlook of the copper supply. Its conclusions point to the need to implement demand outlook models. Finance and economic reforms will open important avenues for trade growth in basic metals, particularly copper. Changes in the consumption patterns of highly populated countries will add to better perspectives of copper demands. The recovery of a fast pace of economic growth in the APEC region will bring new demands for copper, especially as a consequence of high tech applications. More extended policies focused in the need for developing energy efficiency programs and schemes will add to this picture.

Jan 1, 1999

By Antonio Luraschi

The constituents iron, oxygen, silica and cop- per are of principal interest in slags utilized in pyrornetallurgical processes for producing copper. Accordingly, phase relationships in the.Cu-Fe-0-SiO2 system are important when one considers the physico- chemical behavior of slags. These phase relation- ships for the quaternary and constituent ternary systems are developed from available information. Isothermal composition and composition-oxygen potential diagrams, and oxygen potential-temperature diagrams are utilized to describe the' important relationships.

Jan 1, 1976

By K. Hussin

Perlis is one of the major producers of ?Batu Reput? in Malaysia and majority of the deposits contain of high-purity calcium and magnesium carbonate. The composition of Batu Reput is similar with the ordinary dolomite. Currently, the ?Batu Reput? is used as filler in the road construction, however with this new invention, it can be value added and maximized its application in the daily life, for example as construction materials, decorative products, souvenir and etc. This paper presents the fabrication of Artificial Marble from ?Batu Reput? and in this case, it was used as filler in the matrix of epoxy which is acted as a binder.

Jan 1, 2006

By Guo Xueyi

The nonferrous metal industry is facing the resource depletion, energy crisis and environmental deterioration. The resource recycling is a correct way to promote the nonferrous metal industry development towards sustainable. To realize the resource recycling, the technical support is most important. In this paper, the techniques barrier for nonferrous metal resource recycling are summarized, the fundamental on resource recycling of nonferrous metals are proposed.

Jan 1, 2006

By J. L. Jambor

Sulfide-rich tailings accumulated in a 4l-hectare impoundment at the Waite Amulet minesite near Noranda, Quebec, have undergone partial oxidation and destruction of the principal sulfides (pyrite and pyrrhotite) in the vadose zone. Mineralogical studies and whole-rock chemical analyses of 18 samples from 3 boreholes along a cross-section of the tailings pile indicate that the principal chemical manifestations of the alteration are a pronounced depletion in sulfide-sulfur, and an enrichment in total Fe as Fe203' Other elements such as Al, Mn, Mg, Ca, Na, and K in the solids show erratic or inconsistent variations, but a trend to Si enrichment in the oxidation zone is clear. The trend is interpreted to be a relative enrichment whereby the proportion of the stable silicate minerals has increased as a consequence of the consumption of pyrite and pyrrhotite in the oxide zone.

Jan 1, 1989

By G. Cifuentes

It's know that the cathodic purity and the electrolyte treatment is affect for the solid present in the electrolyte. Anodic slimes properties (f.e.: chemical composition, crystalline composition, sedimentation) was studied in copper electrorefining, this properties were modify through by anodic composition and current density. In this paper will be present only the preliminary anodic slimes relationship at different lead anodic composition. The anodic material was doped during the poured process with lead at different composition. It's confirm the apparition of the (Bindheimitte) SMbz07. The specific gravity of this specie is approximately 7.3 - 7.5, with this values is biggest the probability of sedimentation and smaller the slimes not sedimentabel.

Jan 1, 1999

By C. Palacios

The Plant, which was started up in April 1970, was originally designed for a capacity of 40.000 ton of cathodes per annum, using 12 sections, containing 408 cells. Since then the addition of another 8 sections containing 280 cells and using the Reverse Current System has made possible the increased output of 109.000 ton. The quality of the cathodes produced is excellent. The extension of the Electrolytic Refinery, by the introduction of the Reverse Current System, has been a great success and no problem has arisen in the new equipment or in the modifications carried out in the plant. The operation of the plant has improved due to better control procedures.

Jan 1, 1976

By Cody Burcher-Jones

The recovery of rare earth elements (REEs) through heap leach/in situ techniques from so-called ion adsorption clays (IACs) is attractive due to their inherent simplicity. However, the underlying mechanisms of these processes are poorly understood. In this study, the deportment of REEs in a typical IAC material has been investigated and was found to concentrate in the phyllo-layers of the clays, especially hallyosite, and was readily desorbed by various ion-exchange reagents indicating various potential routes to liberate them. Here we are reporting the use of seawater (0.5 M NaCl), spiked with various amounts of (NH4)2SO4, and found better extraction using a reagent mixture than NaCl on its own. Further, the leaching of REEs from a bed of clay material was investigated over time to understand the rate of transport through the stagnant material. Results indicate that REE release is likely to be controlled by diffusion through the clay material, while desorption in agitated systems is rapid. A degree of fractionation between different REEs can be observed during diffusion. Nonetheless, the successful operation of in situ leach operations for this type of material would depend primarily on how easily solution cocktails can be made to flow through the bed material.

By Michael J. Mankosa

The increased emphasis placed on recycling of consumer and industrial waste products has generated a need for advanced separation techniques for recovery of valuable by-products. As a result, the metals recycling industry has made great strides in the recovery of used wire products through the application of chopping and screening processes. Unfortunately, in many instances, the final plastic reject still contains a substantial portion of valuable metal. Typically, this material has been discarded, since an appropriate separation technique has not been available. Recent work conducted by Carpco, Inc. in Jacksonville, Florida indicates that a high-grade metal and/or plastic product can be recovered from this waste material using a novel density separation process. Extensive test work has been conducted using this procedure to validate separation performance as well as equipment capacity. This paper will present the basic operating principle of the separator, as well as results from tests conducted using various feed materials.

Jan 1, 1995

Iron(II), sulphur dioxide and sugars such as lactose are potential reducing agents for manganese dioxide to produce manganese(II) for subsequent hydrometallurgical treatment. The leaching of limonitic laterite and manganiferrous ores with sulphur dioxide produces iron(II) which in turn can catalyse the leaching of manganese dioxide in acid media. This paper presents a critical analysis of the kinetics of reductive dissolution of synthetic manganese dioxide and manganese ore to compare and contrast the effect of sulphur dioxide and iron(II) in acid media containing sulphate or perchlorate anions. Both one-electron and two-electron mechanisms are considered in the case of sulphur dioxide. The current knowledge on chemical speciation is used to construct an Eh-pH diagram to show the effect of complexation of Mn(II), Fe(II) and Fe(III) with sulphate. Heterogeneous and electrochemical reaction kinetic models are combined to propose reaction mechanisms which rationalize the dissolution kinetics.

Jan 1, 2003

By Xiang Lan

A strain of Thiobacillus ferruuxidans No. 8 was isolated from the acidic mine water of an arsenopyrite deposit, South China. It has been found from the experimental results that the growth of bacteria was inhibited by flotation agents. The order of toxic effect of different flotation agents on the growth of Thiobacillus ferrooxidans is ethyl xanthate > butyat ammonium aerofloat > butyl xanthate ? isobutyt xauthate >? flother No. 2 oil. The bioteaching treatment of arsenic and antimony-bearing gold concentrate in Longshan mine, Hunan province, China, was influenced considerably by the presence of flotation agents. The possible causes of the influence of flotation agents were discussed and an improved method was suggested.

Jan 1, 1991

By Viktor Ashikhin, Pavel Arkhipov, Yurii Zaikov

"Lead alloys electro-winning from chloride melts was under investigation. Impurities concentration in cathode lead is strongly depended on temperature, electrolyte composition, anode current density. The equilibrium electrode potentials of lead-antimony alloys with the various content of electropositive metal in the alloy were investigated in the wide temperature interval. Thermodynamic properties of Pb-Sb alloys containing 20-95 mol% of Pb were studied by EMF method in temperature interval 723-873K in molten mixture of potassium and lead chlorides. Partial and integral thermodynamic characteristics were calculated. Small negative deviations from Raul’s law were found. Anode processes were investigated. The lead dissolution was found to be the only process in certain interval of current densities and electropositive metal content in alloy.IntroductionAt present human race is facing the problem of pollution by lead and its compounds and also the pollution influence on population health all over the world. One of the solution ways is the recycling lead containing technical wastes by ecologically clean technologies.World scientific community pays much attention to the electrolysis of molten salts. The usage of salt mixtures, as electrolytes, discovers new possibilities in the production of metals, metal compounds and alloys. ?????????? of the electrolysis at the temperature 50 - 200 °? above the melting temperature of chosen salt mixture allow to unbreaks processes, that undergo in the pre-electrode layer. The rate of the electrodepositing of elements are much higher than in the water electrolytes. At present there are technologies developed for production of metals (Ta, Nb, Ti, Zr, Hf, Ca, Al, Mg, Be, Li and others) by the electrolysis of the melts. Electrolysis of melts might be used in order to convert different technological formations containing lead and other nonferrous metals, that produced by different enterprises. According to the level of the influence on the living organisms lead is in the group of highly dangerous substances alongside with arsenic, cadmium, mercury, selenium, zinc, etc. Toxity and ability to accumulate in the human organism are two main sources of danger for the human being."

Jan 1, 2008

The present work is mainly focused on developing intermetallic inert anodes for aluminum electrolysis. The anode alloy based on Al-Ti-Cu system was prepared by casting, followed by the application of a protective coating. Behaviour of corrosion and the passivation under anodic condition was characterized using the electrochemical and microscopic techniques. The results obtained clearly demonstrate that the oxide coating can provide good corrosion resistance via surface passivation of alloy anodes, rendering them inert in cryolite melt.

Jan 1, 2006