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By N. Shi, T. C. Lowe, S. J. Zhou, M. L. Lovato, Y. T. Zhu, J. A. Valdez, W. R. Blumenthal, M. G. Stout

"A major problem of short-fiber composites is that the interfaces between the fiber and matrix become a limiting factor in improving mechanical properties such as strength. For a short fiber, a strong interface is desired to effectively transfer load from matrix to fiber, thus reducing the ineffective fiber length. However, a strong interface will make it difficult to relieve fiber stress concentration in front of an approaching crack. Stress concentrations result in fiber breakage. We report in this paper an innovative approach to overcome this problem: reinforcement morphology design. Short-fibers with enlarged ends are processed and used to reinforce a polyester matrix. The initial results show that the bone-shaped short-fibers produce a composite with significantly higher strength than can be attained with conventional short, straight fibers.IntroductionThese interfaces between the fiber and the matrix in short-fiber composites play a critical role and, in many cases, become a limiting factor in improving such mechanical properties as strength and toughness of the composites (1-4). For a short fiber, a strong interface is desired to effectively transfer load from matrix to fiber. A stronger interface can reduce the ineffective length at both ends of the fiber and, therefore, can increase the effective length that carries load (5-9). However, with a strong interface it is difficult to relieve fiber stress concentration -in front of an approaching crack; and such stress concentration can result in fiber breakage (10, 11). This effect is particularly severe for ceramic matrix composites, because of their low matrix toughness and lack of plasticity. Even for a composite with a highly ductile matrix, such as plastics, too strong an interface may still cause successive adjacent fiber breakage and subsequently reduce composite toughness (1, 11). On the other hand, a weak interface significantly decreases the fiber load-carrying length due to ineffective load transfer and complete fiber interfacial debonding and pullout during loading. A compromise in the interfacial bond strength will also compromise the load-carrying potential of short fibers."

Jan 1, 1998

By Bo Björkman

A controlled dust generation whereby the dust generated would be enriched with specific metals would considerably facilitate the possibilities of recovering metals from such dusts. A basic understanding of the dust forming mechanisms is of fundamental importance to achieve a controlled dust generation. The present study deals with dust formation in a copper converting process. Dust samples collected from various places in the gas cleaning system were characterised for chemical and mineralogical composition using chemical analysis as well as microprobe analysis. Thermodynamic calculations were used to predict the formation of chemically formed dust at various temperatures and amounts of leakage air to the gas system. The results show that a separation of mechanically formed dust. e.g . Si0:2. Cu and chemically formed dust. e.g .? Ph, Zn, As, Bi. could, to some extent, be obtained due to their different particle sizes. A selective condensation of Pb, Zn and As at various temperatures could. according to thermodynamic calculations, he possible at high temperature. A selective condensation of metals requires an airtight gas cleaning system or a gas cleaning system with a limited amount of leakage air in order to maintain the desired temperature level.

Jan 1, 1996

By Ing. R. Geutskens

Zinc-bearing dust from blast furnace gas-scrubbing operation is a well known environmental health problem in the iron and steel industry. Hoogovens IJmuiden (The Netherlands) developed processes to solve this problem. 90% of the zinc is concentrated in 25% of the dust (the fine particle fraction) by means of slurry-hydrocyclonage. The resulting fine particle fraction is treated in a pressure leaching process. Hydrochloric waste pickle liquors have been used as a leaching liquor. By creating optimal leaching conditions more than 98% of the zinc is brought into an acid' solution, whereas nearly all the iron remains in the residue. The zinc can be separated selectively from the solution. The residue can be reused in the blast furnace (via the sintering plant). In the article information is given about the research work and -results of the pressure leaching process as well as the possibilities of the process for solving comparible problems.

Jan 1, 1990

By James T. Staley

Quenching and aging are critical processing steps used to produce precipitation hardenable aluminum alloy products. This work describes personal computer programs that employ models to predict certain properties after quenching and aging and graphically display them. One of the programs allows the user to predict the attainable strength and toughness of aluminum alloy products after an arbitrary quench. Another program simulates the changes in strength and electrical conductivity occurring during second-step aging alloy 7050-T7X products as a function of thickness, furnace temperature set point, and furnace characteristics.

Jan 1, 1993

By K. Gao, R. Dry

"Carbon boil, which results in excessive spitting and even complete destruction of a metal drop, could significantly influence the efficiency of direct smelting processes. Carbon boil has been studied as a function of some key parameters such as melt sulfur content, oxygen partial pressure, and melt area/volume ratio. The time of carbon boil was determined using a CCO camera coupled with a time/date generator connected in parallel to a video recorder and a computer. The time of carbon boil was in the range ~5 - 15 seconds under the conditions in this study. A mechanism for carbon boil has been proposed.IntroductionThe occurrence of carbon boil in molten iron drops can result in excessive spitting and sometimes even complete destruction of a metal drop. In direct iron smelting processes, this could significantly influence the decarburisation of liquid metal and the post combustion and hence may influence the efficiency of smelting processes. The generation and consequent ejection of metal droplets into the gas phase occurs due to the intense turbulence in the bath which results from the injection of gases and coal. The aim of this investigation is to understand the fundamentals governing the carbon boil phenomenon under direct iron smelting conditions to assist control of process efficiency.Carbon boil phenomenon has been studied as a function of some key parameters such as melt sulfur content, oxygen partial pressure and melt area/volume ratio. The time for the occurrence of carbon boil has been determined in this study at 1440 °C using a novel approach which includes utilisation of a CCD camera coupled with a time/date generator connected in parallel to a video recorder and a computer. This arrangement permits the capture of the entire sequence of events leading up to carbon boil and therefore the determination of time of boil which is in the range -5 - 15 seconds under the conditions in this study."

Jan 1, 1996

By Reinhard F. Dobner

After a short introduction about the HK's secondary smelter process and explanations concerning the anodes produced the regulation and buffering of bleed will be described and the principles of technology for processing of bleed will be presented. Modernization aspects, especially installation equipment, and the different types of evaporators used will be described in detail. Besides, experience made with acid-resistant materials - stainless steel, enamel, plastics - will be reported. Environmental aspects such as water and air pollution will be outlined briefly and in conclusion the quality of products obtained as well as quality control will be presented.

Jan 1, 1997

By Nils Eivind Kamfjord, Halvard Tveit, Ingeborg Solheim

"Because of its negative environmental effect the attention towards NO emissions increases. This again leads to new demands from the authorities for better surveillance and control of emissions. Earlier and recent industrial measurements towards FeSi- and Si-metal furnaces reveal quite high NO-emission. The NO is believed to be produced in the combustion zone above the furnace surface, mainly as thermal NO.In order to expand the knowledge on NO-formation in silicon metal production, a pilot scale experiment in a 440 kVA silicon furnace has been carried out. The experimental set-up was designed with a view to be able to copy and manipulate the formation mechanisms for NO by controlling the flow of false air into the off-gas system.The resulting NO-values corresponding to the different air inlet to the furnace top, show significantly differences between the different air inlet geometries.IntroductionNOx is the common notion for the two gases nitric oxide (NO) and nitrogen dioxide (NO2). Since combustion of fuels, such as gasoline, diesel, bio diesel, propane, coal, and ethanol, forms NOx the dominating contributors to NOx emissions are the on-/offshore transportation industry and power generation based on fossil fuels [1]."

Jan 1, 2012

By André L. de Vegt

Soil and groundwater beneath a zinc production plant in The Netherlands are contaminated with metals and sulfate. To avoid contamination of nearby drinking water aquifers, a hydro-geological containment system and a biological treatment plant for the extracted ground water have been installed. Currently about 5000 m3/day of groundwater is extracted from a combination of 12 shallow and deep wells. Heavy metals and sulfate have to be removed from the extracted water before it can be discharged into a river. Several water treatment methods have been studied and pilot tested at the site. The preferred and selected process is based on the activity of sulfate reducing bacteria (SRB) and combines sulfate removal and heavy metal removal in one single installation. Anaerobic bacteria reduce sulfate to sulfide resulting in the precipitation of metal sulfides. Excess sulfide Is biologically converted to elemental sulfur. A full scale biological treatment system was started up in May 1992. Design, start-up, commissioning and operational experiences are reported in this paper. Concentrations of metals and sulfate in the SRB water treatment plant effluent are well within the limits set by the Dutch Authorities for discharge to surface water.

Jan 1, 1995

By Hong Ouyang

A unified computational model has been developed for the Bridgman growth processes of B-NiAI and CdTe crystals. To handle the geometrical and physical complexities, a two-level approach has been developed. At the gtobatlevel, conjugate heat transfer, phase change dynamics, and variable material properties along with the realistic geometries and thermal boundary conditions are accounted for inside the entire crystal growth system. Refined calculations are then made within the ampoule, with the boundary conditions supplied by the global simulations. This model can optimize the use of computational source, help understand solidification behaviors, and improve designs of crystal growth system.

Jan 1, 1996

By Kurt A. M. Westerlund

The basic function of primary gas handling downstream non-ferrous pyro-metallurgical processes is cooling hot sticky gases to treatable temperature levels (e.g. entering ESP). That means managing efficient the critical gaseous components from a molten via a sticky to a solid phase. The article outlines the modem gas cooling methods combined with efficient heat recovery. Examples of the alternative use of recovered steam energy are outlined; as e.g. drying of concentrate and power generation. The heat transfer impact of the insulating dust is called fouling and circumstances causing fouling are described. Modem cooling surface design and cleaning techniques to keep fouling in reasonable limits are described. Leakage- and false air ingress into the gas handling lines often limits smelting capacity. The objective is generally to minimize the infiltration of air but it still takes place at open interfaces (e.g. at reactor hood, feed port). Leakage air at furnace roofs for example can be reduced to a minimum by adopting the pressure gas sealing used at present In-Bath-Lance furnaces. Modernization and optimization methods to de-bottleneck existing waste heat boiler gas cooling capacity by highly efficient surface cleaning systems and false air avoiding (e.g. bundle roof boxes, dust discharge) are detailed described.

Jan 1, 1999

By Xiao-hui Fan, Li-shun Yuan, Xu-ling Chen, Wei Lv, Min Gan, Yi Wang

"As the amount of ferrous scrap increases every year, it becomes more and more urgent to deal with this iron-bearing resource properly. This paper puts forward a method on resource-oriented utilization of ferrous scrap (cold-bonded pelletizing), and these cold-bonded pellets can be used as coolant in a converter. The influence on the pellets qualities by using different kinds of chloride as rust agents is studied, and results show that the strength of cold-bonded pellets increases significantly by using a combination of the three kinds of chloride -NaCl,MgClz,FeCh, their best dosages are 1.2%, 0.2%, 0.1% respectively. Other iron-bearing materials also have an effect upon the pellets strength, by adding 5% iron powder and maintaining for 48h, the compressive strength of the clumps surpass 2500N/A, dropping strength surpass 4 times/ A, and 10% iron slag or 20% steel slag can replace 5% iron powder while obtaining the comparative quality. The influence of different ratios of three ferrous scrap (converter mud, iron scale and dust) is further studied, and results show that when the ratio is 30% : 30% : 40%, the pellet strength reaches the maximum. After maintaining for 24~48h, the clumps can meet the mechanical as well as the physical-chemical requirements as BOF steelmaking refrigerant.IntroductionGreat amounts of converter mud, dust and iron scale are produced in steel production process. These materials are of great values, and their accumulation not only leads to environmental pollution, but also wastes the precious resources, which restricts the sustainable development of the steel industry [1,2] The main approach at present to dealing with the ferrous scrap is to add them into sintering. But in this way, the utilization factor of sintering and the quality of sinter decline while the energy consumption increases [3].Therefore, more advanced and efficient technology is needed to make the best of these iron resources. Cold consolidation of ferrous scrap is a simple process that has many advantages such as less investment, quicker effect, lower energy and lower cost [4-5] But the conventional maintaining period is too long, usually up to four-six weeks, and the pellet strength is low. Therefore, the key points of the cold-bonded pelletizing are to develop a new adhesive [4,5] to shorten the natural maintenance cycle and to improve the strength of the pellets. A method on resource-oriented utilization of ferrous scrap (cold-bonded pelletizing) is brought forward, and these cold-bonded pellets can be used as coolant in converter. After maintaining for 48h, these cold-bonded pellets can satisfy the mechanical requirements to replace the converter coolant [6]."

Jan 1, 2013

By Yafei Xiong, Yue Wang, Guotao Xu, Shuzhong Li, Huaiyuan Li

"The composition, properties and structure of taphole clay with high strength and friendly surrounding used in a new blast furnace with 3800 M3 volume was studied. The developed taphole clay had been applied in the blast furnace for four months, pouring times were 11-13 every day, flowing rate of hot iron was 7.5 t/min and the consumption of taphole clay was 0.49Kg per ton iron, which can make the new blast furnace attach the designed production quickly and decrease the cost of hot iron. The taphole clay is easy to be opened in the channel of hot iron which can be remained in stable shape under the corrosion of slag or hot iron, and it dose not produce poisonous smoke in yellow or dark color in the use process. The development of new taphole clay is useful to improve the work surrounding of the blast furnace.IntroductionIn the iron-making process, the taphole clay's function is filling up the taphole and protecting the formation as well as the growth of the clay in the blast furnace, maintaining the enough taphole depth; simultaneously it is easily to open a hole and knock out the clay. The taphole clay has a good performance of molten slag and hot iron resistance. The traditional taphole clay uses coal tar or carbolineum as a binder, and the performance of taphole clay is good, but it has the black and yellow poisonous smoke, which is harmful for work condition. Through the investigation on the binder's composition and poisonous performance of taphole clay, the environmental taphole clay is developed by some foreign companies, which is named the third generation product with benzene is less than 300ppm, and it has been used in European steel companies. This application of the taphole clay with high strength and environment-friendly using in 3800m3 blast furnace is introduced and the performance is discussed and analyzed in this paper."

Jan 1, 2012

By B. Q. Li, H. C. de Groh, X. Lu

"A fully 3-D, transient finite element model is developed to represent the magnetic damping effects on complex fluid flow, heat transfer and electromagnetic field distributions in a metallic melt. The model development is based on our in-house finite element code for the fluid flow, heat transfer and electromagnetic field calculations. The numerical model is tested against numerical and experimental results for water as reported in literature. Various numerical simulations are carried out for the melt convection and temperature distribution with and without the presence of a transverse magnetic field. Numerical results show that magnetic damping can be effectively applied to stabilize melt flow, reduce turbulence and flow levels in the melt and over a certain threshold value a higher magnetic field resulted in a greater reduction in velocity. Also, for the study of melt flow instability, a long enough running time is needed to ensure the final fluid flow recirculation pattern. Moreover, numerical results suggest that there seems to exist a threshold value of applied magnetic field, above which magnetic damping becomes possible and below which the convection in the melt is actually enhanced.1. INTRODUCTIONThe imposition of a DC magnetic field on a moving, electrically conducting fluid, such as molten metal or semiconductor melt, produces an opposing Lorentz force that results in a reduction of flow velocity in the liquid. This effect has been explored in both the semiconductor and metals industries to control natural convection and/or surface tension induced Marangoni convection as well as thermally induced flow instability during solidification processing of these melts [1-6]. A mathematical model can be of great use in developing both fundamental understanding of the fluid-magnetic field interactions in these magnetically-assisted processing systems and basic guidelines for process design, control and optimization.This paper presents a 3-D mathematical model for magnetically damped fluid flow and heat transfer in a melt cavity, which is useful for interpreting results for unidirectional solidification processes at slow solidification rate, and some preliminary results concerning the magnetic damping effects on the flow instability in the melt. The model development is based on the finite element solution of the Navier-Stokes equations, energy equations and equations for induced electric field. The model is tested against reported results and is then applied to study the fluid flow and thermal distribution in the metallic melt with and without an external magnetic field."

Jan 1, 1999

By S. Abe

Various copper anodes to be electrorefined were subjected to a heat treatment comprising annealing at a temperature in the range of 700 °c to 1,000 °c followed by a slow cooling preferably on the order of about 150 °c, and using these heat treated anodes , a series of dissolution experiments were conducted under conventional electrorefining conditions. The results obtained have indicated that the above annealing/slow cooling process dramatically improves the dissolution activity regardless of the type of anodes. As an example, passivation times of l to 3 minutes in a standard test have been increased to more than 80 minutes by this innovated heat treatment. Other advantages sterning from the improved anodic activity include reduced electrical short circuiting which results in substantial labor effort in the tankhouse, reduced energy requirement, and reduced cost of processing anode slimes because the amount of anode slimes is reduced. In addition, this process gives rise to a dramatic change in the nature of anode slime layer formed in such a way that a comparable final cathode copper product can be achieved even from high-impurity copper starting material.

Jan 1, 1987

By Michael E. Stout

The recovery of the constituent components of spent lead acid batteries was pioneered in the early 1970's by M.A. Industries, Inc. MA's main reason for research and development in this area was to recover the polypropylene casings for use as feed stock in their injection molding plants. At that time spent and reject casings were either disposed of or being fed with the lead 'bearing materials into the ,smelting process. M.A. has since developed, built and operated plant for the conversion of scrap casing into reusable copolymer resins. The system is composed, of washing, .sizing, extrusion and pelletizing the polymer into a form which is ready to be injection molded into new products.

Jan 1, 1995

By Thomas E. P. Wechsler

The limiting factor for most pyro-metallurgical processes in secondary cop- per melting is the time required to heat and melt the product. American Combustion's proprietary PYRETRON variable £uel/air/oxygen combustion system improves the throughput of existing scrap melting and heating furnaces for copper and copper alloy production by increasing the rate of heat transfer from the flame to the product. The increased productivity and energy savings obtained from this technology can result in sizable reductions in operating costs for smelting operations.

Jan 1, 1991

By Kun Wang, Xinhui Li, Huaqing Xie, Qingbo Yu, Qin Qin

"Three typical model compounds of bio-oil (ethanol, acetone and phenol) were studied in the steam reforming process for hydrogen production. In the thermodynamic analysis, the three componds showed the similar trends. The hydrogen yields increased with the increase of steam/carbon (S/C) ratios, and the temperatures of the maximum hydrogen yields moved afterward to low temperature zone. However, the hydrogen contents were just about 70%. For improving hydrogen yield, a new system for steam reforming of bio-oil with site CO2 capture was put forward. This system required the catalst with the larger granularity having greater mechanical strength and higher abrasion resistance. So, six Ni-base catalysts loaded on Al2O3 particles prepared were used and among them, Mg-Ni/Co catalyst showed the best catalytic performance. For the simulated bio-oil (the mixture of the compounds), the hydrogen yield can attain 63% with Mg-Ni/Co catalyst with the good stability and regeneration ability.IntroductionCurrently the interest in the use of hydrogen as a clean energy carrier is increasing, and the main way for producing hydrogen is steam reforming of fossil fuels, containing steam reforming of nature gas, naphtha and coal. But this way caused substantial amounts of CO2 emitted, and these sources of hydrogen which are non-renewable energy will eventually be used up [1, 2]. As a kind of renewable energy, biomass is recognized as an attractive alternative to fossil fuels, because of its neutral CO2 emissions [3]. There are mainly two thermochemical processes using biomass to produce hydrogen, gasification and flash pyrolysis followed by steam reforming (SR) of the biooil produced in the flash pryolysis process [4]. The latter was known as one of the most promising and economically viable methods for hydrogen production [5]. In the last decades, the biomass flash pyrolysis technology was adequately developed and fairly mature [6]. But the steam reforming of bio-oil is still at the research stage and yet has been leading to more and more concerns by the researchers. In their research, the catalysts were widely studied and yet mainly were powdery[7-10], and the reactors manily were fixed bed reactors[11-13], readly causing the carbon deposition and the catalyst deactivation, against the continuous running. In this paper, a new systerm was put forward and could realize continuous production of hydrogen, yet needed catalysts with the larger granularity having greater mechanical strength and higher abrasion resistance, as well as powdery CO2 sorbents which mainly calcium oxide based ones.In this paper, the thermodynamic analysis of the steam reforming processes of three typical bio-oil model compounds (ethanol, acetone, phenol) was performed, and the effect of S/C ratio and temperature on the hydrogen yield and the compositions of gaseous products were investigated. Then, a new systerm for steam reforming of bio-oil with site CO2 capture was put forward, and the catalysts with a certain granularity were prepared and studied."

Jan 1, 2014

By Mrutyunjay Panigrahi, Takashi Nakamura, Atsushi Iizuka, Etsuro Shibata

"The production of FeTi intermetallic alloys from mixed oxide precursors using direct electrolytic reduction was studied. Fe203 and Ti02 powders were mixed in appropriate molar ratios, pressed into small pellets, and then heat treated at temperatures in the range 1000-1300°C. The pellet heat treated at 1000°C was electrolyzed in molten CaCh at 950°C, using a graphite crucible as the anode and the oxide pellet as the cathode, at a potential of 3.0 V. The products of the electrolytic reduction of (Fe,Ti) oxide were examined by XRD, SEM and EPMA. It was found mat the (Fe,Ti) oxide was reduced progressively from the outside to the inside of the pellet until the metallic state was achieved.IntroductionFast and energy-efficient technologies for materials production are essential for the sustainable development of society, and such development is supported by advanced technologies. Since the introduction of titanium and titanium alloys in the early 1950s, these materials have, in a relatively short time, become major materials for the steel, aerospace, energy, and chemical industries. Its combination of a high strength-to-weight ratio and excellent mechanical properties and corrosion resistance make titanium the best material for many critical applications [1]. Titanium alloys are now used in demanding applications such as static and rotating gas-turbine engine components. Some of the most critical and highly stressed civilian and military airframe parts are made of titanium alloys. The use of titanium has expanded in recent years to include applications in nuclear power plants, oil-refinery heat-exchangers, marine components and medical prostheses.Ferrotitanium is one of the most widespread and effective ferroalloys. It is also a well-known hydrogen-storage material and will be extensively used in the future because hydrogen is emerging as an eco-friendly energy source [2], Ferrotitanium is an alloy consisting of iron and titanium, with a minimum titanium weight content of 20% and a maximum titanium weight content of 75%, and is manufactured by reduction or melting."

Jan 1, 2012

By Honggang Zhong, Xin Cao, Qijie Zhai, Hongmei Song, Congsen Wu, Cheng Zhang, Jingzheng Ye

"The influence of superheat on the solidification structure and ferrite/austenite phase transformation of a novel lean duplex stainless steel (DSS) was investigated on a setup, which designed to thermally simulate the continuous casting process. The results showed that the macrostructure of the samples all exhibited chill zone, columnar zone and equiaxed zone. The distance from chill zone to position of columnar to equiaxed transition (CET) moved from 51.0 mm to 39.8 mm with an decrease of superheat from 70 °C to 10 °C, and that the grains in the chill zone tended to be finer. In equiaxed zone, the fme and uniform grains were observed when superheat higher than 40 °C; while, coarse grains were found in samples poured at low superheat. Generally, the volume fraction of ferrite increased along the dendritic growth direction, and stabilized in equiaxed zone. The high superheat decreased the volume fraction of ferrite in equiaxed zone, while it had indistinctive influence on chill zone and columnar zone.IntroductionDuplex stainless steel with approximately equal volume of ferrite and austenite, offering an attractive combination of corrosion resistance and mechanical properties. [ l]. The production of DSS, worldwide application in structural engineering[2] and petrochemical industry[3], have increase by more than 100% in the latest decade[4]. But due to the sharp prices increase of nickel and chromium, lean duplex stainless steels which have lower contents of alloy elements were developed. They perform well in both mechanical and corrosion resistance[S, 6] and even have TRlP(Transformation Induced Plasticity) effect[?]. Nonetheless , the mechanical properties of DSS was affected greatly by the solidification structure, such as columnar to equiaxed transition (CET), grain size and phase content[8]. So, the solidification behavior of stainless steel was investigated widely"

Jan 1, 2014

By Christopher B. Vierrether

Reflected light microscopy, scanning electron microscopy, and electron microprobe analysis have been used to determine the mineralogy, phase percentages, grain sizes, textures, and partitioning of cobalt and nickel in two cobalt-nickel rich mattes. These mattes were prepared by submerged bath smelting from a flotation cobalt-nickel concentrate containing 4.8% cobalt and 5.1% nickel. The concentrate was derived from lead-zinc-copper ores of the Viburnum Trend, southeast Missouri. Eleven discrete phases have been distinguished in the matte samples, three of which contain significant cobalt and nickel. The phases are cobaltpentlandite ((Co,Ni,Fe)9S8), cobalt-bearing marmatite ((Co,Fe,Zn)S), shandite (Ni3Pb2S2), bornite (Cu5FeS4), galena (PbS), magnetite (Fe3O4), pyrrhotite ((Co,Ni,Cu,Fe)1_xS), chalcocite (Cu2S), CuPbS phase, metallic copper, and metallic silver. Cobaltpentlandite and cobalt-bearing marmatite- occur in coarse grains (50 µm) that would separate readily during grinding, but shandite contains small (5 - 10um), abundant inclusions of pyrrhotite and bornite.. Some mineralogical variations between the two matte samples were due to differing degrees of oxidation during smelting,

Jan 1, 1988