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By W. E. Straszheim

Computerized microscopic techniques were used to determine the size and identity of the ash-forming mineral components, as well as their association with the organic coal matrix, in order to aid in the development of physical methods of beneficiation which require such characterization for the most effective cleaning. Examples of particle size measurements, mineral phase identification, and especially coal-mineral association results are given for selected samples of raw and physically cleaned coals. These measurements can reveal certain characteristics of coals which can be be of significant value in predicting coal recovery and mineral matter rejection for coals undergoing beneficiation.

Jan 1, 1989

By Ray D. Peterson, Garry G. Blagg

"Molten aluminum is routinely transported hundreds of miles to customers in large ""over-the-road"" crucibles. This is especially common for aluminum recycling organizations handling scrap and by-products. Receiving the aluminum in a molten form can save the customer time and money since in-house melting costs and capital equipment can be avoided. Additionally, the alloy can be on specification and nearly ready to use for the casting operation.A number of transport crucible designs are currently in use. The specifics of each design are based on the needs of the customer, the equipment used at both the producer and the consumer, and over-the-road transportation constraints. Crucibles are designed to maximize carrying capacity, and refractory life while minimizing heat flow and dead weight. These conflicting demands place difficult design criteria on the design engineer.This paper will review the basic advantages and disadvantages associated with molten metal transport, give examples of the design restrictions and examine several types design of crucibles currently in use."

Jan 1, 2000

By Katsukiyo Marukawa, Mashamichi Sano, Shigeta Hara

"Various subject of studies are discussed to develop ·innovative refining processes in the 21st century for cost reduction, production of high quality steel and environmental conservation. The future refining reactor should have abilities of highly efficient mixing and separation of different phases. It is stressed ·that applications of electromagnetic and ultrasound energies, and control of flow fields rate required to create the highly efficient mixing I separation reactor.IntroductionIn recent years, it seems that the research and development in the field of steelmaking has shifted its emphasis to the solidification I ingot-making process in which continuous casting plays the leading role. From a long-range point of view, however, the need for continual development of the refining process will probably increase but is very unlikely to decrease. In order to meet such demands, it is required that problems and issues of the present process should be clearly grasped and that there must be rapid progress in process elements, such as highly efficient mixing and separation of different phases.Applications of electromagnetic and ultrasound energies and flow field control will become important options for resolving the above-mentioned problems. By efficiently and skillfully incorporating these new technologies into high-efficiency mixing/separation reactors, the innovative refining process will be established in the early 21st century."

Jan 1, 2000

By Ygor Macabu de Moraes, Jean Igor Margem, Carolina Gomes Dias Ribeiro, Frederico Muylaert Margem, Sergio Neves Monteiro, João Batista Vasconcelos

A natural fiber presents interfacial characteristics with polymeric matrices that favor a high impact energy absorption by the composite structure. The objective of this work was then to assess the Izod impact resistance of polymeric composites reinforced with one or two layers of batt malva and jute fibers. The results showed are markable increase in the notch toughness with increasing layers of mauve blankets and jute.This can be attributed to a preferential debonding of the fiber/matrix interface, which contributes to an elevated absorbed energy.

Mar 1, 2017

By Ali Kucuk, Bekir Karasu, Keriman Karaveli Pekkan

"Zircon (zirconium silicate) is the main opacifier of glossy, opaque, white colored, frit-based wall tile glazes. However, zirconia containing frits employed in the preparation of these glazes increase the production cost and therefore, limit zircon usage as a raw material at industrial scale. With the present study, it was searched whether borax solid wastes could be evaluated as a component in the starting relevant frit recipes. The wastes were obtained from Eti Maden Kirka Boron Company of Turkiye. Frit production, glaze preparation, application, and fast single-firing of glazed wall tiles were conducted under laboratory working conditions in Anadolu University, Department of Materials Science and Engineering laboratories. Beside standard tests applied to the final glazed wall tiles, color and gloss analyses of the fired glazes were conducted with a spectrophoto-meter and a gloss-meter. Characterization of these newly produced glass-ceramic glazes was made by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) techniques. IntroductionFrits are the indispensable constituents of most industrial glazes which mature at temperatures below 1150 °C [1]. In the traditional opaque glazes used in wall tile industry, opacity usually originates through hardening of glass matrix by adding high amounts of zirconia containing frits into the glaze batch [2]. Nowadays, researches point out that certain type of glass-ceramic layers can be alternatively employed as tile coatings lowering the use of zirconia containing expensive opaque frits. A rather high crystallization capacity of glass- ceramic glazes due to zirconia presence in glass network makes them suitable candidate as a glaze coating with a desirable micro-structure. One of the best methods to obtain an opaque glaze surface is to induce a crystal phase in the coating, whose refractive index differs significantly from that of the glassy matrix. The opacity of such coating is determined by the diffusion, refraction and reflection of light through the layer containing emerging crystals, and the degree of opacity mainly depends on the size and quantity of crystals. The development of glazes not consisting of expensive or toxic components is of special interest [3]."

Jan 1, 2008

By C. R. Bennett

The first phase in the design, development and implementation of a comprehensive computational model of a copper stockpile leach process is presented. The model accounts for transport phenomena through the stockpile, reaction kinetics for the important mineral species, oxygen and bacterial effects on the leach reactions, plus heat, energy and acid balances for the overall leach process. The paper describes the formulation of the leach process model and its implementation in PHYSICA+, a computational fluid dynamic (CFD) software environment. The model draws on a number of phenomena to represent the competing physical and chemical features active in the process model. The phenomena are essentially represented by a three-phase (solid-liquid-gas) multi-component transport system; novel algorithms and procedures are required to solve the model equations, including a methodology for dealing with multiple chemical species with different reaction rates in ore represented by multiple particle size fractions. Some initial validation results and application simulations are shown to illustrate the potential of the model.

Jan 1, 2003

By Ann E. Visser

Aqueous Biphasic Systems (ABS) form upon the admixture of certain water-soluble polymers or polymers and salts above critical concentrations, and thus represent liquid/liquid extraction systems whose nature is entirely aqueous. We are currently investigating the utility of ABS (and its solid phase analogs) as "green" alternatives to the use of volatile organic diluents in separations of metal ions. Chaotropic (water-destructuring) metal ions with small negative AGhyd (e.g., Tc04) tend to partition quantitatively to the PEG-rich phase of an ABS, but even hydrated metal cations can be partitioned to the PEG-rich phase if a suitable extractant (e.g., halide, dye, crown ether, etc.) is used to produce a more chaotropic ion-complex.

Jan 1, 1999

By Gregory A. Knapp

Treatment of industrial wastewaters generally advances with specific chemical concentration and mass-flow targets, established by National Pollutant Discharge Elimination System (NPDES) permits. Treated discharges must also address toxicity to test and receiving water organisms. Various parameters might need consideration during treatment design and planning, such as the known toxicants, hardness, alkalinity, solids, nutrients, metals in both the dissolved and particulate state, and even flow. Since toxicity is used as a "catch all" regulatory monitoring tool, design of treatment systems should focus on the various factors contributing to toxicity.

Jan 1, 1996

By Thomas Gliick, Jianming Lu, David Dreisinger

"The recovery of manganese from the Boleo project of Baja Mining is via an acid oxidation and acid reduction process in seawater. Manganese as manganese dioxide is leached into solution as manganese sulphate with the addition of sulphur dioxide gas as a reductant and then precipitated as a manganese carbonate. The use of the manganese carbonate intermediate to produce electrolytic manganese metal (EMM) has been extensively studied. The manganese carbonate can be used in place of natural (MnC03) or reduced ores (MnO) of manganese as a feed to the EMM plant. Manganese carbonate can be dissolved in spent electrolyte from manganese plating, followed by purification using ammonium sulphide precipitation of minor elements and then electrowinning in a selenium free process. The results of small cell testing of manganese electrowinning are reported.IntroductionThe Boleo Project of Baja Mining is a greenfields development currently under construction approximately 5 km north of the town of Santa Rosalia, Baja California Sur, Mexico. The Boleo property is held by the Mexican company, Minera y Metalurgica del Boleo S.A. de C. V. (MMB). MMB is owned 70% by Baja Mining Corp. and 30% by a consortium of Korean companies consisting of KORES - Korea Resources Corporation, LS Nikko Copper, Hyundai Hysco, SK Networks and lljin Copper.The Boleo deposit has Measured and Indicated resources of264.7 million tonnes grading 1.50% copper equivalent (CuEq) & Inferred resources of 159.9 million tonnes grading 1.15% CuEq. The calculation of copper equivalent is based on a combination of metal prices and predicted metallurgical recoveries (Table I). The metallurgical recoveries have been confined by extensive bench and pilot plant testing. Proven and probable reserves are available at Boleo to provide for more than a 30 year mine life. Initially, 25 years of mine life and 23 years of process plant operation have been scheduled in the February 2010 Technical Report Update (www.sedar.com)"

Jan 1, 2012

By Nobuyuki Higashiyama, Ikuo Yonezu

"Hydrogen-absorbing alloys containing rare-earth elements are used in high capacity nickel-metal hydride secondary batteries,' hydrogen storage systems for portable fuel cells, and refrigeration systems. New hydrogen-absorbing alloys containing rare-earth elements have also been developed and introduced into these applications. High performance in nickel-metal hydride secondary batteries is strongly demanded because of the remarkable advancements in portable electric appliances. A large hydrogen absorption capacity, high electrochemical reactivity and superior corrosion resistance in an alkaline solution are required for hydrogen-absorbing alloys used in nickel-metal hydride batteries. The aim of this investigation is to improve the performance of conventional LaNi5 type hydrogen-absorbing alloys. For example, Mm(Ni-Co-Al-Mn)„ type hydrogen-absorbing alloys with various non-stoichiometric compositions were developed. In addition, a new process of rapid quenching process was applied for preparing these hydrogen-absorbing alloys in order to improve their performance.IntroductionRecently, the trend in electronic appliances toward portability has increased the demand for high capacity of secondary batteries as power sources. Since nickel-metal hydride batteries were first commercialized in 1990 in Japan, they have become increasingly popular as power sources for cellular phones, portable computers, electric shavers, and other, products.The performance of a nickel-metal hydride battery, such as its discharge capacity, high rate capability, and charge-discharge cycle life, strongly depends on the characteristics of the hydrogen-absorbing alloy negative electrode. Many types of hydrogen-absorbing alloys have been developed so far. For a hydrogen absorbing alloy to be used as the negative electrode material, (1) it must allow a large amount of hydrogen to be absorbed and desorbed in an alkaline solution, (2) its reaction rate should be high, and. (3) it must have long term durability under repeated charge-discharge cycling. However, LaNi5, a typical rare earth-nickel type alloy, shows significant capacity deterioration during repeated charge-discharge cycling. Therefore the first step in its development was to obtain sufficient corrosion resistance of the LaNi5 alloy for its use as an electrode material. A partial replacement of nickel with cobalt and a substitution of the lanthanum- content with misch metal (Mm), a mixture of rare earth elements such as lanthanum, cerium, praseodymium and neodymium, were very useful in improving the charge-discharge cycle life. However, the discharge capacity of the alloy was still not sufficient for a practical battery. A study of the effect of the partial substitution of aluminum and manganese showed that the best alloy composition was Mm(Ni-Co-Al-Mn)x, as follows.The stoichiometry x of Mm(Ni-Co-Al-Mn)x largely affects the discharge capacity and cycle life. Theose alloys with non-stoichiometric alloys with the compositions of [Mm(Ni-Co-AMn)x: 4.7<x<4.8] have a large capacity and a long cycle life. Nogami' et al. reported that 'a non-stoichiometric alloy with a Mm(Ni-Co-Al-Mn)x (x=4.76) composition showed approximately 10% higher discharge capacity than the stoichiometric alloy (x=5) [1] and greater influence of x on the electrochemical properties of multi-component AB„ type hydrogen-absorbing alloys for batteries."

Jan 1, 2000

By John E. Dutrizac, Tzong T. Chen

"Laboratory experiments were undertaken to ascertain the behaviour of various ""impurity"" species during the precipitation of hematite directly from ferric sulphate solutions at 225°C and in the presence of 40 or 50 g/L of hematite seed. Copper, nickel and zinc are not significantly incorporated in hematite precipitates. Although the nickel contents increase to 0.22% as the Ni concentration increases to 60 g/L, the solid solution Ni contents are low relative to the bulk Ni contents. Thus, part of the Ni may be present as tiny particles of poorly soluble NiS04.H20. Increasing germanium concentrations to 2,000 mg/L result in products containing up to 0.59% Ge. The Ge occurs either in solid solution in the hematite or is adsorbed on the nanometer-size hematite crystallites. Increasing As(V) concentrations to 10 g/L increase the AsO4 contents of the products up to 16%. However, the products consist of hematite together with As04-containing Fe(SO4)(OH) and an unknown Fe-AsO4 species. All the hematite products contain - 1% SO4 which appears to be adsorbed on the nanometer-size hematite crystallites.IntroductionDissolved iron is a common impurity in most hydrometallurgical processing circuits and, generally, the iron must be eliminated prior to the subsequent recovery of the sought after metals. Simple neutralization of iron-rich solutions yields slurries which are difficult to thicken and filter. To address these concerns, the jarosite, goethite and hematite processes have been developed, and these technologies are able to reject the dissolved iron in a readily filterable form [1]. Despite its higher cost, the hematite process offers several potential advantages. Because hematite is an iron-rich, high-density compound, its formation would reduce the mass of residue and the size of a residue storage pond. Hematite is the thermodynamically stable form of iron under ambient conditions, and this stability would facilitate the impoundment of hematite precipitates. Furthermore, hematite has some market potential for cement manufacture and even for iron making [2]. In all the commercial hematite processes, the dissolved ferric ions are first reduced to the ferrous state. Subsequently, the pH of the solution is adjusted and the solution is then oxidized. The ferric ions gradually generated during solution oxidation hydrolyze and precipitate mostly as hematite, although commercial hematite products also contain trace or minor amounts of jarosite-type compounds. However, there are potential advantages in precipitating hematite directly from ferric ion solutions, as the reduction and subsequent oxidation of the iron are not required. Although the precipitation of hematite directly from relatively concentrated ferric sulphate solutions (up to 0.5 M Fe(SO4)is) was recently demonstrated [3], the behaviour of impurity species during hematite precipitation is largely unknown. To address this issue, systematic laboratory experiments were undertaken to ascertain the behaviour of a number of ""impurity"" species during the precipitation of hematite directly from ferric sulphate solutions at 225°C, and the results are presented in this paper."

Jan 1, 2012

By John W. Cash

The mineralogy and textures of cyclone dust, sludge, and occasional build-ups in the American Iron and Steel Institute (AISI) direct ironmaking pilot plant at Universal, Pennsylvania have been studied by reflected light, transmitted light, and cathodoluminescence microscopy, and phase compositions have been determined by SEM-EDS. The cyclone dust consists of particles of carbon, metallic iron, sulfur-bearing iron, and wustite. Measurements of particles in the sludge indicates that 69% are less than 2.5 um across, 21 % are 2.5-5 um, and 10% are larger than 5 um. Mineralogically the sludge particles are mainly carbon and metallic iron, with minor wustite and sulfur-bearing iron. Build-ups that sporadically develop in the furnace consist of olivine, hercynite spinel, metallic iron, wustite, pyrrhotite, pseudobrookite, akermanite-ferroakermanite and gehlenite. The microtextures shown by the build-ups indicate that much of that material has precipitated at the build-up loci. This study has been supported by AISI and the U.S. Department of Energy.

Jan 1, 1995

By Keizo Uematsu, Kumiko Sanda, Nozomu Uchida

"Full understanding of mechanical properties is the most important assignment in ceramics. Establishment of defects-property relationship is crucial for fulfilling the assignment. This study reports detailed characteristics of defects and their relevance to the mechanical properties for alumina ceramics made through a typical industrial processing. Novel characterization methods were applied to evaluate their defects. A very simple direct correlation was successfully found between defects and properties in ceramics. This result is a great epoch in the field of ceramics. IntroductionThe ceramic materials are used in refractoriness, corrosion resistant materials and structural materials. The low fracture toughness and scatter of strength are very important problems in ceramics. The toughness of ceramics is lower than metal and polymer materials, and the allowed defect size is small. Very small internal defects (pore, crack, huge particle) can be a fracture origin in the brittle fracture. The characteristics of defects such as size, distribution and shape change markedly by process condition, which cause the scatter of strength. This study conducts quantitative evaluation and direct observation of the sizes, shape and a number of internal defects with a light microscope, and discusses the relationship for mechanical properties and defect sizes"

Jan 1, 2000

By Yuanyuan Wang, Yuhao Ding, Hao Bai, Kang Zhou, Guangwei Du

"In this paper, the list analysis of GHG emissions of aluminum industry was conducted based on the data from typical electrolytic aluminum plants of a China’s northwest province. The results show that under the conditions of average anode effect coefficient as 0.16 times/(cell• day) and anode duration as 5 minutes per day, equivalent emissions of CO2 reached 1.23 ton per ton of aluminum, in which PFC emissions accounted for about 71%. Compared with foreign advanced level, which is 0.87 ton per ton of aluminum under the conditions of average anode effect coefficient as 0.01 times/(cell•day) and anode duration as 0.46 minutes per day, there is much room for China’s aluminum industry to reduce GHG emissions. Since anode effect plays an important role on PFCs generation in electrolytic aluminum process, how to control anode effect strictly becomes the key factor for remarkable reduction of GHG emissions in China’s aluminum industry.IntroductionTechnology of aluminum electrolysis is a mature and efficient process of aluminum production. Due to the huge demand on aluminum worldwide, so resource consumption, energy consumption and pollutant emissions in the process of aluminum production are still large. The global output of aluminum reached 45193 kt in 2012. A large amount of CO2 and PFCs are produced in the process of aluminum production, and the greenhouse effect and environmental pollution caused by emissions of them is a concern. PFCs belong to a powerful greenhouse gas, thus emission reduction of PFCs is very important for aluminum electrolysis industry. At present, China's aluminum production accounts for about 33% of the world's aluminum production, and controlling PFCs emission has become the key point of pollution control of aluminum electrolysis industry in China [1].Taking the case of a typical electrolytic aluminum plant of a China’s northwest province, this paper studies the list analysis of GHG emissions of aluminum industry in China. GHG emissions of a China’s northwest province were calculated through investigating existing situation of aluminum electrolysis industry in the province, knowing capacity, output, main production technology and equipment level of aluminum electrolysis industry, and using the calculation framework and methods of GHG emissions of aluminum electrolysis industry, which were put forward by the intergovernmental panel on climate change (IPCC), the international aluminum association and other organizations at home and abroad. The list analysis of GHG emissions of aluminum electrolysis industry will offer useful information in promoting emission reduction of GHG in aluminum electrolysis industry, improve the efficiency of energy utilization."

Jan 1, 2014

By T. A. Chepushtanova, B. Mishra, E. O. Kilibayev, V. A. Luganov

"The paper contains the results of studying about modification of pyrite and arsenopyrite specific surface and porosity at their thermal decomposition. The studying of specific surface was carry out by B.E.T. – adsorption of nitrogen at his boiling-point. In our work were using the electron-microscopical, X-ray structure analysis and chemical analysis. There was established that the decomposition of pyrite and arsenopyrite accompany by increasing of pores volume from 0.303 · 10-3 to 1.23 · 10-3 at increasing of pyrite degree of decomposition about 41 % and then decrease about 0.131 · 10-3 m3/g at degree of decomposition near 100 %. The surface area of pores increase from 0.31 to 1.085 m2/g with following lowering due to enlargement and confluence of minor, small pores. Increasing of porosity accompany with increasing of particles windage that appear the result of heightened dust-furnace partially decomposing pyrite and arsenopyrite particles by air flow from furnace reaction zone. This explains heightened contention of sulfide sulfur in roast dust of sulfide concentrate. 1. INTRODUCTION As a result of ore base exhaustion of ferrous and nonferrous metallurgy at metallurgical treatment are involving more complicated and less qualitative ores. Magnetiting ores content considerable quantity of pyrite complicative the technology of iron extraction. At the same time the pyrite concentrates wining at dressing content different nonferrous metals in industrial quantities. Extracting ores of nonferrous metals are contenting considerable quantity of arsenic at the present time. Extraction of base metals from complicated raw materials demands new technologies. Arsenic contenting in ores is necessary to utilize (waste burial) in more ecological compatible form. Arsenic on acting metallurgical and chemical enterprises from technological cycle is withdrawing in the form of arsenate – arsenite cakes, burial of their may lead to seriously ecological problems as times goes by. In Kazakh National Technical University is carry out the cycle of researching by pyrite, arsenopyrite and arsenate – arsenite cakes treatment with the object of arsenic withdrawal in sulfide form – in more ecological and safe form and with the object of preparation of initial ore raw materials to following pyro- and hydrometallurgical treatment. As a result of sulfidizing of arsenate – arsenite cakes by pyrite are forming the volatile arsenic forms and pyrrhotite of variable structure."

Jan 1, 2008

By A. J. Meir, Paul G. Schmidt

"We present a novel approach to the mathematical analysis and computational simulation of fully three-dimensional, nonlinear, viscous, incompressible MHD flow in complex configurations involving several liquid and solid conductors. Such configurations arise in numerous metallurgical processes. Employing the current density rather than the magnetic field as the primary electromagnetic variable, it is possible to avoid artificial or highly idealized boundary conditions for electric and magnetic fields and to account exactly for the electromagnetic interaction of the flow region with the surrounding space. In addition, the approach lends itself naturally to finite-element based discretization techniques. As an application, we simulate the stationary flow of an electrically conducting fluid around a solid spherical particle of arbitrary conductivity, in the presence of crossed uniform electric and magnetic fields, and compute the Lorentz, pressure, and viscous forces exerted on the particle. This problem arises in connection with the electromagnetic filtration (purification) of molten metals before the casting stage.IntroductionNumerous metallurgical processes are governed by MHD effects resulting from the macroscopic interaction of liquid metals with applied or induced currents, electric and magnetic fields. Frequently these effects are technologically exploited in order to drive or to control the flow of metallic melts. Typical examples include the electromagnetic stirring of molten metals before the casting stage [1]; electromagnetic turbulence control in induction furnaces [2]; electromagnetic damping of buoyancy-driven flow during solidification [3]; and the electromagnetic shaping of ingots in continuous casting [4]."

Jan 1, 1999

By Maria Cristina Ruiz

The removal of iron from the leaching circuits is a common problem in the hydrometallurgical processing of non ferrous metals. Among the currently available processes, hematite precipitation is the most recommendable from an environmental point of view. This paper is concerned with the batch precipitation of hematite from ferrous sulfate solutions. One of the main objectives of the study was to determine the effect of the experimental conditions on the extent of iron precipitation as well as the purity and the particle size distribution of the precipitates. The main variables studied were temperature (180 to 220 ºC), concentration of sulfuric acid (1 to 10 gpl), initial iron concentration (1 to 15 gpl) and partial pressure of oxygen (3 to 7 atm). The results showed that increasing the oxygen partial pressure from 3 to 7 atm produced a very small increase on the rate of hematite precipitation indicating that a large partial pressure of oxygen is not needed for an effective ferrous to ferric oxidation. An increase in the temperature produced finer precipitates with lower sulfur contents. On the other hand, an increase in sulfuric acid concentration and initial iron concentration produced precipitates with larger particle sizes and higher sulfur contents.

Jan 1, 2006

By Marc Verhaege

The effluent under investigation results from a catalic oxidation unit in which paraxylene is oxydised to terephtalic acid. The solution contains cobalt and manganese as their acetates in a concentration range of 0,4 - 1,2 g/I of cobalt and 0,8 - 2,4 g/l of manganese. Before being fed into the main waste stream treatment unit of the plant it is advisable to apply a petreatment step in which both metals are eliminated to a great extent from this effluent. Conventional treatment is done by precipitation of both metals either through pH increment with a base or by adding a suitable reagent producing insoluble species. The aim of this study was to look for a treatment (elimination of both metal species) in which no sludge or precipitate is formed.

Jan 1, 1995

By R. D. Irwin, W. M. Mullins, E. A. Medina

"Various stability criteria are introduced and thermo-kinetic models for metallurgical processes are used as concrete examples for evaluation. Kinetic criteria for the process of dynamic recrystallization are proposed. These criteria are compared to the non-equilibrium thermodynamic approaches discussed in the literature. The application of macroscopic stability criteria to materials processing is then discussed.IntroductionThe mechanical behavior of metals at elevated temperature is very well predicted by any of several empirical constitutive relations. Typical is the power-law (or Swift's) form,Equationwhere r-is the stress, y is the strain and m, n , t0, y0 and Q are material constants. This form has been used with some success in the metals processing area [1]. In general, though, all of the empirical constitutive equations are static, failing to account for any dynamical properties of the system they seek to describe.The physics of warm deformation is qualitatively well understood. An example is power-law creep, where the dominant mechanism is assumed to be lattice diffusion limited climb of dislocations, which allows the strain-rate to be determined by the applied stress through"

Jan 1, 1997

By Nicole de Jager, Michael J. Nicol

"In order to liberate gold from refractory gold ores and concentrates it is generally necessary to oxidise the surrounding sulphide minerals, typically pyrite and arsenopyrite. Traditional methods of oxidation include pressure leaching, roasting and bacterial oxidation. In recent years, bacterial and pressure oxidation have found increasing favour, although these methods are by no means completely satisfactory and each is subject to particular disadvantages.A novel process has been developed as an alternative to the traditional methods whereby electro-generated ferrate(VI) ions in alkaline solution are used to oxidise a pyrite concentrate. This process has been observed to proceed fairly rapidly and could prove to be a more economically viable process, as well as being more environmentally acceptable. As an added benefit, operating in an alkaline environment is advantageous for downstream cyanidation processes.Ferrate(VI) is a relatively unknown species, due mainly to its instability in acidic solutions. However, in alkaline solution it has been observed to be sufficiently stable for use as an oxidant when used under favourable conditions. Ferrate(VI) is most conveniently manufactured electrolytically via the dissolution of high-carbon anodes in strongly alkaline solutions. Some literature has been published on the electrolytic generation of ferrate(VI) and relatively high efficiencies have been observed by both the authors and other researchers.This study utilises both electrochemical techniques and leaching experiments to examine the kinetics of the oxidation of pyrite by ferrate(VI), which is produced electrolytically. Cyclic voltammetry, rotating disk voltammetry and potential step experiments have been used to investigate the kinetics and mechanism of the oxidation process."

Jan 1, 1997