Search Documents

By Yunhua Gan, Xiaowen Chen, Yang Tong

Experimental studies of electro-spraying were carried out using ethanol as fuel in a microcombustor under combined electric field. And the effects of different electro-spraying modes on the combustion efficiency were analyzed. Results showed that when ring electrode potential was invariant, there were four different electro-spraying modes with the variations of nozzle potentials, which were varying with the flow of ethanol. The cone-jet mode was the stablest one during the whole experimental process. The atomized ethanol was ignited and combusted stably near the steel mesh, the combustion efficiency increased firstly and then decreased along with the increasing of the equivalent ratios, reached the maximum values when the equivalent ratio equal to 1.0. And the maximum values were the highest at the cone-jet mode, and the lowest at the pulsed-jet mode.

Jan 1, 2016

During electrowinning of nickel chloride, hydrochloric acid was regenerated instead of chlorine in a two membrane cell, by segregating the chloride catholyte with an anion exchange membrane, and the sulphate anolyte with a cation exchange membrane from the middle electrolyte (ampholyte) compartment. Successful operation of such a cell depends on controlling chloride leakage through the cation exchange membrane to the anolyte. Small amounts of chlorine gas could be detected in the oxygen evolved at the anode. In this paper, the chloride. leakage as a function of various types of cation exchange membrane and different composition of the anolyte is reported and discussed. Ag+ was added to the anolyte to eliminate chloride leakage to the anode. The cell voltage, electrode potential and voltage drop over the membrane as a function of current density has also been investigated.

Jan 1, 1996

By B. J. Zhao, F. L. Han, L. E. Wu, M. Chen, Y. H. Chen

Magnesium is the lightest structural metal with a density only two-thirds of aluminium and one-quarter of steel. It can be produced by electrolysis of fused magnesium chloride or high temperature reduction of the oxide. The predominant method for magnesium production is the Pidgeon process which is a batch process starting from calcined dolomite and ferrosilicon. CaF2 is commonly used in the process as the catalyst. Analyses of the slag samples and thermodynamic calculations indicated that liquid phase plays important role in the reduction process. Effects of chemistry, temperature and gas pressure on the production have been discussed and compared with the operating data. Understanding of the reaction mechanisms will provide a fundamental base for alternative processes of the magnesium production.

Mar 1, 2017

By L. Escudero-Castejon, S. Sanchez-Segado, A. Jha, Y. Hara, S. Parirenyatwa

In a world where declining ore grades are increasingly common, it has become necessary to process low-grade feedstock. Carbothermic reduction in the presence of alkali (Na2CO3) has been adapted to beneficiate waste that contains titaniferous minerals (TiO2 ca. 12 wt%), in order to recover valuable constituents such as TiO2, Fe and V2O5. The waste from vanadium metal processing has environmental legacy as it leaves nearly 1 wt% V2O5 process waste, which is environmentally problematic due to V5+ ions in contact with water and soil. This investigation focuses on the kinetics and mechanism for alkali reduction of mineral waste bearing 10–12 wt% TiO2, which we studied in the 1073–1323 K range. The thermogravimetric analysis (TGA) technique was used to record weight loss data. Two distinct regimes demonstrated mixed-control kinetics: (1) at low temperatures the activation energy was found to be 199 kJ mol−1, which corresponds to the outward diffusion of O2− ions; and (2) at high temperatures the calculated value was 130 kJ mol−1, which is consistent with the activation energy for the outward diffusion of Fe2+ ions. The metallic iron, sodium titanate and sodium aluminosilicate phases that formed were characterised using X-ray powder diffraction (XPRD) and scanning electron microscopy (SEM) techniques, and their significance for metal recovery is explained.

Mar 1, 2017

By Gavin Beer

The Chelopech Copper/Gold Mine, located in west-central Bulgaria, has been in operation since 1953 producing a low-grade copper/gold concentrate containing up to six percent arsenic by weight. The penalties and restrictions imposed on smelting this concentrate, have seen the past operators of the mine strive to find a balance between achieving acceptable metal returns from the smelters and installing novel or unproven technologies in the face of changing political and economic climates. This paper documents the colourful history of the concentrate processing alternatives that have been investigated and implemented over the 45 year life of the Chelopech Mine, culminating in the high pressure oxidation option that is now the focus of a Definitive Feasibility Study (DFS) presently being undertaken by GRD Minproc Limited. The fundamental chemistry of the preceding alternatives is outlined followed by a discussion as to why each was ultimately not employed. A detailed description of the technology proposed in the DFS is given including: pressure oxidation, arsenic fixation, SX/EW copper recovery, CIL gold recovery and AVR/SART cyanide/copper recovery processes. Keywords: Arsenic, Scorodite, HPOX, Chelopech, Dundee

Jan 1, 2005

By Yang Xianwan, Zhu Xiaoyun, Guo Zhongcheng, Zheng Yanping, Zhai Dacheng

"Corrosion resistance of RE-Ni-W-P-SiC composite coating and 3 l6L stainless steel in corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations by means of immersion methods and anodic polarization curves obtained by DHZ-1 electrochemical synthetic tester and HDV-7 transistor constant potentiometer. Immersion experiment results show that corrosion rate of RE-Ni-W-P-SiC composite coating as-deposited in HCl solutions increases with the rise of HCl concentrations, on the contrary, the corrosion rate of the composite coating after heat treatment decreases with increasing the HCl concentrations the corrosion rates of the coatings as-deposited and after heat treatment in H2SO4 and H3PO4 solutions respectively decrease with the rise.of H2SO4 and H3PO4 concentrations the corrosion rate of the deposit as-deposited in FeC13 solutions decreases with increasing FeC13 concentrations, while the rate of the composite coating after heat treatment increases .with the rise of FeC13 concentrations.In addition, the corrosion rate of 3 l 6L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations increases with rising of concentrations. Furthermore, the corrosion rate of 316L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions respectively is much greater than that of the RE-Ni-W-P-SiC composite coating as-deposited and after heat treatment in the same corrosion media.1. IntroductionAll the materials and their products, when processed, stored and used, it is inevitable that the corrosion, wear, fatigue and crack occur owing to the actions of surroundings. Those early failure and abrasion, through all kinds of departments and profession that corrosion consumes one percent of tens of the steel products of the whole world; and two or four percent of the GDP is lost because of the corrosion."

Jan 1, 2000

By Hye-Sung Kim, Dong-Wha Kum, Gyeungho Kim

"Mechanical alloying is an effective way to finely distribute inert dispersoids in AI-TM (TM is a transition metal element) systems. It is considered that high melting point aluminides are formed by precipitation from the supersaturated aluminum matrix. The analysis is based on the fact that much higher content of TM than the solubility limit can be dissolved in alpha aluminum during the high energy ball milling. Nonetheless, the role of undissolved TM particles affecting the formation of aluminides is not suitably considered. In this paper, authors present experimental observation on the formation of Ab3Ti particles from mechanically alloyed AI-Ti alloys in the hyper-peritectic region. This study showed that, in the mechanically alloyed AI-20wt%Ti specimen, intermediate phase of cubic Ab3Ti and tetragonal AIz4Tis formed at 300 - 400°C and 400 - 500°C, respectively, before the MA-state reaches to the global equilibrium at higher temperatures. The formation behavior of Lh- Ab3Ti is interpreted by interdiffusion of Al and Ti in solid state based on the fact that large amount of nano-sized Ti particles exist in the milled powder. Present analysis indicated undissolved Ti particles of nanosize should have played an important role initiating the formation of Ab3Ti phase during annealing.IntroductionInterest in the hyper-peritectic AI-Ti alloys is based on industrial demand for high-modulus and high-temperature aluminum alloys. Earlier works on hyper-peritectic AI-Ti alloys with 4 to 12wt%Ti show that these alloys are strong at ambient temperature and maintain high strength above 300°C when titanium-trialuminide (e.g., Ab3Ti) is finely distributed in the aluminum matrix [1,2]. High melting point and high stiffness with low density of AbTi make the AI-Ti alloys strong with greater thermal stability while keeping weight savings as much as possible. Titanium in aluminum shares other merits of transition metal additions because Ti solubility in Al is low (i.e., 1.l5wt%Ti at 665°C and virtually zero below 400°C), and fine dispersion of Ab3Ti particles is readily accomplished and resists grain coarsening effectively."

Jan 1, 1996

By Chang Wei, Zhigan Deng, Minting Li, Cunxiong Li, Gang Fan, Xingbin Li

Iron precipitation occupies a vital position in the metallurgy industry, especially for treating iron-bearing sphalerite in hydrometallurgical processes. This paper emphasizes techniques for removing iron from high-iron sphalerite via hematite precipitation, and describes the results of research performed to examine ferrous oxydrolysis and precipitation. The behavior and mechanism of conversion between the iron phase and hematite residue at elevated temperature under pressure is ascertained by investigating the dissolving characteristic and thermodynamics stable area of hematite at sulfate system. The results show hematite precipitation went through the process of crystallization, dissolve, oxidation and precipitation of ferrous sulfate, and the overall iron precipitation was determined to be controlled by the rate of ferric sulphate hydrolysis rather than the oxidation of ferrous sulphate or the re-dissolution of ferrous sulphate crystals, or the transformation of basic ferric sulphate.

Mar 1, 2018

By E. A. Trillo, L. E. Murr, R. D. Flores, J. C. McClure, B. M. Nowak

Complex vortex and swirl-like solid-state flow phenomena have been observed in the residual microstructures characterizing the friction-stir welding (FSW) of copper to 6061 aluminum; 2024 aluminum to 6061aluminum,2024 aluminum to 1100 aluminum, 2024 aluminum to 7039 aluminum and 2024 aluminum to 2195 aluminum. These flow phenomena are characterized by intercalation lamellae composed of dynamically recrystallized grain structures of the dissimilar metals which provide a super-plastic-like mechanism for the FSW flow in the solid state; there is no melting and temperatures at the weld center do not exceed about 0.8 TM (where TM is the absolute melting temperature (K)). In experiments to be described and illustrated, optical or light metallography (LM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques are utilized in examining residual FSW microstructures corresponding to tool rotation (stirring) speeds ranging from 400 to 1200 rpm, and traverse (or actual welding) speeds of 1 to 2 mrn/s.

Jan 1, 1999

By Fiseha Tesfaye, Pekka Taskinen

"Thermodynamics of the equilibrium phase assemblage Ago_9Cul.lS-Cu2-xS-CuS have been studied by an EMF -method. The ternary phase was synthesized from the pure Cu2S and Ag2S in vacuum furnace at high-temperature and mixed with appropriate compositions of Cu2S and CuS to form the cathode electrode. The EMF-measurements were made on the solid-state galvanic cell Pt(-) I Ag I RbAg,ils I Ago9Cu1.1S-Cu2-xS-CuS I Pt(+), in a temperature range from 316 K to 498K.Based on the measured EMF vs. T relations, thermodynamic functions (?fG° , ?fS and ?fH°) of stromeyerite (Ag0.9Cu1.1S) in equilibrium with Cu2-xS and CuS have been determined. The obtained experimental values have been compared with the available literature values. New experimentally determined thermodynamic properties of the solid solution (Ag,Cu)2Sss were determined.IntroductionDue to intense mining of high grade sulfide ore minerals in the past, recently, the available sulfide ores are poor in metals and becoming increasingly complex; such that, the production of high grade metals by the conventional pyrometallurgical processes is compromised. Consequently, smelters are in need to modify their operating flow sheets and strategies for processing more complex feed materials economically, while meeting the strict environmental regulations. To make the appropriate modifications, accurate thermochemical data of phases and phase assemblages which exist in these complex ore minerals are essential.Silver-bearing sulfosalts are encountered in ore minerals for the production of base metals and are common sources of silver. Among the silver-based sulfosalts, stromeyerite (Ag0_9Cu1.1S) is relatively common ore mineral in most hydrothermal vein and replacement deposits [1]. Recently, the ternary chalcogenide compound Ago0.93Cu1,07S has been studied, intensively, due to its high ionic conductivity and gradual disorder in the sequential phase transitions [2]. Therefore, accurate knowledge of the thermodynamic properties of stromeyerite has considerable fundamental and practical interest in many aspects of extractive, chemical and physical metallurgy."

Jan 1, 2014

By Ruiling DU, Xiao YUAN, Keng Wu, Daan XU, Changyao CHAO

To utilize low grade coals to produce high quality semi-coke which can be used in blast furnaces, the pyrolysis of low grade coals was studied in this paper. According to the characteristics of coal pyrolysis process, the temperature range was divided into three parts. The interfacial chemical reaction model, random pore model and the internal diffusion model with the shrinking volume of resultant were established to describe the different ranges of pyrolysis process respectively. The results showed that the experimental data was fitted well, and all the correlation coefficients (r2) exceeded 0.97. Finally, the kinetic parameters for each temperature range have been calculated, which laid a necessary foundation for the simulation and expanded production.

Jan 1, 2016

By David T. Bunney

In .December of 1987, International Mill Service, Inc. signed an exclusive licensing agreement with Tetronics Research & Development Co. Limited of Faringdon, Oxfordshire., England to commercialize plasma technology which had been demonstrated in an EAF dust processing application. The intent of the process is to reduce and volatize the zinc, lead and cadmium oxides inherent in EAF dust and collect these elements as metals in an ISP (Imperial Smelting Process) zinc splash condenser, and to render the resultant slag an inert, non-hazardous material. With these objectives in mind, IMS started commissioning facilities in 1989 at Florida Steel in Jackson, Tennessee and Nucor-Yamato Steel in Armorel, Arkansas. This paper will address the commercial development and progress of the technology at these two installations. Process Description In the EAF steelmaking process typically the off gas stream is cleaned by some form of baghouse. The particulate collected is known as Electric Arc Furnace dust and has been designated by the U.S. EPA as hazardous waste number K061, once it leaves the collection system. This designation was given to the material due to the high toxic concentrations of lead and cadmium (nickel and chromium for stainless EAF dusts) inherent in the dust. IMS' method of operation is to locate the facilities on the client mill's property adjacent to the baghouse. The dust is transported directly to IMS via a closed conveyance system. This method enables the technology to be an additional processing step in the steelmaking process. Once the dust has been transported to the IMS facility, it is fed, metered and mixed mechanically in the feed conveyance system with a carbon reductant (typically coke breeze). The carbon reductant is approximately 10% of the dust feed rate. This mixture passes through the feed system and enters the furnace

Jan 1, 1992

By Yogeshwar Sahai

Submerged gas injection into melts contained in furnaces, ladles, or similar transfer vessels is commonly used in industrial practice. In this review paper, conditions leading to gas bubble formation at the nozzle are first summarized. The increasing gas injection rates and other conditions, such as nozzle size, lead to regimes which are commonly known as "bubbling" and "jetting". These are explained. The gas/melt interactions result in energy transfer to the melt. In recent years, a large number of researchers have investigated the relationships between the energy density and the mixing times. Their work is reviewed, and the mixing mechanisms is described. Finally, computational approaches of modeling submerged gas injection are briefly presented.

Jan 1, 1993

By Beatryz C. Mendes, Igor K. R. Andrade, Roseli O. G. Martins, Gustavo H. Nalon, Rita de C. S. S. Alvarenga, Leonardo G. Pedroti, Carol F. R. Santos, Marcelo A. Alves

This work presents an experimental investigation of the influence of concrete blocks and mortar’s compressive strength on the flexural bond strength, normal to the bed joints, of concrete structural masonry. Third-point beam tests were performed on concrete prisms, considering two different kinds of concrete blocks (compressive strength of 5.9 and 8.2 MPa) and six different cement-lime mortar compositions (compressive strength around 30, 70, and 120% of the blocks’ net area compressive strength). Units’ absorption and mortar’s initial flow and water retentivity were not varied, but remained within the suitable range for use in structural masonry. For both types of concrete blocks, it was observed an increase on the prism’s flexural bond strength with the increase of the mortars’ compressive strength. A lower mortar’s water-cement ratio led to higher bond strength. When fixing the ratio between mortar’s and concrete block’s compressive strength, it was noticed that the increase on the blocks’ strength contributed to a slight increase on the masonry’s flexural bond strength, except when using high strength mortar, in which the increase was significantly greater.

Mar 1, 2018

By J. M. Toguri

The viscosity of the molten FeO-Fe2O3-Si0z system in the composition range of interest to copper smelting has been investigated using a rotating cylinder technique. The silica content of the slag was varied from 20 to 35 wt percent while the oxygen pressure of the system was varied from 10-7 10-11 atm. The temperature range investigated was from 1200 to 1350°C. It was found that the viscosity of the slag generally decreased with increasing temperature and increasing oxygen pressure. As the silica content was increased, the viscosity was found to increase.

Jan 1, 1976

By Gopalakrishna B. Prabhu, David L. Bourell

"Three mol% Yttria-Stabilized Tetragonal Zirconia (YSTZ) was prepared by a sol-gel synthesis technique using zirconium tetrachloride and hydrated yttrium chloride precursors. After drying and annealing at 823K, the particle size was in the range 10 to 20 nm. The zirconia powder was sintered using a uniaxial hot press at an applied stress of 20 to 40 MPa. One hour, isothermal sintering was performed in air after initial heating at 50K/min. Theoretical density was obtained at densification temperatures above 1498K. After sintering, grain coarsening characteristics were studied using constant heating rate anneals followed by quenching, based on a model for grain coarsening in a linear heating rate cycle. The microstructural change was studied using SEM and TEM and the phases were determined using x-ray diffraction.IntroductionThe ability to sinter nanocrystalline materials to full density several hundred degrees below the normal sintering temperatures is one reason for their current interest. [1-5] Yttria Stabilized Tetragonal Zirconia (YSTZ) of grain size of about 300 nm has exhibited superplasticity, with elongations as large as 800%.[6-7] Fine grain size is critical for superplasticity. Retention of the fine grain size during sintering of nanocrystalline powder is important if a material is to exhibit superplasticity or to exhibit physical or mechanical properties associated with the ultra fine structure. This paper investigates the sintering behavior and the grain coarsening characteristics ofnanocrystalline YSTZ.Techniques for synthesizing nanocrystalline materials have been studied in great detail earlier. [8-12] The techniques used to synthesize nanocrystalline zirconia include alkoxide synthesis [9], the chloride method [11], the peroxide method [13] and the acetone-toluene method. [13] In this paper the method used in the synthesis of zirconia is the chloride technique. With this precipitation technique, either zirconium chloride or oxychloride and a corresponding yttrium salt or even pure yttria are used."

Jan 1, 1994

By T. Thuy Minh Nguyen, Sathish K. Lageshetty, Paul Bernazzani

The addition of nanoparticles to epoxy resins often results in changes in the physical properties of the material particularly when dealing with thin coatings. By characterizing the mechanism of interactions between nanoparticles and polymer chains the material could be tailored for specific applications or properties such as enhanced biodegradability. This study compared the characteristics of common DGEBA resin coated on a silicon substrate and embedded with nanoparticles of TiO2 and Fe2O3. Specifically, we investigated the rate of curing, and the thermal stability of these nanocomposites. Results show changes in the stability for compounds containing TiO2, while Fe2O3 significantly enhanced the curing rates of the nanocomposites while maintaining similar physical properties.

Mar 1, 2017

By Alaina Mallard, Jannette Chorney, David Hutchins, Grant C. Wallace, Jerome P. Downey

Current commercial processes for producing ceramic carbides require temperatures of 1400–2000 °C and often use extensive milling operations to produce a powder product. A process that could reduce the energy requirements of commercial carbide production could allow for these materials to be implemented in a greater number of applications. In this study, tungstate (WO4 2−) and silicate (SiO3 2−) anions were adsorbed onto activated carbon and converted into silicon carbide (SiC) whiskers and a mixture of tungsten and tungsten carbide (W/WC) crystals via carbothermal reduction using inert and reducing gas atmospheres at temperatures much lower than what is required by current commercial processes (950 °C for W/WC/W2C and 1200 °C for SiC). The adsorption process was statistically-optimized via a central composite response surface analysis using DesignExpert 9. Inductive coupled plasma optical emission spectroscopy (ICP-OES) was used to measure, and optimize, adsorption efficiency while the carburization products were characterized using X-ray diffraction and scanning electron microscopy.

Mar 1, 2017

By Teruo Bitoh, Shogo Izumi

"The effect of B203 flux melting on the structure and the soft magnetic properties of the (Feo.1sBo.20Sio.os)96Nb4 bulk metallic glasses prepared by casting has been investigated. The ringshaped bulk specimens were prepared by the B203 flux melting and copper mold casting. It was confirmed that the flux melting promotes the precipitation of the a-Fe(-Si) and Fe2B phases in the central region of the specimens. The ring-shaped bulk specimens show a flat hysteresis curve, indicating a good linear relationship between the magnetic induction and the applied magnetic field. These results show that it is possible to develop a new soft magnetic material that exhibits constant permeability, which is necessary for producing inductors and choke coils.IntroductionSince the success of forming Fe-based bulk metallic glasses (BMGs) with good soft magnetic properties, great attention has been developed to synthesis and properties of the BMGs [l, 2]. The BMGs have high glass-forming ability (GFA) and, therefore, they can be used to prepare bulk amorphous alloys with a thickness of the order of a few millimeters by casting. The soft magnetic properties of Fe-based BMGs are better than those of ordinary amorphous alloys; therefore, these BMGs have wider applications as soft magnetic materials [3-5]. It is often required for soft magnetic materials that the shape of the hysteresis curve is changed according to the demands of applications. For example, materials with ""flat hysteresis curves,"" which means the magnetic flux density (B) and the applied magnetic field (H) show a linear relationship up to rather high magnetic field, are necessary for producing inductors and choke coils. Flat hysteresis curves can be easily achieved by creating an air gap in the magnetic path. However, magnetic flux leakage generated in the air gap inhibits high-density packing of the electronic components. In order to achieve flat hysteresis curves without creating an air gap, Fe-based ordinary amorphous alloys are subjected to crystallization by annealing and transformed into thin surface layers of a-Fe; the crystallization results in the compression of the remained amorphous phase [6]. Another way to achieve flat hysteresis curves is the formation of secondary phase (such as Fe2B) that act as pinning site of magnetic domain wall displacements [7]."

Jan 1, 2013

By Merete Tangstad, Fei Li

This paper studies the quartz and carbon black pellets at elevated temperature with varying temperature and gas atmosphere. High-purity quartz and commercial ultra-pure carbon black was mixed (carbon content wt.15%), and then pelletized into particles of 1-3mm in diameter. The stoichiometric analysis of the pellet during heating is studied in thermogravimetric analysis (TGA) furnace at different temperature in CO and Ar atmosphere. The microstructure, phase changes and element content of sample before/after heating is characterized by X-ray diffraction, scanning electron microscope, X-ray fluorescence and LECO analyzer. The reaction process can be divided into two stages. Higher temperature and argon atmosphere are the positive parameters for SiC formation.

Jan 1, 2016