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By Deborah A. Kopsick

Several minerals were observed and collected in a small gully originating from a weathered coal processing waste (gob) pile in Barton County, Missouri. The rapid alteration of these various minerals after collection suggested that they might represent a dehydration sequence. X-ray diffraction of the dehydrated and rehydrated minerals deposited on the gob pile indicated the presence of the monohydrate and heptahydrate forms of ferrous sulfate, szomolnokite and melanterite respectively. The occurrence of melanterite (FeSO4.7H2O), was limited to isolated areas of ponded water while szomolnokite (FeSO4.H2O), was associated with the outwash areas of the pile. Laboratory dehydration of melanterite collected at the gob pile revealed the formation of rozenite (FeSO4.4H2O), an intermediate form of ferrous sulfate. Szomolnokite was shown to be the stable form of these ferrous sulfates during these experiments while melanterite and rozenite were shown to alter readily. Chemical analysis of szomolnokite revealed enrichment in Fe, Mg, Zn, Cd, Cu and Mn relative to the chemical composition of the gob ad the lechate generated from the gob wastes. Although this gob pile had been weathering for more than 35 years, significant concentrations of trace metals were still being released from the pile through the generation of leachate and the formation of various soluble metal enriched ferrous sulfate minerals.

Jan 1, 1982

By Xueming Lv, Xuewei Lv, Jie Qiu, Lunwei Wang

Non-isothermal multiple scanning rate analysis method was used to analyse the solid-state reduction of nickel laterite by carbon. According to the TG curves, the activation energies were calculated and the most probable mechanism functions were determined by the Malek method. The results show that the process can be divided into three stages according to the reaction degree (a): 0–40%, 40–70%, 70–100%, respectively. In the stage of 0 a 0.40, the most probable mechanism function fits the chemical reaction order function. In the stage of 0.40 a 0.70 and 0.70 a 1.0, the process may not be exactly described by one mechanism function.

Mar 1, 2017

By Gordon Lewis

A complex mixture of hydrated reaction products is obtained from hydrothermally treated refractory cements and castable concretes. TGA can be used both to identify the product phases in the mixture and to determine a quantitative relationship among the phases. When reacted mixtures contain compounds that decompose simultaneously, or nearly so, additional assumptions must be introduced in order to develop a quantitative phase analysis. It is the purpose of this paper to examine some of these assumptions and to demonstrate their application, particularly to refractory cement systems.

Jan 1, 1982

By Dong Hoon Han

The sulfation rates of magnesium oxide and calcium oxide (molar ratio 7:3) contained in calcined CMA ( calcium magnesium acetate) by SO2 were measured. The experiments were carried out in the temperature range 700 to 1100 °C and under the SO2 concentrations of 0.3 to I mol % (5 % 02). In the low-temperature range below 830 °C the reaction produced CaSO4.3MgSO4 and unreacted MgO, but no MgSO4 phase. The formation of CaSO4.3MgSO4 phase has a significant implication in that it allows the utilization of MgO for SO2 removal whereas the sulfation of MgO from conventional sources is so slow that it is of no practical interest. Thus, the calcined CMA can remove SO2 at lower temperatures than conventional SO2 absorbents and at a greater capacity. Above 950 °C only CaO reacts with SO2, but at a much greater rate than the calcined Ca(OH)2, which is one of the most reactive SO2 absorbents.

Jan 1, 1998

By Nobuaki Sato

The electrical conductivity, k, of pure and sodium doped sulfur melts was measured with and without ultrasonic waves at temperatures ranging from 140 to 340'C by the two probe method using an ultra high resistance meter. The k value of the pure sulfur melt with irradiation jumped at around 170°C by an order of 102 after which it mouutuniocally increased from 10-5 to10-4 A' 1 cm-1 with an increase of the temperature. The addition of the sodium metal to the sulfur melt was found to cause a larger jumping in the K value. The k value increased with the increase of Na proportion in the melt. For a 10mol% Na doped sulfur melt it was as high as max ~30 A 1cm -1 above 180 C under the irradiation of of ultrasconics.

Jan 1, 2003

By Dachun Liu, Xuepeng Li

Smelting-acid leaching process is a way to treat high-content arsenic containing copper dust. However, smelting makes a low recovery of valuable metals and acid-leaching produces large amounts of arsenic-iron slag. Arsenic sulphuration volatilization at low temperature was studied, followed by pressure leaching to selectively recover Cu, Zn, and In from copper smelting dust while minimizing arsenic contamination.

Mar 1, 2017

By Rollie E. Dutton, David A. Stubbs

"A sensor has been developed and tested that is capable of emitting and receiving ultrasonic energy at temperatures exceeding 900°C and pressures above 150 MPa. The sensor works with standard ultrasonic pulser-receivers and has demonstrated the capability of measuring workpiece deformation during hot isostatic pressing (HIP). Details of the sensor design, performance, and coupling of the ultrasound to the workpiece are described. Ultrasonic data acquired by the sensor, in situ, during HIP runs and at elevated temperatures in air are presented.INTRODUCTIONHigh temperature structural components, such as structural castings for jet engines, nickel-base superalloy turbine blades, and ceramic and metal matrix composites made from powders are often densified by hot isostatic pressing (HIP). For powder consolidification, the HIP process involves sealing the powder (and reinforcing fibers for composites) within an evacuated ""Can"" made of a material that softens at high temperatures. A hydrostatic pressure is then applied by pressurizing the inside of the HIP vessel with argon gas (up to 140 MPa). The hydrostatic pressure densities the powder through the elimination of the porosity between the powder particles.This paper presents details of the development and preliminary testing of an ultrasonic displacement sensor that can be used to monitor materials processing, in situ, at temperatures and pressures significantly higher than current ultrasonic displacement sensors. The target processing environment for this sensor is that typically found in a hot isostatic pressure (HIP) vessel, i.e., temperatures exceeding 1000°C and pressures above 138 MP a."

Jan 1, 1997

By Guo Chen, Jin Chen, Jinhui Peng

In this paper, solving common problem of electrostatic precipitator (ESP), which was frequently ruptured of the cathode insulation in the production process were studied. The microwave heating airflow technology was introduced, which takes full advantage of its unique properties, solves the output problem of the high temperature air, achieves purpose of energy conservation, important economic significance and environmental significance. The mathematical models and designing of microwave high-temperature hot air system was calculated. The common forms of heat exchangers and comparative analysis were also introduced. The conditions found to be at the temperature of 240 °C. Under optimum conditions, the microwave heating power was 1482 W. Based on the mention results, this microwave heating method can be applied effectively and efficiently way for the production process of electrostatic precipitator.

Jan 1, 2015

By Bhavani Kedika, Venkatagiri Noole, Krishna Thotla, Krishna Reddy Chepyala

Cationic lipids are attractive candidates for transgene delivery and expression and are safer alternatives to viral delivery vehicles. Here, we report the design, synthesis, characterization and transgene expression efficacies of a series of chrysin derived cationic lipids. A series of ten lipids of chrysin was synthesized by treating the 7-hydroxy group with dibromoalkane and further substitution of the bromo derivative with alkyl amines. The synthesized lipids were characterized spectroscopically. Parallel screening of the synthesized lipids for in vitro plasmid delivery expressing luciferase led to identification of several leads that demonstrated higher transgene expression when compared to the standard. Transgene expression efficacy was dependent on the chain length of the lipid. The influence of the various physicochemical properties on transgene expression efficacies was investigated. This study indicates that lipids derived from chrysin results in high levels of transgene expression and may be attractive for gene therapy applications.

Mar 1, 2017

By Mingsheng He, Yunhui Tang

The structure and granularity of biological origin aragonite from abalone shell during wet grinding in a ball mill were studied with X-ray diffractometer, with morphology studied by scanning electron microscope (SEM). It is shown from the results that the particle sizes of aragonite decreased with grinding time, so did the X-ray diffraction (XRD) peak intensities, while the full widths at half maximum increased. A calcite XRD peak with low intensity and great width was observed in nearly all the samples with various grinding time, whereas the intensity of the peak increased obviously after grinding time 300 min. It is shown from the SEM results that the size of aragonite dropped with grinding time until it reached 20 nm and then kept constant, while that of calcite dropped first and then rose at the minimum about 10 nm until to the constant size as in aragonite. It was observed that the mineral content obtained from XRD show an obviously change that the calcite increases while aragonite decreases, which indicated the occurring of a polymorphic transformation of aragonite into calcite.

Mar 1, 2017

By Arvind Thekdi, Cynthia Belt2

"Waste heat from industrial operations in metals industry represents 20% to 50% of the total energy used in most manufacturing plants. Reduction and recovery of waste heat offers the most attractive and cost effective method of reducing energy intensity for an industrial plant to meet corporate energy saving goals. It is possible to reduce or recover 30% to 60% of the available waste heat by using conventional and readily available technologies. Projects to reduce or recovery waste heat may offer less than 3 years payback to as short as a few months. This paper presents information on most commonly used methods for waste heat reduction and recovery in the metals industry operations. It describes the methods and use of analysis tools that would allow a user to estimate energy savings, CO2 or GHG reduction potential, and economic benefit and includes appropriate case histories.Waste Heat SourcesSources of waste heat abound with the metals industry. While the overall quantity of energy is high, the sources are distributed throughout a plant. The largest source within the metals industry is within furnace exhaust / flue gases. This includes the high temperature gases from burners in process heating such melting, calcining, and sintering operations. It also includes lower temperature gases from heat treat, dryers, and heaters. Lower temperatures are also found after post processed hot gases. This could include heat left after heat exchangers, regenerative systems, thermal oxidizers, and emission control systems. Other hot gases include air used in direct and indirect cooling.While waste heat in form of exhaust gases is readily recognized, waste heat can also be found within liquids and solids. Waste heat within liquids includes things such as cooling water, heated wash water, and blow down water. Solids can be hot product at discharge after processing or reactions are complete. Indeed, not only is energy wasted in the hot metal that slowly air-cools, but additional energy may be used in providing air or water-cooling to increase the speed of cooling. Other waste heat sources are not as apparent and include things like hot surfaces, steam leaks, boiler blow down water, etc. Table 1 and Figure 1 show several major sources along with the temperature range and characteristics of the source."

Jan 1, 2011

By Ryosuke Matsuoka

Keywords: Tantalum capacitor, Scrap, Recovery, Titanium, Chlorination A recycling process for tantalum from capacitor scraps using an oxidation process followed by mechanical separation and chemical treatment was investigated. This study demonstrates that sintered tantalum electrodes inside the capacitor scraps can be mechanically collected after the oxidation of the scraps in air, and high-purity tantalum oxide powder (Ta2O5) was efficiently recovered after chemical treatment. By reducing the Ta2O5 obtained through magnesiothermic reduction, tantalum powder with 99 mass-% purity was obtained. Using the chlorination for tantalum recovery was also investigated, and the tantalum or tantalum compounds were reacted with chloride wastes such as FeClx. It was found that tantalum was effectively separated and purified when tantalum powder is reacted with FeClx at 1100 K under an argon atmosphere. This recycling process utilizing chloride scrap has now been extended to other reactive metals such as titanium.

Jan 1, 2004

By Jose Antonio Silva Souza, Emanuel Negrao Macedo, Iara Ferreira Santos, Otacilio Dias, Luis C. A. Venancio

"The Bayer process alumina production generates 0.7 to 2.0 ton of bauxite residue (BR) and an average of 1.0 ton of C02 per ton of alumina produced. The direct reaction of exhaust gases to reduce the alkalinity of the BR may allow a triple gain: improve the storage conditions, open a range of new applications for BR and sequester from 16 to 102 kg of C02 per ton of alumina. This paper shows the measurement of C02 captured during a pilot scale reaction of a suspension of BR in water with flue gas, produced from direct oil burning. Three different types of reactors were used: one spray tower and two packed columns. The inlet and exhaust gases were analyzed using electrochemical and non dispersive infrared sensors. The pH of the suspension was monitored during and after the reaction to evaluate the buffer effect.IntroductionAlumina is mainly produced from refining bauxite using the Bayer process. This process consists of extracting the aluminum oxide through its dissolution in caustic soda and the separation of insoluble residues. The remaining bauxite residue (BR) although not particularly toxic, poses risks to the environment due to the large volume and its reactivity. According to the latest technology it is stacked on sealed deposits specially constructed. To date the vast majority of the bauxite residue that has been produced was stored and were not incorporated into any existing production processes to significant amount with exception to some extent of the sintering process residue at Russia and China [l]. On the other hand, a strategic goal was set in 2010 by the Bauxite and Alumina Committee of the International Aluminium Institute (formed by the majority of the industries) to reuse 20% of BR in 2025 [2]. China has established the same objective for 2015[1].This paper is a sequel of two others presented at TMS 2010/2012 [3-4] and describes:• A pilot plant assembled for testing the carbonation process of BR with gaseous effluents similar of the refining process.• The methodology used to measure the amount of C02 captured during the carbonation process.• The results of the carbonation process, the C02 capture and the buffering effect of the pH.This process is studied in order to consume minimal power and use the effluent as efficiently as possible in different reactors from low cost to ultra high performance. The process is designed for minimizing the power consumption and equipment investment."

Jan 1, 2013

By Volovik A. V. Ivtan, Shelkov E. M. Ivtah

"One of the most power consumption Industrial process is production of Al from bauxites (about 45000KWt.hour electrical energy for production of 1 ton. of technical Al). This process is based at the low efficiency and productivity electrolysis technology.Last years IVTAN investigations give to .us information about possibility to use of high temperature shaft- furnaces for efficiency production of alumina (AL2O3 ) technical. aluminium and some all.oys on the base of the high temperature carbon- thermal reduction process. At this case power consumption for production of unit of last, product will be less at the 3-4 times.The carbon-thermal method is allow produce alumina (Al203 ), technical Al and its alloys not only from deficient bauxites, but practically inexhaustible reserve of other types of Al-contain row materials (cianite, sillimonite and so on/The thermal-chemical economical analises of fulfilled at the IVTAN, production of alumina. Base on facts of production and technical technology are especially for ones arguments at the high temperature shaft-furnace technical Al and its alloysIn the last decades of the 20-th century, the discharge into atmosphere of high temperature and. combustion gases places . problems before humanity more and more sharply and becomes of great importance task.But at the same time, as production of material values increases, intensity of pollution of environment increases all time. And the value of new processes and. technologies of material production, aimed at reducing the expenditure of power and pollution of· the environment, also increases."

Jan 1, 2000

By J. Chen Kuriyama

One method to store hydrogen effectively involves the use of metal complexes such as the alkali-element aluminum hydrides. The hydriding/dehydriding properties of these materials depend on how to prepare them with different structures and microstructures. The present work focused on a high-energy ball milling technique to produce Ti-doped lithium tetrahydridoaluminate (LiA1H4) and lithium hexahydroalanate (Li3AIH6) powders with nanocrystallites. The phase structures and dehydriding/rehydriding characteristics were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller measurement, thermogravimetry, and differential scanning calorimetry. The mechanism of dehydrogenation and rehydrogenation was also examined by means of X-ray photoelectron spectroscopy (XPS). The results on the relation between the reversible hydrogen storage and catalysis function of the Ti-doped complex hydride indicate that both the homogenous distribution of Ti+AI nanoclusters and the Ti¬catalyst with Ti e> Ti3+ (Ti0/Ti2+/Ti3+) defect sites play important roles in optimizing the reversible hydrogen storage.

Jan 1, 2002

By Jinliang Zhang, Jian Pan, Deqing Zhu

"Limestone and burnt magnesite were added to vary MgO content and basicity (CaO/SiO2 ratio) of pellets for investigating their influences on the properties of specularite pellets. At fixed MgO content, the addition of limestone does not affect on the properties of green balls significantly. The addition of burnt magnesite has obvious influence on the quality of green balls, especially on the thermal shock temperature. Without burnt magnesite, the thermal shock temperatures are about 400°C, and, the thermal shock temperature increases to 600~630°C by adding burnt magnesite. For preheated pellets, when the burnt magnesite is added, the compressive strength will be decreased. For roasted pellets without burnt magnesite, the calcium additives can form binding phase of calcium-ferrite, and suitable liquid phase will improve recrystallization of hematite, but excessive liquid will destroy the structure of pellets, so the compressive strength of pellet increases firstly and then decreases. When adding burnt magnesite, the compressive strength will increase as the basicity increases. When the basicity is more than 0.2, the compressive strength of the pellets various MgO content and basicity is above 2500N/pellet and then MgO-bearing fluxes can be added to prepare pellets with good high temperature properties.IntroductionWith the rapid development of the steel industry in China, oxidized pellets, possessing good mechanical and metallurgical properties, are becoming indispensable burdens for blast furnace ironmaking [1-3]. However, this has resulted in the shortage of domestic iron concentrates, so many Chinese steel plants begin to use imported hematite concentrate to prepare pellets. Compared with magnetite pellets, the hematite pellets require high roasting temperature and narrow roasting temperature range (1300–1350°C) and possess low compressive strength [4,5].1"

Jan 1, 2012

By William A. Hockings

Methods for the measurement of liberation of finely ground iron ores are described. The general method consists of separating a sample of the ground ore into a number of size fractions, followed by measuring the liberation of each fraction. The size separation has been done using electro-formed screens of 20-, 10-and 5-micrometer apertures, and also by air elutriation. Liberation (i.e., the distribution of compositions of individual particles) has been measured by optical microscopy. A computer pro-gram was used to adjust the raw count data so that it agrees with the chemical analyses of the size fractions. Various ways of presenting the results are given, and Some applications of the results to flotation processing are discussed.

Jan 1, 1981

By Lu-ming Zhao, Li Zhao, Yu Wang

Mould flux is a vital functional material which is based on silicate including flux and framework material. The effects of magnetic field intensity and frequency on viscosity of mould flux were tested by rotational viscosity tester and a measurement device for electromagnetic characteristics of mould flux viscosity under high temperature conditions. The results show that: with the magnetic field intensity rising (0 –30 mT), the viscosity of mould flux increases by 1.3–1.8 P. With the frequency rising (6–12 Hz), the viscosity of mould flux is increased by 1.2–1.4 P. When the binary basicity is 1.08, the viscous flow activation energy increases with the increase of the magnetic field intensity and frequency. It can be the main reason for the increase of mould flux viscosity that the electromagnetic forces disrupt the ordered structure of mould flux and make the ion migration rate increase.

Mar 1, 2018

By Shenghui Guo, Jianbo Lan, Hongying Xia, Jinhui Peng, Lihua Zhang, Libo Zhang

Spent Hawaii nut shell was converted into a high-quality activated carbon via steam physical activation. Analysis of the experiment including activation temperature, activation duration, steam flow rate on the adsorption capability and yield of activated carbon were identified. Response surface methodology showed that the activation temperature was identified as 866 , an activation duration of 36 min and a steam flow rate of 2.5mL/min with the methylene blue adsorption number of 195 mg/g and yield of 77.75%. The key parameters that characterize quality of the activated carbon such as the BET surface area, total pore volume and average pore diameter were estimated to be 1125m2 /g, 0.94mL/g and 5.21 nm, respectively. Additionally, by the SEM analyses of char and activated carbon, the surface of activated carbon has large number of pores of irregular and heterogeneous morphology.

Jan 1, 2016

By D. A. Meyn, R. L. Holtz, C. S. Pande, M. A. Imam, D. J. Singh

"Various theoretical and experimental techniques used to search and develop new metal hydride systems suitable for hydrogen storage are described. The main theoretical technique under study makes the use of electronic structure of the candidate materials. Microstructural characterization techniques like transmission electron microscopy are being used to study the hydride formation. Novel processing techniques for material preparation such as those needed to produce thin films or amorphous phases are also being utilized. The techniques are illustrated with results from Pd, FeTi and Mg2Ni systems.IntroductionOf the four methods of hydrogen storage, compressed gas, cryogenic liquid, metal hydrides, and gas-solid adsorption, the metal hydride storage method is more attractive from the point of view of high volumetric density and safety. Compressed gas storage has disadvantages of extreme pressure, weight, and volume requirements, whereas storage of hydrogen as cryogenic liquid is unattractive due to the requirements of extremely low temperatures and high consumption of primary energy. Moreover, the number hydrogen atoms present in a volume of 10- 22 Cm3 (nH) in liquid hydrogen state (- 20K) is 4.2 whereas number of hydrogen atoms that can be accommodated in a free volume of 10-22 cm3 of various hydrides are as follows: LiH--5.9, TiH2--9.2, ZrH2--9.2, VH2--l0.2. High hydrogen concentration is usually associated with a large H/Metal atomic ratio but is also a function of structure."

Jan 1, 1994