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By W. H. Pomroy

This report describes research by the U.S. Bureau of Mines to design and in-mine test a rapid response pneumatic fire detection system for multilevel metal mines. The relative merits of pneumatic detection are discussed in the context of typical multilevel mine layouts and environments. The Bureau's prototype system is described, with emphasis on design features that counter commonly experienced and/or perceived operating problems with pneumatic detection systems. Finally, the results of a 3-year in-mine performance evaluation of the prototype system are discussed.

Jan 1, 1990

By Keith G. Wallace

Coal mine ventilation systems are often subject to high leakage rates. As a result, changes in airflow resistance will strongly affect the efficiency with which air is delivered to the working place. One major source of airflow resistance is the line brattice used to direct air from the last open crosscut to the working face. Because it is a great distance from the fan, the resistance of the line brattice can result in more overall leakage than an equivalent resistance closer to the fan. Substituting auxiliary fans for brattice eliminates this source of resistance, with improvements in system efficiency and cost. Also, in some mines, the leakage that leads to spontaneous combustion can be reduced. The benefits obtained by several different brattice and fan substitutions have been studied by Mine Ventilation Services, Inc., Lafayette, CA, under contract to the U.S. Bureau of Mines. Changes in main fan duty were compared with additional costs associated with auxiliary fans. Results indicate that in some circumstances, considerable leakage reductions and cost savings are possible.

Jan 1, 1990

By J. M. Goris

The U.S. Bureau of Mines is conducting research on cable bolt ground supports to assess their material and support properties, to provide design criteria for using cable bolt supports as roof control systems under various types of underground mining conditions, and to provide a mathematical model of cable bolt support systems. Part 1 describes laboratory studies of the support properties of cable bolts made of conventional steel cables and provides recommendations on such topics as the use of thick grouts, selection of breather tubes, and reduction of water bleeding in cement-based grouts. The studies evaluated both single and double cables; effects of different embedment lengths, water-cement ratios, and grout curing temperatures on support strength; effects of use or nonuse of breather tubes; pumpability and water-bleeding properties of grouts; and the strength properties of sand-cement grouts. Part 2 will cover the strength characteristics of birdcage cable bolt supports, epoxy-coated cables, and cables with steel buttons attached.

Jan 1, 1990

By M. R. Peterson

The U.S. Bureau of Mines investigated column flotation for recovery of a high-grade fluorite (CaF2) concentrate and byproduct concentrates from the Fish Creek fluorite deposit in Eureka County, NY. The recovery scheme consisted of (1) grinding the ore to minus 48 mesh, (2) fluorite rougher and cleaner flotation, (3) desliming the rougher fluorite flotation tailings at 20 Jjm, (4) mica flotation, and (5) silicate rougher flotation. Acid-grade fluorspar, mica, free silica (Si02) sand, and low-grade beryl (Be3Al2S~018) concentrate were produced in a 100 lb/h continuous column flotation unit (CCFU). The highest results achieved were %.6-pct CaF2 recovery in a fIrst cleaner concentrate containing 99.7 pct CaF2. Beryl recovery was as high as 92 pct at a grade of 5.3 pct BeO. The silica sand, which assayed 98 pct Si02, was recovered as the rougher beryl flotation tailings. Collector reagent consumption was reduced 45 pct for fluorite and 58 pet for silicate flotation in comparison with bench-scale conventional flotation. All products were signillcantly improved in both grade and recovery over conventional flotation results, and the recovery scheme was simplifIed by removal of several stages of flotation in the fluorite and silicate flotation steps.

Jan 1, 1990

By S. P. Sandoval

Several researchers have shown that the surface of chalcopyrite becomes hydrophobic under oxidizing conditions. Because dissolution of copper from chalcopyrite in dump leaching occurs under oxidizing conditions, the U.S. Bureau of Mines studied the effect of surfactants on chalcopyrite leaching under dump chemical conditions. Surfactants were selected for study because they can lower interfacial tension. The tests were conducted in shaking water baths using 250-mL Erlenmeyer flasks in statistical experimental design formats. The addition of nonionic surfactants increased copper extraction in the fernc sulfate leaching of chalcopyrite when sufficient Fe3+ was present. A positive interaction between Fe3l+ concentration and surfactant concentration was demonstrated. Copper concentration in the leachhing solutions was increased by as much as 100 pct at 25° and 50° C by adding nonionic surfactants. ionic surfactants decreased leaching. The structure of the nonionic surfactants and their hydrophile-lipophile balance (HLB) influenced surfactant performance. The branched hydrophile of an ethoxypolyol was beneficial to surfactant performance. The ethoxypolyol was the superior surfactant at 25° C, but became unstable at 50° C. Four surfactants, an ethoxyalchohol and three block copolymers, performed best at 50° C.

Jan 1, 1990

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990

By J. J. Lukasko

The U.S. Bureau of Mines developed an alternative electrochemical process for the production of calcium metal. The current industrial practice is costly, complex, and inefficient. The Bureau method involved electrowinning of a calcium-tin alloy followed by electrorefining to produce calcium metal. In the electrowinning cell, CaCI2 was fed to a KCI2-CaCI2 electrolyte. The calcium was electrowon at 6500 C into the pure molten tin cathode until the cathode contained 7.5 wt pct Ca. Current efficiency for electrowinning averaged over 90 pct. The resulting calcium-tin alloy served as the anode for the electrorefming cell, which employed a [CaC~-CaF2] fused salt as the electrolyte. Calcium metal was electrorefmed at 8500 C with a current efficiency of 85 pct based on calcium metal recovered. The calcium metal analyzed 99.2 pct, which is purer than commercially produced calcium.

Jan 1, 1990

By Donna L. Anderson

This U.S. Bureau of Mines report discusses the status of a laser-based guidance system to provide position and heading feedback and closed-loop control of tramming maneuvers for a continuous mining machine. The system has been developed and tested at the Bureau, and is now being prepared for underground experiments. The system hardware includes laser scanners, a sensor communication network, and host computer hardware. The system software includes a position and heading computation module and a tram control module. The description of the software includes discussions of laser data acquisition, error compensation methods, position and heading determination, safety checking for continuous miner tramming, and closed-loop tram control. The accuracy of the laser scanner's data, the reliability of the lasers in a dusty environment, and the system's accuracy on tracking the position and heading of the continuous mining machine are shown in the results of experiments performed at the Bureau. Conclusions are stated based on these experimental results, and further work to improve the system performance and prepare for underground testing is discussed.

Jan 1, 1990

By Margaret M. Ragin

In a cooperative effort between the U.S. Bureau of Mines and the Florida Institute of Phosphate Research, with input from the phosphate industry, the conversion of phosphogypsum to sulfur has been investigated. The first step in the conversion scheme involves reduction of phosphogypsum to calcium sulfide. Effects of temperature, catalyst, reaction time, and type of reductant (carbon monoxide and coal) are discussed. It was determined that phosphogypsum could be reduced to calcium sulfide at 850° to 1,000° C using either coal or carbon monoxide as the reductant. The required temperature was lowered to 750° C using ferric oxide or magnetite as a catalyst for the reduction reaction. Results indicate that as the volatiles content of the coal is increased, reaction temperature may be decreased to obtain a given conversion, or if the reaction temperature is maintained constant, the conversion can be increased. Best results were 95- to 100-pct conversion using a high-volatile coal at 800° to 850° C. Addition of a catalyst increased calcium sulfide yield when low- or medium-volatile coals were used as reductants, but had little effect when high-volatile coals were used.

Jan 1, 1990

By Christopher C. Jobes

Computer-aided control of a mining machine requires a guidance system to aid remote positioning of the machine by determining its position and heading. The mechanical position and heading system (MPHS) developed by the U.S. Bureau of Mines provides such navigation information during face maneuvers. This report describes the required theory, which yielded a reliable algorithm for calculating machine position and heading, and implementation of this theory in hardware and software design, which made surface testing of the MPHS possible. Analysis of the errors and test results showed that the MPHS provides reliable results and can, therefore, provide useful guidance information for face navigation.

Jan 1, 2010

By Stephen C. Tadolini

The U.S. Bureau of Mines conducted a laboratory investigation designed to evaluate the stress and deformation characteristics of fully grouted roof bolts subjected to various magnitudes of end loadings. The experiment and subsequent analysis were completed, utilizing axial deformation data obtained -ultrasonically from forty-one 4-ft, grade 40 roof bolts, with a total of 132 measurement locations along the lengths of the bolts. The ultrasonic measurement instrumentation used in this investigation allowed for elongation measurements without requiring extensive bolt modifications. The results indicate that approximately 39 pct o{ the applied end load dissipated within the first 3.4 in of the bolts. However, only 3 pct of the applied load was realized beyond 28 in of the grout column. Data are presented individually for every 6-in increment of bolt length, and analysis was performed using statistical, nonlinear equations developed for 5,000 and 8,000 lb loading conditions.

Jan 1, 1990

By Paul W. Jeran

Subsidence was monitored by the U.S. Bureau of Mines over the ends of longwall panels operating in the Pittsburgh, Kittanning, and No. 2 Gas Coalbeds of the northern Appalachian Coal Basin. The final subsidence over the finishing ends of three panels in the Pittsburgh Coalbed are compared with the subsidence measured over the rib at these panels. The characteristics of subsidence are different. At Mine A, data over the start of a longwall panel shows similar characteristics to the subsidence measured over the rib. Subsidence over the fmishing ends of panels in the Kittanning and No.2 Gas Coalbeds are also different from the subsidence over the rib. The use of a subsidence prediction model based on data gathered over the rib of a panel will not yield accurate results if it is applied to the finishing end of a longwall panel. Acceptable results may be obtained along the centerline over the starting end of a panel.

Jan 1, 1991

By B. R. Eichbaum

To develop technology to assure an ample supply of zinc and to reduce environmental pollution, the U.S. Bureau of Mines investigated alternatives to the roast-leach process for treating complex sulfide concentrates. Previous studies proved that low-grade zinc sulfide (ZnS) concentrates could be leached using chlorine-oxygen to produce zinc chloride (ZnCI2). The process involves high energy requirements for evaporating the pregnant solution to produce anhydrous ZnCl2 needed for electrolytic cell feed. An efficient hydrometallurgical process would facilitate treatment of lower grade ores than can be used in conventional processing and would render roasting unnecessary. An alternative method was devised for recovering ZnCl2 from solution. Zinc diammine chloride [Zn(NH3)2CI2] was precipitated from solution by adding ammonium chloride (NH4CI) and sparging with ammonia (NH3) to a pH of 6 to 7.5. The spent solution was treated with calcium hydroxide [Ca(OH)21 at 60° to 80° C for 1 to 4 h to remove remaining zinc and NH3. The Zn(NH3)2CI2 was heated to 300° to 400° C to remove NH3 and produce anhydrous ZnCI2. A possible flowsheet was devised and is included.

Jan 1, 1991

By Ann G. Kim

The U.S. Bureau of Mines mine fIre diagnostic methodology to locate and monitor fIres in abandoned mines and waste banks is based on the controlled sampling of the mine atmosphere to determine changes in the concentration of hydrocarbons desorbed from heated coal. To provide background data for this methodology, a laboratory study was conducted in which samples of coal and coal waste were heated under controlled conditions. Gas samples from the combustion furnace were analyzed for standard gases CO2 and CO and for the C1 to Cs hydrocarbons. In all tests, the concentration of desorbed hydrocarbons increased during heating and decreased during cooling. A dimensionless hydrocarbon ratio, Rl, was developed as the signature for heated coal. For bituminous coals, the value of Rl increases during heating of coal samples and decreases during cooling of the same samples. Generally, Rl values of 100 or more indicate coal sample temperatures of at least 100° C. The emission of higher molecular weight hydrocarbons from anthracite samples was very low, resulting in relatively low Rl values at all temperatures. Data from fIeld projects confIrmed these results.

Jan 1, 1991

By D. J. MacDonald

As part of a U.S. Bureau of Mines program seeking improvements to the Bayer process, a typical Jamaican bauxite was heated at temperatures up to 500° C in hydrogen, and its leachability under Bayer process conditions was measured and properties of its leached residue were observed. The objectives were to find ways to decrease the amount of organic carbon in bauxite or in leach liquor derived from it without impairing its leachability, and to improve the leached residue's filterability. Techniques employed included heating bauxite under pressure in an autoclave with hydrogen, and in flowing hydrogen at ambient pressure in a tube furnace. Leaching tests were done with a 600-mL stirred reactor. In some of the leaching tests, ferrous sulfate (FeS04) was introduced before leaching to produce a partially magnetic product. Results showed that exposure to hydrogen at temperatures from 160° to 360° C progressively diminished the bauxite's content of organic carbon and decreased the ratio of organic carbon to aluminum in leach liquor, an improvement that would allow a process using hydrogen-treated bauxite to be operated at a smaller recycle ratio, thereby consuming less energy and allowing greater throughput for a plant of given capacity. The bauxite's leachability was not impaired by high-temperature pretreatments, except at temperatures higher than 280° C. Pretreatments in hydrogen produced black, partially reduced bauxite which upon leaching gave a residue that was attracted to a magnetic field and was amenable to separation from green liquor by a magnetic filtration method.

Jan 1, 2010

By J. K. Whyatt

Researchers at the U.S. Bureau of Mines have been exploring recent advances in the use of strain-softening constitutive laws that approximate shear fracturing. The purpose of these tests is to investigate shear-fracture-related rock bursts in hard-rock mines. The capabilities and remaining problems in the use of strain-softening laws in finite-element, distinct-element, and finite-difference methods are reviewed. Performance of the finite-difference implementation of strain softening is compared to classic experimental results and observations of rock mass behavior in the Coeur d'Alene Mining District of northern Idaho. The results show promise for developing methods to identify the general location and orientation of shear fractures and their sequence of occurrence, but such methods cannot be relied upon to quantify post-fracture loads or displacements accurately. Uncertainty over the amount of energy consumed by failing rock and the dependency of energy consumption on model mesh definition prevent direct application of the results to analyses of rock bursts.

Jan 1, 2010

By D. A. Rice

As part of its mission, the U.S. Bureau of Mines continues to develop technologies that will enable cost-effective compliance with environmental requirements. To this end, investigations to improve the kinetics of chalcopyrite dissolution by simultaneous grinding-leaching in ferric sulfate solution were conducted using the Bureau-designed turbo mill. The development of such a hydrometallurgical process would provide a nonpolluting alternative to conventional smelter technology. The effects of mill rotational speed and volume percent solids on the leaching time and energy required for copper extraction from chalcopyrite were evaluated. The results of this laboratory study have shown that the simultaneous grinding-leaching of chalcopyrite concentrate using the turbomill is technically feasible with essentially 100 pet extraction of copper being possible at 90° C. An optimal energy consumption of 1,153 kW?h/st of copper leached was found in batch testing with the mill operating at 400 rpm with a slurry containing 35 vol pet chalcopyrite. This energy consumption, while higher than other proposed leaching processes (about 600 kW?h/st), is of the same order of magnitude. Further refinement of the energy requirements would require additional testing using a continuous circuit. Leaching times of less than 1 h, for 80 pct copper extraction, are achievable using the turbomill grind-leach process.

Jan 1, 2010

By Douglas A. Crum

The Taylor's friction circle method for slope stability analysis can be extended to incorporate multiple circles defining the slip surface in a failure mechanism so that it is a workable method for bearing capacity calculations of foundations and rotational failures of retaining walls and similar structures. The U.S. Bureau of Mines has further extended the multiple-circle method to include friction in the material strength and to utilize computational schemes such that this method can be programmed with optimization capabilities rather than being used as a graphical or semigraphical method. Some examples are given that demonstrate ultimate bearing capacity calculations of embedded foundations with eccentric loads and nearby slopes.

Jan 1, 2010

By D. L. Hollis

An arc plasma reactor, constructed and used for studying extractive metallurgical processing, was adapted by the U.S. Bureau of Mines to separate gases of different masses by using the high rate of plasma rotation. With argon and helium as input gases, peripheral reactor outlet ports had a measured average increase of about 10 pet in argon concentration relative to helium with the plasma on compared with plasma off for the same gas inlet concentrations in both cases. Approximately the same average increase in argon concentration occurred from the peripheral outlet port compared with a central outlet probe with the plasma on. There was no difference with the plasma off.

Jan 1, 2010

By V. R. Shea-Albin

This U.S. Bureau of Mines report discusses elastic wave velocity and attenuation behavior as an indicator for changes in load and structural integrity of coal samples. Measuring changes in compressional (P)-wave and shear (S)-wave attenuation and velocity under uniaxial and triaxial compression tests revealed their effectiveness for distinguishing changes in applied load and structural failure of samples. The velocity and attenuation values were used in further calculations such as ratios of P-wave to S-wave values, dynamic elastic constants, normalized velocities, and attenuation coefficients to reveal trends for loading and failure. The behavior of both P-wave and S-wave attenuation and velocity together define distinct and consistent phases of load change and failure for uniaxial and triaxial tests. The S-wave velocity and attenuation illustrate changing axial load and initial development of microfractures within the sample preceding structural failure more clearly than those of the P-wave. The attenuation and velocity ratios and dynamic elastic constants (except the bulk modulus) respond to closure of small preexisting fractures within the coal sample with initial loading to failure of coal samples. The attenuation coefficients and normalized velocities reveal trends similar to those shown by velocity and attenuation.

Jan 1, 2010