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By Ph. Cauwe

This paper presents the experience that NESA and MECHIM have gained about recovery of non ferrous and precious metals from complex sulfide materials. Processed materials are from natural deposits or metallurgical by-products or residues. Roasting of these materials is closely related to the pyro or hydrometallurgical processes used downstream of the roasting. Conditions of a first step of roasting the SELECTIVE ROASTING, are analyzed and explained. The roasted products so obtained are characterised by an extended elimination of volatile sulfides (AS, Bi, Sb, Sn, Pb, Hg, ?? ) and are readily available for the pyrometallurgical recovery of non ferrous and precious metals. After the SELECTIVE ROASTING, thanks to. the high porosity obtained in the "selective calcine", the SULFATE ROASTING is per-formed in excellent conditions. Hydrometallurgical tests performed for the final calcine show a high recovery of non ferrous and precious? metals and require only simple and well known processes. Many experimental and commercial data are given.

Jan 1, 1983

By E. O. Jacobs

A coupled solid and rock fracture mechanics model is used to analyze the blast driven fracture propagation phase, predict propagation rates, and directly measure shockwave and particle velocity. The study incorporates quasi-static pre-stress conditions for different depths below the surface. The scaled experiments include dynamic material properties and quasi-dynamic fracture mechanics which are shown to significantly affect the fracture propagation. The study was performed using three-dimensional cube-type laboratory models fabricated from Polymethylmethacrylate (PMMA). The test cubes are loaded with explosives and resulting fracture networks are studied. The dynamic evaluation of the spatial crack system is monitored using a high speed image camera. An experimental model set-up is designed to indicate the pre-stress effect on deep borehole blasting and is shown that the pre-stress conditions have a decisive influence on fracture profiles and orientation. It is found that shockwaves rapidly exceed the slower dynamic fractures and a majority of cracks occur due to detonation pressure. Experimental testing using different parameters validate that explosive fracturing can predict the outcome of fracture and crack propagation in any rock type with known material properties. This can be accomplished under great stress conditions deep below ground surface. The experimental study results can be applied to a variety of industries such as mining and quarrying, tunneling, oil and gas, and construction.

Feb 23, 2014

By A. René Silva

The separation of Fe(III) from simulated Ni(II) solutions using different ion exchange resins was studied. The resins tested included cation exchangers with sulfonic and carboxylic groups and chelating resins with iminodiacetic, aminophosphonic, and mixed sulfonic and phosphonic groups. The dosage of resins was varied from 0.1 to 0.5 g/mL to study the impact of resin type and dosage on iron separation from simulated nickel leach solution containing 25 g/L Ni(II) and 25 g/L Fe(III) at pH 1.5. Also, the effects of different metal ion concentrations, Fe (III):Ni(II) ratios in solution, pH, and adsorption times were investigated. Experimental results demonstrate that all the chelating resins selected favored the adsorption of Fe(III) over Ni(II) with high Fe(III) loading. Soft cation exchange resins also favored the adsorption of Fe(III) over Ni(II), but no significant Fe(III) loading was observed. In contrast, strong cation exchange resins did not show adsorption preferences. The most efficient separation was observed using resin with aminophosphonic groups at resin dosage of 0.2 g/mL, having a Fe(III) adsorption over 94% and Ni(II) adsorption below 5%.

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this work was to assess the influence of parameters such as residence time, solid content, and temperature in a process route towards purified rare earth liquor which could be adequate to produce marketable rare earth products. The steps of the process route proposed in this study comprised water leaching of a sulfated rare earth ore and removal of impurities through the purification of the rare earth sulfuric liquor, which is the product of the water leaching step. The sample used in the water leaching experiments was a sulfated rare earth ore produced by the reaction of a beneficiated rare earth ore with sulfuric acid followed by roasting at 700 °C for 2 h in a muffle furnace and cooling at 20 °C. The water leaching experiments showed that the best condition comprised a residence time of 30 min, temperature of 20 °C, and solid content of 10% w/w, resulting in a recovery of 71.3% of the rare earth elements (REE) and a lower impurity extraction, e.g., only 15.0% of Fe, representing the main impurity in the rare earth ore. Even when presenting low amounts of impurities, the rare earth sulfuric liquor still needed to be purified before it can be used in the production of marketable rare earth products. In the study, the rare earth sulfuric liquors were purified in two consecutive neutralization steps, first by dosing the limestone pulp to pH up to 3.5 and secondly by adding the lime pulp to raise the pH from 3.5 to 5.0. The application of two consecutive purification steps at 20 °C resulted in the highest overall REE recoveries (65.4%) throughout all the steps of the process, being 71.3% in the water leaching, 99.6% in the partial purification with limestone pulp, and 92.1% in the purification with lime pulp at 20 °C. Under this condition, there was a total elimination of Fe, P, and Th and a significant reduction in the Al, U, and sulfate concentrations in the purified rare earth liquor. The purified rare earth liquor attained through the experiment is expected to be amenable to be used in the production of marketable products due to the lower impurities/REO mass ratios.

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this work was to assess the influence of parameters such as residence time, solid content, and temperature in a process route towards purified rare earth liquor which could be adequate to produce marketable rare earth products. The steps of the process route proposed in this study comprised water leaching of a sulfated rare earth ore and removal of impurities through the purification of the rare earth sulfuric liquor, which is the product of the water leaching step. The sample used in the water leaching experiments was a sulfated rare earth ore produced by the reaction of a beneficiated rare earth ore with sulfuric acid followed by roasting at 700 °C for 2 h in a muffle furnace and cooling at 20 °C. The water leaching experiments showed that the best condition comprised a residence time of 30 min, temperature of 20 °C, and solid content of 10% w/w, resulting in a recovery of 71.3% of the rare earth elements (REE) and a lower impurity extraction, e.g., only 15.0% of Fe, representing the main impurity in the rare earth ore. Even when presenting low amounts of impurities, the rare earth sulfuric liquor still needed to be purified before it can be used in the production of marketable rare earth products. In the study, the rare earth sulfuric liquors were purified in two consecutive neutralization steps, first by dosing the limestone pulp to pH up to 3.5 and secondly by adding the lime pulp to raise the pH from 3.5 to 5.0. The application of two consecutive purification steps at 20 °C resulted in the highest overall REE recoveries (65.4%) throughout all the steps of the process, being 71.3% in the water leaching, 99.6% in the partial purification with limestone pulp, and 92.1% in the purification with lime pulp at 20 °C. Under this condition, there was a total elimination of Fe, P, and Th and a significant reduction in the Al, U, and sulfate concentrations in the purified rare earth liquor. The purified rare earth liquor attained through the experiment is expected to be amenable to be used in the production of marketable products due to the lower impurities/REO mass ratios.

By Eti Purwaningsih, Widi Astuti, Erik Prasetyo

Increasing demand for high-grade manganese (Mn) ore has led to the practice of selective mining, which produced low-grade Mn ore as waste and in the long term could lead to environmental pollution. Research had been carried out to extract Mn from low-grade ore, which mostly exists as black Mn(IV) oxide (MnO2). Most extraction methods involved the reduction of insoluble MnO2 to soluble Mn2+ in acidic media. Metals other than Mn are also transferred to the pregnant leach solution (PLS) during the leaching process, especially iron (Fe). Due to high Mn concentration in PLS, precipitation is considered the best method to isolate Mn from PLS compared with solvent extraction and ion exchange/absorption. However, due to unselective leaching, the presence of Fe in the PLS makes the Mn separation and purification difficult. Therefore, in this research, the parameters affecting the selectivity of Mn over Fe in leaching process were investigated.

By Eti Purwaningsih, Widi Astuti, Erik Prasetyo

Selective-reductive leaching of manganese from low-grade manganese ore using tannic acid as a reductant in acidic media was demonstrated by XRD, SEM-EDX characterization, and batch leaching studies at room temperature. The pH change in the liquid phase before and after leaching revealed that selectivity of manganese over iron was due to the hydrolysis of iron. The acidity in the liquid phase during leaching was dictated by two mechanisms: proton-consuming reaction (manganese oxide reduction by tannic acid) and proton-producing reaction (ferric ion reduction by tannic acid to produce ferrous ion). Based on the leaching studies, the more prevalent reaction between these two was determined by initial leaching conditions: tannic acid concentration, sulfuric acid concentration, liquid-solid ratio, temperatures, and agitation time. Kinetic studies revealed that maximum recovery was attained within 6-h agitation, which indicated a product layer diffusion process.

By M L. Muller, A R. O’Donnell

The Mount Isa Mines (MIM) Copper Concentrator has an extensive history of reagent trials, with different reagents coming in and out of favour over the years. The research and use of carbon depressants is particularly prevalent, as carbonaceous pyrite is a major source of concentrate dilution. Years of research led to the use of naphthalene sulphonate due to its excellent carbon depression properties. However, due to rising reagent costs carbon depression ceased in the late 1990s. This led to the loss of knowledge about the use and value of naphthalene sulphonate. Cyanide is used at the Copper Concentrator for the sole purpose of pyrite depression and over the years multiple projects have been devoted to finding alternatives to it. In 2012 the neighbouring MIM Lead-Zinc Concentrator replaced cyanide with naphthalene sulphonate which resulted in cost savings and the elimination of a hazardous reagent. In 2013, plant trials were conducted at the Copper Concentrator in hopes to replicate the outcomes obtained at the Lead-Zinc Concentrator. The results of the trials conducted at the Copper Concentrator showed that naphthalene sulphonate could not replace cyanide and this work was set aside to pursue more promising projects. Further research conducted in 2014 found that mineralogy and a better understanding of the depressing mechanism of naphthalene sulphonate held the key to improved pyrite depression at the Copper Concentrator. The findings showed that Mount Isa copper ore contains two forms of pyrite; euhedral pyrite (cubic pyrite) and framboidal pyrite (carbon rimmed spheres of pyrite), both of which require different reagents to sufficiently depress them. Naphthalene sulphonate was found to be an excellent carbon depressant, suitable for depressing graphite and framboidal pyrite, whilst cyanide specifically targets euhedral pyrite.In 2015 laboratory test work was conducted to examine the use of naphthalene sulphonate in conjunction with cyanide to selectively target both forms of pyrite. This work led to a full plant trial, the results of which showed a significant increase in plant performance, with higher copper concentrate grades and recoveries being achieved. This paper aims to focus on the benefits and importance of understanding past work and linking a detailed knowledge of feed mineralogy to reagent selection for improved plant outcomes.CITATION:O’Donnell, A R and Muller, M L, 2018. Selectively targeting hydrophobic gangue minerals at the Mount Isa Mines Copper Concentrator, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 413–421 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Jan Drzymala, Przemyslaw B. Kowalczuk

Froth flotation is widely used for upgrading of ores and other materials. Efficiency of flotation depends on many parameters, including type, chemical structure and dose of flotation reagents. Selection of a proper frother in flotation depends on the material used, necessary dose of frother and its selectivity. The selectivity of flotation can be characterized by proper separation factors and indices. In this paper separation selectivity and power of frothers were evaluated basing on separation data for a given material and frother, plotted as the recovery of the useful component in the concentrate versus the recovery of the remaining components in the tailing. Such a plot is called the Fuerstenau upgrading curve. The selectivity was defined as the location of the whole upgrading curve in relation to no and ideal separation lines, expressed on the scale from 50 (no separation) to 100% (ideal separation). In turn, the flotation power was defined as the dose of frother to reach a certain upgrading level at which recoveries of the useful and unwanted components are equal. The power and selectivity of frothers were determined for the Kupferschiefer stratiform copper ore floated in the presence of a fixed amount of xanthate and varying doses of frothers using a laboratory flotation machine. Basing on the separation results for different poly(propylene glycol) (CnH2n+1O(C3H6O)mH, CnPm) and poly(ethylene glycol) (CnH2n+1O(C2H4O)mH, CnEm) alkyl ethers, it was found that the concentrate yield and recovery of copper as the useful component in the concentrate were greatly influenced by the type and dose of frother. However, the same results plotted in the form of the Fuerstenau upgrading curve clearly indicated that the selectivity of frothers was similar, while their power was different. It proves that both selectivity and power of frothers are useful parameters for characterizing flotation systems.

Jan 1, 2016

By Martin Encinas, Jesús L. Valenzuela, Jose R. Parga, Salvador Aguayo, Roy G. Lewis

Continuous laboratory solvent extraction of gold from cyanide solutions using LIX?79 guanidine based extractant has been investigated. Different variables that affected the selectivity and extraction include aqueous pH, extractant concentration, and modifier concentration. The extraction isotherms of the aurocyanide complex with respect to the other cyano anions were compared, and the following order of selectivity Au > Ag > Zn > Cu > Fe was observed. According to the pH isotherms, aurocyanide can be extracted in an alkaline media, and a better separation with respect to the other cyanoanions was obtained in the pH range 10.5-11.2. From the McCabe Thiele diagrams, better recovery was predicted when using LIX?79 extractant and tridecanol modifier at 10 vol.%. Stripping of the gold from the loaded organic was carried out at pH > 12 using NaOH and NaCN solution. The continuous tests indicate that a two-stage extraction followed by a single stage strip is adequate to obtain an overall process efficiency of >90%. Better results were obtained using a copper wash stage before gold stripping.

Jan 1, 2014

By Farzad Mohammadi, David Kratochvil, Patrick Littlejohn

"With more rigorous regulations being enacted in the mining industry, a need exists for cost effective and environmentally compliant technologies to remove selenium from mine impacted waters to ultra-low concentrations. Existing selenium treatment methods have high life cycle costs, introduce risks of acute fish toxicity, and produce biological waste residues that represent future liabilities. Furthermore, achieving selenium discharge limits of less than 4 ppb is a challenge for existing technologies. Selen-IX™ is a technology developed by BioteQ that selectively removes selenium from mine impacted waters to less than 1 ppb. The technology is purely physico-chemical and takes advantage of the basic principles of ion exchange and electrochemistry. Unlike conventional electrocoagulation that removes suspended solids and breaks emulsions or oxidizes heavy metals, the electrochemical process employed by Selen-IX™ relies on creating conditions where iron acts as a highly effective reducing reagent transforming selenium from a dissolved species into elemental selenium bound in a solid phase. The iron-selenium by-product of Selen-IX™ is an inorganic, non-hazardous and chemically stable solid. Due to their high iron content, the solids produced by Selen-IX™ are of interest to the steel making industry as a low cost feedstock. This offtake potential can not only reduce the life cycle cost of selenium removal by reducing disposal costs but more importantly, eliminate the risk of future environmental liabilities. In this paper, the basics of Selen-IX™ technology are presented along with results of successful piloting on streams from coal and copper-gold deposits.INTRODUCTIONVarious contaminants are released into mining wastewater during the extraction and processing of metals. One such contaminant is selenium. A naturally occurring element found in rocks and minerals, mining activities accelerate its release into the environment. Selenium in trace quantities is essential to all life forms but at higher concentrations it can be harmful, especially to aquatic life where selenium bioaccumulation can lead to reproductive deficiencies."

Jan 1, 2016

By A. West, F. Mohammadi

Growing awareness of selenium bioaccumulation has resulted in selenium management becoming an important environmental issue for mining operations. Selen-IX™ is a novel ion exchange based technology developed by BioteQ to provide an effective solution for removing selenium oxyanions from mine impacted water to single-digit µg/L levels. The technology offers significant potential benefits when compared to incumbent biological treatment processes, including substantially reduced capital and operating costs and significantly reduced production of a selenium-containing sludge for final disposal. This paper reviews the key features of the Selen-IX™ process and presents the results of recent pilot testing on selenium impacted water.

Jan 1, 2014

By Wainer da Silveira e Silva, Marco Antonio Teixeira, Robisom Damasceno Calado, Carlos Alberto Chaves, Tone Takayama Filho

A preocupação com o adequado tratamento de resíduos industriais surgiu com o conceito de desenvolvimento sustentável criado pelo Clube de Roma e contribuiu para o uso racional dos recursos naturais ao longo dos últimos 50 anos. A preocupação com a produção responsável e uso judicioso de recursos naturais priorizou a reciclagem de materiais na agenda das empresas, tornando-se numa atividade de alta relevância, vital para a sustentabilidade econômica e ambiental. Este trabalho aborda os aspectos técnicos, econômicos e ambientais da reciclagem de resíduos contendo zinco através do estudo de caso de reciclagem de resíduos gerados no processo de fabricação de aço em Forno Elétrico, denominado pó de Aciaria Elétrica (PAE). A indústria ainda está em busca de tecnologias para redução da geração e reciclagem desse resíduo. A relevância do estudo está na utilização da Análise Hierárquica de Processo (AHP) para avaliação e seleção da melhor alternativa, entre várias, para tratamento e reciclagem do PAE. Como resultado, demonstrou-se a eficácia do uso da metodologia no empreendimento de reciclagem de resíduos contendo zinco implantado pela Votorantim, em Juiz de Fora, Minas Gerais.

Nov 12, 2019

By Cyro Takano

An alternative use for recycling of waste from bag house of iron ore sinter plant was tested by producing and evaluating" at laboratory scale, the self reducing cold bonded pellets. This waste was characterized and the self-reducing pellets were produced using anthracite coal fines as reductant and Portland cement or hydrated lime/Blast Furnace slag as binder. It was used the molar ratio of Fe2O3/C (fix) equal to 3. Evolution of cold strength with curing time, for different contents of binder, was evaluated. Cold strength of 200N/pellet was obtained, for sinter dust, after 10 days of curing. Suitable hot strength was also presented and no decrepitation and swelling were observed. Good fractional reduction was obtained at 950°C and 1137°C. These results show that this material may be used by the Self-Reducing Processes for hot metal production, as an alternative route for this dust destination.

Jan 1, 1996

By D. G. Klaren, E. F. de Boer

Self-cleaning fluidized bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve any problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials have been used. In addition to the mitigation of fouling effects, a number of other significant benefits for slurry heating are afforded by the mode of operation of the self-cleaning fluidized bed heat exchangers. Increased turbulence at the slurry/tube interface is imparted by the action of the fluidised particles, resulting in very high heat transfers at relatively low liquid velocities. Furthermore, given the thixotropic nature of most process slurries, the action of the fluidised particles imparts additional shear to the process slurry, resulting in shear thinning effects with a consequent reduction in pressure drop and enhancement of heat transfer across the heat exchanger. The benefits provided by the self-cleaning fluidized bed heat exchanger make it the ideal option for the indirect heating of laterite nickel slurry for High-Pressure-Acid-Leach (HPAL) plants. This article explains the principle and application of the self-cleaning fluidized bed heat exchanger technology for the processing of laterite nickel and cobalt slurries in HPAL plants. It also presents an elegant method to revamp existing direct heated laterite nickel and cobalt processing plants into an indirect heated configuration employing self-cleaning fluidized bed heat exchangers.

Jan 1, 2004

By Z. Levinson, R. Dimitrakopoulos

A mining complex is an engineering system where raw materials are extracted from several mines, processed, transported, and sold to the market. The uncertainty and local variability of material grades and their locations within the related mineral deposits are critical for determining the optimal life-of-mine extraction sequence, destination policy, operating modes, and capital investment decisions, which define the production schedule of a mining complex. Infill drilling is used to further characterise a mineral deposit and reveals information that changes the representation of the resource model and potentially the resulting optimal long-term production schedule. A self-learning reinforcement learning approach is proposed to determine the optimal drilling locations that maximise the net-present value of the long-term production schedule and the associated financial forecasts by adapting the schedule to additional information. A case study at a copper mining complex demonstrates a $70 M increase in project value by collecting drilling information with a $1 M budget.

Sep 1, 2021

By R. L. Godfrey

The Custom Coals advanced coal cleaning plant will be designed with a unique blending of existing and new processes to produce two types of compliance coals: Carefree Coal? and Self-Scrubbing Coal?. Carefree Coal will be produced by cleaning the coal in a proprietary dense media cyclone circuit utilizing fine magnetite to remove up to 90 percent of the pyritic sulfur and correspondingly greatly reduce the ash. While may utilities can achieve full S02 reduction compliance with Carefree Coal, others face higher sulfur reduction requirements due to the higher sulfur content of their existing fuel supplies. For these circumstances, a patented Self-Scrubbing Coal will be produced by taking Carefree Coal and pelletizing limestone-based additives with the finest fraction of the clean coal. These technologies will enable over 150 billion tons of non-compliance U.S. coal reserves to meet compliance requirements.

Jan 1, 1995

In 1984/85 financial year Australia produced 529 thousand barrels per day (kbd) of crude oil. By far the major contribution (453 kbd) was light waxy oil from offshore Gippsland, Victoria. When these discoveries were made in the latter 1960s, imported oil was available in abundant supply and at low prices. Because of this, the Gippsland producers persuaded Government to control the marketing and pricing of their crude, and thus provide the required security of offtake. Political events in the middle East created supply shortages during the 1970s, and dragged up government selling prices for OPEC crude oil. Thus Arab Light crude that sold for less than US$2/barrel (bl) in 1970 reached $34/bl in 1981. Following the consequent decline in world oil demand, in 1982, Australian refiners sought to evade their obligation to lift Gippsland crude. Hence, in 1983, the Government was forced to introduce a floor quota of 385 kbd of Gippsland crude liftings and to allow producers to export any additional production refiners did not require. On expiry of the old arrangements, Government introduced a partial free market from January 1985, whereby the balance in excess of 350 kbd may be sold to Australian refiners at negotiated prices, or exported as before. In 1984/85 exports were some 90 kbd and will be higher in the current year. About half this total has been exported by BHP, providing valuable experience and lessons which are described in the paper.

Jan 1, 1986

By Ross T. McGillivray, David S. Graham, Dan A. Brown, Steven D. Dapp

"The Selmon Expressway includes an elevated structure extending across several miles of weathered karstic limestone geology, and represents a challenge for design because of the high variability of the material and the difficulty in characterizing the strength. The nature of the epikarst in this region of Tampa is such that variability can be extreme within distances of only a few feet. The weathered rock includes extremely soft soil infill within solution features on and within the formation. The limestone is so weathered that coring typically does not yield useful samples for strength testing, and in-situ Standard Penetration Testing (SPT) tests often encounter refusal blow counts. Thus the challenge for foundation design includes two components of reliability risks: the uncertainty associated with the ground conditions at a given foundation location plus the uncertainty associated with the foundation performance at a given location even when the stratigraphy is determined.This paper describes the design approach that has been implemented successfully for two projects at the Lee Roy Selmon Crosstown Expressway (LRS) in Tampa, Florida: the assessment and remediation of the reversible elevated lane (REL) foundations constructed in 2004, and the elevated expressways widening project constructed in 2012. Included in this design approach is a method developed for computing axial resistance in this local geology. Design for axial loading relies primarily on the development of side resistance, which was considered less subject to performance risks than base resistance. The calculation method incorporates a statistical analysis of SPT data, tempered by engineering judgment, to characterize stratigraphy at a given location into either soil, intermediate geomaterial (IGM) or rock.IntroductionThe subsurface stratigraphy of sites underlain by weathered limestone formations can be highly variable with respect to material layer thicknesses and strengths, even over short horizontal distances. This is the case for much of Florida, and particularly the Tampa area. These conditions present a challenging environment for the design of drilled foundations because of the need for a reliable determination of subsurface conditions at each foundation location, as they relate to the expected axial performance. Contributing factors include:"

Jan 1, 2015

By P. J. Uggowitzer, K. Steinhoff, A. Wolf

"With the increasing acceptance of the Thixoforging process in the last few years, also the technical and commercial requirements for this forming technology and its components increased. So far, a great deal of work has been done in the development of an efficient process and control design. However, less attention has been paid to the development of new specifically tailored aluminum wrought alloys for this specific manufacturing process. · In this paper a new AlMgSi-alloy (A6082), optimized for the Thixoforging process, is presented. In the first part, the technical potential of the new alloy is specified by its microstructural evolution and flow characteristics in the semi-solid state. In the second part, the mechanical properties of thixoforged components of different conventional AlMgSi-alloys a (e illustrated · and compared to the new alloy.IntroductionSemi-solid metalworking, also known as semi-solid forming, is a hybrid manufacturing method that incorporates elements of both casting and forging. The key to the process relies on the peculiar flow behavior of slurries containing non-dendritic solid, which was first studied at the MIT by Flemings et al. [i], in the early 1970s. It was discovered, that if an alloy is uniformly stirred during freezing, discrete rounded particles of solid are formed rather than the normal dendrites, and the slurry is highly fluid (-5 Pas) up at least 50% solid. In addition, these slurries posses thixotropic flow characteristics: the viscosity is dependent on sheare rate and time. The more vigorously they are stirred, the more fluid they become. However, on standing the viscosity recovers and the material stiffens (-106 Pas).The semi-solid forming process exploits this phenomenon. In a first step, the required non-dentritical- microstructure is obtained by mechanical or electromagnetic stirring during primary solidification of the alloy. The stirred slurry is generally fully solidified as a feedstock billet and - in a second process step - reheated above the solidus temperature into the semi-solid state. In this condition, the thixotropic properties permit the material to be handled by robotic devices and transferred to a die (Thixocasting) or subjected to- a forming process by means of forging (Thixoforging). Owing to the shear stress which acts on the semisolid material during forming operation, the viscosity of the material is reduced attaining so the desired fluid-like flow characteristics."

Jan 1, 2000