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By Claus G. Goetzel

Pressing of powdered metal parts is best done in the direction of the shortest extension of the piece, to avoid too great a loss of pressing force through internal iriction. As long as curved surfaces, re-cessej, or offsets occur only parallel to this shortest axis of pressure, no special difficulties arise: the cross sections, perpendicular to the pressure, do not vary, nor does the shape of the parts change during compression except for a gradually reduced thickness (Fig. IA). The problem becomes more dificult, however, when the curved surfaces or recesses are perpendicular to the shortest axis of the part (Fig. IB) Two processes for molding uniformly dense parts with complicated shapes from powdered metals are described in detail in this paper. Both can be employed successfully by those trained in the art. The first refers to curved parts; the second is especially adapted to parts having one or more recesses or steps. Both methods, as set forth here, are applied under the condition that presents the more difficult problem. For clarity, before description of the two practical methods, the variable factors in molding powdered metal parts will be reviewed, then an idealized procedure will be considered briefly. Variable Factors in Molding Powdered Metal Parts Compression Ratio Compression ratio is defined as the proportion of the final relative density of the compact to the apparent density of the powder. For iron powder of an apparent density of 3.0, for example, a compression ratio of 2 1/2:1 would be required to produce a compressed compact of 7.5 density; whereas for another iron powder having an apparent density of only 1.5, a compression ratio of 5:1 would be required to produce the same density. The lower the powder's apparent density, the greater must be the compression ratio for pressing compacts of high density.

Jan 1, 1946

By B. M. Larsen

Attempting to review the fundamental aspects of segregation in steel ingots of all types in a paper of reasonable length, we encounter two difficulties: (I) the fact that a large number of different physical and chemical effects are involved, and (2) rather incomplete and confusing evidence on certain aspects of detail and mechanism in the freezing process in which the segregation effect is involved. The best solution seemed to be to link together most of the underlying factors into a simplified theoretical picture that appears to the writer to explain most of the observed data, in the hope that this will serve as a reasonably good target for discussion and criticism. Segregation effects, especially in steel ingots or castings, are often divided into " microscopic" and "macroscopic," depending on whether the variations in concentration of solutes or dissolved elements in the iron occur as: (I) a periodic variation over the small distances between the nuclei and the surfaces of the primary grains, or (2) as a larger scale effect involving concentration gradients over distances of the order of several inches, more or less. The reason for this somewhat artificial division is, of course, that it is only the macroscopic scale effect that has much practical importance. About the only effect of practical importance that results from microscopic segregation is the banded structure often left in rolled sections, and even this is relatively harmless in most cases. However, the causes of microscopic segregation also untlerly the larger scale effect, so we must first consider matters such as the formation and growth of crystal nuclei, selective freezing and diffusion, and others that are fundamental to all sepregation effects. Undercooling and Nuclei Formation It is probable that although the degree of undercooling is small in iron, as in metals in general, a certain amount of it takes place, and also that the number of crystal nuclei increases very rapidly with increased undercooling below the liquidus temperature. In practical terms this means that the nuclei number illcreases very rapidly with increased cooling or freezing rate, thus being dependent on the rate of heat flow out from the zone of crystallization. Temperature Gradients and Heat Dissipation during Freezing Each pound of steel evolves about 100 B.t.u. when freezing. In addition to this, the temperature gradient in the solidified portion (required to dissipate the heat as freezing progresses into the axis) necessitates a loss of heat required to cool the solid metal below its freezing range, which is equivalent to an amount of not so much less in magnitude. In a 5-ton ingot, the total would include about one million B.t.u. for freezing alone and about 0.4 to 0.5 million B.t.u. for the gradient, up to the end of the freezing period. Thus the rate of freezing depends primarily on the rate of heat dissipation. In the ordinary ingot shapes, the axial rate of growth of the solid

Jan 1, 1945

By B. Alexander, G. Derge W. Peifer

This is part of a research project in the Metals Research Laboratory of Carnegie Institute of Technology, sponsored by the Carnegie-Illinois Steel Corporation. In organizing our program it became apparent that the problem of analyzing molten steel for hydrogen must be divided into two parts: (I) the correct analysis of a given sample, and (2) the correct sampling of the bath. Emphasis has been placed upon these divisions in the order named because methods of sampling cannot be evaluated until a satisfactory method of analysis is available. Vacuum fusion was selected from the list of possible analytical methods because it seemed to us to offer the best possibilities for giving rapid, accurate results on solid steel samples. A number of objections have been raised against this method as usually practiced. We have sought to meet some of these by proper design of the apparatus. Experiments will be described which show that others are not valid. In the conventional apparatus the sample is held under high vacuum for a period of several hours before it is actually analyzed and one might expect considerable hydrogen to escape during this period. We have provided a means of introducing the sample to the vacuum just before analysis. Another difficulty has been that the entire apparatus has been designed primarily for the purpose of analyzing for oxygen, which constitutes upward of go per cent of the total gases evolved from the sample The volume and pressure measurements have therefore been insensitive to the relatively small amounts of hydrogen present. This difficulty obviously can be taken into account in any apparatus designed especially for the amounts of hydrogen expected. Analysis in Vacuum-fusion Apparatus A number of experiments were carried out to determine the importance of several factors that have been stated as possible sources of error or uncertainty in vacuum-fusion analysis for hydrogen; namely, that hot graphite will absorb some of the gases, that metal vapor will cause discrepancies, and that low results may be obtained as a result of the water vapor (produced by the oxidation of the hydrogen) dissolving in the butyl phthalate of the manometer, or that the blanks obtained from the apparatus are so great as to make the method inaccurate. The experiments also checked on the accuracy and feasibility of using differential freezing as a method of gas analysis in a vacuum-fusion apparatus.

Jan 1, 1945

By W. G. Robinson

"MINING is one of Canada's most important industries and exploration is the life-blood of this dynamic and exciting business. The health and growth of the mining industry of tomorrow depends on the effort and thought that go into exploration today. The Members of the Geology Division of the C.I.M. are directly concerned with exploration, and it is fitting that this Division should periodically sponsor reviews of the thoughts and practices of the exploration com-munity. Accordingly, we have invited seven leading authorities to contribute papers dealing with specialized aspects of this field.Exploration is a science, or art if you will, that is constantly changing in keeping with our expanding knowledge of geology and technology. It started with the old-time prospectors who searched the wilds for exposures of ore, and made finds that developed into some of our most important mining camps. As more discoveries were made, they were able to relate certain types of deposits with particular geological conditions, laying the foundation for modern concepts of economic geology. The mapping by the early field parties lacked detail and usually served to outline the ""greenstone"" areas considered favourable for prospecting. More de-tailed studies through the years by government and company geologists led to new thoughts on the origin, emplacement and geological control of orebodies. The continuing diversity of opinion on these subjects indicates a need for further research, but each year sees an increase in our reserves of factual information."

Jan 1, 1967

By Nicholas J. Grant

It is the purpose of this paper to examine a number of the recent developments in powder metallurgy, being most concerned with those which are yet to prove themselves rather than those which have achieved commercial maturity. Such developments include the production of very much coarser and very much finer powders, down to the near-micron size range. Also considered are activated sintering, direct powder rolling and extrusion (both hot and cold), brazing and welding, hydrides of reactive metals, oxide dispersion strengthened alloys and theoretical evaluations. Introduction T HERE surely can't be very much argument with the fact that powder metallurgy has made large advances on many fronts during the past ten or more years (1). These advances have taken place in raw materials, in processing, in product development and in a better understanding of many of the phenomena which occur in the various steps involved in powder metallurgy. It should be clear, in view of such growth, that it will not be possible to highlight all of the new developments in the present paper. Many of these developments,

Jan 1, 1965

By Robert F. Mehl

Jan 1, 1944

By Robert F. Mehl

Jan 1, 1944

By James Westfield

I welcome this opportunity to appear before you and to review briefly the various health and safety services of the Bureau of Mines available to the mining industry, other than coal, and also to tell of our plans for extending these services to improve safety and health conditions. The Bureau's health and safety activities are basically services by which we attempt to develop and disseminate information on improved techniques in mine accident prevention and promote mine safety education in the mineral industries. Unfortunately, some mining companies, particularly some of the smaller operations, seem to be unfamiliar with these services, The Bureau of Mines is charged by law with the responsibility for inspecting coal mines; other services to the coal mining industry and are provided only on request, Safety inspections and other services that we offer are provided for noncoal mining industries solely upon request.

Jan 1, 1958

By E. M. Norris

Phosphate deposits are distributed widely over the earth's surface. Of the known areas of deposit, eight fields are of particular interest because of their vast reserves of high grade phosphatic material and the volume of their production that goes to the world's great consuming areas. These fields, in the order of their present economic importance, are situated respectively in Florida, French Morocco, Kola Peninsula of U.S.S.R., Tunisia and Algeria, Tennessee, Montana-Idaho-Wyoming-Utah, Ocean and Naru Islands in the Gilbert group, and in Egypt. The Rocky Mountain deposits have a comparatively low ranking in the phosphate trade of today, but this field contains one of the largest known reserves of phosphatic material, associated with which are recoverable trace minerals, which are of increasing importance in our national economy. The first discoveries of phosphate rock in the western states were recorded in Cache1 and Rich2 counties in Utah, respectively in 1889 and 1897. Mining operations were begun on these deposits near Montpelier, Idaho, in 1906. During the latter year geological studies of the phosphate beds were started by Weeks and Ferrier of the U. S. Geological Survey. These studies have been continued to the present day by a distinguished roster of the Survey's technicians. As a result of this systematic exploratory program, the Survey has published a series of bulletins, papers, and maps, which provide the mining public with a comprehensive study of the exposed

Jan 1, 1949

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By A. Mellek, M. Pischtschan, M. Perrucci

ABB has received an order for one of the most challenging mill drive projects in its history. With one SAG mill and one ball mill to be added at an iron ore mine in Sweden, the customer’s plant managers wanted to have the most efficient solution for driving their mills but had the budget limitations typically faced by the majority of mining companies during periods of market downturn. To find the best balance between cost of acquisition and highest performance throughout the lifetime of the plant, ABB was selected to deploy a synchronized bypass solution, in which only one drive system is used for two different mills in series. However, being one of the first grinding mills in the world with such a solution was not the only challenge the ABB team faced: The inclusion of some mill application functions - e.g., frozen charge protection, automatic positioning and creeping mode - brought the demands on the engineers to another level. With only one frequency converter and one mill application controller available, the configuration logic and interlocks had to be meticulously designed and thoroughly tested to ensure a smooth and safe startup. The solution offers a footprint reduction and more operator flexibility at a reduced investment as each mill can be run in both directions, and wear on the mechanical components can be greatly reduced due to ABB’s premium ring-geared mill drive (RMD). This paper will describe the details of the project, the configuration developed and the tests performed to guarantee correct software functionality. Mill startup is scheduled for January 2016.

Jan 1, 2016

By S. Ng, Peter Stapleton, Paul Mankowski, J. Spence, R. Siy

"Syncrude has developed a low energy extraction process for the recovery of bitumen from oil sand. This new process operates at a temperature of 25 °C, resulting in substantially lower energy costs and lower capital costs, especially for the thermal energy generation equipment. The process will be used in Syncrude’s Aurora Mine, which is scheduled for startup in mid 2000. The flowsheet for Low Energy Extraction includes hydraulic transport of oil sand slurry, and bitumen separation using collector and frother chemicals and air as process aids. A number of flow sheet innovations and optimizations have been included, resulting in the next generation of extraction technology. Experimental pilot plant results, engineering progress to date and areas of ongoing work will be discussed. SUMMARYThe Low Energy Extraction Process has been successfully developed for commercial implementation at Aurora. The 1996 100 tonne hour Field Pilot demonstrated that the bitumen recovery target could be met with an 11.1% grade oil sand. However, pilot plant bitumen recoveries for a lower grade oil sand were not acceptable. The subsequent flowsheet optimization study led to a new flowsheet for Low Energy Extraction, which includes a primary separation vessel, a flotation circuit for PSV middlings, and the use of middlings displacement in the PSV cone bottom with flotation underflow. A test program conducted in 1997 showed that the new flowsheet could significantly improve the bitumen recoveries for lower grade oil sands. Engineering work on process scale-up led to selection of a 30 meter diameter PSV, with a tangential feedwell. The successful development and commercialization of Low Energy Extraction for the Aurora Mine Project is a major enabling step in the Syncrude 21 program. The low energy requirements of this process allow Syncrude to develop the Aurora leases more cost effectively. The use of this process results in major capital cost savings, predominantly in the thermal energy infrastructure and also provides long term operating cost advantages for Syncrude."

Jan 1, 1999

By Q Zhou, H Nordberg, W Wang-Geissler

Efficiently controlling foam/froth within mineral processing continues to pose a challenge to the mining sector. The foaming characteristics of aqueous solutions for two-phase systems of air/liquid are well-studied with theories and mechanisms proposed to describe and predict foam formation and stability. The types and structures of reagents that either promote or prevent foaming/froth formation and stability are well-defined in these studies and practiced across various applications. Three-phase systems of air/liquid/solid, such as froth from mineral slurries, however, pose a challenge with the presence of a large quantity of relatively fine mineral particles. Theories and mechanisms that rationalise the effects of chemical additives as a defoamer or foaming agent in aqueous can be applied as a general rule, but do not provide the most effective solution for mineral slurry systems. Silicone-based defoamers, particularly their O/W emulsions, have been widely and successfully used at various stages of mineral processing to efficiently control the mineral slurry foaming properties. However, their foaming control ability could be significantly impacted by different processing aids used during the upstream process. In a zinc-rich mineral system, a silicone-based defoamer starts losing the properties necessary to effectively control foaming in the leaching circuit when throughput is increased. In this study, the synergistic defoaming/anti-foaming effects from surfactants and silicone-based defoamers are discussed to effectively control foaming/froth in the zinc leaching circuit, even with lower total defoamer dosage. Improvements during mineral processing can also lead to a cleaner mineral grade by reducing waste.

Aug 24, 2022

By F. Yang, S. S. Long

Mixed fatty acids, such as oxidised paraffin soap, are frequently used as a substitute for oleic acid in flotation of scheelite in China. Not only because it is cheaper than oleic acid, but also because it is superior in flotation performance to oleic acid. This superiority is generally attributed to the mixed fatty acids' synergistic effect. In this paper, the synergistic effect of oxidised paraffin soap was investigated. We found it mainly consists of a series of saturated fatty acid salts, with six to nineteen carbon atoms. All the contained fatty acids were classified into four groups based on their chain length to make the research work practical. Also, the groups were labelled as 1, 2, 3, and 4 in order. The research was simplified into studying the synergistic effect of four equivalent collectors, instead of fourteen fatty acids. It is justified by the fact that neighbouring fatty acids are expected to have a similar flotation performance. The synergistic effect of the four groups of fatty acids was studied by single-mineral flotation with single groups, binary mixtures, ternary mixtures, and the full component, as collector respectively. The flotation performance index and synergy value were introduced to evaluate flotation performance and synergistic effect of groups, respectively. The results show that the mixture 1+2+3 has the strongest synergy of all followed by the mixtures 1+3 and 2+3. The mixture 3+4 and 1+2, on the other hand, have negative synergy. The synergistic effect of mixtures of groups indicate that being consecutive in length and a broad range of lengths are vital for fatty acids to enhance synergy. Group 3 is fundamental for the collecting action of 733 oxidised paraffin soap in the flotation of scheelite. The fatty acid soap in group 4 is not suitable for flotation due to its low solubility. Keywords: Mixed collectors, synergistic effect, scheelite

Jan 1, 2020

By M. M. C Jiménez, J. A. S Ténorio

For the recovery of valuable materials and for the protection of environment, recycling process of printed circuit board is an important subject of study. Moreover, the popularization of the computers and its technological evolution has generated a large number of waste electrical and electronic equipment. This paper presents a study of synergistic solvent extraction of copper, nickel and zinc from a sulfuric leaching liquor of printed circuit boards (PCB’s). The percent extraction of copper, nickel and zinc from dilute aqueous sulfate media besides synergistic effect of mixture of the .extractants Cyanex 272 and D2EHPA have been studied. Furthermore, different conditions such as temperature, pH of the feed solution have been examined. The results suggest that the synergistic effect of the .extractants mixture enhance the extraction efficiency of nickel.

Jan 1, 2014

By Kretschmar. U. H.

Fieldwork in the Meguma of Nova Scotia and Archean equivalents shows that bedding-parallel quartz lode gold veins (LVs) commonly occur at the top of graded elastic sequences. We define a "gold cycle" (GC) by analogy with Bouma turbidites and show that most "shear zones" and "lamprophyres" correspond to the upper pelagic-pelitic (E) division. We describe GCs from Archean Chester Twp, ON; Elmhirst, ON; Bourlamaque, QC; "intrusions" and interpret them as crystal tuffs and tuff-breccias. Extensive early Archean pyroclastic volcanism is implied: the genesis of trondjhemite-tonalite-granodiorite (TTG) rocks must be re-examined. The geopetal nature and asymmetric alteration of LVs indicates genesis from sea-floor hydrothermal vents. Textures suggest that often quartz was deposited as a gel. Vent geometry (fracture, point source or diffuse seep), bottom topography and vent spacing is reflected in wade-thickness plots. GC facing directions survive metamorphism. The Bourlamaque batholith was a flat-lying sheet of quartz-feldspar-hornblende crystal tuff, and isoclinal folding has repeated one or more gold-bearing horizons. Syngenesis clarifies and simplifies LV formation with major implications for models. Exploration becomes more cost-effective. Basin analysis, whole rock geochemistry, ore lens geometry and vent spacing can be used.

Jan 1, 2011

By Huimin Lu, Min Li, Jinghua Zou

"Zeolitic imidazolate frameworks (ZIFs) are new type of porous materials, form inerratic polyhedral in three-dimensional with large cages and small apertures, and appear structural diversity. Their hole size can be adjusted. These materials have high selective adsorption capacity to carbon dioxide. In this paper, zeolitic imidazolate frameworks were synthesized by solvothermal synthesis method with dimethylformamide (DMF) as solvent and structuredirecting agent, divalent metallic ions as cation, and imidazole as ligand. The crystals were characterized with XRD, SEM for their crystal structures and physical properties, the adsorption of the crystals for carbon dioxide was also tested, and the result suggests that these porous materials have a capacity of 1.35ml/g for storing carbon dioxide at 273 Kelvin under ambient pressure.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the main environment problems, contemporary research has focused on ways to slow or stop this trend. CO2 capture has attracted attention due to the potential to trap and sequester large amounts of CO2 from concentrated sources such as power plants [1]. Traditional technologies in capturing CO2 include absorption by aqueous amines [2]. However, utilization of this process is energy intensive and expensive. Carbon dioxide storage materials investigated so far can be divided into two categories: chemical storage adsorbents and physical storage media [3]. The first kind of materials can chemically adsorb carbon dioxide within their structures and need thermal energy to release the adsorbed carbon dioxide. The examples of the chemical adsorbents include aqueous amines, gas-hyperbranched aminosilicas [4]. The physical adsorbents store carbon dioxide by physical adsorption of carbon dioxide at elevated pressure and release the adsorbed carbon dioxide at low pressure. The physical adsorbents that have been investigated for carbon dioxide storage include zeolites, carbonaceous materials and other porous materials. Until recently, a new type of microporous material, known as zeolitic imidazolate frameworks (ZIFs), has been reported as promising adsorbents for carbon dioxide storage [5 ~ 10]."

Jan 1, 2010

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By Saurav Kumar, Akshay Kumar, Vinayaka R. Kiragi, M. K. Banerjee, Amar Patnaik, Vinod Kumar

Today’s industrial technology offers to optimize and reutilize the resources available in terms of scum that remains after hot rolling in steel rerolling mills in Rajasthan, India. Vast reserves of low-grade coal exist and tons of mill scale are produced everyday after hot rolling in steel rerolling mills in Rajasthan, India. The present research work aimed to optimize the various parameters of solid-state reduction of mill scale using low-grade coal from Rajasthan, India. This study investigates the effect of reduction temperature (850–950 °C in steps of 50 °C), reduction time (60 to 180 min, in step of 60 min), mill scale size (800– 300 μm), and mill scale to coal ratio (1:1, 1:2 and 1:3) on achievable metallic iron percentage and its metallization. A higher percentage of iron content is obtained at a lower particle size of 300 μm. The structural analysis is carried out on 300 μm mill scales using XRD analysis, which shows the percentage of iron is approximately 63%, and metallization above 80% can be obtained under the reduction temperature at 900 °C for 180 min, for 1:3 ratio (mill scale to coal ratio). The chemical composition of the mill scale is obtained using X-ray fluorescence (XRF), and particle sizes as well as distribution of mill scale are determined by scanning electron microscopy (SEM). The elements present in the mill scale are also verified using EDS, which indicates the presence of a major portion of Fe, followed by Fe2O3, Si, and C, respectively.

Aug 14, 2020

By Francisco M. S. Garrido, Fabiano A. C. M. Passos, Carla N. Barbato, Karoline K. Ferreira, Danielle C. Castro, Adriana A. S. Felix, Luiz C. Bertolino, Fernanda A. N. G. Silva, Karla M. A. Simões

Cancrinite and sodalite are characterized by high capacity of adsorption due to its porous structure. The aim of this work was to use kaolin from Borborema-Seridó/Brazil as a source of aluminium and silicon to hydrothermal synthesis of sodalite and cancrinite and to evaluate the best conditions to the formation of these phases. Therefore, kaolin was heated at 700 and 900 °C for 2 h in order to transform kaolinite in metakaolin. Thereafter, experiments with the calcined kaolin’s were carried out between 150 and 230 °C for 30–270 min on a stainless steel pressure vessel using NaOH, Na2CO3 and H2O. The samples were characterized by X-ray diffraction, nuclear magnetic resonance, scanning electronic microscopy, thermogravimetry, and Zeta potential. The most pure sodalite phase was obtained at 230 °C, with the kaolin/NaOH ratio of 1:1, low concentration of Na2CO3 and smaller time of synthesis (30 min). On the other hand, for the synthesis of cancrinite phase at 230 °C, it was necessary to use kaolin heated at 900 °C, a longer time of synthesis (270 min) and a higher concentration of Na2CO3.

Mar 1, 2017