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By F. S. Hoseinian, M. Irannajad, M. Safari

In this study, the effect of chemical interactions of materials used in ion flotation on the removal of Ni(II) ions from low concentration synthetic wastewater was studied. Sodium dodecyl sulfate (SDS) and ethylhexadecyldimethylammonium bromide (EHDABr) as collectors and methyl isobutyl carbonyl (MIBC) and Dowfroth250 as frothers were used. To investigate the effective parameters and interactions of them, 16 experiments including 6 level variables were performed by supporting DX7 software and on the bases of 2-level factorial method. In the first step, the tests were conducted in a Hallimond tube. The result showed that collector of SDS and frother of Dowfroth 250 had appropriate interaction with each other at pH = 3. In the second step, optimal results from the first step were evaluated in a mechanical flotation cell. The removal of Ni(II) ions increased by increasing the time of flotation and they have a direct relation with the water removal. The kinetics study shows that the order and the rate of removal of the reaction do not follow any of the zero-order, first-order and second-order equations. The flotation rate curve on the removal of Ni(II) ions will divide the separation process to two stages, a fast flotation rate at the first stage and a slow flotation rate at the second stage. Ni(II) ions removal was obtained 88% at the best condition.This study showed that the use of ion flotation was a very effective method for Ni(II) ion removal from industrial wastewaters.

Jan 1, 2016

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using Sodium Dodecylsulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).By comparing the coprecipitant type and concentration studies it could be concluded that As5+ removal in the presence of Fe3+ (160 mg.L-1) alone, or a Fe3+ (80 mg.L-1) and Al3+ (40 mg.L-1) mixture, is equivalently effective (99,9%) and greater than in the presence of Al3+ (80 mg.L-1) alone (97,7%).Through SEM/EDS analyses, it was possible to observe that both morphology and composition of the precipitate produced in the solution and retained in the foam depend on the physico-chemical conditions of the system, that is, on the species present in the solution."

Jan 1, 2003

By J. A. L. Napier

An analytical solution to the best choice of cutoff grade for a mine is deduced for an assumed model of selective mining. It is found that this choice is determined by the constancy of a special function, the Hamiltonian, over the life of the mine. It is suggested that the appropriate constant value for this function should be determined by the expected long-term average of the paylimit. In that case, the optimum profile can be calculated at each point in time according to the prevailing working cost and product price. In particular, a decision can be made between operation at the true paylimit or at the subsidized paylimit implied by either the lease and tax formulas or the assistance formula for gold mines. It is also shown how the basic formulation can be extended for 'use in the determination of the optimum joint paylimit for two products over the life of the mine.

Jan 1, 1983

By O Omidi, P D. Katsabanis

The effect of delay time on fragmentation has been discussed for a long period but rarely in a satisfactory and unbiased way. Despite the efforts of many researchers, delay selection for fragmentation improvement or optimisation remains a controversial issue. Large-scale tests have been plagued with scarcity and scatter of observations, while small-scale tests have been associated with boundary effects and energy losses. Theoretical work is often used to produce explanations for available measurements or tries to simplify wave propagation and wave interaction to guide observation and practical work. The present work analyses results obtained from a relatively large number of small-scale experiments in blocks made of grout, and re-analyses results of previous experiments, to conclude on the effect of delay on fragmentation. It is shown that the main contribution of the delay is found in the fragmentation of the larger fragments of the blast, while the small fractions show almost no effect. Samples, where copper liners were used to inhibit penetration of detonation products in the rock mass, showed effect of delay only when short times were used and steady but poor fragmentation when long delays were used. Based on small-scale experiments, it appears that the fragmentation is optimised when a hole fires prior to the radial cracks, produced by the previous hole, reach the free face of the blast. Gas penetration may result in the development of few more fractures that affect the fragmentation of the largest particles of the blast.CITATION:Katsabanis, P D and Omidi, O, 2015. The effect of delay time on fragmentation distribution through small- and medium-scale testing and analysis, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 715–720 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Y. B. He

The effect of the stability and rheological properties of magnetite dense medium on the separation performance of a 6" dense medium cyclone (DMC) is studied with the use of fine density tracers. The tests in which different size fractions of magnetite are used to prepare the dense media reveal that at low medium densities (<1.5 s.g.), the best separation is achieved when using the magnetite with intermediate particle sizes (du3.2=18 11m). At medium densities above 1.5 s.g., however, it is beneficial to use coarser magnetite. With the fine magnetite dense medium, an increase in medium density results in a decrease in separation efficiency. With the coarse magnetite, an opposite trend is observed; the separation efficiency is improved with increasing medium density. An accurate cutpoint control is critical in gravity separation. The cutpoint shift for coarse feed particles is found to decrease with increasing medium stability (density). It assumes values close to zero in a highly stable fine dense medium. When the size of the treated particles is small (<0.5 mm), the cutpoint shift is mainly determined by medium rheology. With increasing medium density, a continuous increase in cutpoint shift is observed.

Jan 1, 1993

By Herty, C. H.

The effect of temperature on the physical properties of structural materials has been the subject of many investigations during the past decade. The literature on the effect of elevated temperatures. is voluminous, and during the last four years a great deal of experimental work has been carried out on the effect of low temperatures on the impact properties of steel. For many engineering purposes it is important to know the shock resistance of steels at low atmospheric temperatures, and with the ever-developing field of refrigeration and separation of materials at low temperatures, the normal limits of atmospheric temperature have been exceeded in practice. Iron and its alloys in the unnotched condition have a high impact strength at low temperatures, but in practice variations in type of notches result either from design or accidentally through scratches and surface or internal defects. A study of notched bar impact tests is, therefore, highly important to the engineer. A survey of the literature on low temperature impact testing indicates that chemical composition, heat treatment and method of testing have been the variables which have been considered in most previous work. In only a few instances has any mention of the steel- making method been mentioned and in these the comparison was between steel-making processes and not between steel-making methods on the same process. In view of the wide variations in impact properties at room temperature, in quench and strain ageing and in grain growth of steels of identical chemical composition, (by this is meant the usual five element analysis reported), it was felt

Jan 1, 1957

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

By T. W. Wlodek

In this paper the relative merits of shot peening, induction surface hardening, spiral-rolling, and the combination of these surface treatments, are evaluated on the basis of their capacity to increase the fatigue strength of drill steel. The S-N relations for plain car-bon steel (SAE 1080) and Ni-Cr-Mo drill steels in the as-rolled condition were determined previously, using the new Canadian method of testing drill steel introduced at the annual meeting of the Institute in Toronto in 1950 (19). S-N curves have now been determined by this method for these two drill steels in the following conditions: shot-peened and drawn, induction hardened, induction hardened and shot-peened, and spiral-rolled. ( S.R.) . The ratios of the fatigue strengths of these steels after surface treatment, to their fatigue strengths in the as-rolled condition, are compared and the most beneficial treatments are thereby pointed out. The expected range of stresses and their distribution during actual drilling operations are estimated from data available, and the mechanism of failure of drill steel in the as-rolled and surface-treated conditions is analyzed. The magnitude of the surface compression stresses and their effect on ?fatigue strength are discussed.

Jan 1, 1958

By Thomas Deschamps

The main objective of this work was to investigate the effect of binder addition on the geochemical properties of surface paste tailings. Nine leaching columns were prepared following different disposal configurations: non-cemented, non-cemented with cemented layers, and cemented .The proportions of cement by total paste weight were between 0 and 1% for a whole column; the maximum amount of cement in a single layer was 2%. The material used was a sulphide-rich tailings coming from a Canadian hard rock polymetallic mine. The columns have been flushed once a week during 30 weeks. The recovered leachates were analyzed for pH, Eh, conductivity, and a wide range of elements. The drainage rates were monitored during the initial disposal as well as after each column flush. The results show that binder addition can improve the whole environmental performances for some of the studied disposal configurations. The disposal configuration consisting of intercalation of three 2% cement paste layers within non-cemented layers (0.66 wt.% of cement for the whole column), and the configuration with 2% cement added only in the two bottom layers (0,44 wt.% of cement for the whole column), showed the best results in terms of water quality and drainage rates.

May 1, 2007

By J Seccatore, T Marin, M Cardu, G De Tomi, F Galvão, A Rezende, E Melo

Small-scale mining operations are characterised by a large variety of equipment availability and a high level of operational flexibility. Mine planning is usually scarce or absent in small quarries in Brazil, and mine management generally focuses on daily operations. As a result, analysis of the effects of unit operations, such as blasting, over the whole mining process is often neglected. The goal of the following project was to study the effect of production blasting on loading and hauling times, secondary breaking times and primary crushing times at the Experimental Mine of the Research Center for Responsible Mining of the University of S&#227;o Paulo, Brazil. The operations analysed included blasts that performed:under the average operational standard, defined in this paper as Case 1according to quarry standards, defined in this paper as Case 2.In order to establish the effects of blasting on the downstream process, three key performance indictors were used:The time taken to load the truck, when there is the need for material selection. Due to the fact that we do not have an operational baseline, the increase in time cannot be established, meaning that we must content ourselves with comparing the mean time in each scenario.The average time used for secondary breaking machinery.The time required for the primary crusher to fully process the load of a single truck. The results obtained indicate correlations between the coarseness of the blasted material and these operational times. Solutions are suggested and evaluated for the improvement of the small-scale mining process.CITATION:Marin, T, Melo, E, Seccatore, J, Cardu, M, Galv&#227;o, F, Rezende, A, Bettencourt, J and De Tomi, G, 2015. The effect of drilling and blasting performance on fragmentation in a quarry and time for loading, secondary breakage and crushing, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 355–362 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By Keith G. Wallace

The effect of face resistance on ventilation air leakage through stoppings was measured in a twin development heading. Face resistance was varied by alternately tightening or loosening the face line brattice to change the line brattice leakage. Results indicated that tight brattice lines are necessary to maintain acceptable airflow at the face but result in higher leakage throughout the entire system, reduced overall ventilation efficiency, and higher operating costs. Conversely, a low face resistance which simulated an auxiliary fan/duct system gave reduced stopping leakage losses, higher quantities of air at the last open cross-cut and greater entire system efficiencies

Jan 1, 1984

By Jr. Raleigh

Three run-of-mine bituminous coals, which ranged in rank from low volatile to high volatile A, were floated at nominal -28 mesh (590 µ m), -100 mesh (150 µ m), and -400 mesh (37 µ m) feed particle sizes with selected pyrite depressants and a dispersant. For the coals tested, pyrite and ash-forming minerals were usually rejected best at a -100 mesh feed particle size. Depressant additions tended to improve flotation selectivity between pyrite and coal. When joint dispersant-depressant systems were used at -100 mesh (150 µ m) feed particle sizes, the total sulfur content of the clean coal decreased further. For a comparable coal yield, less fuel oil collector was required for the flotation of -100 mesh coal than was required for the flotation of either -28 or -400 mesh feed.

Jan 1, 1990

By Ken Rahal, Chris Braun

As head grades of mines around the world decline, generation of tailings is increasing. Along with the increased tailings generation, reduction in water availability, and recent tailings dame failures, are causing mining companies to look at different disposal methods. One of the methods that is gaining traction is filtered tailings. Filtered Tailings currently provides the greatest water recovery and the smallest footprint among all the tailings disposal methods. This paper will present two case studies that analyze the filter and air compressor costs associated with a change in the final cake moisture target (i.e. a change from 17-wt% to 15-wt% cake moisture), for a base metal mine and gold mine.

Sep 30, 2022

By F. G. Miller

To improve coal flotation Bethlehem Steel Corporation&apos;s Research Department has been working on a number of related problems based on both physical and chemical factors. The ideal is of course full understanding of the interrelated effects of both sets of factors. However, detailed studies5 of each physical factor have produced immediately usable results in commercial coal flotation and are providing the bas is for our current work on the effect of chemical factors. Since these detailed studies provided the basis for the present investigation of froth sprinkling, their key results are highlighted here. For example, for a highly floatable bituminous coal, particle floatability was shown to be directly related to the percentage of coal surface available for bubble attachment and inversely related to particle mass. The data also underscored that in a given size range the addition of mineral matter to a particle makes flotation more difficult both by adding to the mass of the particle and by decreasing the amount of coal surface available for bubble attachment. Size also affects particle floatability in that as the size of particles of a given specific gravity increases, mass increases and the ratio between coal surface area and mass of the particle decreases. Flotation tests showed that any recovery of the coarsest particles in a coal feed is accompanied by progressively higher recovery of finer and finer particles. Consequently, fine high-specific-gravity particles are recovered with the coarse good coal. As a result, when the entire 14M x 0 size range is processed by froth flotation, the good coarse coal is contaminated with high-specific-gravity fines. It is the small quantities of these fines that must be rejected from the froth product if flotation efficiency is to be increased above its present level.

Jan 1, 1968

By F. Ngoroma

Concentrators processing PGM bearing ores make use of polysaccharide depressants to reduce the recovery of the undesired naturally floatable gangue minerals, mainly silicates, present in the ore. Recent work has shown that high depressant dosages can completely depress naturally floatable gangue and thus prevent it from reporting to the concentrate. These high depressant dosages can, however, have a negative effect on the recovery of valuable minerals present in the ore by reducing the stability of the froth. In order to counterbalance the effects of depressant addition, frothers are added. It is, however, preferable to maintain independent control over bubble size and froth stability which is difficult to achieve with only one frother. An alternative strategy is, to use a blend of frothers, e.g. a weaker frother in combination with a stronger frother. Such a system allows an additional degree of freedom: changing the ratio of the two frothers, that would provide more independent control of bubble size and froth stability. This study demonstrates, through the use of batch flotation tests, how blending low molecular weight alcohols with commercially available frothers impact the solids and water recovery, as well as the valuable mineral recovery and concentrate grade in different PGM ores. Higher water and solids recoveries together with higher valuable mineral recoveries (>90% copper and >70% nickel) were obtained from tests using frother blends.

Sep 1, 2012

By B. Aydin, G. Erturk, G. Bulut

Coal is a complex material because of its structure consisting of carbon constituents and mineral matter. Flotation is readily carried out due to hydrophobic characteristic of coal. Therefore coal flotation is the most commonly used technique for fine coal beneficiation in order to acquire clean coal separating ash forming mineral matter from carbonaceous matter. In the coal flotation, floatability of coal both depends on characteristic of coal and used flotation reagent. Frothers as a flotation reagent are used to facilitate air dispersion into fine bubbles by prevention of bubble coalescence in the pulp phase, and stabilization of flotation froths. In this study, the effects of frother types and concentrations at different pH and particle size on the coal flotation were investigated. The representative sample was taken from Zonguldak, Turkey. It contains 9.1% ash and 7313 (kcal/kg) calorific value. Pine oil, Dowfroth 250, MIBC and Isooctanol were tested as frother types. It is determined that 1.92 ppm frother concentration is sufficient to float coal, except pine oil. In mixed frother tests, it is seen that Dowfroth 250 is more effective than others. No significant difference in coal recovery was observed for flotation tests at the different pH values. The best results are obtained in size of coal (-0.1 mm) with all frothers.

Jan 1, 2014

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of grinding conditions on galena flotation and galena separation from pyrite. The changes occurring on the mineral surface during grinding were investigated by EDTA extraction and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the type and amount of oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite flotation but had little effect on galena flotation. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled.Grinding conditions had a large effect on the flotation of the galena particles of different sizes. Flotation of fine galena particles (-10 µm) was depressed by iron oxidation species derived from the grinding media. Chromium grinding medium decreased the production of iron oxidation species and therefore increased the flotation of fine galena particles."

Jan 1, 2003

By H. Evans

It is well known that iron-ore pellets are considered one of the best blast-furnace burden materials used today. The demand for pellets is demonstrated by the increase in pellet output from one million tons in 1955 to approximately 37 million tons in 1964. This growth continues as new plants are placed on-stream each year. The consumer generally specified (1) the acceptable content and range of chemical constituents, (2) a minimum strength determined by some standard testing procedure, (3) the size range of pellets, and (4) perhaps a measure of reducibility.

Jan 1, 1966

By K. Narayana Swamy

Experimental results of 3-phase mixing in a physical model of a CCRL for metals refining, at high levels of bottom gas injection (up to a superfIcial gas velocity (Us) of 12.5 cm/min), are presented. A thermal tracer technique was used to elucidate both longitudinal mixing and interphase heat transfer. The results indicate that even under conditions of significant bottom gas injection, it should be possible to maintain acceptably low longitudinal mixing (D. < 20 cm2/s and D/uL < 0.1) in the CCRL. Interphase mass-transfer coefficients of the order of 0.02 cm/s and higher, are predicted from the measured interphase heat transfer coefficients using the mass and heat transfer analogy. Adequate performance is likely to be possible for an industrial CCRL, based on extrapolation of these results to full-scale conditions.

Jan 1, 1996