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By R. Loj

Katowice Coal Holding (KHW) is one of the largest coal companies in Europe. The company owns five coal mines with a daily output of around 60 000 tons of coal. In the Katowice city area, very good quality steam coal is extracted. The depth of mining varies between 400 and 1100 m and some of the mines rank amongst those most afflicted by methane in the Upper Silesian Coal Basin, with the methane hazard having a significant impact on production and safety. ?Myslowice-Wesola? mine, being a part of the Katowice Coal Holding is characterized by high methane and rockburst hazards. The mine is equipped with a modern surface drainage pumping station. At the mentioned mine, longwall 514 was selected for analysis of its methane emission. The longwall was extracting the thick seam 501 (over 4 m), at a depth of over 900 m, which was subject to high stress and high gas concentration conditions. At a distance of about 50 m above, seam 501 is covered by thin seam 416. The strata between these two seams are sandstone and mudstone layers. In the floor of seam 501, with a thin shale interlayer, is located seam 510, which is the thickest (over 10m) and richest coal seam in the Upper Silesian Coal Basin. In longwall 514 and it?s vicinity, methane was the dominant risk. For this longwall three methods of classical gas drainage were carried out. At first, drainage was undertaken using long boreholes from a cross-cut at level 665 m, located far from the production panel. Later, it was performed using typical boreholes drilled from the ventilation gallery (tail gate road). Finally, it was undertaken using a degassing drift executed in the upper coal seam 416. All of these headings, ie. cross-cut level 665 m, the ventilation road and conveyor road in seam 501 and the degassing drift in seam 416, were equipped with media for drilling and proper drainage pipelines. Due to the high rockburst hazard and some problems with caving, several kinds of de-stressing and torpedo blasts were carried out in both coal seams and roof rocks. The subsequent analysis and experiments allowed the establishment of some general rules for carrying out degassing operations effectively. The effectiveness of a degassing drift was demonstrated. In some instances, the system allowed more than 70% of the total methane released to be captured and fed into pipelines. The aforementioned blasts had a marginal impact on methane emissions and the efficiency of degassing methods. Cyclic drilling and regular switching of boreholes in phase with the mining progress and working face advance were shown to be essential.

Aug 1, 2013

By Larry Patts, Jon Hummer, Jim Noll, Aleksandar Bugarski1, George Schnakenberg, Steve Mischler, Mike Crum, Shawn Vanderslice, Rick Anderson

This study is organized under the auspices of the Metal/Nonmetal Diesel Partnership formed by the National Institute of Occupational Safety and Health (NIOSH), the National Mining Association (NMA), the National Stone Sand and Gravel Association (NSSGA), the United Steel Workers of America (USWA) and the MARG Diesel Coalition. The ultimate objective of the study is to reduce the exposure of underground miners to diesel particulate matter (DPM) and gases, and to help in fulfilling the partnership’s goal of identifying technically and economically feasible controls to curtail particulate matter emissions from existing and new diesel powered vehicles in underground metal and nonmetal mines. The majority of current knowledge on the performance of the diesel particulate filter (DPF) systems and other control technologies is based on studies done under laboratory conditions, the results then being applied the results to on-highway vehicles. According to the best knowledge of the authors, only two comprehensive studies that were conducted recently at Noranda’s Bathurst Mining and Smelting Mine and International Nickel Company’s Stobie Mine under the sponsorship of the Diesel Emissions Evaluation Program [McGinn 2001, Bugarski and Schnakenberg 2001, Bugarski and Schnakenberg 2002] offered some insight into the problems associated with the deployment of modern DPFs to underground mining vehicles. The U.S. mining industry has expressed concern that this rather limited knowledge base is not sufficient to help them comply with the rule limiting DPM exposure of underground metal and nonmetal miners [30 CFR 57.5060 2001]. The partnership agreed that a series of comprehensive field evaluations of DPFs in several underground mines was needed to determine their viability of DPF systems and establish confidence in their performance. The first in this series of studies was the one conducted in Stillwater Mining Company’s Nye Mine, Nye, Montana. This study was conducted in two phases. The objective of the first phase was to establish the effectiveness of the selected technologies in reducing diesel emissions by using an isolated zone methodology. The objective of the second phase was to assess the effectiveness of diesel particulate filters in controlling the exposure of underground miners in actual production scenarios. As part of the first phase of the study a series of tests were conducted at Nye Mine from May 19, 2003 until May 30, 2003. The results of Phase I of the study are presented in this report.

Jan 1, 2005

By J. Noll

Many underground metal/nonmetal mines are using enclosed cabs on mining equipment to reduce the exposure of miners to diesel particulate matter (DPM). However, some enclosed cab systems may not be meeting their expected efficiency in capturing DPM, which could be a result of inappropriate filter use, cab leaks, or insufficient pressurization. NIOSH investigated several types of filters for reducing DPM to determine which type had the best capture efficiency. The laboratory results indicated that a MERV 8 (Minimum Efficiency Reporting Value, as defined by the American Society of Heating, Refrigerating and Air- Conditioning Engineers) filter captured about 50 percent of the DPM, a MERV 16 filter collected 96-98 percent of the DPM, and two HEPA (high efficiency particulate air) grade filters captured over 99 percent of the DPM. NIOSH also performed a field study to measure the efficiency of two cabs at a limestone mine. The cab filtration systems of a loader and haul truck were found to be over 90 percent effective in removing DPM except under certain operating conditions when the efficiency was as low as 41 percent. Evidence seems to suggest that these conditions were when a window was open in the cab.

Jan 1, 2011

By A. Cecala, J. Noll, J. Organiscak

Many underground metal/nonmetal mines are using enclosed cabs on mining equipment to reduce the exposure of miners to diesel particulate matter (DPM). However, some enclosed cab systems may not be meeting their expected efficiency in capturing DPM, which could be a result of inappropriate filter use, cab leaks or insufficient pressurization. NIOSH investigated several types of filters for reducing DPM to determine which type had the best capture efficiency. The laboratory results indicated that a MERV 8 (minimum efficiency reporting value, as defined by the American Society of Heating, Refrigerating and Air- Conditioning Engineers) filter captured about 50% of the DPM, a MERV 16 filter collected 96-98% of the DPM and two HEPA (high efficiency particulate air) grade filters captured over 99% of the DPM. NIOSH also performed a field study to measure the efficiency of two cabs at a limestone mine. The cab filtration systems of a loader and haul truck were found to be over 90% effective in removing DPM, except under certain operating conditions when the efficiency was as low as 41%. A possible reason for the low efficiencies is an open window in the cab, but more studies need performed to obtain a better understanding of the cause and solution of the problem.

Jan 1, 2011

By Feida Wu, Yuhang Liu, Huimin Gao, Yuhan Song, Zhi Liu, Zijie Ren

In the process of quartz purification by calcination water quenching, the different expansion rates of gangue minerals and quartz were used to produce cracks or remove fluid inclusions, which is conducive to subsequent purification. However, the role and mechanism of calcination-water quenching are still lacking in research. In this paper, the position of calcinationwater quenching in gangue quartz purification process was adjusted and the removal effect of calcination-water quenching process at different nodes in the process was explored. The results show that the purification effects of grinding-calcinationwater quenching-classification-acid leaching process and grinding-classification-acid leaching-calcination-water quenching process were relatively good. The main reason is that calcined water quenching can make quartz produce cracks, which are more rough. At the same time, calcined water quenching is located after grinding, which has a larger specific surface area, pore volume and pore diameter, and has a strong adsorption capacity for acid solutions.

Nov 2, 2023

By Li Qihou, Li Yuhu, Liu Zhihong, Liu Zhiyong, Yang Xiaofeng

Scorodite samples were synthesized, in adding or without crystal seed respectively by using Atmospheric Scorodite Process (ASP), Hydrothermal Scorodite Process (HSP), and Improved Atmospheric Scorodite Process (IASP) individually; and their crystal structure, crystallinity, morphology, particle size, specific surface area, Fe/As mole ratio, as well as the leaching stability were characterized, aimed to reveal the relationships among the synthesis methods, the compositional and structural properties, and the leaching stabilities of scorodite. The results show that synthesis methods have significant effects on the compositional and structural properties of scorodite. Scorodite samples of high crystallinity, small specific surface area, and low Fe/As mole ratio, possess high leaching stability. The order in the leaching stability of scorodite samples synthesized in this study is as follow: ASP<HSP<IASP. Scorodite particles in the sample synthesized by IASP without crystal seed are in large sizes and of pyramidal morphology enclosed mainly by crystal planes of {111}; and the sample possesses the crystallinity of 84.5%, the particle size (D50) of 28.2 m, the BET specific surface area of 3.72 m2/g, and the Fe/As mole ratio of 1.05; after leaching this sample by using acetate buffer solution of pH 4.95 for 10 days, the total arsenic concentration in the leaching solution is merely 1.14 mg/L.

Jan 1, 2015

By J F. C L Costa, J C. Koppe, C Diedrich

Currently mineral resources evaluation is firstly expressed in terms of volume. Next the resources are transformed into tonnes by using an average bulk density applied to the whole deposit or, in some other circumstances, various different densities to distinct geological domains. Previous work in uranium, copper and nickel deposits used linear correlation between grades and bulk density to derive the density. Geophysics methods are also another good way to obtain density indirectly.These approaches do not take into account that two samples with the same grade but with different bulk densities can characterise different sample supports, leading to severe bias in grade and tonne estimates. It is important that the systematic measurements of bulk density are included into the estimation process, particularly when density is not correlated with the grades. Additionally, the extra time and costs involved in obtaining the bulk density data have made the mining industry disregard it.This study reports the impact in resource estimates by using a methodology that includes the bulk density variability. It involves the determination of a variability model for the bulk density and another model for the composite that was weighted by density as well as by its length. Next, these variables are estimated by kriging and the final grade estimates are obtained. The tonnages are obtained with the bulk density estimates. The conventional methodology was also applied and both estimates are compared to the reconciliation data from a major copper deposit. The results show a significant difference between the tonnage and grade estimates obtained from these two methodologies.The results show that considering density variability when compositing leads to a more accurate methodology resulting in better grade and tonnage estimates locally and globally.

Sep 26, 2011

"Cast blasting is the primary means of overburden displacement in a surface coal mine. It serves two purposes; fragmenting the rock and throwing it directly to its spoil pile using explosive energy. Increased throw minimizes costs by reducing the amount of material that needs to be re-handled. Prior studies have shown that by only changing blast hole timing with the same blast design, fragmentation and throw alters. It is necessary in cast blasting to optimize both fragmentation and throw, since larger fragments will require more wasted energy to throw the same distance. In an operating mine in Georgia, an optimum inter-hole delay for fragmentation has been found by studying timings from 0ms to 45ms. Instantaneous timing between holes increased the throw by over 100 ft, but fragmentation was poor. Shock and detonation wave collision is a potential reason for this increased throw. This paper investigates this optimized inter-hole timing while altering top and bottom column primer time to potentially improve throw while maintaining optimum fragmentation. Timings studied are top initiation, bottom initiation, and top and bottom simultaneously. INTRODUCTION Explosives are utilized extensively by the mining industry in order to break rock, as either ore or overburden, for hauling, loading, and crushing. An effective production blast strives to achieve optimum rock fragmentation in order to increase the efficiency and reduce the costs of those downstream operations, while simultaneously meeting environmental regulations. The goal of blasting with respect to fragmentation is, according to Hettinger (2015), “to decrease the average particle size of the fragmented rock without overly increasing fines or, in other words, improve fragmentation.” Additionally, the distance the rock is transported by the explosive energy from the blast, also known as throw, can increase efficiency by reducing the amount of material that is re-handled by mine equipment. The primary situation in which this is desirable is the cast blasting of overburden across the narrow pit of a surface coal mine. A key variable in a blast design pattern that can be manipulated to optimize both fragmentation and throw is delay timing between detonations. The invention and increased utilization of electronic detonators has allowed for precise delay timings to be used between rows, holes, and even multiple primers within the same hole. These recent developments in the blasting community have also provided an opportunity to investigate whether or not the mechanism of shock or detonation wave collisions caused by short timing delays are responsible for any increased fragmentation or throw. This experiment attempts to demonstrate if an increase in throw can be achieved while maintaining optimum fragmentation. This study consisted of 3 full scale bench blasts at a granite quarry in Talbotton, GA. Each blast was characterized by the timing delay between the top and bottom primer in the blast column of each hole; one simultaneous blast with a 0 ms delay, a bottom-initiated blast with a 1 ms delay, and a top-initiated blast with a 1 ms delay. Fragmentation analysis of the resultant muckpiles was performed using a combination of the PortaMetrics handheld point-and-shoot rugged tablet from Motion Metrics and the software WipFrag from WipWare. Throw was measured by placing strategic distance markers on the floor of the bench and then taking overhead photographs of the muckpiles after each blast. High-speed video footage was captured of each blast using an MREL Blaster’s Ranger II camera."

Jan 1, 2017

By S. Makni, R. E. McIvor

Grate discharges historically outnumbered the overflow type of industrial wet ball mills. However, overflow discharge mills now strongly dominate. In order to understand their comparative advantages and disadvantages, Corem carried out a broad review of this topic. Where the data made it possible, the Functional Performance Equation was used to separate circuit classification from mill grinding effects. Batch tests were conducted in a torque-metered mill at different slurry levels. This paper presents the outcome of these investigations, which is a very strong case for the industry to once again consider grate discharges.

Feb 1, 2023

By Eltefat Ahmadi

Iron-free titanium oxycarbonitride (TiOxCyNz) is a promising feedstock for production of titanium tetrachloride (TiCl4) at low temperatures. In this study, the effects of leaching variables such as temperature, time, particle size of staring material and concentration of the leaching solutions were evaluated on iron removal from nitrided Malaysian ilmenite by Becher process. The nitrided ilmenite was prepared by isothermal reduction with graphite at 1200 °C for 3 h in H2-N2 atmosphere. The aerated leaching experiments were conducted at 50–90 °C with addition of 0.3–2.0 wt% of NH4Cl catalyst. The highest extent of iron removal (XFe) was obtained at about 96.2% for the sample leached at 90 °C for 7 h with 2.0 wt% NH4Cl. The iron concentrate and titanium oxycarbonitride product were characterized by ICP-OES, XRD, XRF and SEM-EDX analyses. The results indicated that the aeration leaching process was a successful route to prepare low-iron titanium oxycarbonitride.

By Richard O. Rouse

Today, I want to challenge this audience by charging each of you to be a greater manager and superior engineer to manage and engineer our way through the 1980&apos;s and profitably overcome all the present and proposed government regulations. May of the present and proposed regulations will tax you and your company&apos;s management and engineering to the brink of physical and monetary exhaustion, but I believe we can succeed and coal can be America&apos;s answer to her hungry energy needs. To put our 1980&apos;s challenge into perspective, I want to give two great challenges we must overcome. First - We must improve on our process of compliance to new government regulations in the technical and equipment end of our industry. The Lord said, "Let There Be Light". MSHA said, "Let there be light in underground coal mines". Since that time, we have lived through an unmanageable and tremendously costly period of compliance.

Jan 1, 1980

By Bradford C. Wesstrom

An overview of the challenges encountered at the Freeport McMoRan El Paso Copper Refinery with higher concentrations of antimony electrolyte will be shared. The observations will cover the detrimental effects on copper starting sheets, commercial cathodes and anode slimes. The study will show negative effects on quality and productivity. Experimental work will utilize a test cell to study the effects on electrolytes by different Antimony, Arsenic concentration and anode molar ratio. Best practices will be shared for producing high quality cathodes while effectively managing the detrimental effects of higher antimony electrolyte.

Jan 1, 2014

By Cris Sideco

This paper describes the concentration processes of the Sullivan. Concentrator, including crushing , transportation, sink-float, grinding , flotation and dewatering. Handling of hot muck has had a deleterious effect on most of the processes, resulting in significant operating problems and poorer metallurgy. These problems are described -in detail. THE SULLIVAN CONCENTRATOR is situated in Kimberley, high up in the Purcell Range of the Selkirk Mountains, at an elevation of 3,600 feet, approximately 4 miles from the Sullivan Mine (see Fig. 1). The original plant went on stream on August 23, 1923 at a designed capacity of 2,500 tons per day. This has been increased in stages to its present rated capacity of 11,000 tons per day. The latest stage was in 1949, when several major projects, including the underground crushing plant, the sink-float plant and the installation of a rod mill, were completed. Some 112,800,000 tons of ore have been treated in this concentrator to November 1975. The plant started on a 48-hour/ week schedule, but was reduced to 44 hours/week in October 1946 and down to 40 hours/week by the end of 1949. Except for a 6-month period in 1952 when the mill operated continuously, the 40-hour/week, Monday to Friday schedule was in effect.

Jan 1, 1977

By A J. Morrison, K Demir, J Kohmuench, K Runge, C Evans

The Eriez HydroFloat® is a flotation device capable of recovering significantly coarser and lessliberated particles than is possible using a conventional mechanical flotation cell. Originally developed for industrial and bulk mineral beneficiation, the HydroFloat® is attracting increasing interest as a means of increasing the required grind size for metalliferous ore flotation. Doing so would reduce the costs of processing complex ores, either by decreasing the energy required to grind the flotation feed or by increasing the throughput achievable with a given comminution circuit. Processing coarser particles would also result in coarser waste streams, potentially improving the mechanical and hydraulic performance of the waste dams that they are sent to. Recent work at pilot – and industrial-scale has proven the potential of the HydroFloat® technology to achieve these gains in metalliferous applications. However, in order to realise the full potential of the HydroFloat® technology, it is necessary to understand not just its performance but also the drivers for that performance. Doing so will allow the design and operation of HydroFloat® devices to be optimised for different ores and applications. For this work, a HydroFloat® pilot rig was deployed to a coppergold plant in Australia and was used to investigate the effect of stream and operating conditions for treating the tailings stream of one of the plant’s rougher flotation cells. Under each set of operating conditions, samples were taken of the HydroFloat® feed, tailings and concentrate streams, and processed to yield the grade and recovery achieved by the device. At the same time, the bubble size and bed behaviour inside the device were measured. This paper presents preliminary relationships observed between the operating conditions and the performance of the HydroFloat® cell, and thus suggests a range of possible drivers for the measured coarse particle flotation performance.

Aug 24, 2022

By J Manuel, L Lu

Increasing bed depth is one of the main options sinter plants consider to increase production, since it is an incremental improvement and less expensive compared with a new plant. To maximise the benefits of increased bed depth, correct blend design and plant operation is critical. This paper discusses test work conducted to show the effects of ore type and bed depth on sintering performance and the adjustments required in both fuel rate and lime addition depending on ore type. The differences in sinter plug macro and microstructure were also examined to show the effect of bed depth on ore assimilation and matrix formation. Finally, the benefits of blending ores to achieve the best sintering performance as bed depth increases is discussed.

Jan 1, 2007

By S. M. Hossaini, M. Ataei, H. Moosavi

The abstract highlights the importance of pillar stability in underground coal mines and the influence of rock mass strength and joint orientation on pillar behavior. The study employs numerical modeling using the distinct element code (UDEC) to investigate the impact of these factors on pillar stability. The research considers different joint orientations and varying rock mass strengths, analyzing parameters like stress distribution, displacement, and failure patterns. The findings reveal that both joint orientation and rock mass strength significantly affect pillar stability, with specific combinations leading to reduced safety factors and increased deformation. The study concludes by emphasizing the importance of considering these factors in pillar design for safe and efficient mining operations.

Apr 4, 2022

By P. T. Bissert, L. Yan, J. R. Srednicki, J. A. Yonkey

"Refuge alternatives (RAs) are required in underground coal mines to support life post-disaster. RAs are mandated by MSHA to maintain an apparent temperature (AT) at or below 95°F (35°C) while providing a safe and livable shelter for a minimum of 96 hours. Because strata composition and mine temperatures will affect the final AT within an occupied RA, NIOSH researchers have collaborated with five underground coal mines across the US to characterize the effects of geographic location and seasonal temperature fluctuations on mine air temperature, relative humidity, and mine strata temperatures. The data collected indicates that some mines will experience greater temperature fluctuations than others, based on geographic location. The mine which demonstrated the greatest temperature differential over the course of the year resulted in a mine air temperature that ranged from 53.4°F (11.9°C) to 84.2°F (29.0°C) and a rib surface temperature that ranged from 55.4°F (13.0°C) to 82.8°F (28.2°C). This data suggests that the location and seasonal peak temperature can significantly affect the mine strata temperature, which could lead to a fully occupied RA exceeding the 95°F (35°C) AT limit over the course of 96 hours. The data reported in this paper could be used to examine the heat buildup inside an RA for actual mine conditions. Thermal simulations could be implemented to evaluate maximum occupancy ratings based on actual mine temperatures and strata compositions. INTRODUCTION In the event of a mine disaster, miners’ primary focus is to escape. Should their attempt be futile, they can enter a refuge alternative (RA) to await rescue. In 2008, the Mine Safety and Health Administration (MSHA) mandated that underground coal mines implement RAs within 1,000 ft (304.8 m) of the working face and spaced within one-hour travel distances in outby areas where persons work such that persons in outby areas are never more than than a 30-minute travel distance from an RA or safe exit. These RAs are required to provide a safe and habitable shelter for a minimum of 96 hours and to prevent the apparent temperature (AT) from exceeding 95°F (35°C) [1]. There is concern throughout the industry that in some cases the internal ambient of occupied RAs may exceed the 95°F (35°C) AT limit due to the potentially hot mine atmosphere as well as the metabolic heat generated by RA occupants and the carbon dioxide scrubbing system. The National Institute for Occupational Safety and Health (NIOSH) has conducted tests in its Safety Research Coal Mine (SRCM) and its Experimental Mine (EM) to investigate heat buildup in RAs. It was found that the number of occupants in an RA may need to be reduced based on the ambient mine temperature, which varies from mine to mine [2]. Further testing and analyses were completed to evaluate the mechanisms (conduction, convection, radiation) by which heat is transferred from an RA to the mine surroundings. Additionally, the effects of varying mine strata compositions on the heat buildup inside an RA were studied [3]. The mine strata temperatures will increase due to heat transfer from within an RA. Depending on the mine strata composition, some mines may be more thermally conductive than others. For example, sandstone is much more conductive than shale or coal (i.e. it disippates heat at a quicker rate). All things being equal, the air temperature inside of an RA after 96 hours will be higher for a mine with strata that has low thermal conductivity compared to a mine with high thermal conductivity."

Jan 1, 2017

By P. R. Jochens, D. D. Howat, R. B. Atmore

INTRODUCTION The Miller chlorination process has assumed a preeminent position in the refining of gold bullion, a position it has maintained for over half a century. In the early sixties considerable interest was aroused by the idea of producing a consistently high grade bullion at the mine smelthouses themselves. However, as the use of chlorine in industrial plants is associated with considerable hazards, oxygen was considered a natural alternative, apart from bing less expensive than chlorine. Partial refining at the mine smelthouses would considerably decrease the requirements made on Rand Refinery Limited as well as indicating the possibility of reducing final refining costs. An added factor would be the purer silver chloride obtainable, after prior removal of the base metals by oxygen injection, which would facilitate the production of high-purity silver. The free energies of formation of the oxides of the metals;- silver, copper, lead, zinc, iron and bismuth indicate that, with the exception of silver, these metals should be capable of removal as oxides by oxygen injection. Rose1 had shown that during injection of gold bullion, considerable loss of silver to the boraxsilver slag occurred and, furthermore, that copper removal was not efficient and oxide attack on the refractories was severe. Plant test work2 had confirmed the difficulty of copper removal, but had shown that zinc and lead were almost completely removed. The difficulty of copper removal by oxygen injection warranted further investigation. Also, the high decomposition pressure of silver oxide suggested that by suitable control of the slag composition it might be possible to reduce to very small proportions the silver carried into the slag as oxide. The oxidation of copper by oxygen injection and subsequent dissolution of the oxide in a slag may occur according to the following reactions; Reactions 4 and 5 were considered because of the relatively high solubility of oxygen in molten silver and silver alloys. Thermodynamic data indicate that there is little possibility of any reaction involving the formation of CuO occurring at temperatures above 1 000 °C. To ensure that the operative reactions 1 and 4 take place to the maximum extent, the following factors He significant. (a) an increase in the activity of the copper in the bullion, (b) an increase in the partial pressure of oxygen in the system, (c) an increase in the activity of the oxygen in solution in the metal, (d) a decrease in the activity of cuprous oxide in the slag. From practical considerations, the operative variable most easily susceptible to control is the composition of the slag. SOLUBILITY OF COPPER OXIDES IN BOROSILICATE SLAGS Very scanty information exists on systems containing copper oxides but the indications are that slags containing considerable amounts of boric oxide would possibly prove to be the best solvents for cuprous and cupric oxides. This is attributed to the fact that the activities of copper oxides are much lower in boric oxide slags than in slags in which silica is the main network former. The number of possible slags containing boric oxide was limited by consideration of liquidus temperature, viscosity, corrosive action on refractories, volatilization, and ultimately cost (for industrial application). Slags in the systems soda-boric oxide-silica and lime-boric oxide-silica were selected paying due attention to the above limitations. Additions of 5, 10 and 15 per cent cupric oxide were made to the finely ground, premelted slags. These mixtures were then reground and 2g quantities held in re crystallized alumina crucibles at temperatures of 1150°C and 1 250°C respectively for 30 minutes. The crucibles were removed from the furnace, rapidly cooled, cut in half longitudinally, and a thin section taken from one half was subjected to microscopic examination.

By A. M. Alfantazi, M. Boissoneault, D. B. Dreisinger, J. Synnott

"The effects of five commercially available foaming reagents (range of 0 to 25 ppm) namely Dowfroth 250, Saponin, Yucca, Licorice and Meta-Para Cresol on acid mist control, current efficiency, polarization behavior, and deposit morphology and orientation were investigated. The deposition was carried out using a bench scale electrolysis apparatus (cell volume 3L) at 500 Nm-2 and 38°C for 3 hours from Kidd Creek zinc electrolyte. The acid mist control capability of the various reagents was studied and compared by characterizing the foam layer generated during actual electrowinning conditions and by direct quantitative measurements of acid mist levels on top of the electrowinning cells. Within the range considered, the addition of these reagents reduced the current efficiency, refined the grain size of the deposit, and changed to preferred orientation of most of the deposits. Among the reagents tested, acid mist measurements indicated that Licorice and Dowfroth 250 were the best acid mist suppressant at emissions of 0.30 mglm3 and 031 mg/m3 respectively while Yucca and MPC produced the most mist at 3.0 mg/m3 and 33 mg/m3 emission rates, respectively.IntroductionMost of the world's primary zinc is produced via a combined roast-Ieach-purificationelectrowinning process. Depending on the electrolysis conditions, several additives may be added to the electrolyte. Some (e.g. glue, antimony, sodium carbonate) are added to mainly counteract the detrimental effects caused by impurities while others (e.g. licorice, Saponin) are used as foaming reagents to prevent excessive acid mist formation. Acid mist emission is a problem in many electrolysis operations because it corrodes the equipment and is a health hazard to the workers in the tankhouse as well as it pollutes the environment. Due to recent trends towards more environmental protection and more stringent in-plant hygiene, there is an increasing need to minimize these aerosols. In order to eliminate or minimize these aerosols foaming agents are usually added to the electrolyte to produce a foam layer on top of the electrolyte, thus trapping most of the mist. The ideal foaming agent would trap all of the mist and would not interfere with the electrowinning process. It is also evident that the reagent toxicology, cost and availability are important factors that need to be considered.Review of the available literature clearly indicated that very little work has been done in the past on the subject of acid mist control in electrowinning operations particularly in the area of foaming and anti-misting properties of surfactants. Two papers [1,2] have reviewed briefly the existing technologies for acid mist control. Recently, most of the work in this area has focused on the development of special mechanical devices that could be attached to the electrodes and control the mist generation at the source before it is emitted to the cellhouse [2-5]. On the other hand, extensive body of literature exists that deals with the effects of anti-misting reagents on the electrowinning aspects [6-7]."

Jan 1, 1997

By Neal Lee

Often the effects of wet boreholes are not taken into consideration when designing a blasting program to exhibit a certain amount of explosive energy per unit of rock such as design by powder factor, expressed in lbs./bcy (pounds explosives per bank cubic yard) or kg/bcm (kilograms per cubic meter), often the effects of wet holes are not considered. This paper examines different methods of loading wet holes and the effects they have on actual explosive quantities/unit of rock. In particular, we are looking at the amount of water trapped within the explosive column (bulk loading from the collar), or the annular space left void of explosives product around and between cartridges (wet-bags) with many of the current wet hole loading methods in use. We will focus on the effect this has on actual powder factor relative to “as designed” dry hole loading values, as well as the effect on performance of the explosives.

Jan 1, 2011