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By Jan Vrestal, Josef Tomiska, Pavel Broz

"Thermodynamic investigations on fcc solid ternary Fe-Ni-Cr alloys have been performed by means of the computer-aided Knudsen cell mass spectrometry. Ternary T.AP.-series (Thermodynamically adapted power series) are used for the algebraic representation of the thermodynamic excess properties. At 1650 K the molar excess Gibbs energy GE is negative over the whole field of stable fcc phase. The molar heat of mixing HE is exothermic in the predominant part of the fcc phase field. Only between the section with a constant ratio of mole fraction Xcr/XNi = 0.64 and the fcc phase field boundary the HE values are slightly endothermic. The results of this work can be used successfully for phase diagram calculations.IntroductionThermodynamic investigations on multicomponent alloy systems such as the Fe-Ni-Cr ternary system including the three binary boundary systems are very time-wasting and usually beset with considerable experimental difficulties. Additionally, the required experimental equipment is very expansive and the obtained results are not always satistying. Therefore it is understandable that many phase diagram calculations are based only on few experimental values of the molar excess free Gibbs energy GE. Consequently, Kundrat and Elliott [1] as well as Hillert and Qiu [2] used in their reassessments of the phase diagram of the Fe-Ni-Cr system thermodynamic data mainly assumed and/or optimized by means of various reasoning.Lee [3] reported recently, a revision of the used thermodynamic description of the Fe-Ni liquid phase is necessary to obtain a better agreement with the experimental data on the bcc/liquid or fcc/liquid tie lines and liquidus temperatures in the Fe-rich region of the Fe-Ni-Cr ternary system than in the previous assessments. This is 'in full agreement with mass spectrometric investigations of Fe-Ni alloys in the liquid and in the fcc solid phase, published earlier [4,5]. Indeed, phase diagram calculations based upon the molar excess free Gibbs energies GE obtained in these studies yield liquidus and solidus lines in excellent agreement with experimental phase diagram data [5]. Nevertheless, these experimental data have not been considered later on any more, not even in the revision by Lee [3]."

Jan 1, 1996

By D J. McDougall

Due to changes in the solid-state conditions of minerals in the rocks surrounding hydrothermal, contact meta-somatic or metamorphosed ore deposits, positive or negative thermoluminescent anomalies may be found in their vicinity. Several types of equipment which can be used for both quantitative and semi-quantitative measurements of the emission are discussed and compared. Methods of selecting, preparing and testing samples to ensure reproducible results are outlined, along with the kind of data which can be obtained from different types of equipment. The normal thermoluminescence of rock-forming min~ erals in the common rock types is noted, and variations in the solid-state conditions in the wall rocks which will cause marked increases or decreases of true thermoluminescence are outlined, as well as the thermolum-nescence-like emissions which are present in the vicinity of ore deposits. Introduction T HERMOLUMINESCENCE occurs when certain crystalline materials are heated to temperatures ranging between 180' and 400°C. The light emission can be ascribed to the release of electrons metastably trapped within the crystal lattice, with peak emissions taking place at temperatures which are more or less specific for a particular set of traps; the area under

Jan 1, 1965

By D. Larouche, M. Mardan

Hot tearing is a complex defect in aluminium castings which is produced during solidification when a certain amount of liquid phase remains and weakens tensile resistance of the alloy. In direct chill casting of aluminium alloys, hot tears initiate at the surface of sheet ingots just after the primary cooling zone, where the microstructure is particularly vulnerable. In order to study the hot tearing susceptibility of these alloys, and the effect of grain refiners on their thermo-mechanical behavior , tensile tests were carried out in the semi-solid state ( ~95% solid) and at low strain rates using an apparatus called DCSS, for Direct Chill Surface Simulator. This apparatus, originally developed at Alcan Arvida R&D Centre (ARDC), is an instrumented rig test reproducing the conditions prevailing during the primary cooling stage of the DC casting process. The mechanical behavior of solidifying shells and the hot tear formation under applied tensile loads were measured and the occurrence of hot tearing was observed. Temperature in different locations of the casting, applied load and surface strain were monitored during the tensile tests conducted on aluminum alloys AA5182, AA6111 and AA3104. The microstructure of the tested samples was examined using the optical microscope to evaluate their columnar or equiaxed aspect and their effect on the mechanical response of the alloy. A special emphasis has been given to the evaluation of fractions solid existing in the castings at the start of the tensile tests, taking into account the local temperature, thermal gradient and cooling rates experienced. It was found that excessive grain refiner additions decreased the strength of solidifying shells because of the increased level of porosity induced by easier nucleation of new phases (gas included). It was also observed that cooling rates increased with the level of grain refiner, a phenomenon that was associated to the higher number of contact points obtained with small equiaxed grains. Finally, the concept of a stress based criterion for hot tearing was reinforced by the strengths obtained on not grain refined AA5182 and AA6111 showing similar fraction solid near the surface, but significantly different grain sizes.

Jan 1, 2006

By W. C. Patrick

The Spent Fuel Test-Climax (SFT-C) was con- ducted to evaluate the feasibility of retrievable deep geologic storage of commercially generated spent nuclear-reactor fuel assemblies. One of the primary aspects of the test was to measure the thermomechanical response of the rock mass to the extensive heating of a large volume of rock. Instrumentation was emplaced to measure stress changes, relative motion of the rock mass, and tunnel closures during three year of heating from thermally decaying heat sources, followed by a six month cooldown period. The calculations reported here were performed using the best available input parameters, thermal and mechanical properties, and power levels which were directly measured or inferred from measurements made during the test. This report documents the results of these calculations and compares the results with selected measurements made during heating and cooling of the SFT-C.

Jan 1, 1986

By Xingye Guo, Yeon-Gil Jung, James Knapp, Zhe Lu, Jing Zhang, Li Li

La2Zr2O7 is a promising thermal barrier coating material due to its low thermal conductivity and superior high temperature stability. In this work, Bilayer La2Zr2O7 and conventional 8 wt% yttria stabilized zirconia (8YSZ) coatings were deposited using plasma spray technique. Both singlelayer La2Zr2O7 and double-layer 8YSZ/La2Zr2O7 coating architectures were designed. Thermal cycling and thermal shock tests were used to evaluate coatings’ thermomechanical properties. All La2Zr2O7 coats were delaminated in the furnace cycle test in less than 20 cycles. This is because residual thermal stresses accumulated during thermal cycling. In the jet engine thermal shock (JETS) tests, the SCL La2Zr2O7 and DCL dense 8YSZ/La2Zr2O7 coatings were fully delaminated. In contrast, the DCL porous 8YSZ/La2Zr2O7 coating sample only partially delaminated on the edge. This is because of the porous 8YSZ layer provides strain compliance. The findings will help to propose efficient thermal barrier coating systems.

Jan 1, 2016

By K. C. Mills, P. N. Quested, A. P. Day, R. F. Brooks

"Methods have been developed to measure the physical properties of molten materials relevant to the fluid flow in high temperature processes. Data for the densities, viscosities and surface tensions of Al-, Ni- and Fe-based alloys are compared with (i) values for the pure metals and (ii) estimated values obtained from models making use of chemical composition of the alloy. Experimental values for metallurgical slags are also given and compared with estimated values.1 IntroductionPhysical property data has proved very useful in improving process control and product quality. For instance, in the continuous casting of steel the viscosity (TJ) of the mould flux is important since it determines (i) the optimum casting conditions, nVc = 2.5±1 dPas (m min-1) where V c is the casting speed and (ii) the level of slag entrapment (which leads to inclusions) in the metal. Thus data for properties like viscosity are exceedingly useful in understanding the process and the problems encountered and the causes of defects and problems.Another interesting development which has helped to increase our knowledge of processes and improve process control and product quality is the development of mathematical models of the fluid and heat flow in the process. These models have been developed to the stage where one of the prime requirements is for good physical property data for the industrial materials involved. Recently, Oxley [1] has shown that the use of reliable, experimental, property values for the commercial alloy in a commercial software package produced a significant improvement in the prediction of casting defects. Thus reliable property data are required for liquid metals but also for (i) liquid slags since many processes involve the use of a slag to refine and protect the metal or to lubricate the mould and (ii) refractories, sand and investment moulds."

Jan 1, 1999

By M. Q. W. Jones

This paper presents a compilation of physical properties of rocks from the Bushveld Complex. The database consists of more than 900 measurements each of thermal conductivity and density. The data are well distributed from localities around the Complex and most rock types are well represented. Thermal conductivity and density are shown to vary widely in the ranges 1.8-4.2 W m-1K-1and 2600-4200 kg m-3respectively. Although only 190 heat capacity measurements are available, this parameter is quite uniform for most rock types present, 800-900 J kg-1K-1, except for chromitite, which has a lower average, 750 J kg-1K-1. Rocks encountered in deep platinum mines are particularly well characterized and this has important implications for prediction of mine refrigeration requirements. The heat flux into a semi-infinite region with properties typical of the Bushveld Complex as a function of time is substantially lower than an equivalent model for the Witwatersrand Basin.

Jan 1, 2015

ABSTRACTFor the binary system copper-lead two relationsEquation 1andEquation 2have been derived for the activities of copper and lead at compositions and absolute temperatures within the liquid region of the phase diagram.These relations give, with greater accuracy than is given by previously published relations, the activity-composition temperature variations for all regions of the phase diagram of interest to metallurgists.These relations are essentially simple forms of the Margules equations but with linear temperature dependence applied to their coefficients. This has been done in such a manner that a phase diagram obtained from these relations agrees well with the data available for this system. The methods of obtaining the relations and constructing a phase diagram from them are both given in detail. The enthalpies and entropies of mixing are compared with those derived by other methods.

Jan 1, 1971

By V. L. Mitsopoulos

This paper provides a summary of tailings disposal techniques and the improvements that have been made through the introduction of thickened tailings disposal. The general properties and characteristics of thickened tailings are described, as is a design process for selecting appropriate technologies for thickening, pumping, transporting and storing tailings. The factors affecting the selection of an appropriate disposal site and operational considerations for the effective utilisation of tailings storage areas are also documented.

Jan 1, 2006

By Jonathan Matthews

Efficient and effective management of mine tailings is essential for continued successful development of Alberta?s vast oil sands resources. Syncrude Canada Ltd. continues to research novel tailings management techniques in an effort to improve production efficiency and environmental sustainability. During the summer months of 2001, Syncrude Canada Ltd., in collaboration with members of the Canadian Oil Sands Network for Research and Development (CONRAD), conducted field-scale trials of thickened tailings technology at Syncrude?s Aurora mine, north of Fort McMurray, Alberta. This paper provides an overview of the test program including discussion of objectives, test configuration, and program observations. 0Data collected during the field trial indicate that substantial swings in feed slurry composition challenge effective thickener operation. When coarse mineral solids dominated slurry composition, thickener rake torque rose to unmanageable levels. It was determined that the end-of-pipe depositional characteristics of thickened oil sands slurry were generally consistent with present understanding of oil sands tailings slurries. After shear, thickener underflow product exhibited very shallow beach angles and a limited capacity to keep coarser particles in suspension indicating that stacking of ?paste-like? thickener underflow product from a conventional thickener is not practical in an oil sands setting unless process adjustments can be made to increase the underflow density and/or preserve the initial high yield stress of the underflow during transport and deposition. These technical challenges notwithstanding, Thickened Tailings technology offers considerable promise for recovery of warm water from oil sands process tailings.

May 1, 2003

By Graham Swan

The case is presented for the development of a spray-on liner for ground support, but only in the context of a new mining system, consistent with the technical and business case advantages of liners compared to alternatives. Over the past 10 years much effort has been expended in specifying and testing the mechanical/environmental properties of various liners, without actually fulfilling any mining system requirements. The results have been generally disappointing, with no consistent and sustained application in a dayto- day production environment being achieved, anywhere. Central to this shortcoming has been the failure of mining/liner ma nufacturing companies to realise that screen/mesh or shotcrete cannot simply be replaced with thin, deformable liners: success will depend upon closely defining and evolving a new, liner- functional mining system. The paper begins with a discussion of some fundamental technical capabilities and constraints associated with 3M Canada?s liner material that has been developed in partnership with Falconbridge Limited. Intended applications for this liner include the support of bursting ground associated with deep mining conditions. With safe application and consistent performance in mind, the paper argues for a new mining system that derives in the first place from best quality drilling and blasting practices. Taking this as a given, a system for waterscaling and liner application prior to mucking out is proposed, followed by bolting through the liner while arranging for the bolts to be explicitly connected to the liner. Some logistical and equipment related challenges of such a mining system are then reviewed and discussed in the context of the business case for liners. It is concluded that this approach, if successful, will provide the greatest benefits in the areas of safer mining, due to reduction in worker exposure, and in reduced mining cycle times.

May 1, 2003

By John Marsden, John Mansanti, Jim Arnold, Mike Gleason

DOUG HALBE: We're not quite to the end of our session, but we're close. We've had a lot of fun with some of these spill ideas. But these are serious problems, and I think we might be able to benefit by continuing to compile these. Several years ago, the metallurgists at the various operations of Gold Fields Mining Company had a newsletter that came out every two months for several years. This publication consisted of short articles by the staff at the various operations, plus a few others, on problems they'd had and how they solved them. One very useful article, "Things We'd Have Done Differently at Chimney Creek," was written shortly after start-up. John Marsden was the editor and John Mansanti contributed to it, as did Jim Arnold (our distinguished co-chair) and Mike Gleason. I would be interested, with the permission of the audience, in editing that article to make it a little bit less abrasive and putting it into the record here. I think it's a useful SME function to maintain a list of things we've done wrong in plant design, things we don't want to do again. If we have another open session in the future, would others be willing, even anonymously, to contribute, bring slides, and say "Hey, look at the goofs we made?" [laughter, followed by support from the audience] Okay, we'll plan on that. And we'll try to include the Chimney Creek list in the transcript of this session-perhaps edited a bit.

Jan 1, 1998

By W B. Gregg

"A review, update, and expansion of Thiokol’s presentation at BAl’s Fiih High Tech Seminar titled ‘ADetonator - An Era of Precision in All-Electronic Detonators” is provided herein (and should be considered as a supplement to that publication). Thiokol is currently in the development and field evaluation phase of activities for our ACCUBLASTTM all-electronic detonator. The ACCUBLASTTM detonator uses a semiconductor bridge (an electronic match) in place of a conventional hot wire to initiate a safer, less sensitive material, titanium subhydride potassium perchlorate. The device is programmable to provide blast delays in one millisecond increments ranging from 1 to 500 milliseconds. The ACCUBLASTTM detonator combines an all-electronic programmable timer coupled with a semiconductor bridge to ensure detonation timing accuracy with +I00 microsecond precision. Initial development and field testing have been completed. These tests have verified ACCUBLASTTM detonators’ precision."

Jan 1, 1995

By M. A. Belokrys, F. O. Milovich, D. D. Aksenova, V. A. Ignatkina, V. A. Bocharov, A. A. Kayumov

Copper remains one of the most sought-after metals in the industry. Tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that occur in pyrite copper, copper-zinc and polymetallic ores are an additional reserve for increasing technological parameters of flotation. Pyrite mass (85% and more) has similar flotation properties to other sulfide minerals, and imperfection of reagent regime is a common problem that occurs during quality copper concentrate processing. Due to tennantite's and chalcopyrite's differences in flotation properties with butyl xanthate at pH > 10, tennantite often reports to the flotation tails. Hight alkalinity of the medium increases the oxidation level of sulfide minerals, thus increasing the concentration of S2O3 2-, SO3 2- SO4 2-. At processing facilities in the Russian Federation, the concentration of thiosulfate ions in pulp is in the range of 0.5 to 1.5 g/l and higher, which leads to a decrease in flotation activity of the tennantite. The effect of butyl xanthate (as standard), thionocarbamate, dithiophosphate and M-TF (a mixture of dithiophosphate and thionocarbamate) on monomineral (tennantite and pyrite) flotation in the presence of sodium thiosulfate was studied. The variable parameters of the "thiosulfate-collector" flotation complex were thiosulfate concentration (100-900); pH (8-12,5). The scientific methods included contact angle for hydration assessment; TEM for surface studies; UV spectroscopy and iodometric titration for solubility control. Comprehensive studies have established a connection between the concentration of thiosulfate ions and tennantite flotation selectivity. Flotation activity of tennantite is higher at pH 8 with a thiosulfate concentration under 300 mg/l. Pyrite remains active with butyl xanthate under the same conditions. TEM images of the surface films of the collectors on pyrite were acquired at pH 8. The MTF provides the biggest difference in adsorption, wettability and flotation activity between tennantite and pyrite at pH 8 and thiosulfate concentration under 300 mg/l, in comparison with butyl xanthate. The results of the research will be applied to improve selective reagent regimes of tennantite minerals flotation. Keywords: Tennantite, pyrite, chalcopyrite, sphalerite, flotation, sulfhydryl collectors, thiosulfate, adsorption, mechanism, reagent regime

Jan 1, 2020

By P Breuer, X Dai, A Bergamin, D Hewitt

"Copper-ammonia-thiosulfate?leaching of gold has been researched for several decades as a potential alternative to cyanidation. However, this technology has not yet been applied commercially due to many challenges such as complex solution chemistry, reagent degradation and losses, system instability with losses of precious metals and difficulties in gold recovery from the leachate. Progress has been made at CSIRO in tackling some of these challenges including:better understanding and control of the leach conditions to minimise reagent losses whilst maximising gold recovery use of strong base ion exchange resins to recover the gold strategies to deal with polythionates that adsorb competitively with gold on ion exchange resins development and evaluation of process flow sheets.As a result there has been increased interest from the gold industry and renewed activities to develop thiosulfate based processes for gold recovery. One application area, which has been developed to the point of piloting, is the treatment of gravity gold concentrates using a copper-ammonia-thiosulfate leach with ion exchange recovery of the gold thiosulfate. This paper describes some of the advancements in the development of a potential process flow sheet for this application.CITATION:Dai, X, Breuer, P, Hewitt, D and Bergamin, A, 2013. Thiosulfate process for treating gold concentrates, in Proceedings World Gold 2013, pp 61-70 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By O. Celep, H. Deveci, Ersin Y. Yazici, F. Ahlatci

"There are increasingly stricter environmental regulations imposed for use of cyanide leaching for the extraction of gold from ores. Alternative lixiviants to cyanide, preferably with low toxicity, have been extensively studied. Thiosulphate has emerged as one of the most suitable alternative leaching agent in place of cyanide due to its low toxicity and technical attributes e.g. fast leaching kinetics, high gold extractions from carbonaceous ores in particular. High solubility of most copper minerals in cyanide solutions results in low gold extractions due to excessively high consumption of cyanide. In contrast, low reactivity of copper minerals in thiosulphate solutions makes thiosulphate leaching potentially suitable alternative for treatment Cu-bearing gold ores. The extraction of gold/silver from a copper-bearing pyritic gold concentrate (62 g/t Au, 110 g/t Ag and 0.3% Cu) in thiosulphate solutions was investigated in this study. The concentrate is composed of predominantly quartz (25%) and pyrite (32.7%) as well as sphalerite (5.37%), galena (2.12%) and anglesite (1.13%). Other minor minerals are arsenopyrite, chalcopyrite, covellite and bournonite. Previous studies by the authors indicated that the concentrate did not respond well to cyanide leaching (i.e. 45-46% Au/Ag at 1 g/L NaCN). The effects of concentration of ammonia (0.2-1.5 M NH3), thiosulphate (0.1-0.75 M S2O3) and copper (0-20 mM CuSO4) on the extraction of gold and silver over 8 h. was investigated. Increasing the concentration of thiosulphate and ammonia substantially improved the rate and extent of gold leaching while high copper levels produced an adverse effect particularly at low concentration of thiosulphate (i.e. 0.1 M). Complete extraction of gold was achieved under suitable conditions. In contrast to gold, silver extractions remained consistently at low levels (i.e. 28%). These findings demonstrated that thiosulphate leaching could be used to achieve acceptable levels of gold extraction from the copper-bearing pyritic gold concentrate."

Jan 1, 2018

By Kazutoshi Haga, Batnasan Altansukh, Shirchinnamjil Nyamdelger, Atsushi Shibayama, Narankhuu Ariunbolor, Gunchin Burmaa

In this study, the authors investigated the capability of an acidic thiourea solution and silicon-organic polymers (PSTM-3c, PSTM-3T) as ion-exchange resins to recover of gold from gold-bearing ore concentrates. Firstly, elemental gold present in flotation concentrates was dissolved by leaching with a solution of nitric acid and thiourea under the optimized conditions. The best result on gold thiourea leaching was obtained under a nitric acid concentration of 2 N, thiourea concentration of 2 %, and oxidant (Fe2(SO4)3) concentration of 3 %, solid:liquid ratio (S:L) of 1:20, leaching time of 6 hours at 20 °C with a gold recovery of 93.7 % for a gold flotation (unroasted) concentrate. For the roasted gold concentrate, the dissolution of gold was 94.8% under the optimized leaching condition as nitric acid concentration of 0.5 N, thiourea concentration of 2 %, and the oxidant concentration of 1 %, S:L ratio of 1:10, leaching time of 4 hours at 50 °C. Secondly, a series of sorption tests was carried out on a pregnant leach solution containing gold complex Au[S=C(NH2)2]2+ using silicon-organic polymers (PSTM-3c and PSTM-3T), respectively. The effects of solution pH, adsorption time and temperature in the sorption process are also studied. As the results, the PSTM-3c and PSTM-3T polymers were adsorbed about 94.4 % and 95.1 % gold from the pregnant leach solutions under the optimum sorption conditions, respectively. It was found that the both PSTM-3c and PSTM-3T polymers were effective for the recovery of gold from the pregnant leach solution of thiourea. Adsorption activity of the PSTM-3c and PSTM-3T polymers was confirmed by new peaks near 1700 cm-1 in the FT-IR spectrum of the gold-adsorbed polymers, respectively.

Jan 1, 2014

By Cheryl M. McInnes, Graham J. Sparrow, James T. Woodcock

Three composites, assaying about 3 g/t Au and 0.75% Cu, were investigated. Each contained oxide copper minerals, iron oxides, and silicates. One composite also contained copper and iron sulphides. Maximum gold extractions by thiourea leaching were obtained after copper removal by acid pre¬leaching at pH 1.5 and redox potentials of 400 mV (Pt versus SCE). Best thiourea leaching conditions were pH 1.5, redox potentials over 200 mV, and 0.4% thiourea. This gave 90% gold extraction in 2 h with thiourea consumptions of 25 kg/t. Lower potentials gave poorer extractions. Ferrous iron additions before leaching halved thiourea consumptions. Longer leach times and the presence of sulphide minerals sometimes resulted in reprecipitation of gold.

Jan 1, 1989

The U.S. economy showed further strength during the third quarter of 1983, continuing the upward trend discussed in the last two issues of Minerals and Materials. The National Association of Purchasing Management composite index increased to a 10-year high of 67. 1 in July. (A value of 50 or greater indicates expanding industrial activity.) The index, a weighted composite of new orders, production, employment, vendor performance, and inventories, is derived from a survey of purchasing agents for about 250 industrial firms. Investment and Other National Economic Indicators The strong consumer surge of second quarter 1983 was reinforced during the third quarter by the performance of private investment. Because of this, many analysts became more optimistic about the strength of the recovery and its potential for being sustained. Capital investment growth, negative since 1980, was positive for every investment component in the third quarter of 1983. Preliminary estimates indicate a real increase of $1.4 billion (at an annual rate) in private investment expenditures on nonresidential structures, an increase of $4.3 billion (at an annual rate) for producers' durable equipment, and an increase of $4.8 billion (at an annual rate) in real inventory levels. The second quarter 1983 increase in expenditures on producers' durable equipment was the first indicator that investment recovery would occur during the rest of the year (table 1). Corporate profits in total manufacturing increased $6.5 billion from first quarter to second quarter 1983 (table 2).

Jan 1, 1983

By Walter Bonsack

THE CHAIRMAN.-This is the third and last session of the Institute of Metals Division's Symposium on Secondary Metals, and certainly the best of those that I have attended in the last few years. I would say that the increase in interest in secondary metals is quite noticeable by the steadily increasing attendance at these meetings. We have heard about the necessity of utilizing salvaged materials, but we still speak about them as low-grade, or down-graded materials. We still have the wrong perspective. We must willingly admit that these materials are valuable; we cannot go on using the choicest primary metals as morsels for our economic diet in a war of such unbelievable dimensions. This brings up the question-why are we so selective. The answer certainly is not that we know nothing else will do, but rather that we do not know what else will do. To be honest, we should admit our lack of knowledge concerning our complex alloys. Compared to the organic chemists, we metallurgists are very conservative, and the sooner we realize this and start to overcome it the better, because if we do not eliminate this difference, many customers of the metals business will go over to the plastics. If we take for example the development of aluminum alloys, you will see what I mean. From the binary aluminum alloys of 1920, we have progressed to ternary and quarternary alloys in the 1930's. We are only now beginning to use more complex alloys as we are forced to learn more about the effect of various elements on existing alloys. The effects of these elements should be studied now. They can be studied by two methods of approach. The usual method is to start from the base alloy and add various elements one by one in increasing amounts and study the resultant changes in properties. This is a tedious, long way. The other method which the smelters frequently use is to take the off-grade heats and study their characteristics. While the producer of primary alloys often has difficulties in alloying certain elements with the alloy under investigation, the smelter often finds them well alloyed in his raw materials and has no difficulties at all. Elements such as lead are difficult to alloy with aluminum and they tend to segregate severely. However, the amount which will remain alloyed in the metal is usually found in some "secondary" aluminum alloys. If one considers such concentration as the saturation, then by dilution with the same type of alloy, but free of such element, one can produce numerous intermediary alloys for investigation. In this fashion one is fairly certain to get uniformly spaced concentrations of the element under investigation. Similar cases probably exist with other metals. Nevertheless, the amount of work necessary to study all possible combinations is still tremendous. Necessity forces us now to utilize alloys which contain more elements than we are accustomed to. It is, therefore, necessary to study carefully the more complicated alloys. In secondary aluminum we are working and using the alloys which contain as many as 6 to 10 elements and we have learned over a period of several decades to balance

Jan 1, 1943