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By Courtney A. Young

Cyanide is a fast-acting, highly toxic substance but, at the same time, is deemed essential for sustaining life as well 'as our standard of living. In this manuscript, the facts about cyanide are presented beginning with a brief history and definition and ending with a discussion on cyanide alternatives. Other topics include speciation, physical characteristics, toxicity, manufacturing, cyanogenics, cyanide cycle, separation, destruction, and markets including those outside the mining industry. Emphasis, of course, is placed on gold production by leaching and how it is influenced by ore type, mineral characteristics and economics as well as its advantages and disadvantages.

Jan 1, 1998

By C. G. McLachlan

Abstract This paper deals with the application of the cyanide process to recover gold from a pyrite concentrate produced by means of differential flotation. This concentrate before cyanidation contains from 0.09 oz. to 0.14 oz. gold per ton, of which only about 60 per cent is recoverable. The rest is so fine that it remains interlocked in the pyrite and therefore is not acted on by the cyanide. The concentrate also contains about 15 per cent pyrrhotite and 0.4 per cent chalcopyrite, both of which are cyanicides. The cyanicidal effect of the pyrrhotite is inhibited by preacracing the pulp with lime, and maintaining a high lime alkalinity during cyanidation. The effect of the chalcopyrice is reduced as far as possible by removing those particles which are free by means of a further flotation step immediately prior to cyanidation. This involves the flotation of some very fine material. After nullifying as far as possible these two cyanicides, the concentrate is cyanided directly, i.e., without being roasted. This leaves the pyrite available for subsequent sale as a source of sulphur dioxide and sulphuric acid, and the entire residue of the cyamde plant, amounting to about 500 tons per day, 1s now being disposed of in this way. Prior to deciding on direct cyanidation, a number of laboratory roasting tests were made. These showed chat, 1f proper control were exercised, a better recovery of gold could be effected from the roasted product than by the direct method of treatment. The tests also showed that the capital cost o the plant would be much higher than that needed for the procedure adopted. The possibility of subsequently selling the pyrite for its sulphur content would also have been eliminated. Introduction A previous paper has described in considerable detail the application of the flotation process to improve gold recovery from Noranda's milling ore, and in so doing has covered the production of an auriferous pyrite concentrate. The present paper deals with the recovery of gold by cyanidation from that concentrate. This gold, though intimately associated with the pyrite, can, for metallurgical purposes, be considered as all occuring in the native state.

Jan 1, 1946

By T. H. Oxnam

INTRODUCTION. THE predominating value of the ores now being treated by the Palmarejo and Mexican Gold Fields, Ltd., is silver, although some gold is also carried. The present method of treatment consists of wet-crushing and concentrating, followed by the cyanidation of the unroasted sands and slimes. The sands are treated by leaching and the so-called accumulated slimes by a system of agitation and decantation. It is only within very recent years that the cyanidation of unroasted silver-ores has been commercially successful. In fact, at the time operations were begun at the cyanide-plant at Chinipas, February, 1902, I knew of no other leaching-plant treating similar ores successfully. The cyanide treatment of the Palmarejo ores differs but little from the ordinary practice in cyaniding gold-ores; and perhaps but little, if any, new information concerning the metallurgy of silver is to be gleaned from it. PALMAREJO MINE. The Palmarejo mines are located in the southwestern part of the State of Chihuahua, Mexico, on the foothills of the Sierra Madre mountains, at an elevation of 3,200 feet. The mills, 12. miles distant, are situated on the Chinipas river, near the town of Chinipas, which is about 150 miles northeast of Agiabampo, on the Gulf of California. Supplies are shipped via this port as this route is the best and most direct to the property. The ore-bodies in the Palmarejo mines have been deposited. along a series of rock-fractures, caused by an intrusion of eruptive rock. The most important of these fractures or fissures, both in width and value, are the Prieta and Blanca veins, which.

Jul 1, 1905

By Mark R. Lamb

THE various methods of treating pulp in air-agitation tanks offer problems for experiment and study which are fascinating as well as practical. The usual method heretofore has been to fill each tank in turn, agitate the mixture the required period and then discharge the treated pulp into a storage-tank, from which it. is drawn to the filter as required. A later method is to run the pulp from the tube-mill, classifier, thickener, or settler into the first of a set of tanks, and thence continuously or in series through the remaining tanks, finally drawing off the pulp to a continuous filter, or to a pulp-storage tank if the filter is of the intermittent type. It is this method which I propose to discuss here in a preliminary way, with the idea of going exhaustively into the examination of the results of a series of experiments in a later paper. It may be of interest to note that the design of a cyanide-plant has recently been completed in which the estimated cost of the agitation-tanks, storage-tanks, and pumps was 30 per cent higher for the charge-agitation arrangement than for the series plan. The first question in studying the series method is, "What is the actual period of treatment undergone by the pulp?? One first supposes that by chance some of the pulp may get through with little or no treatment, while other portions may stay in the tanks a needlessly long period. The former is not probable or even possible, and the latter is, practically, true to only a limited extent. The greater the number of tanks the greater is the percentage of chance that all the pulp will be treated equally. Without going into the mathematical analysis of the problem (which is of little value, since it is based on problematical premises), its important terms may be clearly grasped by thinking of, or " visualizing," the conditions when,

Jan 1, 1910

By Yazen Khasawneh, Osvaldo P. M. Vitali, Mohammad Nassim

Wind turbines are subjected to complex form of cyclic loadings with variable amplitudes and frequencies. The cyclic loading and the accumulation of plastic strains with the number of cycles will result in degradation of the foundation soil stiffness. The foundation stiffness degradation will result in a shift (reduction) of the fundamental frequency of the wind turbine. Although this issue is recognized in the guidelines for wind turbines foundation design, no specific provisions are provided in the guidelines to consider the long-term stiffness degradation. In this paper, a practical procedure to consider the long-term cyclic loading effects on the stiffness of wind turbine foundations in cohesive soil is proposed. The procedure is based on 3D FEM modeling and reliable empirical methods to estimate the stiffness degradation due to the cyclic loading. Using the proposed procedure, the long-term performance of the P&H tensionless pier foundation with and without a reinforcing collar at the top of the pier is assessed. The numerical results demonstrated that the long-term performance of the P&H tensionless pier foundation with a reinforcing collar at the top of the pier is outstanding with negligible long-term degradation of the foundation stiffness.

Sep 8, 2021

By C. -S. Jiang

In most copper refineries, addition agents are added at predetermined rates with no further monitoring of their activity or concentration in the electrolyte. Increasingly stringent cathode quality requirements, and a desire for better process control in tankhouse operations, have recently directed a number of refineries to search for a better addition agent control strategy. Extensive development work has been carried out at the Noranda Technology Centre for the monitor in of glue and thiourea in copper refinery electrolyte using cyclic voltammetry (cv~. Data from both synthetrc and commercial electrolytes are presented, showing the ability of CV to produce reliable and easily identifiable fingerprints of addition agent concentrations in copper refinery electrolyte.

Jan 1, 1991

By A. G. B. Hayes, C. L. Renzoni

"AbstractThis paper provides a rough outline of economic expectations for the near future and then goes on to discuss their effect on the expected demand for metals, using zinc, copper, nickel and aluminum as detailed examples.IntroductionMINING, as you are all painfully aware, is a cyclical business. We believe that it will remain so as long as there are economic cycles.The fortunes of the industry are tied to those sectors of the economy where decisions can be postponed until more favourable times: automobiles, housing, appliances, inventory building and capital spending. Over the past two years, while U.S. GNP fell by 3.8%, automobile production declined by 31 %, from 9.7 million units in 1973 to 6.7 million in 1975. Housing starts plummeted some 43% from 2.1 million units in 1973 to 1.2 million in 1975. Little wonder that U.S. copper consumption fell by 37% and zinc consumption by 38% over the same period.With the rest of the world's economies moving in unison with that of the United States, it is also not surprising that times have been tough for mining.Arthur Burns, chairman of the U.S. Federal Reserve, contends that each recession sows the seeds of its own recovery. The worse the recession, the better the subsequent recovery. If this is true, then the lot of the mining industry should improve significantly over the next two to three years."

Jan 1, 1977

By Roy A. Grancher

CYCLING WITH CEMENT "THE WHEEL IS COME FULL CIRCLE" Shakespeare's King Lear Act V, Scene 3, Line 176 The time clock of the cement industry has been turned back to the early 1950s. After the trials and tribulations of the decade of the Sixties, the hands now stand where they did just over twenty years ago. Cement shipments have steadily increased, with a record 419 million barrel level (78.8 million tons) being reached last year. Plants are operating at average utilization rates in excess of 85 percent of rated capacity. The spread between supply and demand has narrowed to where a definite shortage of cement now exists within the industry. The notable and unfortunate difference between the two periods however is that, back then, cement's returns were a respectable 14 to 18 percent, whereas today they stand at less than half those levels. Insufficient return forms the present foundation of the U.S. cement industry. This lack is destined to have a cumulative effect. Just as the industry's balance between supply and demand is returning to favorable proportions, promising a period that has historically and now should generate those profit levels required to modernize and provide for capacity addition, cement instead finds itself frozen by federal price controls into the semi-depressed condition that has existed for over a decade and from which it was just starting to emerge. Capital is not attracted to continued low returns, and increasingly restrictive pollution control measures are necessitating great non-productive expenditures be made as definite costs to stay in business. Even a clouded crystal ball would reveal that additional cement plant closings can be expected.

Jan 1, 1972

By D. A. Dahlstrom

Although the liquid-solid cyclone is a relatively recent innovation in the field of coal preparation, various authors have already indicated three distinct applications to operations encountered in the modern tipple. Driessen's articles and work at the Dutch State Mines exhibited its possibilities in the beneficiation of fine coal with apparently high efficiencies down to the 200-mesh fraction. 1 2 3 4 Other publications point out its use as a recoverer, thickener, and preliminary dewatering agent of fine coal which in too many cases is being wasted due largely to former high operating cost limitations 5 6. Finally, certain authors have emphasized the practicability of applying the cyclone to the elimination of coarse and fine solids from water slurries in the tipple in order to produce a water suitable for recycle purposes containing only minute particles far below the 200-mesh size.6 This would result in a closed water system for many cases, with its accompanying economic and operating advantages to locations where water quantity and quality problems are severe; better operation of washing equipment using a consistent water devoid of injurious fine particles; lowered maintenance costs due to the lesser abrasion resulting when the fine abraiding particles are removed; and the greater ease of disposing of refuse streams of reduced volume containing greater percentages of solids.

Jan 1, 1949

By Kingman, Robert I.

SUFFICIENT testing has been .performed with the Dutch State Mines Cyclone for thickening and desliming flotation feed at the concentrator of the National Lead Co., Tahawus, N. Y., to prove its application for this work. It is the purpose of this article to present some of the test results, operational details and advantages of cyclone thickening and classification. The metallurgy of the mill operation was described by Frank R. Milliken, assistant manager of the titanium division.

Jan 1, 1950

By P. R. Taylor

Recent research by the investigators has evaluated the oxidation roasting of refractory gold concentrates in the presence of hydrated lime. (Taylor, 1990, 1991, 1992, 1993). These results have indicated that it may be possible to roast concentrates in such a way as to contain nearly all of the sulfur and arsenic in the roaster calcine and that cyanidation may be possible. To further evaluate the behavior of this type of roasting system a laboratory cyclone reactor was built and operated using pyrite and hydrated lime as a .model system. Approximately 50 years ago, the principle of cyclone firing entered practical boiler construction. The appeal of the cyclone configuration was that it afforded the flash combustion process greater efficiency due to turbulence-induced increased mass transfer, heat exchange, and combustion rates.

Jan 1, 1994

By Norman A. Jull

"IntroductionThe scope of this paper is intended to deal mainly with cyclones in grinding circuits. However, the section on Cyclone Equipment, contains more general descriptions, to cover most of the cyclones used in mineral separation plants.Cyclones as heavy media separation vessels are discussed by Mark Freberg (this volume). Their use in tailings deslirning is discussed by P.C. Lighthall, eta/. (this volume).Cyclone EquipmentCyclone TerminologyApexObviously, the apex of a cone is the smallest end. However, with cyclones the term is usually used for the fitting which is attached there to control discharge of the underflow stream.Note that the cyclone need not be so mounted that the apex is the lowest point, although that is the most common method. Keeping the apex below the rest of the cyclone helps avoid plugging when the underflow contains very large particles and the tonnage of underflow solids can fluctuate.Various devices for adjusting apex diameter or otherwise controlling the underflow are discussed later under ""Cyclone Construction"".BypassingThe transport of a portion of feed slurry directly to underflow so that classification is bypassed by that portion of feed.This action is fundamental in any hydraulic classification, whether gravity or centrifugal, because the large particles going to underflow have some void volume between them, which remains filled with feed slurry.D50By definition, D50 is that particle size which has an equal probability of going to overflow or to underflow.It is calculated by drawing a curve of recovery vs particle size and noting the size at which 500Jo recovery occurs.This may be done equally with corrected or with gross recovery (see below) and the resulting value should therefore be identified as d50c (corrected d50) or as d500 (gross d50).Note also that it is common in industry practice to plot size analysis data on the retained size rather than on the average of passing and retained (the middle of the size band). To portray sizing alone it makes no difference, but to read a D50 value off a curve of corrected or gross recoveries, it is essential to plot those values on the average size of each band."

Jan 1, 1989

By John L. Watson

The processes of magnetic separation and cyclone classification are common in the mineral processing industry, and frequently the two are found in consecutive stages in the beneficiation of a magnetic mineral ore. The application of a magnetic field across the cyclone, to combine the two stages in treating a magnetic mineral pulp, has been investigated with a view to possible practical applications in the mineral industry The results of this research reveal that magnetic particles can be manipulated within the cyclone body by the application of a magnetic field, and that magnetic grades may be significantly upgraded with recoveries in excess of 90%.

Jan 1, 1983

By Raymond L. Jones

With the inauguration of the open pit operation in Bagdad, plans were formulated for a large scale leaching operation. Dump stockpiling was started almost immediately, but actual production was not initiated until the spring of 1961. Like all neophytes, we started something about which, on a commercial scale, we knew next to nothing, either dump preparation or leach procedure, and as a consequence, we are still paying the piper. True, we had been through an extensive laboratory pilot program, but it soon became apparent that there was considerably more to increasing solution volumes than simple multiplication. Had we initially possessed our present acumen, the Cyprus Bagdad plant could be operated more efficiently and at a better profit. During the past several years, the art of dump leaching of copper has improved in many ways, primarily because of the application of scientific principles gleaned from general mining practice. Rigid pH control and the use of atomic absorption techniques for rapid," accurate assaying have probably played a leading role in this respect, although we cannot overlook the other sophisticated electronic controls lending improvement to acid addition and pumping, better piping materials, and lastly, the more efficient use of our pregnant liquors. Thin too, the years of experience have given us a greater understanding of dump behavior in general; and, we can, to a greater extent, measure, predict, and avoid some of the idiosyncrasies inherent in every dump. However, it is my firm belief that we will still be confronted with unexplainable dump behavior as long as we are involved in leaching. We have found our dump to be a wonderful money bank, but one that is capable of yielding a wildly fluctuating profit.

Jan 1, 1975

By Raymond L. Jones

With the inauguration of open-pit copper mining in Bagdad, Ariz., plans were formulated for a large scale leaching operation. Dump stockpiling was started almost immediately, but actual production was not initiated until spring 1961.

Jan 9, 1977

By Ross R. Bhappu

Anticipating a major power cost increase in 1990, Cyprus Copper Company decided to modernize the Miami Smelter at a cost of $92.5 million. The modernization project included the addition of an Isasmelt vessel for use as the primary copper smelter and the modification of the existing electric furnace to a slaglmatte separating vessel. The project was completed in June of 1992 and is currently operating at close to its design capacity. This paper provides a summary of the decision making process, a description of the project, a summary of start-up problems and solutions and the current status of the smelter operation.

Jan 1, 1994

By Jack E. Bailey

From a start in 1957, milling 3,000 TPD of copper ore, the Cyprus Pima Mining Company, which is located 20 miles south of Tucson, has expanded its operations four times, and is currently treating over 55,000 TPD of ore.1 The most recent expansion added a 14,000 TPD semi-autogenous concentrator to the operation. Shortly after startup in January, 1972, the semi -autogenous plant exceeded the designed tonnage rate.2 Ore from the mine is delivered to a 54 inch gyratory crusher and is reduced to a minus 8 inch product. From the crusher the ore is stacked on a surge pile and then reclaimed and fed to the two parallel grinding circuits. A 28 ft. diameter by 12 ft. long semi-autogenous mill and a 16.5 ft. diameter by 19 ft. long ball mill make up each grinding circuit. The semi-autogenous mills are in closed circuit with screens and the ball mill circuits are closed with hydro- cyclones. Rougher flotation follows the grinding operation. Concentrate regrinding and cleaner flotation is performed in Mill I, the older mill. The generalized flowsheet is shown in Figure 1.

Jan 1, 1975

By AIME AIME

THIS year's Chairman of the Institute of Metals Division is a relatively rare phenomenon in the metallurgical profession; he is an expert historian of metallurgy, he is a confirmed collector and student of old works on alchemy, chemistry, and metallurgy-vide: the famous Biringuccio and he is a profound student (with a somewhat idealistic slant) of recent trends in world affairs and in what some incurable optimists call civilization; and at the same time he is still possessed of a sense of humor. Incidentally he is also one of the bestknown nonferrous metallurgists in this country and abroad, and for fifteen years has been a willing worker in A.I.M.E and the Institute of Metals Division.

Jan 1, 1943

By A. Kalmes, B. Dehler, D. Kopp

Nutrien has six potash mines in Saskatchewan and has been proactive in maintaining the integrity of their tailings facilities through ongoing assessment, design, operation, inspection, and monitoring. Nutrien commissioned a system inventory and semi-quantitative risk analysis (SQRA) of all dikes to further environmental stewardship at their potash facilities. The inventory assessed nearly 100 dikes; each dike was rated according to a probability and consequence factor and assigned a risk score. The risk scores were used to develop a risk matrix for each of the six sites and risk-response actions for each dike and segment. The inventories and SQRAs will help each site assess priorities for investigation and risk mitigation, if necessary. The study results will also help Nutrien refine corporate wide tailings governance standards and demonstrate compliance with various governance regulatory obligations.

Mar 2, 2022

By Krishna Nand

For assessing the safety of structures during underground explosions, ground particle velocity gives the best damage criteria, and 100 mm/see of ground particle velocity has been internationally accepted as the threshold value of safety (no damage). Results of extensive controlled underground explosion experiments conducted by the author to study the effects of ground vibrations on specially prepared concrete blocks, and also on low rise buildings and dams showed that no damage normally occurred when ground particle velocities were less than 100 mm/sec. Analysis of a large number of accelerograms from a dam site in India also indicated that no damage occurred to normal structures when integrated ground particle velocities were less than 100 mm/sec. Major damage in well built structures like a dam was noticed for ground particle velocity as high as about 350 mm/sec. These results are also generally substantiated from damage data obtained for various structures during other earthquakes, including Elcentro (1940), Taft (1952), Parkfield (1965), and San Fernando (1971). These studies, therefore, suggest that the damage criteria during underground explosions and earthquakes are similar; and 100 mm/see of ground particle velocity seems to be the general threshold value of safety (no damage) against ground vibrations.

Jan 1, 1988