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By M R. Drumond

The present work presents a new theoretical interpretation of the flotation process, which can also be applied to other mineral processing physical unit operations. This interpretation is part of the æModelo OperacionalÆ (Operational Model) that was developed as an attempt to establish a new theoretical basis for mineral processing unit operations. In the case of flotation, a book was edited by one of the authors in Brazil (Mass Concentration by Froth Flotation, in Portuguese and Spanish).The model establishes a link between a natural phenomenon (migration of particles from the pulp to the froth) and a real industrial phenomenon (mass concentration by operational interference). In this model, flotation is viewed as a phenomenon of macromolecular mass transport (of particles) between froth and slurry phases. Mechanisms for mass transport and particle flow between phases as a function of the hydrophobic potential in each phase are discussed. By establishing the so-called equilibrium distribution curve between phases it is possible to calculate macroscopic balances that are related to metallurgical results, which in turn are a function of the operational line that is required by the process itself. The number of cleaning stages and their efficiencies can also be determined by simple laboratory-scale experiments.

Jan 1, 2005

By S. N. Opperman

Testwork at Goedehoop Colliery showed that fine coal, essentially?150 microns can be successfully beneficiated using froth flotation. Both conventional and column flotation were tested. It was found that the traditional stirred tank type of flotation machines used in conventional flotation produced the best recovery of fine coal. After extensive testwork it was decided to develop a flotation machine on Goedehoop Colliery that would combine stirred tank and quiescent column technology. It was thought that this design would give the best combination of recovery and selectivity. The Multicell was developed and is producing results acceptable for Witbank coal flotation. Keywords: Multicell, Witbank coal flotation, froth, stirred tank, quiescent column.

Jan 1, 2002

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By G J JAMESON

The flotation cell has undergone a number of changes since the process was first introduced in Broken Hill in the early years of this century. The development of the mechanical flotation cell is reviewed, followed by a discussion of more recent developments such as the flotation column, the air-sparged hydrocyclone, the Wemco-Leeds cell, the Bahr and Deister columns and the Jameson cell.

Jan 1, 1992

By Hinkley JT, Smitham JB, Nicol SK

Historical investigations of mineral flotation have highlighted the many factors which affect flotation. Some of these are related to the mineral, its degree of liberation (however defined), solution chemistry and flotation reagents. The complexity of the interactions between these factors often leads to uncertainty over whether the final grade/recovery results obtained in either laboratory or pilot scale tests are in fact the maximum recovery at a specific grade. The reason for this is that there has not previously been a general technique for establishing the floatability of an ore. This study describes the further development of the 'tree' flotation technique for minerals other than coal, and in particular its application to iron ores. Oxides have been chosen as a system of intermediate complexity between the simple coal system and sulphide minerals to illustrate the principles and develop the concepts. The 'tree' flotation procedure consists of the progressive flotation to completion of successive froth products, followed by reflotation to remove entrained material. It therefore represents an 'equilibrium' approach to floatability rather than a kinetic approach. By ordering the various products and tails in order of increasing grade, a cumulative curve of grade and recovery can be constructed against which an isolated batch or plant result on the same ore can be compared. In this investigation, a Jaspilitic iron ore was tested at various grind sizes to determine the 'best' flotation grade-recovery that could be obtained with a given set of reagent conditions. The separation characteristics of a process are best measured on a system which contains particles which behave as 'middlings' with respect to the process in question. For this reason a natural ore was chosen in preference to model systems in order to relate more readily to plant situations.

Jan 1, 1993

By M Brooks, M Nelson

A fundamental study was carried out on super pit sulphidic gold ore to establish the most influential flotation characteristics which were subsequently used in the development of an optimum flowsheet to achieve best economical recovery of gold. In developing the flowsheet, consideration was given to existing operational constraints in the treatment of the Super Pit ore. The fundamental study also included an innovative diagnostic investigation to establish the location and value of gold in the major mineral assembly of the super pit ore from a metallurgical rather than a mineralogical perspective. This study mapped a metallurgical fingerprint of the major types of super pit ore in relation to the location and association of gold.

Jan 1, 2000

By Adrian C. Dorenfeld

Laboratory data form the basis for the design of flotation circuits. These data, obtained from testing samples of the ore, should show the optimum con- ditions for concentrating the ore and the effects of change in process vari- ables. Among the more important variables commonly met in flotation practice are: Liberation Size-This is the particle size at which substantially all of the valuable minerals are detached from the gangue minerals. Reagent Additions- Experimental data will show the reagents used and their quantity, quality, and point of addition. Pulp Density-This is an important variable in the design of the flotation circuit because it is one of the factors determining the size and number of flotation cells. Flotation Time-The time necessary to make the separation into concentrate and tailing depends on such factors as particle size and reagents used and must be known for determination of the size and number of flotation cells in the plant. Temperature of Pulp-Temperature affects flotation reactions. Water at approximately room temperature is satisfactory for most flotation separations, but some minerals such as fluorspar are best floated in hot water. Type of Circuit-Many types of circuits can be designed, as discussed in detail later. The laboratory tests should provide data for design of the plant circuit best suited to the ore. Water-Knowledge of the quality of the future plant's raw water is important because water quality may drastically affect flotation results. If possible, flotation tests should be made using samples of the water to be used in the plant. Flotation results may vary with seasonal temperatures and with circulation of reclaimed water. Experimentation can show whether it will be necessary to provide for heating, cooling, treating, or reclaiming the water. Uniformity of Ore-The extent of variation of the ore in hardness, grind- ability, mineral content, and floatability should be investigated so that the designer can ascertain methods to overcome problems caused by ore variations. Settling and Filtration Data-To design the plant flotation circuits, settling and filtration rates and ultimate percentage solids of the various products must be determined. Corrosion and Erosion-Corrosion and erosion tests should be made on the flotation pulps, particularly if the pulps are acid or at an elevated temperature, so that suitable materials of construction can then be chosen.

Jan 1, 1962

By Frederick Laist

0. C. RALSTON, Salt Lake City, Utah.-I have merely glanced over this paper, consequently, I am hardly in a position to discuss it intelligently. There is one thing, however, that is of interest, that is, the claim that the oil mixture which they have chosen is the best adapted to the work at hand. I would like to ask Mr. Mathewson if they still feel that that is the case-if that really does give the best grade of concentration and the best extraction for the same money, compared to any particular oil mixture which they could get. E. P. MATHEWSON, Anaconda, Mont.-We are still using that mixture, and we consider it the most economical mixture used. DAVID COLE, El Paso, Texas.-I would like to ask Mr. Ralston if there are some other mixtures that would be better? E. P. MATHEWSON.-We are open to suggestions. 0. C. RALSTON.-My own paper on oils* calls attention to the fact that certain hardwood oils, especially the tars, are now being burned or wasted. A great deal of hardwood tar is available as low as 4 or 5 c. per gallon, that being its value as fuel under the boilers. As a matter of fact, a great deal of testing has been done with only the commercial products that are as a usual ride sold on the market. Very little hardwood tar is sold on the market. In asking a great many people who have tested flotation oils, I have not heard hardwood tar mentioned very often. I think I would add to that that the hardwood tars can probably be bought in quantity comparable with the sludge acid at Anaconda, and. should contain a greater proportion of the frothing constituent, and at a price fairly commensurate with what they pay for the sludge acid. E. P. MATHEWSON.-I would like to make a correction in one statement I made that there has been no change made in the mixture. This change has been made: We found that the amount of wood creosote in treating the sand from tables was extremely small, and we tried some experiments on a large scale, dropping it out and using simply the sludge acid and sulphuric acid. We found that this gave practically as good results as wood creosote. We use wood creosote in treating the slimes. We find it necessary in that operation. DAVID COLE.-I would like to ask, what is sludge acid?

Jan 10, 1916

By Grano S. R, Ralston J

It is the perennial problem most metallurgists face when examining data collected from laboratory float tests and plant surveys - there are more numbers than we know what to do with! The objective of this paper is to analyse and interpret a set

Jan 1, 1994

By B. Yu, Y. O. Oyediran, M. Robart

"This paper presents the latest flotation development testwork conducted in 2015 on the ‘B Zone’ samples from the Strange Lake Alkalic Complex (SLAC). Since the discovery by Iron Ore Company of Canada (IOC), metallurgical development has been under taken by a number of mining companies targeting various value metals, including yttrium, zirconium, niobium, and rare earths.Most recent, Quest Rare Minerals Ltd. (Quest) completed a Pre-Feasibility Study (PFS) in 2013 where the flowsheet was relatively complex and led Quest to explore alternative options. In 2014, the PFS flowsheet was simplified and one of the features introduced was pre-concentration by rougher flotation. The combined rougher flotation concentrate and slimes successfully recovered >90% TREE in 60% mass thus reducing capital cost and technical risks of the downstream hydrometallurgical processes. The latest flotation development testwork focused on achieving a pre-concentrate in which >80% TREE are recovered in 20% mass. Two separate reagent schemes, based on an ester phosphate collector (Clariant 1682) and a benzoylhydroxamic acid collector (Florrea 7510), were developed. Parameters evaluated in the development testwork included desliming, secondary yttrium and zircon collectors, depressants, temperature, conditioning temperature, time, and density, pH, sodium silicate type, cleaning, and flowsheet configuration. Both developed reagent schemes achieved the targeted metallurgy.INTRODUCTIONThe Strange Lake Alkalic Complex (SLAC) was discovered after geological survey and mapping studies by Geological Survey of Canada and Newfoundland and Labrador Department of Natural Resources between 1967 and 1980. Subsequent exploratory drilling programs by Iron Ore Company (IOC) in the 1980s found that the REE and high field strength element (HFSE) mineralization were within the central region of the SLAC which was named A Zone by IOC and later renamed Main Zone by Quest Rare Minerals Ltd. (Quest). Additional exploratory drilling outside the Main Zone by IOC and later by Quest, led to the discovery of B Zone, which was recognized as the most significant deposit of rare earth elements, yttrium, and zirconium in the SLAC. The B Zone Indicated Resources are estimated at 278.13 Mt at 0.93% total rare earth oxide (TREO) and Inferred Mineral Resources are estimated at 214.35 Mt at 0.85% TREO (Oyediran et al., 2014)."

Jan 1, 2016

By Priyanka Dhar, Kurt Aasly, Hanumantha Rao Kota, Hassan Bouzahzah, Maria Thornhill

The interest in investigating the processing characteristics of mineral deposits in Norway has seen an upsurge in the last decade. One of the major areas of interest is a huge copper deposit, operated by NUSSIR ASA located in the Repparfjord Tectonic Window in the caledonides of west Finnmark. This study reports analysis of ore from the deposit for development and modifications in the flotation flowsheet for the NUSSIR ASA copper ore. The mineralogical characterization for the ore sample was achived by optical microscopy and Zeiss automated mineralogy while grinding characteristics were tested using Bond Index tests. The results confirmed the presence of Cu minerals in the form of chalcocite, chalcopyrite and bornite in the samples, which are mainly liberated in the – 105 µm size range. The majority of non-liberated copper sulphides associated with silica and the carbonates varies from 3 to 28 percent in the –250 µm samples . It is also observed that the copper minerals are uniformly distributed in all size ranges. Selective flotation of NUSSIR copper ore was performed in different size fractions with a motive to identify the correct liberation size and thus to obtain a copper concentrate meeting the quality requirements. The flotation experiments are essentially performed in two stages: the rougher and the cleaner stage. Mass balance calculations were performed showing that approximately 88 percent of copper can be obtained at the end of the process. Ultimately, overall circuit copper recoveries ranged between 83.5 to 88.1 % with a concentrate grade of 35 to 48 % Cu.

Jan 1, 2018

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By S. Castro, L. Gutierrez

"Mining operations are often located in remote arid environments with limited access to fresh water. Shortage of fresh water in such cases makes it necessary to use seawater in mineral processing plants. Such plants treating Cu- Mo sulfide ores in seawater have been fully operational in Chile (e.g. Las Luces, Centinela). In many cases process waters used in commercial flotation plants (e.g. Mt Keith in Western Australia) are even more concentrated electrolyte solutions than seawater. This paper is an attempt at classification of the flotation operations carried out in process waters that are concentrated electrolyte solutions.INTRODUCTIONAccording to Gleick (1966), of the total Earth’ water resources 97.5% is in the oceans and ice caps, and thus only about 2.5% is fresh water. Shortage of fresh water in many parts of the world makes it necessary to use seawater in mineral processing operations. The existing commercial operations using seawater as well as recent research projects that deal not only with sulfide ores but also with apatite ores provide a lot of information that can now be generalized. The progress that has been made in this area is reviewed and based on this information an attempt is being made at classifying the flotation operations carried out in highly concentrated electrolyte process waters.SALT FLOTATIONFlotation in highly concentrated electrolyte solutions was studied by Klassen (Klassen, 1963). He reported that hydrophobic, bituminous coals, could float in salt solutions without addition of any other flotation agents. The process is referred to as salt flotation. Other inherently hyhrophobic minerals (e.g. talc, graphite, sulfur, etc.) were shown to behave similarly (Klassen and Mokrousov, 1963)As Figure 1 shows, some coals float quite well in solutions of Na2SO4, NaCl and NaNO3 (Klassen, 1963). While there are differences between the tested salts (explained by different foamabilities of these solutions) all the tests indicate that only bituminous coals float well in concentrated electrolyte solutions. 0.3 M solutions are quite sufficient to initiate a good and very fast flotation. If wettability of various coals is compared it becomes obvious that these well floating coals are very hydrophobic bituminous coals (Figure 2)."

Jan 1, 2018

By J P. Moodie

Recent trends in flotation technology are briefly reviewed. These show that considerable development has been made as the operators, suppliers and technologists have responded to the challenges of the industry. Most of these advances have been based on empirical and phenomenological methods. There is a considerable opportunity to make further advances through a more fundamental, scientific approach. Some of this work is discussed and, although progress is being made on this front, industrial uptake has been somewhat slow. A number of specific issues facing the industry are discussed.

Jan 1, 2005

By Kidd, Robert L.

INASMUCH as galena and sphalerite flotation concentrates are being produced that contain over 95 per cent galena or sphalerite, it is not unreasonable to believe that a flotation concentrate assaying at least 80 per cent of native gold can he secured provided the gold is free. As yet, little if any fundamental information has been published concerning the flotation of free gold either alone or in the presence of sulfides. So far, we are unable to make as complete a separation of gold from sulfide minerals by flotation as is possible in, the separation of one sulfide from another by this method. An introductory study of the flotation of several free gold ores has been made in our Utah laboratories. For this study three general types of gold ores were chosen, namely: (1) Quartzite containing 0.26 oz. gold per ton in which no base metals are present; (2) sulfide ore (2.04 oz. Au; 1.31 oz. AO containing pyrite as the only sulfide present and the gold free; and (3) oxidized ore (1.10 oz. Au; 0.70 oz. Ag) from an oxidized zone of the vein from which sulfide ore (No. 2) was taken; little sulfide iron was present.

Jan 1, 1932

By B Wong, R G. Coleman

In flotation, the selection of the size, number and type of cell for a particular duty depends on two important factors. Firstly, the required flotation residence time and secondly, the physical constraints of how much concentrate can be recovered for a given froth surface area and concentrate lip length. The residence time is influenced by ore type and characteristics such as liberation, kinetics and reagent dosage. The amount of concentrate that can be recovered for a given froth surface area and lip length depends on ore type and other characteristics such as particle size, specific gravity and mineral grade. Residence time is determined through a combination of laboratory-scale test work and design scale-up factors. However the critical froth transport parameters such as froth carry rate and froth lip loading cannot be determined in a laboratory. This is because the froth is scraped during a laboratory flotation test and thus does not exhibit natural behaviour, and it is not possible to scale-up froth transport distance or air rate. These values are generally compared via calculation to rule-of-thumb maximum values to establish if these values will be exceeded by the flotation cell selection.This paper first reviews these critical froth transport parameters and then discusses actual parameter values across diverse operating sites, with varying cell duties, cell sizes and types, orebodies and particle sizes. These values are compared against the industry rule-of-thumb to test the applicability of the rule-of-thumb to actual performance. Options are also presented for adjusting these parameters in operating flotation cells.CITATION:Coleman, R G and Wong, B, 2018. Flotation launder design and the measurement of critical froth transport parameters, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 353–362 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By J. F. Myers, F. M. Lewis

THE selection of the proper type of flotation machine involves the consideration of a wide variety of factors. Under any condition, all types of machines will promote some kind of separation. Obviously, the correct way of deciding which type of machine is best suited for a particular problem would be to set up all types of machines and test them out in a competitive manner, but the vast number of small concentrating plants are unable to make such complete and exhaustive tests. The experience of the authors of this paper indicates that if all the factors involved in any particular problem can be determined, and if all the flotation-machine characteristics are understood, some basis for selection could be arrived at other than actual comparison. This paper is presented to show how the process factors and machine characteristics have been combined at the mills of the Tennessee Copper Co. from studies of several types of flotation machines. At the two mills of the Tennessee Copper Co. in the Ducktown Basin of Tennessee, four distinct flotation separations are made on the complex sulphide ore. Three different concentrates are produced from the ore-in the order of their importance: iron concentrate, copper concentrate, and zinc concentrate. Four different types of flotation machines are used. The selection of these four machines, for the plant operation, was based upon the study and operating experience of the machine units shown in the following list: Fagergren machine; square cell, size 56 inches Fagergren machine; level type, size 56 inches Denver machine; conical disk impeller, size 24 inches Denver machine; receded disk impeller, size 24 inches Minerals Separation Sub-A, size 24 inches Munro-Pearce deep cell, pneumatic Southwestern air machine, Hunt principle To date the study of flotation machines has been confined almost entirely to the rougher circuits. The various cleaning operations, being relatively a much simpler matter, have not been investigated so thoroughly. Table 1 shows a typical analysis of the two ores as well as of the mineral content. []

Jan 1, 1944

By A E. C Peres, P R. M Viana

The role of flotation columns in comparison with conventional mechanical flotation cells is discussed under the scenario of Brazilian flotation technology. All iron ore concentrator circuits commissioned since 1990 incorporated column only flotation technology in rougher, cleaner, scavenger configuration. Columns were also added to existing circuits, especially at the cleaner stage. Columns were also incorporated to phosphate ore flotation circuits operating mechanical cells. In two phosphate concentrators, columns substituted for all mechanical cells. Columns perform the cleaning stage in a large sulfide copper concentrator, following rougher flotation in tank cells. Scavenger of the cleaner tailings is performed in tank cells at this plant. Other ores that are concentrated in flotation columns include graphite, talc, lead-zinc sulfide, and a zinc hydrometallurgical residue for silver recovery.

Jan 1, 2005

By T. Bhambhani

Research at Cytec over the past two decades has shown that the traditional approach for ore metallurgical characterization (typically conducted via laboratory-scale batch flotation tests), which involves changing reagents and conditions one-factor-at-a-time, leads to several pitfalls. The chemical solution thus selected has a narrow un-optimized window of performance and will likely fail in the plant. A holistic approach, called the Flotation Matrix 100? process for ore metallurgical characterization, was developed at Cytec about a decade ago and has been successfully used to develop robust reagent solutions for several operations around the world. The premise for the approach is that flotation outcome from ores is variable and is determined by complex interactions between various physical, chemical and operational factors. A key component of the process is the use of efficient multivariate designs focused on the chemistry aspects (reagents and pulp chemistry), which helps identify the best processing conditions for each ore type, as well as the conditions resulting in poor performance. It also includes advanced statistical methods for dealing with the complexity and variability of experimental data. The holistic approach is illustrated in this paper with a case study on Pb/Zn ores. Using just 18 carefully designed batch tests, it is possible to partially simulate the behavior of each ore type in the plant. The best conditions for each ore type, along with the conditions to avoid, are identified. Along with this, insights are obtained into the reasons for high reagent dosages for certain ore types, and interactions between variables. Keywords: flotation, holistic approach, metallurgical characterization, multivariate experimental designs, base and precious metals recovery, sulfide collectors and modifiers, Pb/Zn sequential flotation

Sep 1, 2012

By R Coleman

The flotation mechanism plays a key role in the flotation process. It is used to provide the contact between solid particles and bubbles and also the energy for these particles and bubbles to attach. The mechanism must therefore provide sufficient mixing to keep the solids in suspension so that they can be transported into the froth and recovered to the concentrate. The design of the mechanism is critical and over the past decade Outotec has developed and optimised a new mechanism design to improve metallurgical and energy performance. The FloatForce® mechanism consists of a rotor and stator arrangement and has been specifically designed to provide sustained mixing at higher air flows and lower power inputs.Over 500 FloatForce® mechanisms have been installed in existing and new operations. This paper outlines the technological aspects of the FloatForce® mechanism and provides metallurgical, operational and energy performance results from a number of flotation circuits in which these have been installed.

Aug 8, 2011