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By Jan E. Nesset, James A. Finch, Frank Rosenblum, Rebecca Payant

"Under certain conditions of moisture and oxygen, sulphides can spontaneously heat, a phenomenon known as self-heating. In this paper, we test a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by restpotential difference between minerals and their surface area of contact (particle size). In order to decrease rest-potential, four sulphides were tested: pyrite, chalcopyrite, sphalerite and galena. Two series of samples consisting of mixtures of two sulphides, each representing a mass fraction of 50 %, were run in standard self-heating tests. The first series comprised five mixtures, two with low rest-potential difference (pyrite-chalcopyrite and chalcopyrite-sphalerite) and three with high rest-potential difference (pyrite-galena, chalcopyrite-galena and pyrite-sphalerite). The second series was performed on a pyrite-sphalerite mixture at four particle sizes (80 % passing 850 µm, 300 µm, 75 µm and 38 µm). The first series showed that the individual sulphides and the mixtures of low rest-potential difference did not self-heat but the mixtures of high rest-potential difference did self-heat. The second series showed that self-heating increased inversely with particle size (increased specific surface area) and revealed that it was the fineness of the pyrite (high rest-potential sulphide) that governed the self-heating effect, indicating the rate-limiting step is the reduction reaction on pyrite (cathodic mineral). The increase in self-heating with high rest-potential difference and increasing particle fineness supports the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on the hydrogen sulphide hypothesis is proposed where the reduction reaction at the cathodic mineral surface is ferric to ferrous. The understanding gained will be of interest to those involved in storage, shipping and disposal of sulphide minerals.INTRODUCTIONSulphide mineral ores are the major source of most base metals such as copper, zinc, nickel and lead. Once the ore is extracted, the sulphide minerals are liberated by size reduction (crushing and grinding), concentrated by flotation, and the concentrates sent for further processing to extract the metal (smelting and refining). At the various stages from mining to concentrate shipment and tailings storage, the sulphides are exposed to a variety of environments, which under certain conditions of air (oxygen), humidity and temperature can cause them to heat. Since no external heat source is involved, this pyrophoric process is known as spontaneous heating or, more commonly, self-heating. The self-heating of sulphides is associated with oxidation reactions under moist conditions. If the heat generated is greater than the heat dissipated, the sulphides will self-heat and the material temperature will rise. This can make working conditions potentially dangerous as oxygen is consumed from the surrounding air and significant quantities of sulphur dioxide (SO2) can be released (Ninteman, 1978)."

Jan 1, 2011

By Elizabeth Carvalho L. Cardoso, Ademar B. Lugão, Sandra R. Scagliusi

This research investigated how gamma-radiation affected PP/HMSPP structural foams filled with biodegradable synthetic polyester PLA in terms of thermal properties, biodegradability and infrared spectrum. Polymers are used in various applications providing enormous quantities of wastes in environment and contributing with 20–30% of total volume of solid residues. Besides, shortage of plastics resins obtained from fossil base is addressing research and development toward alternative materials; environmental concerning in litter reduction is being directed to renewable polymers for manufacturing of polymeric foams. Biodegradable polymers, a new generation of polymers produced from various natural resources, environmentally safe and friendly, can contribute for pollution reduction. PLA (poly(lactic) acid)) was chosen to be blended with PP/HMSPP. Blends thereof were subjected to gamma radiation at 50, 100, 150, 200 and 500 kGydoses.Soilburialtestpointedtowardapartialbiodegradationofirradiated PLA-PP/HMSPP foams; other characterizations involved TG/DTG technique and FTIR assessments.

Mar 1, 2017

By Gordon T. Austin

Garnet is the general name for a family of complex silicate minerals having similar physical properties and crystallizing in the isometric (cubic) system. All garnets have the same general chemical formula but vary greatly in chemical composition. The name garnet is derived from the Latin word granatus, meaning like a grain, which refers to the mode of occurrence wherein crystals resemble grains or seeds embedded in the matrix. GEOLOGY Mineralogy Chemical Properties: The general formula for garnet is A3B2(SiO4)3, whereas A can be calcium, magnesium, ferrous iron, or manganese, and B can be aluminum. ferric iron, or chromium, or rarely titanium. The formulas and names of common garnet species are: [ ] Almandite and almandite-pyrope solid solution garnets are the best abrasive types, but andradite, grossularite, and pyrope also are used. All species of garnet have been used as gemstones. The structure of garnet consists essentially of isolated SiO, tetrahedra connected by oxygen-cation-oxygen bonds through the distinct A and B group cation sites. Within this structure magnesium, ferrous iron, and manganese easily interchange and substitute for each other in the A cation position, and calcium does so less readily. Additionally, aluminum, femc iron, and chromium substitute for each other to a limited extent in the B cation position. This ability to substitute or exchange ions without changing the crystal structure is called isomorphism, and garnet is one of the finest examples of a isomorphous series. Because of this isomorphism there is complete solid solution between certain garnet species but not between others. Fig. 1 illustrates these solid solution relationships. Some rare species of garnet are known that illustrate the wide range of cation substitution that the garnet crystal structure can accommodate. They include: [ ] These rare species are not of interest for industrial applications, but can be of interest to mineralogists and the gem industry. Physical Properties: Garnet displays the greatest variety of color of any industrial mineral. Garnets have been found in all colors except blue. For example, grossularite can be colorless, white, gray, yellow, yellowish green, various shades of green, brown, pink, reddish, or black. Andradite garnet can be yellow- green, green, greenish brown, orangy yellow, brown, grayish black or black. Pyrope is commonly purplish red, pinkish red, orangy red, crimson, or dark red; and almandite is deep red, brownish red, brownish black or violet-red. Spessartite garnet can be red, reddish orange, orange, yellow-brown, reddish brown, or blackish brown. A few garnets exhibit a color-change phenomenon. They are one color when viewed in natural light and another color when viewed in incandescent light. Because of the great variation in color of garnet within each species and similarities in color between garnets of different species it is recommended that garnet identification not be based on color alone. The Mohs hardness of garnet varies from 6.5 to 9.0. Grossularite and uvarovite have a hardness of 6.5 to 7.5; andradite is 6.5 to 7.0; and pyrope, almandite, and spessartite are 7.0 to 7.5 in hardness. There are reports of almandite having a hardness of between 8.0 and 9.0. As with hardness, the specific gravity of garnet varies considerably. The specific gravity may be as low as 3.2 or as high as 4.3 depending on chemical composition. Garnet crystallizes in the isometric system with rhombic dodecahedra and trapezohedra the most common forms. Crystals also form in combinations of dodecahedra and trapezohedra or either of these in combination with hexoctahedra. Crystals can have cubic or octahedral faces, but these are rare. Under favorable conditions of formation garnet will crystalize in nearly perfect forms that rival study models. Garnet also forms as irregular blebs, grains, knots, or masses, with or without distinguishable crystal faces, and as coarse- or fine-grained granular masses that appear to be totally lacking in crystal form. The fracture of garnet also shows great variation. In some garnets, particularly those that are well crystallized and glassy in appearance, the fracture is subconchoidal to conchoidal. Other, more poorly crystallized garnets exhibit a fracture that can only be described as uneven. Garnet occasionally has an indistinct dodecahedral cleavage. Certain species of garnet from specific locations have a pronounced laminated structure consisting of planes of weakness along which parting takes place. This parting may resemble cleavage, but since it is mechanical and not related to crystal structure it is not true cleavage. The optical properties of garnet are sensitive to even small changes in chemical composition or strain in the crystal structure. For this reason each species does not have a single index of re- fraction (IR) but has a range of 1Rs. Uvarovite in its pure form should have an IR of 1.870, but in nature samples vary from 1.74

Jan 1, 1994

By John Oskam

In 1873 Barton tines Corporation mining Garnets for Abrasives. From providing bulk Garnet Concentrate the technology has advanced to the sizing and classification of micron sized particles utilizing a Barton process. Processing of Garnet involves extensive quality control at all steps, first to insure product purity and secondly to insure the correct size range. Barton Mines produces about 30 different sizes of Garnet products to lead the world in the manufacture of technical abrasive Garnet. This paper will examine the present technology of Garnet Abrasive Manufacture and the specification to which the sizes are produced as well as some of the markets served.

Jan 1, 1980

By D Cliff

Despite advances in technology, the Australian underground coal mining industry continues to have incidents involving spontaneous combustion. Managing these incidents relies heavily on understanding the state of the event as it develops and controls are applied. Gas analysis plays a major role in aiding this interpretation. This interpretation is based upon laboratory testing of coal samples under conditions very different to those found in an underground coal mine. This paper will explore the links between laboratory data and actual events. It will highlight the difficulties of using laboratory data. It will outline the relevance of laboratory data and how it can be usefully applied to manage spontaneous combustion events as well as in establishing relevant trigger action response plans to facilitate early detection and control of such events. The paper will identify some of the factors that need to be applied when adapting laboratory data to apply to the underground coal mine. It will outline the need for comprehensive knowledge of the local conditions and gas concentrations to be expected at all locations in an underground coal mine. Further, it will demonstrate the need for mine environment monitoring to go beyond simply measuring gas concentrations but also to include reliable atmospheric pressure, temperature and air velocity monitoring.CITATION:Cliff, D, 2013. Gas analysis - Linking the laboratory with reality, in Proceedings The Australian Mine Ventilation Conference , pp 277-282 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By K. C. Sclater

GAS as a factor in the efficiency of oil production, might be a better title for this paper as it deals in general with the significance of the gas-oil ratio as an index of the efficiency of oil production and briefly discusses oil production methods with reference to the gas-oil ratio in wells, particularly during the early life of a field. In the recent hearings held at Washington before the Federal Oil Conservation Board the fuller utilization of the energy contained in the gas occluded in or associated with the oil underground was stressed by some of the speakers when referring to greater ultimate recovery of oil. One speaker commenting on this point said in part, "There is ample evidence indicative that if the gas associated with the petroleum in our fields were conserved and elevated gas pressure maintained in the oil sands during their productive life, the ultimate production of oil could be greatly increased."

Jan 1, 1926

By Manuel Gutierrez, Roberto Gomez, Juan Aravena, Johan Gjoevad

The use of explosives in mining operations is a process that involves the search for an ideal explosive for the type of geological condition of the mineral to be extracted. For the explosives present on the market the majority are based on Ammonium Nitrate. This as it is an ideal balance of high energy efficiency achieved with low development of gas emission. The manufacturing and loading operation of the explosive requires multiple process stages and different raw materials, which, if is not correctly supervised and controlled may cause the development of harmful gases or, in the worst case, even toxic gases. The majority of mining operations are located at remote locations without the presence of communities, and hence individuals, which could be affected by emission of the harmful or even toxic gases. In these operations the protection is mainly to protect the employees of the operation. However, if the operation is located near communities, the effect of these gases becomes a serious problem. The communities' perception of post-blasting gases, according to interviews carried out in this project, describes these as smells of black gunpowder, damp soil with a volatile permanence and medium intensity, sometimes a stinking tone is added. The legislation in Chile that controls the exposure of “workers” to different gases is Supreme Decree 594, 2019 (Decreto Supremo 594). Currently the Chilean Ministry of Environment and Sernageomin (Servicio Nacional de Geología y Minería) are taking actions to reform and strengthen oversight, seeking through a short law to provide more tools to the government to decentralize decisions in case of non-compliance with the decree. This paper describes the development and implementation of a permanent and remote gas monitoring system, considering the reasons for choosing the gases to be included in the equipment, the types of sensors and their capabilities, the way to verify in the field the correct functioning of the technology throughout the project, and finally how the data collected in the field is meeting the government's expectations in terms of permanent and online reportability. Additionally, it addresses the continuity of gas monitoring in the community that will disappear in the short term due to the expansion of mining operations, thereby ensuring the protection of both workers and affected communities.

Jan 21, 2025

The effect of superficial gas rate distribution (Jg profile) on down-the-bank metallurgical response was tested in the rougher-scavenger bank (eight 10-m3 tank cells, 4 roughers and 4 scavengers) at Highland Valley Copper Mine's Cu/Mo separation circuit. Three Jg profiles were tested: (a) as found (i.e., typical practice), (b) increasing decreasing (i.e., increasing from cell 1 to 4 and decreasing from cell 5 to 8), and (c) decreasing-increasing (i.e., decreasing from cell 1 to 4 and increasing from cell 5 to 8). The Jg profile approach proved to be of considerable value. Profile (b) gave the best metallurgical results, i.e., the highest down-the-bank grade/recovery (increase in grade at constant recovery was approx. 3-4% compared to the as found case) and the most efficient Cu/Mo separation (cumulative Cu recovery was reduced by almost half - approx. from 20% to 12%, at 99% Mo recovery). The success of the evaluation prompted the implementation of profile (b). Detailed gas dispersion characterization tests (Jg and Db (bubble size)) showed significant discrepancies between the Jg measured directly (using the McGill University sensor) and the Jg calculated from field instrument readings (volumetric gas flowmeter) and machine dimensions (cell cross-sectional area). Tests were designed to reveal the source of disagreement. It was observed that a significant number of bubbles were not able to float (i.e., they were entrained with the tailings), the evidence appearing to be a significant number of very small bubbles (approx. 200-300 µm) which did not have sufficient buoyancy to rise. Consequently, rather than relying on the field instrument, the evaluation depended on the McGill University Jg sensor, which collects bubbles in a tube near the pulp-froth interface, thus providing significance to the data as the measurements were obtained from bubbles that almost certainly floated.

Jan 1, 2007

By J. A. Finch

The metallurgical performance of a flotation cell is strongly influenced by the features of the bubble population, characterized by the gas dispersion properties, a collective term including bubble size, superficial gas velocity and gas holdup. It is required that gas be well distributed throughout the cell. Gas distribution is estimated here by simultaneous measurement of gas velocity (Jg) at different distances from the center (radial Jg mapping). This communication describes a technique to perform radial Jg mapping together with fundamentals for the interpretation of the data.

Jan 1, 2009

By Xia Lou, Hossein Dashti

Gas hydrates technology has been considered as an alternative method for carbon dioxide (CO2) separation. A wide range of studies have been reported in the past decade on the improvement of the separation efficiency by using chemical additives. While most of these studies have shown improved kinetics, thermodynamics and/or separation efficiency at the laboratory scale, there has been no quantitative analysis of the energy consumption for viable industrial applications. Comparison of the effectiveness of the chemical additives from separate studies or groups also is impossible. The present work is focused on the modelling of the hydrate-based CO2 separation process and provides a quantitative approach that is new in its analysis of the effectiveness of chemical additives in relation to the energy required and the kinetic parameters involved in the process.

Mar 1, 2018

By J. T. Ryan

POISONOUS, irritating, or explosive gases are found in almost every industry, and manufacturers of gas masks are called upon to provide gas mask protection for a great variety of conditions, such as operators in horseradish factories, fumigators of homes and ocean liners, and men engaged in the manufacture of tetra-ethyl-lead, the new motor fuel. The modern type of gas mask and respirator, to provide protection against all such industrial gases, is an outgrowth of the gas mask developed during the World War to protect the soldiers against the poisonous war gases. So far, it has been possible to develop ample mask protection from all known noxious gases and fumes present in atmospheres encountered in mines, metallurgical works, and chemical and other industries, so long as there is sufficient oxygen present to support the flame of an oil lamp. The most important development of the gas mask was in providing protection against carbon monoxide- which is the noxious gas that mining men are most concerned with and, in fact, is the noxious gas that man is most frequently exposed to. This paper will be con- fined largely to the discussion of masks for underground use in metal mines. Gases that contaminate the normal air in mines can be divided into two classes: those that are given off normally by the workings, and those that are produced in mine operation.

Jan 1, 1926

By M. A. Hardie

"CASES and mixtures of them are so common and so much a part of everyday existence that they become so taken for granted that their individual characteristics and idiosyncrasies rarely become of curiosity to others than those involved in tl1eir production, processing, treatment, transportation, and for utilization. The use of the most common and universal mixture of gases -air -is begun at birth by ail living creatures and their discontinuation of its use terminates existence. Modern man rides on air in his tires, rides through it for high-speed transportation, and uses it for his comfort in the heating and air conditioning of his domicile. It is neither the aim nor the in-tent, in the next few moments, to provide a panacea for even a portion of the problems inherent in the gas industry nor to delve deeply into any particular facet of its diversities. The purpose is primarily to touch upon some of the peculiarities and generally to consider approaches to employ in the pursuit of solutions."

Jan 1, 1959

By C. A. Lavery

A DISCUSSION is presented of natural gas production and field processing equipment as now utilized in the gas producing areas of the United States, with reference to use of such equipment in Canadian gas areas. The scope of the paper is confined to a general description of various types and methods of using surface production equipment. The discussion is divided under two general groups: well-head production equipment, and field processing. The first will be concerned primarily with indirect heaters, separators, knockouts, and special versions of this equipment. The second major group includes the field processing equipment for handling natural gas. A delineation should be made here as to the meaning of field processing as used in this discussion. We will limit our term to mean such processing equipment as may be used in producing fields to process gas or its by products in a manner that does not require conventional plant practices either in operation or supervision. This covers such equipment as is necessary to complete preparation of gas for sale to pipeline and/ or is necessary to recover valuable components. Under this heading we will discuss glycol dehydration, solid desiccant dehydration, low-temperature separation, mechanical refrigeration, and desorbtion-stabilization. These are all processes involved in preparing gas for final sale or disposal. They do not include the more conventional and large-scale plant process systems.

Jan 1, 1956

By AIME AIME

A discussion of the Papers by Prof. H. Hubert, Liege, Belgium ; Mr. Tom Westgarth, Middlesbrough, England ; and Mr. K. Reinhardt, Dortmund, Germany, presented at the London Meeting, July, 1906, and printed in Bi-Monthly Bulletin, No. 12, November, 1906; pp. 910 to 930, 971 to 987, 1037 to 1163. MR. ADOLPH GREINER, Seraing, Belgium :-I have nothing special to add to Professor Hubert's paper except to say that there are some little things that it would be well to have cor-rected when the paper comes to be published. In dealing with the thermal efficiency of the engine, you will find that the 29.84 per cent was a very high one. Professor Hubert has forgotten those engines built under the Cockerill type, but he has referred to them in Appendix II. At our works at Cockerill we have built 63 engines, giving 63,000 h.p., and the other companies who have received licenses have built 113 engines, making 103,000 h.p., and aggregating 176 engines and 166,000 h.p. Eight years ago I had the pleasure of giving to the Institute the results obtained up to that time. Since then a good many engines have been constructed. In 1898 I thought a blast-furnace producing 100 tons of pig iron would allow 3,000 h.p. Professor Witz and Professor Hubert show that with the same production of pig the new engines take 3,800 h.p. out of the gas. At present at Cockerill we make 700 to 800 tons of pig iron per day, and we hope to have 26,000 h.p; in a few years. At present we have only half of that in gas-engines, but we hope to have in five or six years all the gas out of these furnaces to the number of 25,000 or 26,000 h.p. MR. Tom WESTGARTH, Middlesbrough, England:-My contribution is not a paper in the ordinary sense of the word, because I am sure you will agree with me that what I have written is only supplementary to the other two papers. The notes are schedules of the larger-size gas-engines built by the engine-makers, of 500 h.p. and upwards. If you look at the schedules you will find that in England gas-engines have be-

Jan 1, 1907

By A. D. Pienaar

The aqueous chemistry of niobium and tantalum compounds with hydrofluoric acid is a mature field of investigation. In contrast, very little attention has been paid to reactions of these compounds in non-aqueous environments. Similarly, reactions of elemental fluorine with niobium and tantalum compounds have received little more than cursory attention in literature. This work discusses the isothermal reaction kinetics derived from thermogravimetry, using a less redundant approach than is currently the standard. We also discuss the most likely kinetic models for this reaction.

Jan 1, 2012

By Samuel S. Wyer

THE installation of the gas-producer power-plant in America has been so unusual that all engineers have viewed it with in¬terest; a large majority, however, regard it with a lack of con-fidence and many with positive distrust. Despite the fact that European engineers have usually been less inclined to take the initiative along experimental lines than are Americans, they have, nevertheless, developed the gas-producer plant to a very high state of efficiency to which they were forced by the neces¬sity of economy in fuel-consumption. The gas-producer power-plant is so common in Europe that engineers as well as the general public regard it with the same degree of confidence that is now universally placed in steam¬plants. Gas-engines, both small and large, are in general use there, and central stations, aggregating several thousand horse¬power, are quite numerous. The fact that gas-producer power-plants have received so little attention in America may be attributed to five conditions:-1', ignorance and prejudice; 2, newness of work; 3, in-

Mar 1, 1905

By Clinton M. Young

(Pittsburg Meeting, March, 1910.) I. INTRODUCTION. THE experiments herein. described were carried on in 1908-9 . by the State Geological Survey of Kansas. Some months before taking up work on black powder the Survey had resumed work on an interrupted investigation of explosions in coal-mines, a subject which is engaging the attention. of numerous investigators. An unusual number of serious disasters has directed to. the subject a study which discloses the disquieting fact that, in the. United States, the ratio of lives lost per ton of coal mined has been on the increase. Methods of coal-mining have changed to some extent with the great increase of output, attained in, comparatively recent years. These changes involve the working of very extensive mines, with increased difficulty of ventilation, increased accumulation of coal-dust, and. a very great increase in the amount of explosive used.. . This last point assumes truly startling proportions when it is carefully observed. In the fields of the Middle. West it is not now uncommon for a miner to use six ,kegs (150 lb.) of black powder in a "pay" of two weeks, while within the memory. of men still active, one keg (25 .lb.) would last two men for a " pay." So. great has . the use of explosives become in some fields that the skilled coal-miner is hard to find, and the coal is not mined, but blasted. A preliminary study of the subject. of explosions in coal-mines has. led to the belief . that the use of, large -quantities of explosives, in some cases by slightly-trained men, had not been * Associate Professor- of Mining Engineering, University of Kansas, Lawrence, Ran.

Aug 1, 1910

By Baojun Zhao

Primary lead production using the lead blast furnace in conventional practice is carried out using sinter feed. At YMG, China, the sinter plant has been replaced with a lead ISASMELT furnace. The ISASMELT furnace produces lead bullion plus a high-lead slag, which is cast into lumps to provide a suitable feed for the blast furnace. In the present study the relative microstructures and reduction characteristics of industrial lead sinters and synthetic ISASMELT slag in CO/CO2 gas mixtures have been measured and compared. The microstructure and property changes, and the mechanisms of reduction in each case are examined and discussed. The results of the study are used to explain the successful implementation of cast slag feed in commercial ISASMELT- lead blast furnace practice. Key words: lead slag, lead sinter, lead blast furnace, reduction kinetics and mechanisms

Jan 1, 2008

By AIME AIME

ON Thursday a most interesting symposium on "Gases in Metals" was held, with both morning and afternoon sessions. The morning was devoted principally to the considerations of the steel maker, the nonferrous field being taken up in the afternoon period. Dr. John Johnston, as chairman, introduced the subject with "A Short Analysis of the Gas-metal Problem and Its Practical Importance." He then introduced P. H. Brace who explained in considerable detail the various vacuum fusion and other methods in use at present, both here and abroad, in the study of "gases" in metals. He was fol¬lowed immediately by H. W. Graham on "The Effect of Oxygen in Steel." The papers elicited considerable discussion, the point being particularly noted by both Dr. Rawdon and Dr. Sauveur that a knowledge of "total oxygen" alone is not sufficient information for the metallurgist, distribution of oxygen being probably the more important. Dr. Johnston, in commenting on the lack of agreement among many of the methods now in use, such as the Ledebur and vacuum fusion, spoke of the contemplated plan of the Iron and Steel Division to have a number of standard samples analyzed by many laboratories by the various methods, the Bureau of Standards acting as a clearing house, so that more definite information may be obtained on the comparative accuracy of the method.

Jan 1, 1933

By D. Harrington

When the word "gas"' is mentioned in connection with mining almost invariably it is inferred that the explosive gas, methane, is in mind and that the reference is to coal mining. Although methane is likely to occur in any coal mine the metal mines of the world contain by far a greater variety of gases than do the coal mines. Often the gases in metal mines are as dangerous as the gases likely to be found in coal mines, and sometimes are even more deadly. A coal mine is more likely to contain methane than a metal mine. In rare instances it may contain high percentages of nitrogen or carbon dioxide or it may be deficient in oxygen where the air is confined in a blind end or in a sealed region. Much more rarely relatively small percentages of ethane or other hydrocarbons with an odor of ether, gasoline, or kerosene, or minute percentages of hydrogen sulphide are found in a coal mine. During a coal-mine fire or explosion carbon monoxide content is likely to be high (4 per cent or more), and if the coal contains much sulphur the high fumes may contain some sulphur dioxide.

Jan 1, 1931