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By Jirí Faltus

The paper deals with studying the impact of structural properties and anodizing of surface on the corrosion properties of extruded rods from commercial aluminium alloys: AA6082, AA6262, AA6012, AA2007 and new lead-free aluminium alloys AA6023, AA2015 and AA2111B. Samples were exposed to the corrosive atmosphere NSS, AASS in the chamber by EN ISO 9227. Surface of samples were either in the original state or anodizing by selected mode. The depth of corrosion attack and the form of corrosion attack are evaluated depending on the type of alloy, the metallurgical condition and surface treatment of the samples.

Jan 1, 2015

By J. A. Venter, M. K. G. Vermaak, J. G. Bruwer

Electrostatic separation is employed in the concentration of zircon and rutile. The zircon concentrate undergoes an acid treatment to remove impurities from the surface of both the zircon and rutile. The purpose of the acid treatment is to increase the difference in the resistivities of the two minerals, thus ensuring the best possible electrostatic separation efficiencies. Previous test work suggested that these impurities are not removed, but only modified; the surface modification seemed more prevalent in the case of the rutile. The resistivity of the rutile changes with pH and thus the electrostatic separation of the rutile is influenced. X-ray photoelectron spectroscopy (XPS) indicates that there is an increase in the OH and adsorbed H2O concentrations on the rutile surface. XPS also showed significant differential charging on the rutile surface, which indicates that the species on the rutile surface have different resistivities. The zircon particles from the conducting and non-conducting streams have similar resistivities and no major differences in their surface species. Zircon losses during the final electrostatic separation appear not to be due to surface effects, but due to shielding of particles during the separation.

Jan 1, 2007

By Seoul National University, Ki-Ho Kim, Jong-Pyo Kim, Sung-Min Joo, Hee-Chan Cho, Hyung-Seok Kim

Aragonite was synthesized in addition of Mg2+ ion and SrCO3 seed by carbonation process, and the best condition and mechanism of the synthesis was studied by analysis of continuous pH change, ICP, XRD, and SEM. As MgCl2•6H2O addition increased, aragonite phase increased at condition of CO2 flow rate of 100 mL/min and stirring rate of 250 rpm. It was the dissolution of Mg(OH)2 that determined overall reaction time. As SrCO3 seed addition increased at 0.2 mole MgCl2•6H2O, the amount of aragonite increased and the aspect ratio was from 5 to 9. And it was thought that Mg2+ ion prohibited calcitetransformation of aragonite formed by SrCO3.

Jan 1, 2003

By Pedro Henrique L. M. Lopes, Édio Pereira Lima Jr., Fernanda Santos da Luz, Fábio de Oliveira Braga, Sergio Neves Monteiro

Several works have been dedicated to study the ballistic response of multilayered armor systems (MAS), including those using natural fiber composites as second layer. These composites disclosed good ballistic performance, having economic and environmental advantages. In the present work, the objective was to investigate the effect of areal densities of each MAS layer, in the overall performance of a MAS with an alumina ceramic front, a curaua fabric reinforced composite filling, and an aluminum alloy backing the target. Ballistic “backface signature” tests were conducted, varying the areal densities of the MAS layers according to a Box-Behnken design. The results showed a similar influence of the ceramic and aluminum layers in the MAS “backface signatures”, although deformation and failure mechanisms were significantly different. The composite also showed significant participation in the overall MAS performance. Since the composite is cheaper and lighter, a balance minimizing the other layers would be advantageous.

Mar 1, 2018

By Beatryz C. Mendes, Igor K. R. Andrade, Roseli O. G. Martins, Gustavo H. Nalon, Rita de C. S. S. Alvarenga, Leonardo G. Pedroti, Carol F. R. Santos, Marcelo A. Alves

This work presents an experimental investigation of the influence of concrete blocks and mortar’s compressive strength on the flexural bond strength, normal to the bed joints, of concrete structural masonry. Third-point beam tests were performed on concrete prisms, considering two different kinds of concrete blocks (compressive strength of 5.9 and 8.2 MPa) and six different cement-lime mortar compositions (compressive strength around 30, 70, and 120% of the blocks’ net area compressive strength). Units’ absorption and mortar’s initial flow and water retentivity were not varied, but remained within the suitable range for use in structural masonry. For both types of concrete blocks, it was observed an increase on the prism’s flexural bond strength with the increase of the mortars’ compressive strength. A lower mortar’s water-cement ratio led to higher bond strength. When fixing the ratio between mortar’s and concrete block’s compressive strength, it was noticed that the increase on the blocks’ strength contributed to a slight increase on the masonry’s flexural bond strength, except when using high strength mortar, in which the increase was significantly greater.

Mar 1, 2018

By E. Herrera, L. Mariscal

"Ilo Copper Smelter operates since 2007 with an ISASMELTTM furnace as a single smelting unit (1,200,000 tpy) associated with two Rotary Holding Furnaces for separation of matte and slag, and which directly produces a discard slag. Southern Peru continually has been improving the slag chemistry of its ISASMELTTM furnace in order to reduce copper losses, given its big economic impact due to large slag mass generation. The present paper describes the influence of the CaO, Al2O3 and magnetite content in the slag of the ISASMELTTM furnace correlated with the SiO2/Fe ratio and its liquidus slag. Also it defines the best slag chemistry and operating practice in order to reduce the copper losses without compromise the bricks life of the furnace.INTRODUCTIONIlo Copper Smelter of Southern Peru (Grupo Mexico) is located on the southern coast of Peru, and treats mainly copper concentrates produced in its own mines (Toquepala and Cuajone).The modernized smelter was commissioned in 2007 and operates with an ISASMELT™ furnace as a single smelting unit (1,200,000 tpy), which is associated with two Rotary Holding Furnaces (RHF) for separation of matte and slag. This slag is directly sent to the dump. Figure 1 shows the smelter flow diagram.The ISASMELT™ process is a bath-smelting process using a single lance. The lance tip is immersed into a molten slag bath contained within the stationary, vertical, refractory-lined ISASMELT™ furnace. The injection of oxygen-enriched air, through the lance into the slag results in a highly turbulent molten bath. Feed material falling into the turbulent bath from above reacts rapidly, resulting in extremely high productivity for a relatively small bath volume."

Jan 1, 2012

By R. Winand, M. Degrez, C. Temmerman

"The influence of the copper electro crystallization inhibitors (mainly thiourea, gelatin and chloride ions) is studied in a new fully automatic pilot plan. This paper describes the conception and the building of this plan. The new approach is to reproduce the experimental conditions observed in the industry with the three additives present simultaneously in the electrolyte and secondly to study the influence of a slight modification of the concentration of one inhibitor, the others being present in the electrolyte with their industrial nominalconcentrations.1. INTRODUCTIONDespite the fact that gelatine, thiourea and chloride ions have been used in copper electrorefining for a long time, precise knowledge concerning their influence on the cathode deposit, metallographic structure and associated properties is still lacking.Many authors studied the influence of each additive separately, or of two added at a time. Only a few authors studied the combined influence of the three additives added simultaneously. The general conclusion that can be drawn is that the combined influence is far from that forseen from the influence of each additive separately, or even from two additives used at a time. Moreover most of the experiments described in the literature were performed by adding all additives at once initially. It is however, well known that gelatine looses a great part of its activity during the first half hour due to degradation by sulfuric acid (as shown by the cathode overpotential drop). Thiourea is rapidly replaced by a number of degradation mole,cules and complex ions including cations from the solution, changing even the equilibrium between Cu, Cu(I) and Cu(II).Chloride ions are consumed by precipitation.A number of successive research projects [1-9] led pregressively to the concept that, in order to obtain reproducible results representative of industrial cathodes, it was necessary to simulate as far as possible industrial conditions. It was essential that all additives were added continuously during the electrolysis, with, as consequence, a continuous bleed.The purpose of this paper is to describe the concept of a new fully automatic pilot plan for copper electrorefining and to present the first results."

Jan 1, 1997

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT An overall study was conducted to evaluate the properties and processes influencing the rate and magnitude of consolidation for oil sands fine tailings produced using different extraction processes. As part of the overall study, a comprehensive description of physical and chemical characteristics of fine tailings generated by caustic and non-caustic processes was carried out. Ultimately, the influence of these fundamental properties on the compressibility, hydraulic conductivity and shear strength properties of the fine tailings was assessed. The characteristics of the fine tailings are presented in terms of index properties, mineralogy, specific surface area, water chemistry, liquid limits, particle size distribution and structure. A difference in water chemistry was concluded to be the cause of substantial differences in particle size distributions and degree of dispersion of the comparable caustic and non-caustic fine tailings. The degree of dispersion was consistent with predictions for dispersed clays established by the sodium adsorption ratio (SAR) values for these materials. A linear variation of increasing dispersion with increasing SAR up to a SAR value of about 40 has been suggested, above which fine tailings are completely dispersed. The observed dispersed or flocculated structures (viewed using a scanning electron microscope) supported the predictions based on SAR values.

Jan 1, 2010

By Mehdi Asadi, Heinz Palkowski

"In recent years, the increased demand for advanced high-strength steels (AHSS) mainly had been driven by the need of the automotive industry to reduce weight and to improve safety. Beside good ductility and high strength, those steels have a high bake hardening (BH) effect, giving additional contribution to the strength of structural parts, subjected to the paint baking process. In this paper we concentrate results gained for hot rolled dual phase (DP) steels.For the simulation of changing process conditions within the final hot rolling the specimens were hot deformed using different schedules of temperatures and reductions, selected according to the non-recrystallization temperature (TnRX). It was possible to refine the DP steel structure by control-ling the deformation temperature and the amount of strain below TnRX during the thermo-mechanical controlled processing (TMCP). This structure refinement resulted in an improvement of the strength and BH behaviour. A wide spectrum of mechanical properties could be obtained depending on the different hot deformation schedules. The best strength and BH levels were recorded for the deformation below TnRX at the highest amount of strain.IntroductionDP steels are characterized by a good formability, high strength and a good compromise between strength and ductility [1]. Moreover, the DP steels exhibit a continuous yielding behaviour, low yield point and a high strain-hardening coefficient [2]. Furthermore, the DP steels often show a large potential for bake hardening (BH). BH refers to the increase in yield strength as a result of the paint baking treatment of the shaped auto-body parts. The primary mechanism that causes the additional strengthening is the immobilization of dislocations by the segregation of interstitial atoms, known as classical static strain aging [3]. The increase of strength thus achieved allows a further reduction of sheet thickness and improves the crash safety and the dent resistance. The BH of special steel qualities is technically used in DP, where e.g. the increase in strength is realized in the final heat treatment [4]. Previous own investigations [5-6] stated that the BH effect of DP is much stronger than that one for conventional BH steels."

Jan 1, 2012

By Takashi Furuyama, Sukeyuki Mori, Takafumi Okuma, Norio Hashiguchi

The Tower mill KD-3 is an improved version of the laboratory mills VD-1, KD-1 and KD-2 in which the classifying column has been modified to ensure a quick discharge of products from the comminution section and, on the other hand, a better separation of coarse and fine particles; the latter being collected in a cyclone with a central spiral ribbon. To level the circling airflow through the classifying column and have a strict control over the maximum size of collected particles, a series of experiments was carried out, modifying the internal structure of the column: insertion of a vertical plate, a cone, or a horizontal net. The relationship established between the maximum size of products collected in the cyclone and the duct airflow rate indicates that, independently of the latter, the insertion of a cone in the classifying column could stabilize the maximum size of products collected in the cyclone around 15.1 - 17.5µm. With a horizontal net, the maximal size could be reduced to 8.4 - 11.3µm. This occurrence might result from the collision of coarse particles blown from the comminution zone with the base of the inserted materials and their settling down the bottom of the classifying column.

Jan 1, 2003

By D. R. Murray

A four-year study was carried out to determine the ability of coniferous trees to aid in the reclamation of uranium tailings at Elliot Lake. Five species were planted: white cedar, white spruce, jack pine, scotch pine and red pine. More than 570 bare-root, two-year-old seedlings were planted on bare tailings and in areas of established grasses. A further division was made between areas of coarse and fine tailings. Over-all survival and growth of the trees has been far below expectations based on previous experience with several varieties of grasses. The criteria for assessment have been per cent survival and yearly growth as determined by plant height. Pine was superior, with 68% survival when planted in bare coarse tailings, 45% for vegetated coarse tailings and 34% for vegetated fine tailings. Cedar had the worst survival rates at 49%, 14% and 7% respectively. No species survived on bare fine tailings. The survival and growth of the coniferous trees have been related to species, environmental conditions and tailings properties.

Jan 1, 1978

By Aaron Noble, Mahmud Esad Uluer

Respirable coal mine dust (RCMD) is one of the biggest occupational health hazards for underground coal miners. Dusty mining environments can cause long-term health problems, including pneumoconiosis and progressive massive fibrosis. The Mine Safety and Health Administration (MSHA) has recently revised regulations promoting enhanced dust mitigation technologies, which have sparked renewed interest in the development of dust mitigation technologies. The flooded bed dust scrubber (FBS) is one of the most widely used technologies; however, it is limited by technical challenges, the most notable being the potential to clog. Recent studies have shown that applying vibration to filter mesh can improve the overall efficiency of the scrubber and that the system can be readily integrated to existing continuous mining equipment using an energy harvesting approach. In this follow-up study, the impact of mesh design and surface modification on system efficiency was examined using different vibrating liquid-coated stainless-steel mesh panels in a laboratory-scale FBS. Based on the two-way interaction data from a multi-factor experimental design, the results show that the performance of the system can be optimized by using hydrophilic 20- or 30-layer filters and by excitation frequencies between 67 and 134 Hz. This laboratory study suggests that a 20-layer mesh screen with hydrophilic surface applications and optimized vibration parameters can perform similar to that of a 30-layer static mesh, which is typically used in industrial units.

May 23, 2024

By D. Yu, Y. Thibault, D. Paktunc

"Prereduction and flux-aided direct reduction of chromite provide significant advantages in reducing energy consumption and greenhouse gas emissions during ferrochrome production. In this investigation, a comparative evaluation of the influences of several alkali fluxes was carried out based on experimental observations supplemented by advanced material characterization and thermodynamic predictions. Direct reduction of a chromite ore with alkali fluxes at 1300°C for 1 hour produced (Cr,Fe)7C3 type alloys with Cr/Fe mass ratios from 0.7 to 2.3. Among the alkali fluxes, reduction aided by NaOH resulted in a high degree (85%) of Cr metallization with the ferrochrome alloy being Cr4.2–4.6Fe2.4–2.8C3. The formation of liquid slag, which facilitated Cr metallization, was limited by the formation of NaAlO2 between 800 and 1300°C. This, in turn, restricted the collection and transport of the charged ionic Cr species (i.e. O2–) to graphite particles. Under the conditions studied, ferrochrome particles were often small and largely unliberated, which would make the physical recovery of ferrochrome challenging. At 1400°C, the amount of liquid slag increased, enabling the growth of alloy particles. Direct reduction of chromite aided by NaOH is promising as an alternative technology to conventional flux-based smelting in electric arc furnaces. IntroductionConventional smelting processes are energyintensive (Riekkola-Vanhanen, 1999) with the energy requirements greater than 4 MWh/t (Naiker and Riley, 2006; Beukes, van Zyl, and Neizel, 2015), and the greenhouse gas emissions can be significant, exceeding 10.5 t CO2 per ton Cr in ferrochrome produced (International Chromium Development Association, 2016). These include emissions occurring on-site (smelter), emissions due to electricity production, and emissions due to upstream processes. Overall energy requirements are influenced by the degree of prereduction and smelter charge temperature. Significant reduction in electricity consumption can be realized if the charge is prereduced before feeding to the submerged arc furnace (Niayesh and Fletcher, 1986). This consideration has led to the development of several prereduction technologies, with the most important example being the Premus process. In comparison to the conventional smelting processes, this prereduction process lowers the overall energy consumption and greenhouse gas emissions by about one-third (Naiker, 2007)."

Dec 1, 2018

By Francisco Morganti

Weight reduction is the main target of all carmakers, which results in a continuous development of new steel grades. Latest 3rdgeneration advanced high-strength steel grades (AHSS) are complex materials with special chemical compositions and multiphase microstructures. The pickling, annealing and galvanizing processes of these grades aresomewhatdifferent due to the changed chemical compositions and microstructures. Therefore, these innovative steel grades place new demands on the plant technology of pickling, annealing and galvanizing lines. The most significant challenges for the pickling process are sludge occurrence during pickling, varying pickling times, weld ability of the materials, changed visual appearance and required high surface qualities. The most important topic concerning annealing line is a precisely controlled and very flexible heating and cooling process in the furnace.One of the new requirements in galvanizing linesis the prevention of surface faults caused by bare spots, which can occur since these materials feature a higher content of alloying elements like silicon or manganese. Prevention is possible with the special pre-oxidation technologies.Due to the higher strength of the material also the mechanical equipment has to be designed differently in these lines. This paper describes the influences of the changed chemical composition and material characteristics of modern steel grades on the pickling, annealing and galvanizing process and gives an overview about the technical solutions.

Oct 30, 2017

By Fabiana Fonseca de Morais

A sinterização é um dos mais importantes e mais antigos processos de aglomeração da indústria metalúrgica. Entender a realidade atual do processo de sinterização e as qualidades requeridas para o sínter é primeiro passo para o desenvolvimento de equipamentos ou processo. Este trabalho visa entender o impacto das diferentes características de minério e resíduos empregados em uma sinterização, seu comportamento na qualidade do sínter e a sugestão de equipamentos para amenizar problemas encontrados. Parâmetros como CaO/SiO2, SiO2, Al2O3 e MgO são avaliados para entender a tendência do mercado e o efeito na qualidade final do sínter. A correta avaliação das necessidades da planta para otimização dos equipamentos a matéria-prima disponível se faz necessário para o melhor resultado no alto-forno. A granulometria da matéria-prima também é um ponto importante a ser analisado. O sinter feed tradicionalmente possui uma maior fração entre 0,7 e 6 mm, uma fração menor entre 0,2 e 0,7 mm e um conteúdo de ultrafino (<0,150 mm) limitado a 15%. Estudos identificam uma tendência do sinter feed com maior conteúdo de sílica e o consequente aumento da utilização de ultrafinos. Como resposta ao incremento de ultrafinos na sinterização as grandes siderúrgicas já estão investindo em equipamentos que minimizem grandes perdas de produtividade, como a instalação do misturador intensivo, utilizado em projetos da Pau Wurth. Outra solução inclui a instalação de uma mini-sinterização dedicada para receber este material mais fino e resíduos. O sínter produzido poderá ser adicionado diretamente no forno e/ou ser utilizado como nuclueante na sinterização grande para aumento de sua produtividade.

Aug 16, 2017

By Gilberto Yanarico Apaza

"El presente texto señala las pautas necesarias para realizar una evaluación técnica integral de la influencia del collar de bolas para las operaciones de molienda, afectando al desgaste de los revestimientos de los molinos convencionales. Para la determinación del collar de bolas es necesario realizar los análisis granulométricos con la finalidad de obtener el F80 y el P80 de las muestras obtenidas en la alimentación y producto de los molinos, definir el índice de trabajo (Wi) y consumo de energía. Asimismo, se debe considerar el porcentaje de la velocidad crítica, las dimensiones de los molinos, la densidad de los medios de molienda (bolas), el porcentaje de la carga de bolas, las características geométricas de las bolas para molienda y el diámetro real de bolas, que influye de forma inversamente proporcional en la tasa específica del consumo observada."

Jul 1, 2015

By Thais da Silva Rocha

O objetivo deste trabalho é avaliar a reatividade de um metacaulim comercial a partir da análise de sua cristalinidade. Um tratamento térmico é proposto a fim de tornar o material mais amorfo e para isso o metacaulim comercial já calcinado foi submetido a três tempos e temperaturas de queima em forno mufla (700°C em 1h, 600°C em 2h e 500°C em 1h). Após a queima o tratamento térmico que alcançou o melhor resultado foi o de 600°C em 2 horas, apresentando quase que somente picos cristalinos de quartzo nas análises de DRX. Para avaliar a influência do amorfismo na resistência mecânica de argamassas geopoliméricas foram moldados corpos de prova cilíndricos de Ø 50x100 mm com o metacaulim comercial como referência e com os metacaulins calcinados. Todas as argamassas foram feitas com a mesma dosagem e ensaiadas com 24 horas após a moldagem. O aumento de resistência à compressão chegou a 53% com o metacaulim queimado a 600°C, mostrando que assim como acontece com argamassas de cimento Portland a calcinação completa é um fator crucial para o ganho de resistência mecânica em argamassas geopoliméricas.

Oct 30, 2017

By Sérgio Fernando Nunes

No presente estudo foi realizada uma investigação da influência do teor de hematita especular, percentual e granulometria da carga circulante do pelotamento nos parâmetros de qualidade física das pelotas cruas e queimadas de minério de ferro da Samarco Mineração. Preliminarmente foram executados testes exploratórios em escalas de laboratório e industrial objetivando avaliar o melhor teor de umidade, área superficial específica do pellet feed e carga circulante do pelotamento. Após essa fase exploratória, foi feito o projeto de experimentos dos ensaios de pelotamento e de queima no pot grate, empregando três fatores em dois níveis com ponto central e réplica. A resistência á compressão a úmido e a seco, diâmetro médio e bulk density, foram os parâmetros de qualidade física avaliados para as pelotas cruas. A resistência á compressão, índice de tamboramento e abrasão, porosidade e bulk density, foram os parâmetros de qualidade física avaliados para as pelotas queimadas. O atributo percentual de pelotas nucleadas queimadas também foi avaliado. Concluiu-se que a mineralogia, granulometria do pellet feed e composição da carga circulante influenciam fortemente na qualidade física das pelotas cruas e queimadas.

Aug 1, 2018

By Jorge Luiz Soares do Couto

O presente trabalho tem como objetivo realizar uma análise comparativa do comportamento de quatro metais de solda obtidos pelo processo arame tubular de forma a avaliar o efeito da relação Ni-Mn nas propriedades mecânicas. Foram soldadas juntas multipasse, com consumíveis da classe 110ksi de resistência mecânica, preaquecimento de 200°C, corrente contínua e posição plana e aporte térmico nominal de 1,2 kJ/mm. Após a soldagem, realizaram-se ensaios mecânicos e metalográficos em corpos-de-prova retirados integralmente do metal depositado, na condição de como soldado e após tratamento térmico pós-soldagem. Os resultados mostraram que as melhores propriedades mecânicas foram obtidas para uma composição contendo 1,35%Mn e 2,50%Ni. Adicionalmente, verificou-se que o tratamento térmico pós-soldagem propiciou uma redução da tenacidade ao impacto dos metais de solda de maior resistência devido à precipitação de carbetos nos contornos de grão.

Aug 7, 2018

By Leandro de Almeida

As curvas limite de conformação (CLC) são utilizadas há mais de 50 anos. Propostas inicialmente para o desenvolvimento de produtos provenientes da indústria automobilística, em função das necessidades apresentadas pela indústria de estampagem elas são aplicadas atualmente de maneira geral na produção de inúmeros tipos de peças, oferecendo previsões de possíveis falhas e/ou defeitos durante as etapas do processo de estampagem. As CLC´s permitem prever o afinamento excessivo, enrugamento, estiramento e é claro, a fratura da peça. A raiz da curva limite de conformação (CLC0) é considerada como a mínima deformação obtida pela curva, ou seja, a obtenção de deformações superiores pode levar a peça a falha. As ligas de latão compostas por cobre e zinco, são utilizadas em inúmeras aplicações que necessitam de excelente estampabilidade, como o repuxo profundo, objetivado na fabricação de projéteis. Desta forma, torna-se interessante o entendimento da CLC ou CLC0 para liga de latão em estudo. A obtenção da CLC0 através de ensaios de tração uniaxial no plano da chapa pode ser realizada de acordo com corpos de prova de formatos específicos, como os propostos por Björklund e Nilsson (2014), IRSID (1975) e Wagoner (1980 e 1981). Concluiu-se que o corpo de prova proposto pelo IRSID (1975) é o que melhor se apresentou na determinação das deformações e1 x e2 e com rompimentos dos corpos de prova na região central.

Oct 30, 2017