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By M. F. Chambers

Neodymium metal was electrowon from a molten-chloride electrolyte at 650° C using a molten-metal cathode. A 50 mol pct NdC13-50 mol pct KC1 mixture served as the electrolyte. Binary metal alloys of 'Mg with Zn and Mg with Cd were used as molten cathodes. Under the best conditions, current efficiencies were 90 pct with a Mg-Zn cathode and 80 pct with a Mg-Cd cathode. Vacuum distillation was performed at 1,100° C for 30 min under a vacuum of 10-3 to separate the cathode metals from the neodymium. Neodymium metal of 99.9+ pct purity was recovered from the Mg-Cd alloy cathode. Almost 2 pct zinc remained in the neodymium recovered from the Mg-Zn alloy.

Jan 1, 1989

By Y. Ye

Typically, rougher molybdenite flotation and recovery from bulk copper/ molybdenum concentrates involves the use of alkalisulfides, Nokes reagents, cyanides, oxidants, and/or thermal treatment for the depression of copper sulfide minerals. The bulk copper/molybdenum feed generally varies from 0.2% Mo to 1.0% Mo, and with traditional reagents the single-stage rougher flotation recovery of molybdenite varies between 40 and 90% at a concentrate grade of 5 to 10% Mo. With ozone conditioning for copper depression, however, improved separations appear to be possible, as demonstrated by tests with Cu/Me concentrates from both the Phelps Dodge Morenci Operations and the Kennecott Copperton Operations. Single-stage rougher flotation after ozone conditioning can provide a molybdenum concentrate at a recovery of more than 90% and a rougher concentrate grade higher than 20% Mo in some cases. Subsequent cleaner flotation with additional ozone conditioning results in relatively copper-free molybdenum concentrates containing as much as 52% Mo. Preliminary analysis indicates that, with a multistage ozone conditioning/flotation strategy, the process is technically and economically viable and should be suitable for industrial application.

Jan 1, 1990

By C. R. McClung

"Molybdenum, in the form of molybdenite, is a common byproduct of many copper mining and concentrating operations. Contrary to most copper sulfide minerals where recovery is principally liberation controlled, the recovery of molybdenite is much more complex with fully liberated particles commonly lost to tailings. It is this complexity that facilitated the necessity for a geometallurgical investigation of molybdenite from the Bingham Canyon deposit. The aim of this investigation was to determine the effect mineralogy and/or mineralogical attributes (i.e. morphology, angularity, liberation, size) have on the recovery of molybdenite in the processing circuit. A set of samples was collected from the ores and products produced by Rio Tinto Kennecott’s Copperton Concentrator. All samples were analyzed using normal polarized reflective light, Mineral Liberation Analyzer (MLA) and X-ray diffractometery (XRD) techniques. The results of this investigation revealed the presence of two distinctly different types of molybdenite, which have been identified as the two polytypes of molybdenite, i.e. hexagonal (2H) and rhombohedral (3R). The 2H polytype occurs as textbook-shaped particles in quartz-molybdenite veins that are located in the core of the Bingham Canyon deposit. The 3R polytype occurs as disseminated, “ball”-shaped particles with a dull or frosted appearance along the margins of the mineralized intrusive body or central core. Concerning their metallurgical behavior each type exhibits unique metallurgical properties that are consistent with those reported in the published literature. For instance, the 2H polytype is easily ground and kinetically “faster” floating with surface attributes that are amenable to higher rates of recovery. This commonly results in the production of a high quality molybdenum concentrate under normal operating conditions common to most copper concentration operations. In contrast, the 3R polytype is difficult to grind and kinetically “slower” floating with surface attributes that less amenable to recovery under normal operating conditions. Therefore, in deposits with higher concentrations of the 3R polytype, modifications to the normal operating parameters may be necessary to improve the recovery of molybdenum. Finally, a preliminary investigation into the metal budget of porphyry Cu and Mo deposits indicates that a positive correlation may exist between the total economic metal budget and the polytype content. For example, higher concentrations of the 3R polytype appear to be more prevalent in Au-enriched porphyries versus Mo-enriched porphyries. This observation may also serve to help explain why it is easier to obtain high rates of recovery in Mo ± W-rich deposits, which contain little to none of the 3R-polytype. Consequently, the potential for the metal budget of a porphyry deposit to be used as an indication of the molybdenite polytype present, as well as its impact on the economics (exploration) and/or on the processing circuit (plant design) could exist. In conclusion, this investigation highlights the necessity of understanding the mineralogical properties or characteristics of molybdenite and/or other economic mineral(s), as these can and will have a direct impact upon the performance and plant optimization."

Jan 1, 2016

By R. Craig McClung

Contrary to other sulfide minerals, where recovery is principally liberation controlled, the recovery of molybdenite is more complex. It is this complexity that initiated a geometallurgical investigation of molybdenites from Bingham Canyon. The aim of this investigation was to determine the effect mineralogy and/or mineralogical attributes have on recovery. All samples were analyzed using normal mineralogical techniques. The results reveal the presence of two distinctly different types of molybdenite. These have been identified as the two polytypes of molybdenite: i.e. hexagonal (2H); and rhombohedral (3R). The 2H-polytype occurs as textbook-shaped particles in quartz-molybdenite veins that are located in the current pit bottom. The 3R-polytype occurs as disseminated, “ball”-shaped particles with a dull or frosted appearance and are concentrated along the margins of the current pit. Concerning their metallurgical behavior, each type exhibits unique metallurgical properties that are consistent with those reported in the published literature. The 2H-polytype is easily ground and kinetically “faster” floating with surface attributes that are amenable to higher rates of recovery. This results in the production of a high quality concentrate under normal operating conditions. The 3R-polytype, by comparison, is difficult to grind and kinetically “slower” floating with surface attributes that are less amenable to recovery. Therefore, in deposits with higher concentrations of the 3R-polytype, modifications to the normal operating parameters may be necessary to improve recovery. This investigation highlights the necessity for understanding the mineralogical characteristics of any economic mineral(s), as these will have a direct impact on recovery.

By C. R. McClung

"Molybdenum, in the form of molybdenite, is a common byproduct of many copper mining and concentrating operations. While the recovery of most copper sulfide minerals is principally liberation controlled, the recovery of molybdenite is much more complex, with fully liberated particles commonly lost to tailings.A geometallurgical investigation was undertaken of molybdenite from the Bingham Canyon deposit with the aim of determining what effects, if any, mineralogy and the mineralogical attributes of morphology, angularity, liberation and size have on molybdenite recovery in the processing circuit. A set of samples was collected from the ores and products of Rio Tinto Kennecott’s Copperton Concentrator. The samples were analyzed by normal polarized reflected light microscopy, X-ray diffractometry, and scanning electron microscopy using a Mineral Liberation Analyzer, revealing the presence of two distinct types of molybdenite, which are the two polytypes: hexagonal (2H) and rhombohedral (3R). The 2H polytype occurs as textbook-shaped particles in quartz-molybdenite veins located in the core of the deposit, while the 3R polytype occurs as disseminated, ball-shaped particles with a dull or frosted appearance along the margins of the mineralized intrusive body or central core. Each polytype exhibited metallurgical properties consistent with those reported in the literature. The 2H polytype is easily ground, kinetically “faster” floating and displays surface attributes that are amenable to higher rates of recovery. This commonly results in the production of a high-quality molybdenum concentrate under normal operating conditions at most copper concentration operations. The 3R polytype is difficult to grind, kinetically “slower” floating and displays surface attributes that are less amenable to recovery. Therefore, in deposits with higher concentrations of the 3R polytype, modifications to operating parameters may be necessary to improve the recovery of molybdenite.A preliminary investigation into the metal budget of porphyry copper and molybdenum deposits indicated a possible positive correlation between total economic metal budget and polytype content. Higher concentrations of the 3R polytype appear to be more prevalent in gold-enriched porphyries than in molybdenum-enriched porphyries. This may help explain why it is easier to obtain higher rates of recovery in molybdenum ± tungsten-rich deposits, which contain little to none of the 3R polytype. There is a potential for the metal budget of a porphyry deposit to be used as an indication of the molybdenite polytype present as well as its impact on the economics, in terms of exploration, and the processing circuit, in terms of plant design."

Jan 1, 2016

By D. L. Morgan, J. A. Butterfield

"Geological data, production trends and current projects underway suggest that enough molybdenum will be available from more diversified sources to meet the world's growing demands. The growth in molybdenum consumption has been primarily related to its beneficial effects as an alloying agent in steel. This rapid growth has been deliberately fostered by stable prices, adequate supply and application research. The molybdenum industry is now in a process of change which has been seen in several other metals, such as aluminum and nickel. As supply sources have become more diversified, the market has become more competitive. The recent drop in consumption has led to excess production capacity, accumulation of substantial producer inventories and increased market uncertainties. While consumption is expected to increase in the next two to three years, it will take some time to absorb the excess capacity and inventory. The increased proportion of by-product capacity indicates that prices may become more variable. Producer discipline will be required to prevent serious price erosion in times of surplus. Future prices may not continue to increase with inflation. For the longer term, several factors favour the increased consumption of molybdenum. Engineering requirements are becoming more severe and molybdenum alloys can help to meet these changing needs. In addition, consumers can rely on a large and increasing supply of molybdenum. A 7 per cent growth rate in consumption can probably be sustained through the next decade, but new applications and reasonably stable prices will be needed to make this possible."

Jan 1, 1972

By J. Andres

"Freeport-McMoRan’s Sierrita operations refines molybdenum disulfide in a ferric chloride leach to remove impurities. To understand bottlenecks in the leach process and the true capacity of the leach system, a cross-functional team was established to look at theoretical models, kinetics of the leaching process, equipment limitations and operational strategies. A series of in-plant tests were run which resulted in a road map for improved throughput. INTRODUCTION Molybdenum, a vital component in the steel industry, is often found in nature as molybdenum disulfide (MoS2). Molybdenum disulfide deposits can exist as standalone components in an ore body, or can also be found within copper porphyry nodes. Processing for these copper/molybdenum porphyry ore bodies involves a first stage of flotation to produce a bulk concentrate before separation of the copper and molybdenum concentrates in a second stage of flotation. In this second stage of flotation, a reagent is added to suppress the copper particles, while allowing the molybdenum disulfide particles to remain hydrophobic and continue to float. This separation is very good at keeping the molybdenum out of the copper concentrate; however a portion of the copper continues to float through the circuit. As a result, there is typically some amount of copper in the final molybdenum concentrate. This copper must be removed in order for the molybdenum disulfide product to meet product quality specifications. Once the raw molybdenum disulfide product has been made, a separate process must be applied to remove any copper, lead, or other impurities remaining in the concentrate. This process usually involves the selective leaching of impurities out of the bulk solid. Gupta mentions three specific types of leaching agents, sodium cyanide, ferric chloride, and hydrochloric acid for the removal of sulfide impurities. Sodium cyanide is useful for the removal of copper compounds such as bornite, covellite, and chalcocite.1 Sodium cyanide solution dissolves these copper compounds, and the remaining molybdenum solids are filtered to produce a pure molybdenum concentrate. Ferric chloride works similar to that of sodium cyanide, but is particularly efficient in removing chalcopyrite and galena compounds. These compounds are easily chlorinated at elevated temperatures, producing copper chloride and lead chloride, through the reactions presented below:"

Jan 1, 2015

By T. McCallum, C. Cooper, C. Lewis

"Following a successful solvent extraction (SX) pilot plant demonstration in 2016, CYANEX® 600 has been used commercially to recover molybdenum from concentrate leach liquor since March 2017. Consistent with the piloting results, the commercial plant has achieved expected molybdenum recovery, a significant reduction in base consumption, and a step-change improvement in physical performance. This paper highlights the optimization activities and plant performance from startup through normal operation. INTRODUCTION Historically, tertiary amines have been the most commonly used extractant for molybdenum and rhenium recovery. Tertiary amines utilize a protonation of the ligand combined with an anion exchange mechanism as proposed in equations (1-2). R3N + H+ ???R3NH + (1) 4R3NH+ + Mo8O264- ???(R3NH+)4Mo8O264- (2) In addition to the transfer of Mo and Re, the amine transfers acid and other anions to the strip liquor. The undesirable transfer of other species increases base consumption during stripping, impacting operating costs. Additionally, lower solubility of molybdenum-amine complexes create operational challenges, resulting in diminished physical performance. The presence of colloidal Si in concentrate leach liquors and the formation of Pickering Emulsions adds to the physical plant performance challenges with the amine extractant. CYANEX® 600, a phosphinic acid-based extractant, uses a cation exchange mechanism proposed by equation (3). 2(H2R2) + MoO22+ ??(HR2)2MoO2 + 2H+ (3) The cationic exchange mechanism eliminates chemical transfer of acid and other anionic impurities and avoids some of the physical challenges of the amine extractant (emulsion and 3rd phase formation). In addition, the reagent offers high selectivity for Mo over Re, which may be desirable in certain moly pressure oxidation (POX) flowsheets. Alkali base (ammonium hydroxide, sodium hydroxide, sodium carbonate, etc.) is used for molybdenum stripping. Therefore, reduction or elimination of chemical acid transfer from extract can significantly reduce base consumption in strip. Extensive laboratory and pilot plant testing was completed to evaluate the use of CYANEX® 600 for molybdenum recovery at Freeport-McMoRan’s Bagdad operation. The test work and pilot demonstration confirmed a reduction in base consumption along with improved selectivity. In addition, the evaluation highlighted a step-change improvement in physical performance over the incumbent amine extractant. The decision was made to convert the commercial operation to CYANEX® 600 in March 2017."

Jan 1, 2018

By Joseph Hyde Pratt, Douglas B. Sterrett, CHAPEL HILL

I. DESCRIPTION. MONAZITE is one of the minerals which, for a long time, was considered rather rare in its occurrence, but, upon a commercial demand arising for it, prospectors and engineers soon located large deposits of it in the Carolinas and Brazil, and the supply has always been able to meet the demand. During 1908 further sources of supply of monazite have been discovered and developed in Idaho. North and South Carolina, however, are the only States that have thus far put any monazite on the market. Monazite is essentially an anhydrous phosphate of the rare-earth metals, cerium, lanthanum, and didymium (Ce, La, Di)PO;. There is nearly always present a varying but small percentage of thoria, ThO2, and silicic acid, SiO, which are very probably united in the form of a thorium silicate, ThSiO4 Some monazites contain but a fraction of a per cent. of thoria, while others have been recorded that showed the presence of from 18 to 32 per cent. ; but the majority contain from 3 to 9 per cent. of this oxide. It is the presence of the thorium oxide that gives the monazite its commercial value. The analysis occasionally shows also the presence of other constituents, as the yttrium and erbium oxides, zirconia, alumina, magnesia, lime, iron oxides, manganese oxide, and titanium oxide. Monazite is light-yellow, honey-yellow, reddish-, brownish-, or greenish-yellow in color, with a resinous to vitreous luster, and is translucent to subtransparent. It is brittle, with a conchoidal to uneven fracture, and is from 5 to 5.5 in hardness, and from 4.64 to 5.3 in specific gravity. It crystallizes in the monoclinic system, and some crystals have been observed that were 6 in. in length. The more perfect crystals are, however,

Jun 1, 1909

By Spencer S. Shannon

This chapter is concerned with the uses, geology, exploration, evaluation, preparation for markets, and future of 90thorium and 39yttrium, along with 14 rare-earth elements. The rare-earth metals or lanthanides were divided into three categories by Berzelius. The cerium subgroup is comprised of 57lanthanum, 58cerium, 59praseodymium, 60neodymium, and 62samarium. 61Promethium does not occur naturally. The terbium subgroup includes 63europium, 64gadolinium, and 65terbium. The remaining lanthanides are placed in the yttrium subgroup. Strictly speaking, yttrium is not a rare earth. Because the properties of yttrium resemble those of heavy rare earths, its name has been used as a designating adjective. The yttrium subgroup includes 66dysprosium, 67holmium, 68erbium, 69thulium, 70ytterbium, and 67lutetium. Rare-earth elements, especially those of the same subgroup, tend to occur together rather than in discrete minerals.

Jan 1, 1975

THE CHAIRMAN.- This meeting is under the auspices of the American Institute of Mining and Metallurgical Engineers, and I think the germ of the idea originated in the steel business. Last year there was a meeting of prominent people in the steel industry with the idea of getting together and discussing practical phases of their business, so that everybody could contribute and from that there might be benefit derived for the industry. Several months ago when Mr. Bain was in Salt Lake City, he and Mr. Oldright asked me what I, as an individual, thought of it. From that originated this idea of having the copper people come together to discuss reverberatory smelting and all its phases. In starting out, it seemed the best plan to ask members what particular subjects they wished to discuss first; that is, the ones that would be considered more important. We asked Mr. Oldright, or suggested sometime ago that the meeting be postponed until May because May is a lovely month in Salt Lake. There are a number of attractive features around the city. We have a number of smelters here and I think that probably the most of the benefit will be derived from talking in an informal way and visiting the various plants around. the valley. At any rate, speaking as a resident of Salt Lake, I am glad to see all of you gentlemen here, and hope you have an interesting and instructive time. The tentative list of subjects for discussion at this conference is as follows: Construction Walls, etc. Walls, proper design and thickness of brick for various types of charging. Bottoms, construction of. Binding steel, correct weight and arrangement, where thrust of arch should be taken. Refractory materials, feasibility of using different material in various parts of the furnace. Water jackets, where applicable. Should bricks be used inside of same. Gas space, proper design for, height of roof above bath, etc. Roof Shape of Roof, in hot zone and elsewhere, longitudinally. Construction of roof, in various zones, around openings.

Jan 1, 1930

By Meylin Terrel-Gutierrez

El presente texto muestra un modelo cuasianalítico para predecir la SD (Sechi) en cuerpos de agua claros y turbios. El enfoque está basado en el la relación inversamente lineal entre la SD y las concentraciones de OAS, donde la última ha sido reemplazada por su banda de reflectancia correspondiente o sus combinaciones propuestas por estudios previos de acuerdo con el tipo de cuerpo de agua.

Jan 1, 2014

By Klaus Rabensteiner, Klaus Chmelina

"INTRODUCTION Urban tunneling is often related with special geotechnical risks. Typical causes are difficult (hydro)geological conditions, a very low overburden and the presence of critical and vulnerable (infra)structures in the influence zone of the construction (e.g. existing tunnels, roads and pavements, sewer pipes, gas and power lines, landmarked buildings, historic monuments). To manage these risks appropriately, an early detection and warning of unexpected behavior of the affected geotechnical objects ground and tunnel, as well as existing structures are mandatory. To accomplish this, the design and execution of a dense geotechnical monitoring program is of high importance. In more detail, this means specifying and performing a systematic and continuous acquisition, processing and analysis of monitoring data to support decision making. In recent years the development of new automatic sensors and (wireless) data transfer techniques and the general trend towards an automatic acquisition of monitoring data has led to an enormous increase of data production frequencies and volumes. In order to handle this data explosion efficiently, information systems and geo-databases have been developed and used successfully in many projects. They represent IT tools that support the different tasks of a given geotechnical monitoring program including data acquisition, transfer, check, processing, backup, analysis, distribution, reporting and, last but not least, alarming. Meanwhile, some tools already have developed the capability to connect to other theme-specific databases used in the project and, thus, serve as a central data management system for all kind of digital data produced. This makes possible the implementation of further useful functions and services supporting tunneling tasks such as machine control, tunnel simulation, geological prediction, process optimization, etc. where data from different engineering disciplines must be combined and processed in an integrated way. In the following chapters our aim is to describe how monitoring data management, geotechnical monitoring, alarming and reporting are organized and technically implemented at the metro project Cityringen in Copenhagen (Denmark). We want to highlight the specific role and tasks of the used tunnel information system in the project, and particularly inform on the most relevant challenges."

Jan 1, 2016

The prediction and control of ground deformations due to underground mining are important considerations in the permitting, planning, and monitoring of coal mining operations. The prediction of mining-induced ground movements using the influence function method is a mature technology and is widely used in many coal basins around the world. Such movements mainly include subsidence, horizontal displacement, and horizontal and/or ground strain. Predictions can be accomplished using regional subsidence parameters and site-specific data.

Jan 7, 2020

By Marcia L. Harris

Toxic fumes produced by detonating explosives in surface mining and construction operations pose potential hazards to workers and the public. Blasting operations produce both toxic and nontoxic gaseous products; the toxic products are mainly carbon monoxide (CO) and the oxides of nitrogen (NOx). Since 1988, there have been 17 documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through ground strata into occupied enclosed spaces as a result of proximate trench blasting or surface mine blasting. These incidents resulted in 39 suspected or medically verified carbon monoxide poisonings as well as one fatality. At worst people may be fatally poisoned and the least to be expected is increased public objections to blasting. Local and state agencies could demand a cessation of the blasting requiring more expensive mechanical means to break the rock. This paper discusses the most feasible means of preventing CO migration, mitigating CO that has migrated, and detecting CO in an underground enclosed space and may help reduce the exposure of unsuspecting area residents to carbon monoxide and help prevent the implementation of unnecessary regulations and limitations on blasting. Single-hole shots and small-scale multiple-hole blasts were performed that indicate promising means of prevention and mitigation.

Jan 1, 2008

By D. Pacey

"This paper reviews the installation, start-up, and operation of a comprehensive monitoring and targeting management technique in which all plant utilities (i.e., electricity, natural gas, compressed air, and water) are managed as controllable resources in the same way that raw materials, mined ore, personnel and capital are managed.The essential elements of monitoring and targeting (M&T) include:•gathering in a systematic, disciplined way the utility information by energy account centres;•closely monitoring the utilities used in each centre and comparing them with production on a common time base (e.g., kWh/ton per day);•bench marking and target setting to pro-vide attainable energy reduction goals which can be further refined as they are achieved; and•establishing an implementation plant that may provide efficiency enhancing benefits to various operating areas within the plant.The M&T system will reduce utility consumption per unit of production on a continuing basis.This would translate into sustained operating cost and waste. M&T will also provide better information for assessing the plant operation and progressively implementing further enhancements."

Jan 1, 1997

By S J. Schafrik, C Keles, C Schlosser, E S. Gilliland, A K. Louk, N S. Ripepi, S Keim, J Amante, E Diminick

Three legacy coalbed methane production wells have been converted to injection wells for a one-year carbon dioxide (CO2) injection test to evaluate the potential for CO2 storage in the coal reservoir and the potential for enhanced gas production at offset wells. The injection reservoir is composed of 15–20 individual coal seams with an average thickness of 30 cm (1.0 ft), spanning a depth range of approximately 240 (800 ft) to 670 m (2200 ft).The monitoring program for this test includes gas and water sampling of the three injection wells, three dedicated monitoring wells and approximately 20 offset production wells. Key technologies used for monitoring the study area include time-lapse GPS and interferometric synthetic aperture radar (InSAR) acquisitions for surface deformation measurement, a 28-station buried passive microseismic monitoring array, real-time downhole pressure and temperature sensing and perfluorocarbon tracer fluids, which will be injected with the CO2 stream. The schedule for the monitoring program includes pre- (baseline), during- and post-injection data collection. This schedule will allow data to be analysed for time-lapse changes and trends, which are important for understanding the migration of gas and fluid phases in the reservoir – including CO2, methane, other hydrocarbons and water – and for observing the changing distributions of reservoir pressures and stresses.The results of the monitoring efforts for this study have implications for monitoring mining operations. The combined use of GPS and InSAR geospatial data to evaluate elevation changes across and beyond the study area may prove to be an accurate option for measuring surface deformation, including mining-induced subsidence, in unstable terrain. Long-term microseismic monitoring using high-sensitivity instruments has several applications in mining operations, including rock stability monitoring, production monitoring and miner location detection during emergencies. Tracer studies and short-term microseismic monitoring used to assess methane extraction can also be used to develop and optimise degasification systems for underground coalmines.CITATION:Gilliland, E S, Ripepi, N S, Schafrik, S J, Schlosser, C, Amante, J, Louk, A K, Diminick, E, Keim, S, Keles, C and Karmis, M, 2015. Monitoring design and data management for a multiwell CO2 storage/enhanced coalbed methane test in a stacked coal reservoir, Buchanan County, Virginia, USA, in Proceedings Third International Future Mining Conference, pp 47–56 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By Stephen Hardcastle

Presentation Outline ? Introduction ? Mine Ventilation Facts ? Ventilation-on-demand (VOD) ? Sensors/Controls ? Continuing Work ? Conclusions ? Mine ventilation engineering practices were published in 1556 in Agricola?s De Re Metallica (wind sails, bellows, etc.) That was then? This is today? Large fan installations handling >1M cfm

Nov 1, 2011

By P. Schmidt, M. Hopf

Water-cooled parts of submerged arc furnaces are potentially dangerous, especially if molten matte or slag contacts the water. Explosion hazards and metal run-outs generate high costs for production loss and repairs - not mentioning the possible loss of human life. This paper reports about practical results of wear measurement on intensive water-cooled tap-holes and spray-cooled side walls. On the one hand an embedding technology has been developed, that is used e.g. in water-cooled copper tap blocks or copper side wall coolers. Second the application of the sensor installation on the inner side of a water-cooled steel shell will be discussed. The fibre-optic sensor is fed through a specially arranged piping system and measures numerous temperatures over its entire length. By using the thermal conductivity of the installed refractory materials the lining thickness is calculated. The practical installation of the sensors will be discussed and the results of the wear measurement will be compared to the theoretical FEM calculations. The highly sensitive and accurate temperature measurement, as well as the recalculation of the impact of differences in the cooling water temperature, allows the exact determination of the remaining lining thickness. The discussed technologies offer efficient and safe monitoring of tap-holes, side walls and other endangered parts of pyro-metallurgical smelters.

Jan 1, 2015

By K. Thuro, H. Käsling, C. Wieser, G. Nuijten

"The time-dependent behavior of brittle rocks during stress relaxation is of great interest for mining industry, nuclear waste disposal as well as tunneling and underground construction. Several studies have shown that both elastic as well as inelastic deformation occur during stress relaxation (Emery, 1964; Zang & Berckhemer, 1989). While elastic strain occurs already during the drilling process, inelastic deformation is time-dependent and can endure for hours, days or weeks. To investigate the evolution of microcracks during core relaxation, two crystalline core samples were recovered from high in situ stress conditions in Europe’s deepest mine in Pyhäsalmi (Finland). Samples were prepared for testing within one hour after coring such that a large portion of the time-dependent component of relaxation could be recorded over several days using ultrasonic velocity as well as acoustic emission (AE) measurements.Results from AE analysis show an exponential decrease in the number of events over a period of several hours. Repeated sudden increases of acoustic events can be related to the propagation or the interaction of cracks. In the first hours of recording also the signal energies reached the highest values and the increases in signal energy correlate well with increased event rates. On additional drill cores, P-wave velocities were measured parallel and in 45° distances perpendicular to the core axis. After core recovery, stress-induced microcracking caused an exponential decrease in wave velocities similar to AE rates. Lowest compressional wave velocities were measured parallel to the core axis and thus normal to the foliation and in the direction of the maximum in situ stress component. The highest measured velocities occurred parallel to the foliation plane. Within the samples, the anisotropy ratios were up to 1.37 at the beginning of the measurements and increased to values of up to 1.8 after 45 days. The wave velocity anisotropy is in agreement with the in situ stress orientations."

Jan 1, 2015