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By Thomas Niehoff, Dave Stoffel

"Energy in the form of natural gas, oil and electricity is expensive and will continue to be a rare resource in the future. Recycling of metals, instead of primary production, is a logical and crucial step towards energy conservation. Energy consumption can be impacted by using advanced combustion systems for metals recycling. Air-fuel combustion has been the conventional method to melt and recycle metals. Global competitive pressures, “greenhouse” gas emissions, and high energy prices force melt shop operations to optimize energy usage and reduce overall operating costs. Oxy-fuel combustion and process technology can be applied to metal recycling operations to meet these objectives. Linde has converted several hundred furnaces from air-fuel to oxy-fuel technology and has extensive experience in optimizing the use of oxygen in furnaces. Additionally, Linde has the process knowledge necessary to avoid costly start-up issues that can accompany the transition to oxy-fuel technology. This paper will describe the benefits and potential issues for conversion to oxy-fuel.IntroductionThe furnace combustion system is the heart of a fossil fuel fired melting process and must be properly matched to the furnace to work as one cohesive unit. Furnaces vary widely in size, shape and features. Rotary furnaces are barrel-shaped and can be designed for tilting or nontilting operation. In a rotary furnace, the products of combustion create a single or double pass through the furnace prior to exiting. Reverberatory furnaces are box-shaped and can also be designed for tilting or non-tilting operation. Reverberatory furnaces are constructed of single or multiple chambers, with or without metal bath movement, and designed for continuous or batch processing. Different furnaces are used for different feedstock materials and products.Furnace combustion systems also vary in many ways. Combustion systems can be of air-fuel or oxy-fuel based technologies, or a combination of the two, resulting in an air-oxy-fuel system. Each of these types of systems has different combustion characteristics which can produce very different results. Here we will describe specific differences in melting processes and their associated energy requirements."

Jan 1, 2009

By Massimiliano Zanin, William Skinner, Owusu Clement, Jonas Addai-Mensah, Daniel Fornasiero

This paper highlights the importance of pulp aeration in the selective separation of chalcopyrite from chalcopyrite/pyrite mixtures of varying pyrite content (20-80 wt.%). Laboratory batch flotation studies and oxygen demand tests were performed to predict the optimum amount of air required for the selective separation of chalcopyrite from pyrite. The pulp oxygen demand was shown to increase with increasing pyrite content but decrease with time as more air is introduced into the system. Complementary batch flotation tests showed significant improvement in chalcopyrite flotation under moderate pre-aeration of the pulp. However, a continuous decrease of chalcopyrite flotation was observed under highly aerated conditions. The amount of air required to achieve maximum chalcopyrite flotation recovery correlated positively with the mass fraction of pyrite in the pulps. The greater the wt.% of pyrite in the chalcopyrite/pyrite pulp, the longer the aeration time required. The optimum aeration time was established as the time before which the oxygen consumption rate constant reaches a bottom plateau. Surface analysis (XPS) indicated that the continuous decrease in pyrite recovery observed with increasing aeration time was due to the formation of more iron oxy/hydroxide on its surfaces, the same species accounting for the decrease in Cp recovery after prolonged aeration.

Jan 1, 2014

By S Brown

With oxygen conditioning routinely used in both the lead and zinc circuits at Pasminco Elura Mine a more sophisticated method of determining oxygen demand was required. It is known that different ore types have different oxygen consumption rates, however oxygen is added at a fixed rate regardless of ore type in the plant. Therefore, a simple laboratory test was devised to measure the oxygen demand of ores. The paper describes the technique employed, and provides an interpretation of the results. These data, together with pulp chemical measurements (Eh, pH and EDTA extraction data) were correlated against laboratory flotation performance to establish the relationship between oxygen demand and the position of the grade/recovery curve.

Jan 1, 2000

By David J. Krichten

A method of retrofitting air-fuel burners with oxy-fuel capability overcomes the potential problems associated with oxygen combustion in aluminum melting furnaces. The retrofit burner uses the existing combustion air connection, burner housing, and burner tile and replaces the gas tube with an oxy-gas burner. Maintaining a portion of the air flow to the burner reduces the potential for localized overheating. Proper design of the burner reduces NOx emissions by moderating the flame temperature with furnace gas recirculation. Economic analysis of using oxygen shows the benefits are increased productivity and reduced overall unit cost of melting. In practice, the melt rate in rotary furnaces increases by up to 50% and by up to 35% in reverberatory furnaces. Oxygen utilization reduces total melting cost by 112-314 cents per pound of aluminum melted.

Jan 1, 1997

By G. S. Victorovich

Technical progress in primary smelting has changed the face of the copper industry in the years since the Second World War. Much of this change has resulted from a wide acceptance of flash smelting technology. In addition, research has been directed toward devising converting processes to replace conventional Peirce-Smith converting technology. One major thrust has involved a revival of the old " ", idea of oxygen flash converting of comminuted mattes. This paper reviews the 60-year history of flash converting. Particular attention is paid to Inco's investigations into the processing of white metal containing significant amounts of nickel and, in some cases, iron. Thermodynamic analysis and laboratory experimental results are presented which throw light on the behaviour of nickel and other salient features of flash converting. The possible role of oxygen flash converting in the copper pyrometallurgy of the future is briefly discussed vis-a-vis direct production of copper.

Jan 1, 1993

By Helmut Attlfellner

The selection of the best process for the oxygen generator for a metallurgical process requires the determination of all aspects which impact the economics of this facility. Concepts and features of modern air separation plants will be presented based on installed facilities for various metallurgical processes. The special features of advanced automation' of oxygen generators with load following and optimization of power consumption, automatic restart and unattended remote controlled operation will be investigated.

Jan 1, 1992

By L. A. Taylor

The production of oxygen on the Moon utilizing indigenous materials is paramount to a successful lunar colonization. And several processes have been put forth to accomplish this. The LLOX generation schemes which have received the most study to date are those involving?: 1) the reduction of ilmenite (FeTi03) by H2, C, CO, CH4, CO-CI2, & Cl2 plasma, 2) magma electrolysis, both unadulterated and fluoride-fluxed, and 3) several others, including carbo-chlorination, HF acid leaching, fluorine extraction, magma oxidation, and vapor pyrolysis. The H2 reductions of ilmenite and magma electrolysis processes have received the most study to date. They are both feasible schemes with various pros and cons, including their feedstock requirements. However, all processes should be addressed at least at the onset of our considerations. There is an obvious need for considerably more experimentation and study. Some of these requisite studies are in progress, and this paper reviews several of the most studied and feasible processes for winning oxygen from lunar materials.

Jan 1, 1991

By K. J. Murphy, A. R. Smith, A. P. Odorski

"The need for large quantities of oxygen for use in metallurgical processes was a major driving force in the commercialization of tonnage air separation plants. Oxygen, nitrogen and argon impact the quality, energy efficiency and environmental aspects of metals production. Cryogenic air separation processes have been used to supply most industrial requirements, however, newer technologies are available or under development to meet the needs of today's and tomorrow's metallurgical processes. This paper reviews the technical features and state of development of adsorption, chemical, cryogenic and membrane technologies. The technologies are compared in terms of plant size, oxygen purity and pressure, nitrogen and argon co-production, product use pattern and back-up requirements. Computer control systems are described that optimize operation over varying load patterns and ambient conditions; substantially lowering energy consumption. IntroductionOxygen production totalled 390 billion cubic feet in 1987. Although current production is lower than the peak of 455 billion cubic feet reached in 1979, oxygen remains the fifth leading chemical product manufactured in the u.s. (1) Metals manufacturing and fabrication accounts for sixty percent of the oxygen consumed in the u.s. Oxygen use in the steel industry consists of air enrichment for conversion of iron ore, purification of the iron in basic oxygen or other furnaces, and for cutting and welding the finished steel product. Nonferrous ores are smelted in oxygen enriched atmospheres to reduce energy consumption and increase capture of sulfur compounds to meet environmental requirements. In the future oxygen usage is expected to become even more important in metals production as energy costs increase, environmental standards become more stringent, and as new coal based processes become commercialized. Oxygen usage per ton of metal in the new direct reduction processes can be up to ten times higher than traditional steel making."

Jan 1, 1988

By Ismar Antônio Sardinha

Usually outer straight steel tubes are used to blow supersonic oxygen into LD converters (BOF) to make liquid steel, although conical tubes are used too. Inner tube for oxygen blow and intermediary tube for water IN and water OUT are normally straight steel tubes. Present paper shows the influence of outer tube shape and metal used to in lance cooling and, consequently, a skull retention on lance surface. There are two parameters more important related to lance cooling: velocity of water out and the total lance cooling by addition of thermal conductivity of outer tube metal to it. For this comparison outer tubes are made of carbon steel or copper, and can be straight or conical. As related to velocity of water OUT, outer straight tubes have bigger efficiency than conical tubes. As related to total lance cooling, outer tube metal made of copper has much bigger efficiency than steel because of its thermal conductivity 7 to 12 times more depending on work temperature. The lance cooling has much bigger efficiency for the patented SKULLS3® technology with no skulls on the lance and no skulls into the mouth of LD converters (BOF).

Aug 17, 2017

By K. W. Deter

The gold ores in the Jerritt Canyon district have been recognized as refractory since they were first encountered by FMC geologists in 1976. Upon obtaining managing rights as joint venture partner, Freeport McMoRan Inc. developed an operating plan featuring carbon-in-leach gold recovery techniques for the oxide portion of the ores and a patented sulphide oxidation step followed by chlorination for treating the organic carbon constituents of the refractory ores prior to CIL gold recovery. The plant was successfully started up in 1981 with the first gold poured on July 4, 1981. Initial plant throughput was designed to be 2495 MTPD (2750 STPD) total through the dual processing trains.

Jan 1, 1991

By CHARLES R. KETES

I. INTRODUCTORY. INDUSTRIALLY, the most important service that geological science can now render to mining in the Upper Mississippi leadand zinc-fields is to devise some practical scheme whereby the productive ore-belts may be located with greater certainty than they have been in the past. Up to the present time there has been little service of this kind, and in spite of all that has been worked out concerning the geologic features of the region, and notwithstanding all that has been written about these ore-deposits, this particular phase of the subject has been, for some reason or other, the very one that has received the least consideration. The neglect by geologists in this respect has been all but complete. The following notes are suggestive of some practical solutions to the problems presented. As here suggested, the geologic relationships of the ore-bodies were surmised some years ago, though somewhat vaguely perhaps. No opportunity for securing critical data appeared until recent investigations of a private character were undertaken, which bad in view the extensive prospecting of undeveloped areas. Fresh from rather wide experiences of a decade in the principal mining-regions of four continents, and after a lenstrum's residence among the chief mining-camps of the West and of Mexico, under conditions which measured geologic hypotheses in meters and rigidly tested their values in, terms of dollars, the recent return to the Joplin field and a new survey of its ore-conditions were fraught with somewhat unexpected results. Aspects of the ore-deposition were presented of which previously there was no hint. Ten years' absence from the district had tended greatly to clarify former hazy impressions. It enabled many features, then only dimly outlined, to be considered more nearly in their true perspective and in their real relationships to their surroundings. It permitted a great mass of details collected a dozen years before in connection with the work of the Missouri Geological Survey to be viewed under new light and to

Feb 1, 1909

P.T. Freeport Indonesia's latest expansion has increased total mill throughput to 125,000 dry metric tonnes per day. The most recent expansion included the installation of a Semi Autogenous Mill designed to treat more ore than any other single SAG mill currently operating in the world. Also included in the expansion were two large ball mills, rougher and cleaner flotation including conventional and column cells and a regrind circuit. All equipment is supported by a modem distributed control system. This paper describes the design considerations, construction, commissioning and start-up of the SAG concentrator and support facilities and includes an overview of the oreflow and milling facilities.

Jan 1, 1996

By Benjamin W. Haynes

The Bureau of Mines conducted research to provide technical information needed to devise waste management plans for the processing of manganese nodules. Studies included summary descriptions of Pacific manganese nodules, process options and flowsheets, methods for characterizing nodules and their tailings, and results of analyses of laboratory and pilot-plant generated tailings. This information is the result of a cooperative research effort of the Bureau of Mines and the National Oceanic and Atmospheric Administration (NOAA), with NOAA providing funding and the Bureau conducting the research. A summary of the extensive literature review is provided for manganese nodule mineralogy, chemistry, processing techniques, and methods of analyses. Characterizations and analyses of laboratory-generated tailings and slags are given, as well as the results of the leaching studies on these waste materials. Leachability was determined by three standard leachate tests- the Environmental Protection Agency (EPA) extraction procedure (EP) toxicity test, the American Society for Testing and Materials shake extraction test, and the U.S. Army Corps of Engineers-EPA seawater elutriant test. While the wastes generated in the laboratory may not be entirely representative of those to be generated in full-scale plants, results of these studies provide a positive indication that commercial recovery of cobalt, copper, manganese, and nickel from manganese nodules would be environmentally acceptable.

Jan 1, 1985

By A. E. Aho

"The Pacific Nickel property lies 7 miles northwest of Hope and 100 miles east of Vancouver, in the Coast Mountains of southwestern British Columbia. Nickel-copper sulphides were discovered in ultrabasic rocks on this property in 1923 and the deposits were explored by Pacific Nickel Mines until 1937, then again between 1951 and 1954 by Pacific Nickel Mines and by Newmont Mining Corporation through its subsidiary,Canadian Ore DepositsWestern Nickel. The property was studied by C. E. Cairnes (1) in 1924, by W. E. Cockfield and J. F. Walker (2) in 1933, by H. C. Horwood (3), (4) in 1936 and 1937, and by the writer in 1951 and 1952. Except for a few thousand tons for trial shipments, the property has never been mined. Indicated ore reserves now total somewhat over one million tons averaging about 1.4 per cent nickel and 0.5 per cent copper, with lesser values in precious metals and cobalt.GEOLOGIC SETTINGThe nickeliferous ultrabasic rocks form part of the core of a 15-milewide block of Late Palæozoic metamorphic rocks and Mesozoic intrusives which extend north-south between the coast batholith of British Columbia and the Chelan batholith of Washington. Margins of this block are faulted in part against less metamorphosed volcanic and sedimentary rocks largely of Jurassic and Lower Cretaceous age (Geo/. Surv., Canada, Map 737 A, 1942). Serpentinites, suggestive of deep transgressive structure, occur within the block, and also at its east margin along faults which are southern extensions of the regional Yalakom-Fraser River fault zone. Some of the other mineral deposits in the Hope area appear to be spatially related to these major faults.The mineralization at Pacific Nickel occurs almost exclusively within a stock-like mass of ultra basic rocks which mingle with, and partly cut, a larger batholithic mass of genetically related diorites and norites of late Mesozoic age (Figure 1 ). The ultra basic mass consists essentially of fresh, medium-grained hornblendic pyroxenite with peridotitic cores and with a remarkable margin of pegmatitic hornblendite. The most hornblendic rocks appear to be chiefly products of reaction and replacement of the pyroxene and olivine rocks. The mineralization consists of disseminated and massive pyrrhotite, with subordinate pentlandite and chalcopyrite, amongst fresh olivine, bronzite, and, Jess commonly, augite and hornblende. Both the ultrabasics and mineralization are cut by small hornblenditic and dioritic dykes, and by veins and alteration zones."

Jan 1, 1949

By G Corbett

Epithermal Au-Ag deposits form in the upper 1 km of the crust and are therefore best preserved in the less eroded Pacific rim arcs, although also recognised elsewhere. Two profoundly different ore fluid types give rise to low and high-sulfidation styles apparent as variations in ore and gangue mineralogy as well as characteristic zoned wall rock alteration. Low sulfidation epithermal Au deposits are derived from near neutral composite magmatic-meteoric fluids and divided into a group with a stronger intrusion association within arcs grading in time and space from: quartz-sulfide Au + Cu, to carbonate-base metal Au, and the epithermal quartz Au + Ag, whereas in strongly extensional settings the influx of meteoric waters promotes the development of chalcedony-ginguro banded Au-Ag epithermal veins. In the presence of continental crust particularly in Latin America polymetallic Ag-Au veins represent a Ag-rich equivalent of carbonate-base metal Au and passes upwards to chalcedony-ginguro Au-Ag style. By contrast high-sulfidation epithermal deposits are deposited from an acidic magmatic fluid which provided characteristic hydrothermal alteration by reaction with wall rocks grading outwards as mineral assemblages dominated by: vughy silica, alunite, pyrophyllite-diaspore, dickite-kaolin and then illite-smectite neutral clays. Au mineralisation is commonly refractory with enargite deposited dominantly later within the silica zone.Exploration for epithermal Au deposits benefits from an understanding of the controls to mineralisation which commonly give rise to the development of ore shoots with widest and highest Au grade ore zones. In low-sulfidation systems a combination of competent host rocks, dilatant structures, higher grade styles of mineralisation and efficient mechanism of Au deposition, contribute towards ore shoot formation. High-sulfidation epithermal Au systems occur in permeable volcanic and breccia host rocks which are linked by major structures to the magmatic source.CITATION:Corbett, G, 2013. Pacific Rim epithermal Au-Ag, in Proceedings World Gold 2013 , pp 5-14 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By George E. Edwards

Pacific Rim markets for export coal already represent a larger market than the total tonnage imported into the European Community countries and they will continue to expand. The largest importers will continue to be in the sector comprising Japan, Korea, Hong Kong and Tai- wan. It is likely that the total Pacific Rim markets will reach 206 m.t.p.a. by 1990 and 290 m.t.p.a. by 2000, with the major growth in steam coal demand. Australia has an efficient coal industry, represents a stable long term source of supply and is favourably situated geographically to continue to be the largest single supply source.

Jan 1, 1982

By D. G. Ball

Other than being used to convey fill material for the gob stowage or building of ribside packs on advancing longwell faces, pneumatic conveying has not been used for the transport of materials on a large scale in mining operations. The technique is extensively used in the wood products industry for conveying wood chips, limestone and other ingredients for the manufacture of paper, for the transfer from railcars, barges or ships to silos or stockpiles and further transfer into the pulp mills. This method of material transfer has the distinct advantage of transporting suitable material over horizontal and vertical distances within the same system. In considering material associated with mining, this includes, ore, coal and rock up to 4 inch cubed size, throughputs of 200 tons per hour over horizontal distances of 3000 feet or vertical lifts of 2000 feet. In recent years tests have been carried out to determine the physical and economic limitations of pneumatic hoisting, the results of which have led to the installation of two fully productive coal hoisting systems at mines of the National Coal Board in Great Britain. The equipment used for the pneumatic hoisting of coal or waste rock is described in this paper, together with a brief history of the tests which led up to the installation of the two hoisting systems in Great Britain.

Jan 1, 1977

By Ray Brainard, Adriana Ventimiglia, Amanda Kerr

The $2 billion Horizon Lateral includes over 30 miles of trenched and tunneled pipeline with diameters up to 120 inches.Related infrastructure includes large and small pumping stations, reservoirs, and flow control facilities. This paper will discuss the strategy and processes used to determine contract packaging and contracting delivery methods for the various project elements with an emphasis on the tunnels and trenchless crossings. Prior Authority experience and the rigorous risk-based approach to develop the preferred alignments played a large role in determining the outcomes along with schedule concerns and permitting and easement acquisition.

Jun 13, 2023

By J. Ye

A comprehensive flotation study has been carried out on a Chinese fluorspar ore using the packed flotation column developed at Michigan Technological University. The results are compared with that of a conventional mechanical flotation method on the same feedstocks. Key factors controlling flotation performance of both methods are evaluated based upon a simple statistic design. The flotation concentrate produced in one stage of the packed column has 4-S% higher recovery and much lower silica impurity content than that produced by up to six stages when a conventional mechanical cell is used. The results also show that the packed column flotation process is particularly suitable for recovery of finer fluorspar particles.

Jan 1, 1992

By David Yang

Commercially available flotation technologies for recovery of mineral fines have remained essentially unchanged for several decades. Recent studies have focused simply on improving mechanical and open column cells. Such studies have explored different control strategies and have aimed to improve reagent selectivity, fine air bubble generation and particle-air contact. However, no study has questioned whether current techniques are the most efficient technology for recovering mineral fines. Given that both mechanical and open column cells have a widely accepted carrying capacity limitation, the lack of extensive research into an alternative technology is surprising. Most recently, open column flotation has become an entrenched technology, and it is undermining the efficient recovery of mineral fines worldwide. An alternative exists. Packed column flotation overcomes the above-stated problems as the technology surpasses the carrying capacity limitation of current means by several-fold and almost always achieves the best performance in many comparative pilot tests and full-scale plant operations. Filling a column with packing plates creates a network of sloped walls capable of supporting a froth bed many times deeper than conventional machines. Having froth up to 75 percent of the total column volume tolerates all feed changes encountered in the plant environment and permits maximum flexibility in concentrate quality control. Furthermore, its scale-up is straightforward by increasing column volume or the number of interconnected small cells. As the air breaks upon rising and is distributed horizontally through packing plates, the air spargers can be replaced with a simple blower, resulting in considerable savings in operation and maintenance costs. Packed flotation technology provides a break-through solution for the separation of fine and ultra-fine minerals. Its simplicity, superior performance, and low cost structure make it an appealing alternative to current technologies and allow greater flexibility in downstream processing. Future industrial applications include a wide variety of metallic and non-metallic ores. This paper focuses on some recent scale-up campaigns for nickel and copper sulphide flotation applications compared directly to conventional equipment.

Jan 1, 2014