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By G. H. Khoe

Although some hydrometallurgical process liquors contain significant amounts of ferrous and arsenate ions, no reliable thermochemical data for the aqueous complexes and the solubility of the ferrous arsenate precipitate are available. The complexation of iron(11) with arsenate has been investigated using the potentiomemc titration method. The results indicated that virtually no complexation of iron(@ with arsenate has been observed. This is in contrast to the significant complexing reported for iron(1n) with arsenate. The solubility product of the precipitate was calculated using the concentrations of appropriate arsenate species pertaining to the observed precipitation pH's. The fit of the observed precipitation points on the solubility curve of the computed stability diagram was used to assess the appropriateness of the equilibrium model.

Jan 1, 1991

By Francis Breton, Daniel Larouche, Pierre Heugue, Rémi Martinez

"Nowadays, in order to fit environmental restrictions, automotive markets are demanding cast aluminum alloys working at high temperature (180–300°C). New generations of alloys are required for higher strength components in engine downsizing or start-stop systems which lead to higher loading and higher specific power and stretch current materials to their limits. Recently, transition metals, such as zirconium and vanadium, have been added as alloying elements into an AlSi7Cu3.5Mg0.1 alloy to improve physical, mechanical, thermodynamic properties with the aim of increasing service life of parts. In such alloys, the best mechanical properties are associated with the formation of precipitates through an optimum heat treatment sequence, including: solutionizing, quenching and artificial aging. This study is focused on the modified AlSi7Cu3.5Mg0.1 cast alloy with Mn, Zr and V additions for high temperature application. The characterization of the cast alloy in this study, firstly, helps to evaluate and understand its performance both chemically and structurally according to their physical state: as-cast or as-quenched. Comparison of precipitation kinetics between a binary Al-3.5%wt.Cu alloy and the AlSi7Cu3.5Mg0.1 (Mn, Zr, V) alloy has been characterized by differential scanning calorimetry, TEM observations and micro-hardness testing. The Kissinger analysis was applied to extract activation energies from non-isothermal DSC runs conducted at different stationary heating rates. The study focuses on the impact of the chemical composition such as Si content on the kinetics parameters.INTRODUCTION Pure metal Aluminum shows poor mechanical properties and its malleability is high, that is why alloying elements are added to the mixture before casting to improve physical, mechanical and thermodynamic properties (Javidani, 2015); such as Silicon (Si) for casting properties (castability, cold crack capability, wear resistance, shrinkage behavior), Magnesium (Mg) and Copper (Cu) to generate precipitation hardening systems. Aluminum hypoeutectic alloys (<12% Silicon) with Cu, Mg additions used in the automotive industry for manufacturing mechanical parts (Larouche & Javidani, 2014) are mostly subject, after casting, to precipitation hardening heat treatment (Mohamed & Samuel, 2012) according to specifications and associated standards. The best mechanical properties are associated with the formation of precipitates through an optimum heat treatment sequence, generally including: solutionizing, water quenching and artificial aging (Manente & Timelli, 2011). Hypoeutectic aluminum-copper alloy with amount of Cu around 1 to 4.5wt% is an elementary case for precipitation in heat treatable aluminum alloys. Researchers essentially focused their work on the full precipitation sequence of binary Al-Cu alloy during aging which is presented below."

Jan 1, 2018

By S. Hunt, S. Jayasekera, J. Kyle, N. Perera, K. Stone

A preliminary investigation has been conducted to determine the conditions for the precipitation of phosphate from the liquor produced after a hydrochloric acid pre-leach and rare-earth recovery from a rare earth containing fluorapatite concentrate from the Nolans rare earth deposit in the Northern Territory of Australia. The results show that at 50oC the phosphate can be precipitated in two stages using limestone to produce a Stage 1 precipitate containing most of the impurities including iron (94%), aluminium (92%), fluoride (98%), uranium (84%) and thorium (94%), followed by a relatively pure Stage 2 dicalcium phosphate precipitate (DCP) containing only 0.05% Fe, 0.05% Al, 0.1% F, 0.01% U, and <0.01% Th. The initial Stage 1 precipitate contained about 25% of the phosphate while the remaining 75% reported to the Stage 2 phosphate precipitate. Depending on the required radioactivity specifications, the amount of phosphate in the Stage 1 precipitate could be reduced. Reagent requirements were 11.4 kg limestone (as pure CaCO3) per cubic metre of solution for the Stage 1 precipitate and 39.7 kg limestone (as pure CaCO3) per cubic metre for Stage 2. The analysis of radionuclide balance indicated that radionuclides deported mainly to the final filtrate (86.4%) compared to Stage 1 precipitate (5.4%) and Stage 2 precipitate (8.2%). Settling and pressure filtration tests indicated the precipitates were both readily settled and filtered. The final moisture contents of the Stage 1 and Stage 2 precipitates were 62.5% and 49.3%, respectively.

Jan 1, 2014

By L. Becze, S. J. Hock, G. P. Demopoulos

"Regeneration of HCl from chloride solutions is commercially practiced by high temperature (800-900 °C) pyrohydrolysis associated with high energy consumption and capital cost. As an alternative to pyrohydrolysis a novel low temperature ( <200 °C) non-autoclave hydrolytic process has been studied in this research work, which comprises two steps. In the first step, ferrous chloride is oxidized by oxygen at 1;150 °C, followed by hydrolytic decomposition of ferric chloride to coarse hematite particles and superazeotropic hydrochloric acid (8-9M) operated at approximately 180 °C. This paper provides a summary of the laboratory results related to both oxidation and hydrolysis and presents a newly designed conceptual process flowsheet.IntroductionRecovery of base, noble and rare metals from ores and secondary materials (slags, dusts, residues) by chloride-based hydrometallurgical processes holds a lot of promise if a low cost HCl process becomes available. This is particularly so due to the high activity of HCl or more accurately activity of hydrogen ion [1] in concentrated chloride media and the formation of chlorocomplexes allowing for effective leaching under atmospheric leaching conditions and simultaneous ease of metal separation. However, during leaching significant amount of iron, which is associated with most of ores and secondary materials, goes into the solution. Hence, the obtained leach solution has to be treated to convert iron chlorides into easily filterable iron oxide and simultaneously produce concentrated hydrochloric acid. Apparently the critical operation of these processes is the regeneration of the lixiviant (HCl). Currently in the industry, its regeneration is accomplished by high capital and intensive pyrohydrolysis which operates at 700- 900 °C. Aimed at lowering the operational cost of pyrohydrolysis a process called PORI [2] was developed and tested in pilot plant scale in the 1970s for the purpose of treatment of pickle liquors without, however, resulting in industrial application."

Jan 1, 2011

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By D. M. Muir

Many plants produce iron(II)/(III) waste liquors which must be treated by neutralisation and precipitation to remove the iron. Iron can be precipitated as crystalline goethite or jarosite by controlled oxidation at low pH and as magnetite by controlled oxidation at high pH, but only at elevated temperatures (>70°C). This study focuses on the characterisation and settling properties of the iron oxides produced at ambient temperatures using various neutralising agents in order to improve the performance of thickeners. It was found that two-stage addition of caustic to FeC12 solutions produced a fast settling material characterised by Mossbauer spectroscopy and XRD as maghemite and magnetite. However, lime and magnesia additions resulted in more ferrihydrite formation and much lower settling rates because of the enhanced oxidation of Fe(II) by air. Settling rates decreased significantly as the proportion of Fe(III) to Fe(II) in the liquor increased. The mechanism of iron oxide precipitation is discussed together with some reasons for the different behaviour of the neutralising agents.

Jan 1, 2006

By G. L. Oldright

As sponge iron is much like porous, coarse sand, it is a tempting material to use in place of coarse scrap iron as a precipitant of metals, for scrap iron is relatively awkward to handle and exposes only a small amount of surface to pregnant solutions. The results of the experiments described in this bulletin are largely a record of the behavior of sponge iron as a precipitant of lead and copper under laboratory conditions comparable to those that would obtain in a commercial plant were it attempted to secure the maximum contact of surface between solution and precipitant. Physically, the study is largely one of the rates of diffusion of the metal ions in the solutions and through the metallic coatings surrounding the sponge iron particles. The practical objectives are to remove completely the valuable metals from solution and at the same time to obtain a precipitate of good grade. In order to fulfill this latter requirement, the precipitant should be almost completely consumed. These practical ends are usually secured by having the two substances involved pass each other counter-currently-that is, in such a manner as to have the strongest precipitant in contact with the most impoverished solution, and vice versa. EXPERIMENTS WITH LEAD SOLUTIONS In nearly all of the schemes involving the leaching of lead from its ores the metal has been put into solution as the chloride, and fairly concentrated liquors have been employed. The solubility of lead under such conditions is comparatively small at best; the hot pregnant liquors from which the metal is to be precipitated are then made nearly saturated with respect to lead, and only a very small amount of acid is used. Therefore it was not as necessary to learn the behavior of the sponge iron in precipitating lead from solutions of widely differing composition as to learn under what conditions, and with what mechanisms, this precipitation might be carried out most readily.

Jan 1, 1928

By N. Geoffroy, E. Benguerel, G. P. Demopoulos

In the late 1990s, a chemical process to remove mercury and selenium from weak sulphuric acid solutions was patented and implemented in the CEZinc refinery in Valleyfield, Quebec. The CEZinc process comprises two stages. In the first one, sodium sulphide is added to the weak acid solution in order to precipitate the soluble mercury. The solution is then treated with sodium dithionite in order to reduce the selenium to elemental form. Because of recent changes in the composition of the industrial solution, a project to study the background chemical reactions was started. In this paper, a review of the background chemistry is presented on the basis of several eh-pH diagrams on one hand, while on the other experimental results are reported dealing with the reaction of selenium (IV) species with either dithionite, sulphide or a combination of the two. According to this work, elemental selenium enjoys a wide pH-eh range stability with selenium sulphide being metastable. Selenium (IV) in single metal synthetic solutions was found to be reduced - to elemental state - at ambient temperature down to ppb range with dithionite as long as the stoichiometric ratio (dithionite/selenium) was in excess of two and the pH < 1.7. Under these conditions the reaction was very fast reaching completion within one minute. Sodium sulphide proved equally effective in reducing selenium (this time as selenium sulphide) to ppb range from single metal solutions. However, in mixed Se-Hg solutions deviations from this "ideal" behaviour was observed resulting in higher levels of residual soluble selenium left in solution.

Jan 1, 2008

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

"The chief aim in style ought to be absolute precision", said Flaubert. "There is only one noun that can express your idea, only one verb that can set that idea in motion, and only one adjective that is the proper epithet for that noun." Let this be your motto. The engineer tries to be exact in all his measurements; he should measure his language with similar exactness. The technical term is a word of precision. It is not only precise, it is a word-saver. To the unscientific the earth is "a ball slightly flattened at the poles, something like an orange". To the scientific it is "an oblate spheroid". A similar contrast between the precision of the technical term and the vagueness of common words is afforded by a conversation between Ivanhoe and Rebecca: " &apos; What device does he bear on his shield?&apos; asked Ivanhoe. &apos;Something resembling a bar of iron, and a padlock painted blue on a black shield.&apos; &apos;A fetterlock and shacklebolt azure&apos;, said Ivanhoe"-using the technical terms of heraldry. It is good style in writing, however, to adapt your manner of expression to the intelligence and experience of the person or persons to whom the writing is addressed. The description of a mine should be worded differently according as it is intended to inform a mining engineer, a director, or a bishop. REMEMBER THE READER. It is as incorrect to write in a technical way for a non-technical reader as to write in a popular way for a technical or scientific reader. That style is best which enables the writer to place himself in the closest mental touch with his reader, to establish the maximum of sympathetic understanding. Let your precision be proportioned to your accuracy. You should not try to be precise in matters that do not admit of

Jan 1, 1931

By T. A. Rickard

"The chief aim in style ought to be absolute precision", said Flaubert. "There is only one noun that can express your idea, only one verb that can set that idea in motion, and only one adjective that is the proper epithet for that noun." Let this be your motto. The engineer tries to be exact in all his measurements; he should measure his language with similar exactness. The technical term is a word of precision. It is not only precise, it is a word-saver. To the unscientific the earth is "a ball slightly flattened at the poles, something like an orange". To the scientific it is "an oblate spheroid". A similar contrast between the precision of the technical term and the vagueness of common words is afforded by a conversation between Ivanhoe and Rebecca: "&apos; What device does he bear on his shield?&apos; asked Ivanhoe. &apos;Something resembling a bar of iron, and a padlock painted blue on a black shield.&apos; &apos;A fetterlock and shacklebolt azure&apos;, said Ivanhoe "-using the technical terms of heraldry. It is good style in writing, however, to adapt your manner of expression to the intelligence and experience of the person or persons to whom the writing is addressed. The description of a mine should be worded differently according as it is intended to inform a mining engineer, a director, or a bishop. REMEMBER THE READER. It is as incorrect to write in a technical way for a non-technical reader as to write in a popular way for a technical or scientific reader. That style is best which enables the writer to place himself in the closest mental touch with his reader, to establish the maximum of sympathetic understanding. Let your precision be\ proportioned to your accuracy. You should not try to be precise in matters that do not admit of

Jan 1, 1931

At Cliffs Natural Resources Ltd (CNR) crushing and shipping sample stations, precisions are estimated for the sampling, preparation and measurement stages of iron ore sampling in accordance with ISO 3085 (2002). In this Standard, gross duplicate samples are prepared at each of the three stages, yielding eight measurement assays. Appropriate calculations of the differences between assay pairs are then made to estimate precision of each stage of sampling. The International Standard for checking precision in iron ore sampling, ISO 3085 (2002) prescribes a method for identifying outliers that is ambiguous and possibly inappropriate. The procedure also makes an unnecessary implicit assumption, that the differences between assay pairs are normally distributed. The Anderson-Darling statistic is used to demonstrate that in some cases the assay pair differences have distributions significantly different from normal. When applied at CNR as specified, the Standard leads to precision estimates well below the expected values, thus overestimating the sampling method&apos;s capability and limiting the opportunity for real process improvement. This paper suggests an improved method of estimating sampling, preparation and measurement precision. A bootstrap procedure is used to estimate confidence limits for the calculated precision estimates. The proposed method would be suitable for testing blasthole precision. The discussion is supported by extensive simulation modelling of realistic data.

Mar 1, 2010

By B Mohanty, M Alam, F Gauthuer

A series of eleven full-scale production blasts has been earned out in a limestone quarry to study the effect of delay interval and its precision on overall blasting performance. The quarry employed ANFO and cartridged aluminized emulsion in 75 mm diameter boreholes with 2.6 m burden and 2.9 m spacing on a 6.7 m bench. Both V-cut and echelon designs were studied. The types of detonators tested were regular short period electric detonators with expanding delay intervals, a more precise pyrotechnic-based electric detonator (EXADET) with a fixed (25 ms) delay interval, and the ultra-high precision electronic delay detonator (EDD) with constant (but site-selectable) delay interval. The various techniques employed to assess the blast results are described, and the performance of the three types of detonators compared. The use of both EXADET and EDD lead to improved blast results in echelon design. Of the three delay intervals (25 ms, 38 ms, and 50 ms) studied, the best results were obtained with EDD with a 38 ms delay interval, which translates into a delay of 38 ms/m of effective burden. The results also show the need for modification of current V-cut delay designs to derive full benefits from these high precision detonators.

Jan 1, 1991

By M. Y. Wong

Electronic detonators have been used on a trial basis for over a decade, and found more recent application in production blasting as well. The relative merits of these detonators and their applicability are outlined through examples from actual blasting operations. They offer unprecedented flexibility in the design of mass blasts and in control of vibration and blast-induced damage. However, the drive towards replacing the pyrotechnic detonators by electronic ones in general could prove to be counter productive without a re-examination of prevailing blasting practices. In fact, such an approach tends to blur the tremendous potential of the electronic detonators in redefining many standard blast designs and practices.

Jan 1, 2004

By C. J. Konya, A. Konya

"Presplitting is a form of blasting that when executed properly will create a smooth wall that will minimize secondary conditioning. In recent years, presplitting has become a popular technique to be used in both the mining and construction industry, however, presplitting fails on many occasions because of ‘geologic conditions’. This is typically because of improper explosive loads consisting of overloading and underloading blastholes. In this paper the authors introduce new factors such as a presplit factor which varies for different rock types, selection criteria for the spacing of presplits, the optimization of explosive load, as well as prediction methods for the environmental affects for the technique of Precision Presplitting. BACKGROUND Methods of controlled blasting in which a smooth, stable wall could be blasted have been an important consideration since blasting in mining and construction has begun. How can one use an explosive, with its massive energy and power, to break a non-homogenous rock without causing backbreak, poor walls, or deviations in the wall over large distances? The blasting industry has known for a long time that blasting ‘high benches’ would result in better walls and less backbreak. However, this was not a sufficiently controlled technique for critical projects, such as the Niagara Power Plant. This was one of the main challenges Hercules Powder faced when they began the project. In order to achieve this, they used a new tool in the explosive engineer’s toolkit, presplitting. The presplitting done on the Niagara Power Project utilized 1 ½” x 8” (38mm x 203mm) 40% gelatin dynamite in 2 ½” (63.5) diameter boreholes. This was done on multiple levels with benches between 12 feet to 52 feet (3.6m to 15.8m) with a total powder factor of 0.75 pounds/cubic yard (0.45 kg/m3). The spacing on these holes ranged between 18 inches to 24 inches (0.46m to 0.61m), center to center (Langfors & Kihlstrom, 1973). The strange aspect of this project was that this “lightly loaded” closely spaced row was fired before the production blast, yet this project produced some of the best walls seen at that time directly from blasting. In today’s blasting industry, presplitting is a more common way to produce smooth, stable high-walls for both the construction and the mining industry. Today, explosive loads for traditional presplitting is generally measured in pounds per foot (kilograms per meter) and typically ranges from 0.30 lb. /ft. to 0.5 lb. /ft. (0.45 kg/m to 0.75 kg/m). MECHANICS OF PRESPLITTING When analyzing a blasting process like the Niagara Project, many wonder how did that work when normally confining a charge would cause cratering and increased backbreak. Since then, presplitting mechanics have been studied extensively. It has been shown in many models that presplitting is not achieve through the collision of shockwave, but by gas pressure in the boreholes. In addition to models and finite element simulations, this has been proven full scale using Pyrodex, a propellant, to create a presplit plane with no shock wave present (Konya, Dean Barrett, & Smith Jr, Presplitting Granite Using Pyrodex, A Propellant, 1986)."

Jan 1, 2017

By Calvin Konya, Anthony Konya

Presplitting is a form of blasting that when executed properly will create a smooth wall that will minimize secondary conditioning. In recent years, presplitting has become a popular technique to be used in both the mining and construction industries, however, presplitting fails on many occasions because of ‘geologic conditions’. This is typically because of improper explosive loads consisting of overloading and underloading blastholes. In this paper the authors introduce new factors such as a presplit factor which varies for different rock types, selection criteria for the spacing of presplits, and the optimization of explosive load for the technique of Precision Presplitting.

Jan 1, 2017

Precision surface mining is increasingly occupying a significant role in open pit mining. Improvements in technology now allow continuous surface mining of material well above 140 MPa (20 300 psi) efficiently and cost effectively when compared to drilling and blasting/primary crushing methods. These include the elimination of the use explosives and primary crushing, the ability to precisely extract the ore from the waste, or separate ores of varying chemistry and mine thin seams and non-homogenous orebodies cost effectively. In addition, precision surface mining extends the useful life of a mine by extending the mine boundaries. It can expand production capacity in existing mines and is particularly cost effective in greenfield start-up mines. Precision mining techniques result in higher percentage recoveries. This paper reviews several of these techniques for the Terrain Leveler« surface excavation machine (SEM), and shows their impact. Vermeer&apos;s current approach to precision surface mining is utilisation of the T1255 Terrain Leveler SEM. Several units have been proven in round-the-clock, seven day operations throughout the world. Among other innovations are design simplicity, stability, maneuverability, rear-mounted tilting drum and top-down cutting. The impact of these items are discussed in more detail in the paper. After a detailed analysis of the importance of machine availability on overall mine performance, Vermeer has extended its equipment line to include a direct-drive option for its T1255 Terrain Leveler SEM. In addition, improvements in dust suppression are presented. While the T1255 Terrain Leveler SEM is of optimum size and cost in small and medium sized mines, Vermeer has recognised that larger mines require larger machines with increased capacities. Vermeer will prototype the T1655 Terrain Leveler SEM later this year. Specifications of this machine and up-to-date preliminary results are presented. A discussion of the role of each machine size and driving mechanisms are included. Finally, the next stage in Vermeer&apos;s providing solutions to the surface mining community will be described - a continuous loader. The impact on current mine planning is presented using a detailed computer program developed for studying the impact of loading techniques and higher production rates on mine plan optimisation.

Dec 6, 2010

By L. Filippov

"Nickel is an important metal with the total global consumption of about 2 million tons per year. It is sourced from both sulfide and laterite ore, but currently laterites are becoming more attractive for nickel production due to the depletion of high grade nickel sulfide ores. Laterites are generally processed by hydro or pyro-metallurgy and therefore, pre-concentration of nickel before such processes is very important. In this paper the effect different physical methods (including flotation) on the pre-concentration of nickel in laterite ores will be discussed. The ore used in this study was a laterite from South East Asia. Nickel was upgraded using different methods such as magnetic separation, flotation and sizing. The effect of ore mineralogy on choosing the best strategy to upgrade nickel will be discussed. The findings of this project will help to unlock a substantial volume of nickel with significant value from laterite ores.INTRODUCTION Nickel is an important metal with the total global consumption of about million tons per year which has grown rapidly during last decades (Mackey, 2011). Nickel is sourced from two different types of ores, sulfide and laterite. The majority (about 70%) of the world’s nickel resources occur as laterite ores which are often complex, and low grade, and therefore expensive to treat using conventional methods (Xu et al., 2013). Today, nickel laterites are more attractive for production of nickel as the amount of high grade nickel sulfide ores has diminished (Janwong, 2012). Therefore more economic processes to recover nickel from these resources should be developed.It should be noted that nickel laterite mineralogy is complex, and nickel often presents as ultrafine inclusions in a number of mineral phases. Because of the low nickel concentration and variable distribution in these phases, effective upgrading by physical separation processes would be challenging. Researchers have tried to improve nickel laterite flotation recovery by using a number of feed preparation techniques. A summary of the nickel grades obtained using flotation and magnetic separation as reported in the literature is presented in Table 1. It can be seen that only minor nickel upgrades have been reported. Quast et al. (2015) have concluded that the complex mineralogy of nickel laterite ores makes it difficult to achieve any significant nickel upgrading by physical techniques, including flotation. They achieved 40% increase in the nickel content (from 1.0% to 1.4%) at a nickel recovery of 43% (Quast et al., 2015). Various attempts in USA, New Caledonia, India and Australia, to upgrade nickel in laterite using magnetic separation have not been successful (Quast et al., 2015). A recent comprehensive review on topics influencing nickel laterite flotation has shown that further investigations in the flotation of laterite ores are undoubtedly warranted (Farrokhpay & Filippov, 2016)."

Jan 1, 2018

By I Auranen, J Raatikainen

IMA Engineering (IMA) and Mine On-Line Service (MOLS) companies have used on-line sensors for analysing ore and waste rock in mining for more than 25 years. Today IMA on-line sensors are used in various stages of the mining process including on-line analysis of drill cores, drill chips, ore and waste in loader bucket, ROM ore analysis on belt conveyor belt and in bulk ore sorting and in slurry analysis in concentrators. During years of extensive field experience and testing we have found that the waste rock dilution and ore losses create much larger economic and environmental losses than has been previously recognized. According to our studies the main reason is limited number of analysis already in exploration when drill cores or drill cuttings are used in block modelling. The same happens in production because too few and biased samples from benches are used to estimate the ore grade. Much more than today estimated amount of waste enters the mill and considerable volumes of ore losses happen at the same time. The ore grade on the benches and in muck piles is averaged and “homogenized” with averaged and biased samples. These are the main root causes of waste rock dilution and ore losses. Sensor based preconcentration can be the remedy to waste rock dilution and ore losses. This presentation will show examples of the use of on-line sensors in preconcentration when analysing ore and waste rock in drill cores, drill cuttings, on conveyor belt and in bulk ore sorting. Waste rock removal in preconcentration has direct effect on energy consumption in crushing and grinding and chemicals in concentrator. In concentrator waste is separated and goes to tailings pond, however, preconcentration directly reduces the volume of the tailings. In our presentation we will cover cases in base metals and in gold mines.

Nov 10, 2020

By T BoBo, D La Rosa, P Cameron

Efficient pre-concentration using natural and induced deportment starts with effective blast design. Leveraging these characteristics using Size-Based Grade Engineering® techniques requires detailed understanding and measurement of the particle size distribution (PSD) of the Run of Mine (ROM) ore. In turn, blasts must be designed to optimise fragmentation for the pre-concentration method. To be successful, fragmentation outcomes must be predicted and measured as part of the blast design process to account for the response ranking of the rock mass. The upgrade achieved using Size-Based Grade Engineering® methodologies will rely on the proportion of feed that reports to the screen undersize, so particle size distribution of the feed stock is of paramount importance if the potential benefits are to be achieved and maintained. Measuring actual fragmentation in the ROM ore and comparing with predictions allows the modification of subsequent blast designs to optimise fragmentation for pre-concentration scenarios. Automating this process can deliver significant increases in productivity and mine site profits. This paper discusses the importance fragmentation plays in Size-Based Grade Engineering® and explores technologies and methodologies used to measure it, consistently ensuring the best outcomes.

Nov 10, 2020