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By C. Taschereau, G. A. Vickell, A. R. Laplante

Evidence in support of an iron-gold corrosion cell during the high-temperature/highpressure elution of loaded carbon is presented herein including, but not limited to, its discovery, mode of genesis, and confirmatory laboratory testwork. A discussion of metallurgical and economic impacts, remedial investigations, plant design considerations, and future work including mitigative possibilities is presented.

Jan 1, 2006

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

Orebodies of the Renison Bell - Mt. Bischoff tinfield in Tasmania are stratabound, conformable lenses of massive cassiterite-bearing pyrrhotite, with underlying discordant, fault-fracture-controlled and more siliceous ore. The deposits occur in eugeosynclinal, trough-deposited sedimentary and mafic volcanic rocks which are stratigraphically equivalent to diff erentiated volcanic rocks that contain volcanogenic massive base metal sulphide deposits in a parallel arc to the east. Textures of the massive pyrrhotite ore suggest that it has undergone metamorphic recrystallization. Although the massive ore contains both monoclinic and hexagonal pyrrhotite, a study of a few samples from one orebody suggests that their distribution is stratigraphically controlled, with the monoclinic variety abundant only at the base. The distribution pattern of rare-earth elements in massive ore is similar to that of volcanogenic massive base metal sulphides in New Brunswick, and suggests that mixing of sea water with exhalative hydrothermal brines occurred during ore deposition. Tin is a common accessory element in many volcanogenic massive base metal sulphide deposits providing strong evidence that it, too, is transported and deposited by volcanic affiliated hydrothermal brines. Sedimentary rocks containing the massive orebodies are fine grained, thinly laminated, compositionally banded and of mixed chemical sedimentary-tuffaceous origin. They include finely recrystallized chert, carbonate-rich and pyritic varieties; and soft sediment deformation structures in these rocks suggest that dense sulphides deformed underlying, less dense chert prior to lithification. Close to ore the chert becomes massive and coarsely recrystallized, as does the carbonate, which is here strongly enriched in Fe and Mn. Apatite is present in pyritic, cherty and carbonate-rich beds and in the ore itself, in all of which it shows a similar pattern of rare-earth element distribution, suggesting that it is of marine sedimentary origin. These deposits have traditionally been considered as epigenetic replacements of favourable carbonate horizons by hydro thermal flu ids derived from later Devonian porphyritic intrusions. Some of these intrusions have associated tinbearing greisens. The above relationships suggest, alternatively, that, like massive base metal sulphides, the tin deposits were of original syn-sedimentary origin. Circulating hydrothermal brines generated during early Cambrian eugeosynclinal subsidence and tectonism rose through steep fault-fractures, there giving rise to the discordant orebodies, and were discharged on the sea floor, where the massive pyrrhotite lenses were precipitated with the associated cherts and carbonates. In some places, Devonian intrusions remobilized the earlier deposits, forming greisens and newepigenetic veins. Finally , the geologic selling of these deposits, in trough deposited sedimentary and mafic volcanic rocks, suggests another favourable environment for massive sulphide exploration which is quite different from the domal felsic volcanic environment so heavily favoured currently in North America

Jan 1, 1979

By Pei-Yung Huang, Carle R. Hayward

IN order to understand more fully the actual state of copper lost in copper reverberatory slags, a systematic study on the various reactions between certain metallurgically important copper compounds and synthetic copper reverberatory slags was undertaken by the authors in the Massachusetts Institute of Technology from 1942 to 1945.1 This paper, being only a part of the work completed, is published first because it furnishes the first experimental evidence of the formation of copper ferrite from reactions between cuprous oxide and copper reverberatory slags. CHOICE OF SLAG COMPOSITION The choice of the composition of the synthetic reverberatory slags to be used was much deliberated. Commercial copper reverberatory slags, neglecting minor constituents, average:2.3 45 to 47 pct FeO; 38 to 42 pct Si02; 5 to 6 pct CaO; 5 to 6 pct A1203. Since the ternary system CaO-FeO-SiO2 has been much more thoroughly studied4 and is much simpler than the quaternary system CaO-FeO-Si02-A1203, it was decided to use calcium oxide only instead of calcium oxide and alumina in the synthesis of the slags. Fortunately the composition of the average copper reverberatory slag with calcium oxide substituted for alumina lies in the region of the phase diagram clarified by the investigators. A survey of the phase diagram (Fig I) suggested two compositions: (I) the com¬position near the invariant point S, which is made up of 46 pct ferrous oxide, 37 pct silica and 17 pct calcium oxide; (2) the composition near the invariant point K with 45.5 pct ferrous oxide, 43 pct silica and 11.5 pct calcium oxide. Composition S has the advantage that the percentages of ferrous oxide and of silica almost exactly coincide with those of the average reverberatory slags, and that of the lowest melting point (1093° ± 3°C) in the whole ternary system. The calcium oxide content, however, obviously is high. Since we have already substituted calcium oxide for alumina, and since calcium oxide is more basic than alumina, the resulting slag is decidedly too basic. Composition K has a slightly higher melting point (1105° ± 3°C) and a higher silica content, but this is preferred because the slag is saturated with respect to tridymite and thus should not corrode siliceous refractories. Besides, it is less basic than composition S. The final slag composition, therefore, was chosen to

Jan 1, 1947

By M Furche, U Noell, C Grissemann, J A. Meima, T Graupner, A Romero-Baena

The mining residues at the abandoned copper mine site Pe±a de Hierro, located at the headwaters of the Rio Tinto, contribute substantially to the pollution of the river with high loads of Fe, As, Pb, Zn and Cu. The pH of the outflow ranges from 0.5 to 2.4 in the dry and wet season, respectively. One heap composed of alternating layers, which were deposited parallel to the slope, was investigated in detail. Unsorted blocky to fine materials including gossan material, pyritic volcanics, ashes from pyrite combustion and slate were observed here. The top of the heap has a gentle slope and a hill contouring channel-rip morphology. The initially rugged surface was smoothed by heavy rainfalls filling up the pores of the blocky material with fines. These fines are capable of storing the water for a prolonged time, providing an extended reaction time close to surface in a dry climate at extremely low pH conditions (one to four). All minerals, pyrite, mica, barite and even quartz (probably due to F released from dissolved mica) have been digested and silica gel precipitates have formed a stable and quasi impermeable 100 ¦m layer with very low porosity (<5 area per cent, estimated using scanning electron microscopy (SEM) imaging). The silica layer itself is covered by Fe-oxy-hydroxide (ie FeOOH) coating (10 ¦m) and seals a 1 - 5 mm thick stable hardpan. This hardpan covers the channels and part of the rips almost entirely, guiding the rainwater subhorizontally towards slopes and sinkholes. By geoelectrical measurements, a 3D-resistivity model of the internal structures and the bedrock relief underlying the heap was generated. Internal structures relate to lithological changes in a number of layers. Zones of low resistivity may be attributed to washed-in fines within the mega pore system, whilst zones of high resistivity close to the surface probably reflect the advanced stage of drying beneath aging hardpans. The water movement at the surface was investigated by an artificial precipitation experiment with monitoring of the subsequent changes in resistivities.

Jan 1, 2008

By B. Salopek, D. Rajkovic, D. Rumenjak

Among other types of sustainability indicators, linguistic variables have been proposed. During the past few years considerable effort for using the fuzzy logic and linguistic variables (LVs) in environmental decision-making for the mineral industry has been made. The linguistic variables defined could, among others properties, describe the property of acceptability for environment for various environmental indicators. Some proposals for construction of such variables are based on administrative decisions from environmental impact assessment procedures for mining, which provide information for acceptability of quality kind for environment (e.g. obtained from public participation, experts, environmental administration). The measures of evidence for construction have to be based on sets (not only on the members of sets). The administrative decisions with their statements and explanations could be considered as such sets. The measures of evidence appropriate are plausibility and belief measures. Using the more elaborated methods from the theory of evidence, the better estimation of those measures could be achieved. The methods of constructing the linguistic variables, previously suggested and based on obtained measures, are also discussed.

Jan 1, 2011

By Zhongxue Li, Wenguang Li, Yiqing Zhao, Shuaiqi Wang

"Faced with the serious managerial situations and diverse conditions and needs for mine safety, occupational health and environmental stewardship in Chinese mining communities, an evidence-based approach is proposed for the management of mine safety, health and environment integrity. By the proposed approach, tangible and effective scientific evidence should be collected and accumulated, and the authenticity, accuracy and applicability of the evidence should be assessed to form an evidence-based approach for characterizing mine safety, health and environmental hazards and risks from multidimensional perspectives. The results are then used to formulate diverse safety, health and environment functional requirements. In an evidence-based approach, the evidence is combined with the professional experiences and the actual economic and technological situations, availability and affordability of a mine. This approach is helpful to establish scientific, reasonable, acceptable and effective solutions for identifying and mitigating hazards and improving the level of mine safety, health and environment integrity of mining operations.Introduction / Background In recent years, economic reforms have opened China's economy so that Chinese society has rapidly modernized. Along with this advancement, the exploitation and utilization of mineral resources continues to be active and the scale of mining production continues to increase, which has created a deterioration in resource reserves and as well as the general condition of mining technology. There are many hazards and safety problems in mine production and occupational health as well as in the community environment in China’s mining industry. These problems threaten the security of China's mines and present serious obstacles and challenges to the industry and the government. According to the statistics from the State Administration of Work Safety Supervision, there were 50,500 mine safety incidents in China between 2001 and 2013, which consisted of 31,439 coal mine safety accidents and 19,061 non-coal mine safety accidents, resulting in 30 deaths (Qin 2014). At the same time, mineral dust and radioactive material from mine production processes have increased the morbidity rate of silicosis and cancer in mining workers."

Jan 1, 2017

By Percy Zamora, José Quispe

La alteración es típica de los depósitos de alta sulfuración con sílice en la parte central rodeado de argilica avanzada y argílica, cuya mineralización en óxidos está relacionada principalmente a brechas hidrotermales y tufos de cristales y líticos con textura de sandy sílica, vuggy sílica y sílice masiva. Sin embargo los trabajos geológicos y algunos sondajes realizados recientemente en el proyecto, han permitido reconocer un cuerpo mineralizado de oro-cobre (0.40 g/t Au y 0.054% Cu), con ensamble de alteración clorita-caolín-paragonita-muscovita, relacionado a un intrusivo dioritico; observándose una gradación de los ensambles de alteración (arcillas a micas blancas), es decir de una alteración argílica intermedia (dickita-illita) a una alteración filica (paragonita-muscovita), lo cual evidencia una transición de un sistema de alta sulfuración a un sistema pórfido.

Sep 1, 2017

By J. Quispe, P. Zmora

La alteración es típica de los depósitos de alta sulfuración con sílice en la parte central rodeado de argílica avanzada y argílica, cuya mineralización en óxidos está relacionada principalmente a brechas hidrotermales y tufos de cristales y líticos con textura de sandy sílica, vuggy sílica y sílice masiva. Sin embargo, los trabajos geológicos y algunos sondajes realizados recientemente en el proyecto han permitido reconocer un cuerpo mineralizado de oro-cobre (0.40 g/t Au y 0.054% Cu), con ensamble de alteración clorita-epidota-paragonita-muscovita, relacionado a un intrusivo diorítico; observándose una gradación de los ensambles de alteración (arcillas a micas blancas), es decir de una alteración argílica intermedia (dickitaillita) a una alteración filica (paragonita-muscovita), lo cual evidencia una transición de un sistema de alta sulfuración a un sistema pórfido.

May 1, 2008

By Eden Santos Silva

Usando os testes de torção a quente isotérmico contínuo e relaxação de tensão determinou-se as curvas de escoamento plástico e de relaxação de tensão, juntamente com a evolução mecânica e microestrutural do aço inoxidável austenítico ISO 5832-9 segundo as condições de deformação expressa pelo parâmetro de Zener-Hollomon (Z). Equações constitutivas foram usadas para avaliar e prever o amaciamento dinâmico. Verificou-se que os níveis de tensões são elevados com alto valor de energia de ativação aparente e descolamento da deformação crítica e de pico para as condições de alto Z. A tensão crítica encontra-se muito próxima do pico de tensão produzindo um retardo no início da recristalização dinâmica. Além do pico vê-se que o estado estacionário de tensões é alcançado para grandes deformações evidenciando um atraso no amaciamento dinâmico. Este comportamento é consequência da moderada valor de energia de falha de empilhamento (EFE), átomos de soluto em solução sólida (Nb, N, Mo) e presença de partículas de precipitados da fase Z (NbCrN) reduzindo a mobilidade das discordâncias e contornos de grãos retardando a cinética de recristalização.

Aug 16, 2017

By Remo Grandori, Manfred Jaeger, Fabrizio Antonini, Luis Vigl

The EVINOS-MORNOS tunnel project with its 30 km of length is one of the longest hydraulic tunnel in the world realised with TBM method. The adverse geological conditions, the high cover and the short construction schedule were a great challenge for the successful construction of this tunnel. The paper will describe: the criteria adopted for the tunnel design, the selection of the construction methods and equipment, the productions of the 4 TBMs adopted and the comparison of the behaviour of the different type of TBMs in the various rock conditions, including special conditions, the characteristics of the adopted in situ and precast linings, a comparison between the foreseen and actual construction schedules, the contractual implications of realising a tunnel in such a severe and complex conditions.

Jan 1, 1995

La incidencia de silicosis en algunos asientos mineros, conlleva la necesidad de un estudio evaluativo del departamento de Higiene industrial sobre aquellos yacimientos situados a 4000 m.sn.m, para determinar las condiciones del medio ambiente y estado de salud de sus 200 trabajadores. Por tal motivo, el presente trabajo señala el proceso de adquisición sobre la enfermedad durante la estadía del trabajador en la mina, y su posterior evolución, pese a las medidas preventivas. Las condiciones ambientales para el desarrollo de la silicosis son el terreno cuarcífero y los lugares de ventilación ventilación deficiente, donde el término medio de partículas de polvo encontradas fue de 0.7 a 1.15, incidiendo particularmente en el operador de lampa. Para ello, se recomendaron medidas preventivas como la adecuada ventilación de los frontones, la omisión inicial de la perforación en seco, el uso de respiradores adecuados para las trabajadores y el empleo de un mejor equipo para la ventilación de los stops. Sin embargo, los resultados obtenidos del proceso, no ofrecieron mejoras sobre el avance de la enfermedad, situándola en un primer estadío con 7.0% en comparación con otras enfermedades. Después de un periodo de 7 años, el departamento de Higiene industrial, nuevamente reevalúa este estudio, encontrando resultados similares con los anteriores, sin reparar en las recomendaciones sostenidas. Así, de los 200 trabajadores examinados, se conoce el estado actual de 103, de los cuales 97 trabajadores tienen silicosis sin determinar aún su estado de su evolución. Luego, en 1956 se diagnosticó que el 27.3% de trabajadores silicosos, evidenciaba un porcentaje considerable en el primer estadio y una dismimución en el estado de sílico-tuberculosis. Por consecuencia, se necesita mejorar no solo las condiciones del ambiente del trabajador, sino eliminar las jornadas laborales de 12 horas de trabajo en subsuelo. Así como la evaluación periódica, integral, radiográfica del estado del trabajador por medio de un personal médico altamente capacitado.

Jul 20, 1957

By Simón D. Strauss

El presente estudio revisa la evolución de la producción de los principales minerales (plomo, cobre y plata) en Estados Unidos desde la década del 70, asi como su repercusión en Chile, Perú y algunos países latinoamericanos. En esta perspectiva, se pronostican algunos datos sobre los cambios políticos, sociales y económicos que ocurrirán dentro de los próximos 28 años y que afectarán la demanda de productos minerales y la capacidad para producirlos.

Nov 20, 1972

By José Cuadros

"El presente trabajo señala el proceso de evolución del método de minado en la mina Chupa, perteneciente a la unidad minera de Iscaycruz. La evolución del método de minado se determinó por la búsqueda de mejores condiciones de seguridad y eficiencia en la operación. En ese sentido, los resultados logrados con cada una de las alternativas de minado por subniveles, indica que se ha logrado optimizar las diferentes variables mineras y cumplir con el plan estratégico de Empresa Minera Iscaycruz S.A. (EMISA). Para cumplir con el citado plan estratégico, se debe optimizar el método de minado de Chupa, a través de una mayor producción a un menor costo,así como del aprovecho de las labores de desarrollo y preparación ejecutadas según el planeamiento inicial del minado. Por ello, la secuencia del avance del minado y la reestructuración del sistema de relleno de la mina son los aspectos importantes para lograr este objetivo. "

Jul 31, 2003

By Jorge Oviedo

La planta de lixiviación, extracción por solventes y electrodeposición (L-SX-EW) de Southern Perú es una operación hidrometalúrgica dedicada a la lixiviación ácido – bacteriana de los botaderos de mineral de baja ley de la Mina Toquepala, para la producción de cobre catódico de la más alta pureza. En ese sentido, el presente trabajo describe la evolución del sistema de control y supervisión de esta planta minera en Cuajone. Para ello, dicha planta debe tener una actualización constante de sus sistemas de control y ser capaz de cambiar con la velocidad a la que avanza la tecnología de Control de Procesos. Asimismo, debe contar con personal calificado que permita el desarrollo y modernización de los sistemas sea continuo y no dependa solo de expansiones y ampliaciones ejecutadas por especialistas externos. De forma que este software de supervisión, no solamente considera la capacidad de operar la planta, si no debe ser una ayuda tanto para el operador como para brindar información en la correcta toma de decisiones.

Aug 25, 2002

By J. P. Navarro

Se reporta el registro regional de las facies sedimentarias de la Formación Jumasha-Celendín, con la finalidad de entender su extensión, distribución y evolución vertical. Con ello se determinó la evolución sedimentológica y paleogeográfica de estas calizas durante el AlbianoConiciano. El sistema sedimentario comenzó en el Albiano superior con un cinturón regional carbonatado compuesto por ostras mezcladas con fuerte material terrígeno dadas en condiciones mesotróficas. Seguido por el levantamiento del bloque Marañon en la parte central de Perú, causando la instalación de un ambiente restringido de material terrígeno en condiciones oligotróficas durante el Cenomaniano superior.

May 1, 2008

By Thierry Sempere, Jorge Acosta

En este trabajo empredemos una síntesis preliminar de la evolución geológica y tectónica que se puede reconstruir actualmente en base a las investigaciones en curso, junto con el análisis de datos metalogenéticos disponibles a la fecha. Se hace énfasis en el magmatismo dado que la gran mayoría de los depósitos minerales se relacionan con fenómenos magmáticos occuridos en un arco de subducción.

May 1, 2008

By D. Z. Wang

A red copper plate, discovered in the ruins of Dachengshan in Hebei province, was recognized as a forged one rather than a cast one, which means it was probably made from natural copper during the Longshan Culture period (2200~2208 BC) in the Chinese history. The copperware, found in the Niangniang Tai relics in Wuwei city, Gansu province, contains 99.6% copper and 0.4% Sn, Pb, Sb and Ni, which was guessed to be made during the Qijia Culture about 2000~ 1900 BC in the Chinese history in the late Neolithic before Shang dynasty. This shows that Chinese ancestors were able to distinguish, sort and use some native metals and minerals more than 4000 years ago.

Jan 1, 2014

By S. Koppalkar

ABSTRACT: The development and evolution of the gravity recoverable gold (GRG) test procedure at McGill University is reviewed in this paper. Since the late 1980s, the research group led by the late Professor André Robert Laplante at McGill University has undertaken fundamental studies and applied research of the Knelson concentrator to develop a sustainable method of estimating GRG. Historically, a concept of “free gold” was used, and it was de?ned as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, the practical use of amalgamation has declined. Around 1994, a methodology using a 3-in Knelson concentrator to measure gravity recoverable gold was established at McGill University. As a result of more than 10 years of improvement and optimization, this technique has become a standard method of evaluating GRG for gold ores, gold plant streams and platinum group metals. By 2006, about 200 GRG tests were carried out at McGill University on ores from all over the world. Recently, a modi?ed version of the GRG test (a simpli?ed test) was developed to provide a quick and rough estimate of the GRG in a sample; this simpli?ed test has the advantage of reduced mass, processing time and cost. To recognize and honour the contributions made by the late Professor Laplante towards the establishment of a standard test procedure for assessing gravity recovery potential, the authors propose that the GRG test be named after Laplante.

Jan 1, 2010

By S. Koppalkar

ABSTRACT: The development and evolution of the gravity recoverable gold (GrG) test procedure at McGill university is reviewed in this paper. Since the late 1980s, the research group led by the late Professor André Robert Laplante at McGill university has undertaken fundamental studies and applied research of the Knelson concentrator to develop a sustainable method of estimating GrG. Historically, a concept of “free gold” was used, and it was de?ned as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, the practical use of amalgamation has declined. around 1994, a methodology using a 3-in Knelson concentrator to measure gravity recoverable gold was established at McGill university. as a result of more than 10 years of improvement and optimization, this technique has become a standard method of evaluating GrG for gold ores, gold plant streams and platinum group metals. By 2006, about 200 GrG tests were carried out at McGill universityon ores from all over the world. recently, a modi?ed version of the GrG test (a simpli?ed test) was developed to provide a quick and rough estimate of the GrG in a sample; this simpli?ed test has theadvantage of reduced mass, processing time and cost. to recognize and honour the contributions madeby the late Professor Laplante towards the establishment of a standard test procedure for assessing gravity recovery potential, the authors propose that the GrG test be named after Laplante.

Jan 1, 2010