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By R. Schlüter

"The global mining industry is facing increasing challenges in terms of geological, technological and social aspects. Potential exploi-tation of deposits shows a tendency to increasing depth with complex ores and decreasing grades. A promising approach to deal with these constrains is by applying alternative extraction methods like (bio-)hydrometallurgy as in-situ leaching (ISL) technology. The Bergakademie Freiberg University of Mining and Technology established the “Biohydrometallurgical Center for strategic Elements” (BHMZ) to foster the interdisciplinary research along the entire biohy-drometallurgical process chain to extract indium from sulfide ores. The involved Department of Underground Mining Methods deals with the design and implementation of a pilot-scale underground testing facility for microbial in-situ stope leaching in its “Research and Educational Mine”. This paper discusses the potential of in-situ bioleaching under technological aspects. In addition, different conditioning approaches based on hydraulic and explosive methods for enhanced permeability in the formation are introduced and the gathered data will be presened. INTRODUCTION A reliable, substantial and sustainable supply of raw materials is of crucial importance for any industrialized country. This dependency applies to “strategic elements” including rare earth elements (REEs), platinum group metals (PGMs) as well as a variety of other metals like indium and germanium which are needed for high-tech industry and products such as electric and electronic devices, fibre optics and laser technology (Barakos et al., 2016; European Commission, 2010). Due to the economic growth of the BRIC-countries (Brazil, Russia, India, China), the resource policy of China as well as the volatile world mar-ket prices of different metals the availability of these critical raw materi-als and therefore the dependency of the high-tech producing countries has become increasingly important (Barakos et al, 2016). Adequate supply is often affected by the increasing depth of de-posits, lower metal concentrations and more complex ore mineralogy. In addition, mining activities are increasingly restricted by their envi-ronmental and social impact and footprints. As a consequence, con-ventional mining and processing methods are limited by high energy consumption and technical constraints."

Jan 1, 2018

By A. M. Johnson

Although known primarily for native copper, the Keweenaw Peninsula of northern Michigan also has deposits of copper sulfide (chalcocite) ore. A number of small, but rich, deposits are present at relatively shallow depths near the base of a thick, steeply dipping sequence of volcanic and sedimentary rocks. Because much of the ore is fracture-controlled, the deposits appear to be ideal candidates for in-situ leaching. Fracture mapping from drill core and borehole logs coupled with borehole packer permeability tests are being applied to evaluate the suitability of the ore for in-situ leaching. A leaching scheme utilizing a bacterial-assisted ferric iron lixiviant is being tested at bench scale. A pilot scale test is being designed to evaluate the system in the field.

Jan 1, 1988

By James C. Foley, David K. Rehbein

"In-situ characterizations of green state part density and sintering state have long been desired in the powder metal community. Recent ·advances in non-contact electromagnetic acoustic transducer (EMAT) technology have enabled in-situ evaluations of the acoustic attenuation and velocity as sintering proceeds. Pure aluminum (99.999%) and aluminum alloy powders were prepared with high-pressure gas atomization (HPGA). The powders were pressed in a uniaxial die and examined with acoustic waves for changes in velocity and attenuation during sintering. The changes in acoustic properties were correlated with sample microstructures and mechanical properties. Evolution of the acoustic echo train during sintering is shown to provide information on the state of sintering as well as having the potential for detection of interior flaws.IntroductionThe versatility of powder metalallurgy (PIM) technology in the manufacture of complex shapes has enabled an increasing amount of wrought and casting production capacity to be converted to PIM technology. However, ultrasonic inspection of green components produced using PIM techniques remains a challenge and is not generally practiced [1]. Inspection of PIM components in the green state is highly desirable, because the green part can be reclaimed with only accepted components being subjected to further costly processing. Another potential benefit is characterization and greater understanding of the sintering process itself. An increased scientific understanding of the sintering process enables intelligent process control, greater reliability of the production process and a lower rate of rejection of the finished product. In order to realize these potential benefits, it is necessary therefore that accept/reject criterion be based on real time nondestructive evaluation of the green-state components and the sintering process.Most current nondestructive inspection techniques suffer from their inability to perform inspections below the near-surface region with the exception of X-ray and to some extent pulsed eddy current [2]. X-ray inspection requires extensive shielding of production personnel and expensive film and film processing. While development of pulsed eddy current techniques have lessened the impact of the well-known skin effect, the depth of penetration of the induced eddy currents remains somewhat of an issue [2]."

Jan 1, 2000

By P. Somasundaran, A. Sivakumar

Surfactants and polymers are used in a number of processes such as flotation and flocculation. The structure of the adsorbed surfactant and polymer layers control the interfacial properties of the solid and hence an understanding of the structure of the adsorbed layers at the molecular level is essential. In this paper, a review of different spectroscopic techniques (fluorescence, electron spin resonance and Raman) used to characterize the adsorbed layers [in-situ] is presented. Information on the micropolarity, microfluidity and size of the surfactant aggregates was obtained and the growth of the adsorbed layer was followed. [In-situ] conformational states of polymers at the solid/liquid interface were determined for different pH values.

Jan 1, 1989

The principles and utility of in-situ coal gasification are discussed, and a first field test conducted by the Alberta Research Council in 1976 near Forestburg, Alberta, is described. The test was carried out in a 12-ft subbituminous coal seam under 60 feet of cover. Within this seam, a 30 by 60-foot block , containing approximately 650 tons of coal, was delineated by four injection/production holes which were oriented to take advantage of the natural fracture system in the coal. Linkage between holes was established by reverse combustion and gasification was accomplished by injecting air into the ignited coal. No steam was injected but operating pressures were adjusted to utilize formation waters for partial carbon -steam gasification. The coal gasification runs lasted six weeks and gasified an estimated 900 tons of coal ,' during sustained periods of gasification, a fuel gas with heating values of between 110 and 150 Btu/scf was obtained. Plans are now being developed for excavating the test site and inspecting the subsurface cavities created by gasification.

Jan 1, 1977

By Kot F. Unrug

Strength of coal is one of the governing factors in size determination of mine pillars, and therefore affects the percentage of extraction and thus, utilization of reserves. Coal strength is also important from the subsidence control standpoint, where mine pillars with appropriate safety factors should be designed for long term stability. Determination of coal seam strength has been addressed through the extrapolation of the coal strength obtained from a small number of samples on the whole section of the seam. This procedure often gives unreliable results. Presented in this paper is a method of in-situ strength testing of coal, allowing for a realistic determination of seam strength. Results of a field case study dealing with the coal seam, where samples for the laboratory strength tests could not be obtained due to the dense cleat, are presented. However, in these conditions, the in-situ testing was successful. A comparison of both conventional and the in-situ penetrometer method was carried out. It was found that the penetrometer data not only improve the accuracy of strength determination of the entire seam, but also prove to be much more cost effective than the conventional method on a per test basis.

Jan 1, 1995

By J. Stumper

The control of the distribution and movement of liquid water is crucial for increased reliability and durability of PEM fuel cells: whereas the proton exchange membrane requires a minimum amount of liquid water for optimum operation, water excess in the GDL will impede reactant gas access to the catalyst layer thereby reducing performance. In order to understand the relationships between water management on one hand and fuel cell performance and durability on the other, Ballard has been developing a number of minimally invasive techniques that can throw light on the role of liquid water for both cell performance and durability. This paper introduces a novel measurement method that can provide information about the amount and distribution of liquid water under operation. It is shown how the MEA Resistance and Electrode Diffusivity (MRED) method can be used to determine i) the amount of liquid water in the fuel cell, ii) the pure ohmic cell resistance and iii) the O2 -diffusivity of the cathode. Furthermore, through a combination of the MRED method with current mapping it is possible to determine spatially resolved MEA resistance profiles.

Jan 1, 2005

By W. Lin, E. Heuze

This paper focuses on tests performed on sandstones and shales from four gas wells in the Mesaverde formation. A previous document showed a comparison of the static and dynamic laboratory moduli. This publication describes how field velocity logs were used to derive field dynamic moduli. A 3-way comparison was then performed for these stiffness properties; the results show no agreement between the three sets of values. Differences between dynamic stiffness coefficients from the field and the laboratory exceed 200%; differences between static and dynamic coefficients range up to 600%. In turn, this indicates that a reliable method of estimating mechanical rock properties for hydraulic fracturing design has not been established, and that such a task should be pursued.

Jan 1, 1986

By Sidney A. Suhler

The persistent requirement for methods and equipment capable of detecting hazardous anomalies in advance of underground mining has led to the development by the U.S. Bureau of Mines of a directional radar probe. The probe operates from boreholes drilled from the surface into the underground region to be mined. The engineering model radar was completed in early 1982 and field demonstration tests were performed in May of that year at a selected coal mine. Preliminary in-situ electromagnetic tests were performed at several candidate coal mines to evaluate the radio-frequency characteristics of the coal. A coal mine in New Mexico was selected on the basis of low EM propagation losses in the coal and the presence of an extensive coal seam displacing fault as a radar target. The borehole radar was operated in two vertical boreholes which intersected the coal seam at approximately 25 and 40 feet from the fault interface. Radar reflections from the coal/ rock interface were detected in both tests. Underground tests in a horizontal borehole in the coal were less successful because of interfering reflections. Additional borehole-to-borehole tests were performed with a separate ground penetrating electromagnetic system to obtain radar range calibration data. The coal was found to be bounded by very lossy roof and floor sandstone and shale while propagation through the coal seam was obtained at distances up to 175 feet between test boreholes. Coal seam continuity was indicated by the hole-to-hole experiments through a section of the seam previously thought to be completely cut off by the fault.

Jan 1, 1983

By Weining L

In-situ experiments were performed in a tunnel built in loess soil with the displace- ment components of the tunnel lining and the acceleration components of the tracks measured during the passing of trains. The measured parameters were then studied by the spectral method. As a result, the dynamic forces of trains was simulated numerically and a deter- ministic dynamic nonlinear analysis was carried out by means of finite element method. The results obtained by two different approaches were in fair coincidence. Results of the study indicate, that the low and medium frequency components of the dynamic train loading would be crucial for the dynamic responses of the tunnel lining and surrounding mass, and their effects would increase with the speed of passing trains within a certain range.

Jan 1, 1987

By Mario Karfakis, G. Langlois

Well stimulation is the process by which any production well, whether for production (extraction), storage (injection) or deep interaction (remediation, monitoring, etc) can be made or stimulated to flow at higher levels. This stimulation is driven by active methods to increase the permeability in the near-well environment and create a larger zone of communication between a well and the reservoir it services. Well stimulation is a crucial aspect of well completion and reservoir engineering and is a subject of careful pre-drilling planning. In many modern industrial endeavors the effectiveness of well stimulation is often critical to economic viability. Because of the broad impact of well engineering on several large industries (petroleum and natural gas extraction and storage, geothermal power, groundwater monitoring, extraction and management, environmental remediation, mining and minerals extraction, etc.) changes in the state of the art in well engineering and well stimulation can affect the capabilities of very diverse and disparate industries. This paper is an effort to communicate the status and effectiveness of current practice and technology in well stimulation. The intention being that effective communication of progress can spur innovation in industries that require well stimulation but are removed from immediate communication of technological or practical improvement.

Jan 1, 2009

By C. A. Young, J. D. Miller

Adsorption isotherms previously determined by in-situ Fourier transform infrared/internal reflection spectroscopy (FT-IR/IRS) for oleate adsorption at calcite and fluorite surfaces near pH 9 and at various temperatures are compared. Results indicate that, at both mineral surfaces, chemisorption occurs at equilibrium concentrations below approximately l x l0-5 M oleate while calcium dioleate surface precipitation occurs at higher equilibrium oleate concentrations. The extent of chemisorption at the calcite surface is 3 to 5 times less than that at the fluorite surface while the extent of calcium dioleate surface precipitation on calcite is nearly a magnitude larger than that on fluorite. However, for both minerals, surface precipitation decreases with increasing chemisorption. Contact angle measurements and flotation recoveries show the hydrophobicity of fluorite to be greater than that of calcite at each of the temperatures and oleate concentrations studied. Significant differences are noted only in the chemisorption region. Unlike calcite, the hydrophobicity of fluorite was sensitive to the presence of oxygen in the system. Multichannel Laser Raman Spectroscopy (MLRS) showed this behavior was caused by the double-bond reactivity of adjacent chemisorbed oleate molecules and subsequent formation of an epoxide/polyether complex at the fluorite surface. Such a reaction product could not be detected at the calcite surface. These differences in adsorption density, hydrophobicity, and polymerization behavior are discussed in terms of the intrinsic surface properties of the minerals.

Jan 1, 1999

By Jon J. Kellar

The adsorption of oleate at the surface of a fluorite single-crystal internal reflection element has been investigated using Fourier transform infra-red/internal reflection spectroscopy (FTIR/IRS). The application of this innovative experimental technique has added a new dimension to the investigation and understanding of collector adsorption phenomena. It is now possible, for the first time, to measure in-situ and in real time the adsorption density and bonding nature of collector species adsorbed at mineral surfaces. In this regard, oleate adsorption densities were calculated from spectral data, and the equilibrium adsorption isotherms were found to agree quite well with other adsorption isotherms reported in the literature. At low equilibrium oleate concentrations(<10-5 M), monolayer-type cover-age was observed in the chemisorbed region. It was found that in this region the adsorption density increases with an increase in temperature, which sup-ports experimental results from previous ex-situ FTIR studies and thermochemical studies in which it was shown that the chemisorption reaction was endothermic. At higher equilibrium oleate concentrations (>10-5 M), the adsorption density increases dramatically at the point of surface precipitation. The oleate adsorbed in the chemisorbed region has a distinctly different spectrum than the oleate adsorbed in the surface precipitation region of the adsorption isotherm. In the chemisorbed region, the oleate appears to be mono-coordinated at the fluorite surface.

Jan 1, 1989

The properties of interfacial water at hydrophilic surfaces are of great importance in many technological areas including flotation, solid-liquid separation, dispersion and emulsions, flocculation, adsorption, corrosion, and soil contamination. This paper examines the use of FTIR/internal reflection spectroscopy (FTIR/IRS) to study the spectral characteristics of interfacial water at silica surfaces. FTIR spectra were characterized by consideration of the OH stretching region (3000-3800 cm-1) associated with the vibrational spectra of interfacial water. The broad peak in this region was deconvoluted in order to isolate overlapping spectral features that describe the nature of hydrogen bonding in interfacial water. Three distinct bands were found; -3600 cm-1 (free OH), -3400 cm-1 (incomplete tetrahedral coordination), and -3240 cm-1 (complete tetrahedral coordination) and the variation of their intensities with pH was found to be significant. This spectral information helps to explain orientation and bond ordering of interfacial water molecules at hydrophilic surfaces.

Jan 1, 1998

By M. Maldonado, P. Olivares

"A submersible sensor for real-time gas holdup measurement in the collection zone of industrial flotation machines is introduced. The working principle is based on the generation and measurement of a pulp flow using a gas-exclusion cell immersed in the aerated slurry. The gas exclusion cell consists of a variable-area open vertical tube designed to be filled only with pulp by preventing gas bubbles entrance. The higher density of the fluid column within the cell generates a downward flow of pulp; the rate of this flow is proportional to the gas holdup outside the cell. The gas holdup measurement is achieved by tracking the velocity of the pulp flow leaving the gas-exclusion cell, using a magnetic flowmeter. Construction details of a prototype and its testing in two- and three-phases are discussed.INTRODUCTIONFlotation process optimization consists of finding and maintaining operating conditions that maximize flotation performance measured in terms of recovery and grade. The selective separation of mineral particles proceeds in two interactive zones where different and simultaneous phenomena take place: in the collection zone, the valuable particles are separated by collection on the surface of bubbles, while in the froth zone, the bubble-particle aggregates are gathered, drained to remove entrained particles, and taken into the concentrate stream. The cell overall performance, which can be determined from proper stream sampling, is a function of the recoveries in the individual zones. These zone recoveries cannot be independently measured nor calculated from operating variables. Progress in the assessment of these recoveries has been slow because on-line and reliable sensors to measure properties of the drastically different dispersions existing in both zones are not available.In the case of the collection zone, it has been demonstrated that the recovery of hydrophobic particles on the surface of bubbles, considered as a process with first-order kinetics, correlates with the bubble surface area flux (Finch et al., 2000; Hernandez, et al., 2003; Lopez-Saucedo et al., 2012). Bubble surface area flux (bubble area generated per unit time and cell cross-sectional area), is a variable affected by gas flow rate, bubble size distribution, and frother type and concentration. Gas holdup (volumetric fraction of gas dispersed in the slurry) is also affected by the same variables, and as such, carries information on the interacting variables that define the performance of the process. Therefore, a correlation between gas holdup and bubble surface area flux was expected and demonstrated (Finch et al, 2000), and since gas holdup is easier to measure as no bubble size is required, it has the potential to be the basis of a cell control and optimization strategy if a continuous sensor is available."

Jan 1, 2016

By Halvor Dalaker, Alain Marc Ferber, Thor Anders Aarhaug, Pål Tetlie

Off-gas monitoring of experimental reactors give little information about intermediate reaction products and reflect chemical equilibria at reduced gas temperatures. A reactor design with optical access was designed and tested in order to be able to qualify and quantify gaseous species from their emission spectra. By use of a sequence of sapphire, UV fused silica and IR transparent sapphire and CaF2 windows and lenses optical access to a hot, maximum 1800 °C, reaction zone was gained. A cooled area behind the reaction zone was used as a background in order to avoid signal saturation from reactor walls. In addition to molecular emission spectra, atomic emission lines are used to characterize stable gas constituents and radicals. The setup has been designed for the study of methane dehydrogenation experiments in order to investigate the carbon activity of reduction of oxide with methane, but has also been used to monitor gaseous silicon suboxide.

Jan 1, 2015

By Brian H. Jasperse, Nicholson Peter J.

Gravity retaining walls have been constructed using Deep and Shallow Soil Mixing (DSM and SSM) since 1991 in the United States. These walls, for both temporary and permanent uses, were constructed by mixing cement with in-situ soils over a volume containing 100% of the required gravity wall zone. Modern design techniques have reduced costs substantially by forming the required gravity wall section as a composite mass. Using ratios of 15-35% by volume, treatment f the ground forming the required gravity section has reduced the cost from about $40 to about $20 per square foot. Design, construction and actual performance of these gravity walls are presented.

Jan 1, 1999

By P. J. Nicholson

The methods of reinforcement to be discussed in this paper are all insitu methods, ones that can be used on the soil structure as it exists in the ground, and do not rely on excavation and replacement of the soil. Current practice in the United States, as well as new ideas and methods, will be discussed as they relate to slope stability, retaining walls, and to other uses such as control of mine or cavity related subsidence and to liquefaction control under existing structures. The method is based on the concept of "nailing" or reinforcing the soil in place, and thereby causing a mass of soil to act as a coherent unit. When performed properly, a true gravity structure can be constructed, one that will remain intact under both horizontal and vertical loadings and that will also resist vibrational and seismic loadings.

Jan 1, 2010

By R. Patel, D. R. Taylor, P. M. Varley

In-situ measurements of ground stress were made from surface boreholes, using overcoring and hydrofracturing techniques, to obtain data for the detailed design of the underground works at Pergau. Unexpectedly low stresses were measured and appeared to correlate with apparent hydrofracturing observed during permeability testing. The low values of the minor principal stress had a major impact on design, particularly of the lining for the pressure tunnel and shaft. Additional hydrofracture tests were made underground during construction of the low- and high-pressure headrace tunnels and the pressure shaft, to define the vertical reduction in the minor principal stress with overburden. These data were then used to locate and design the steel and reinforced concrete linings

Jun 19, 1905

By J. Nielen van der Merwe

The main objective of the research described in the paper was to determine the causes of falls of roof in South African coal mines. The south African Colliery Manager&apos;s Association and the members of the South African National Institute of Rock Engineering (SANIRE) who are employed by coal mines lent full support to the work. Fifteen major roof falls were investigated in detail and their causes established. This data was supplemented by mapping a large number of roof falls on four coal mines in less detail. The total number of recorded roof falls was 182. The data bank simulated the data bank of roof falls that resulted in fatalities in terms of the total number of falls recorded and the thickness distribution of the collapses. It was found that the causes of the falls differed for different thickness ranges of roof falls, The thin falls, classified as "Skin falls", which accounted for approximately 70% of all fatalities, were predominantly caused by ineffective joint support and excessive bolt spacing. Ineffective joint support was found to be a dominant cause of roof falls for all thickness ranges, while the influence of excessive bolt spacing diminished with increasing fall thickness. However, it remained a significant cause of roof falls even for the major falls. Burnt coal, dykes, bad mining practice, weathering and inferior materials were found to be minor causes, but nonetheless contributed to the falls. Horizontal stress was a minor cause, with increasing contribution for thicker falls. It was also found that the indicators of horizontal stress coincided with areas of reduced roof rock strength. In general, roof falls occurred in areas where the roof rock was found to be less competent in terms of rock mass rating systems. It was concluded that the Coal Mine Roof Rating (CMRR) system developed by NIOSH in the USA held promise for application in South Africa and should be investigated further.

Jan 1, 2001