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By S. A. Vorobyev, Yu. L. Mikhlin, Ye. V. Tomashevich, A. A. Karacharov, M. N. Likhatski1, A. S. Romanchenko, S. V. Saikova

"A set of state-of-the-art methods have been applied to study ultrafine particles and nanoscale species arising on mineral surfaces upon milling, interaction with flotation reagents, and leaching of base metal sulfide ores in order to gain insights into interfacial mechanisms. The fine fractions produced by ball milling of a Pb-Zn Gorevsky ore and four Cu-Ni sulfide ores studied with laser diffraction, dynamic light scattering, zeta-potential measurement, Xray photoelectron spectroscopy (XPS), SEM, TEM and other techniques. The particle size distributions had, aside from the peaks at 20-60 ?m, maxima near 1-2 ?m; the flotation was considerably suppressed when the yield of positively charged ultrafine particles approached tenths % (several kg per ton). High-energy XPS and X-ray absorption spectra revealed that sulfide minerals depleted in metal in air and aqueous solutions were composed of outer “polysulfide” layers, strata with disulfide species, and heavily defective underlayers, and “passivation” was explained by stability of the metal-deficit structures. Dixanthogen at pyrite and copper-activated sphalerite, dixanthogen and then cuprous xanthate on chalcopyrite, and chemisorbed xanthate at galena were specified as the main interfacial products using cryo-XPS of fast-frozen flotation slurries. The particle size, zeta-potential and behavior of colloids of Cu and Pb xanthates and dixanthogens were largely determined by the initial ratio of a cation and collector; the properties of copper xanthate nanoparticles were also affected by incorporated dixanthogen (about 15 wt.%). Submicrometer gas domains of 3-8 nm in height and “hydrophobic” forces upon the probe retraction were found on xanthate-treated minerals using atomic force microscopy and spectroscopy; their impact on flotation is briefly discussed.INTRODUCTIONInterfacial phenomena play a key role in flotation, leaching, water purification and related environmental processes. The mineral processing and extraction of metal from sulfide ores commonly involves milling the ore, which produces, along with the particles of 20 µm to 100 µm, mineral entities ranging from micrometer to submicrometer and nanometer scale. Furthermore, ultrafine particles of flotation reagents, products of metal sulfide oxidation, and so on may form spontaneously and accumulate in production water, flotation froth, deposit on mineral surfaces, affecting the flotation performance, and then enter waste waters, mine and natural drainage, polluting soils, surface- and ground waters (Miettinen et al., 2010; Wang et al., 2014). The efficiency of flotation and hydrometallurgical recovery of values, environmental issues are crucially dependent on the state of mineral surfaces. Particularly, it is generally accepted that the surface non-stoichiometry of sulfide minerals induced by oxidation and leaching should affect their hydrophobicity and reactivity, including so-called “passivation”, but the nature of such surface layers are still a matter of controversy (see, for example, Holmes and Crundwell, 2013). Another phenomenon attracting rapidly growing interest in several areas is low-dimensional gas species (“nanobubbles”) at hydrophobic surfaces that may play a decisive role in particle-bubble attachment in flotation but remains scarcely investigated up to now (Xing et al., 2017). Here, we survey our recent results on the abovementioned problems applying a series of rather new methods and approaches; more details can be found in refs. Karacharov et al., 2016; Mikhlin et al., 2015; 2016; 2016a; 2016b; 2016c; 2016d; 2017; 2017a; Vorobyev et al., 2017."

Jan 1, 2018

By Ulf B. Andersson, Christina Dahnér-Lindkvist, Bruno Figueiredo, Jessa Vatcher, Jonny Sjöberg, Joel Andersson

Hydraulic fracturing to precondition the rock mass in high seismic risk environments has great potential. Unfortunately, there are many unanswered questions about how to best implement a hydraulic fracturing program at individual mine sites, and even how to best use our engineering tools to evaluate these plans. To give the hydraulic fracturing field tests at LKAB’s Kiirunavaara Mine the best chance of success, fully-coupled, discontinuum numerical modelling Itasca’s 3DEC code was used together with statistical simulations of the fracture network. For modelling purposes, it was assumed that hydraulic fracturing successfully reduces seismic risk through 1) the creation of hydraulic fractures along a plane at each injection site, and 2) activation of existing discontinuities. A variety of scenarios for the mine were evaluated, which focused on site specific uncertainties (such as the spacing of the pre-existing discontinuities) and practical solutions (such as the hydraulic fracture spacing, selection of injection medium, and hydraulic fracture site location relative to production). The discrete fracture network (DFN) realizations were developed using available statistical data for discontinuities near where hydraulic fracturing was planned.

Apr 26, 2022

By F. X. Prins, L. R. Nelson

Tight control of electrode paste additions, hard and soft paste levels, baked zone position and electrode temperatures are integral to superior Söderberg electrode management practices. Paste addition is typically effected through briquettes, cylinders or large blocks. Each electrode paste form has its advantages and disadvantages, but probably a more crucial element from an electrode control perspective is the frequency and amount of electrode paste addition into a Söderberg electrode column. The detrimental effects of excessive soft paste levels leading to Stokes? Law segregation of paste in the electrode column are well documented, while several operators have effectively implemented the use of electrode thermocouples to monitor paste temperatures and automated slipping algorithms to control baking conditions within electrodes. Somewhat less well appreciated are the negative influences of inadequate soft paste levels, especially when coupled with excessive paste cylinder or block additions and resulting high hard paste levels. The alternative of insufficient hard paste levels and associated overheated electrode paste must also be considered, and can contribute to paste segregation directly. This condition also has the potential to generate gas mixtures in the electrode column that are concurrently a potential health hazard, while being prone to spontaneous combustion. Results of industrial trials on electric furnaces using Söderberg electrodes in a variety of applications from ferrochromium, to ferromanganese and even platinum-bearing base metal sulphides smelting are presented to illustrate the influence of paste loading practices on the dynamics of hard and soft paste levels. Possible electrode failure mechanisms attributable to inadequate paste level control will be discussed through some industrial examples. Suitable paste loading practices to mitigate the risks of inappropriate paste levels and associated electrode incidents are presented.

Jan 1, 2004

By J. D. Steenkamp, J. Muller

"Excavation of an industrial-scale submerged arc furnace, utilized in the production of silicomanganese, identified two high-wear areas in the refractory lining: the tap-hole, built with cold rammed carbon paste and SiC bricks, and the hearth, built with cold rammed carbon paste. To obtain insight into the potential causes of wear, thermodynamic calculations were conducted on eight sets of data, obtained for seven furnaces on three plants based in South Africa. FACTsage software and associated databases – FACTPS, FToxid, and FSstel – as well as the Mn-Fe-Si-C database of Tang and Olsen (2006), were applied. Theoretical indications are that chemical reaction between carbon refractory and slag, as well as dissolution of carbon and SiC refractory in metal, contributed to tap-hole refractory wear; and dissolution of carbon in metal contributed to hearth refractory wear. IntroductionDuring the excavation of a 48 MVA submerged arc furnace (SAF) used for silicomanganese (SiMn) production, it was found that the taphole and hearth were high refractory wear areas (Steenkamp, 2014). In both these highwear areas, carbon-based cold ramming paste formed the hot face refractory lining (crucible). The wear profile of this SAF is presented in Figure 1.The hot face refractory lining was formed by cold ramming of high-grade carbon ramming material. This material consisted of 50–70% anthracite, 15–25% graphite, 6–12% resin, 2–7% tar, 1–5% clay, and 1–5% alumina. The tap-hole was built using SiC bricks, consisting of 75% SiC, 23.4% Si3N4, 0.3% Fe2O3, 0.3% Al2O3, and 0.2% CaO.In the tap-hole area, the wear of the SiC refractory material was estimated at 0.4 t, and that of the high-grade carbon ramming material, at 1.9 t (Steenkamp, Pistorius, and Tangstad, 2015). The amounts of slag and metal tapped during six years of operation of the tap-hole (September 2007 to April 2013) were estimated at 33 088 t (Steenkamp et al.,2015) and 41 360 t, respectively."

Jan 1, 2016

By Fred N. Kissell

The U.S. Bureau of Mines was established in1910 to reduce .the high accident rate in the nation's coalmines. For 85 years, it conducted a wide variety of tasks related to mining before it was abolished in 1995. The BOM had many technology transfer successes in its lifetime, including more than a dozen "R&D100" awards. This essay identifies and discusses five "transfer factors" that can explain the success (or failure) of many Bureau of Mines projects. These five factors are termed "pressure, pitfalls, path, price, and profit."

By Alejandro Rubio-Lopetegui, Gonzalo Montes-Atenas

The occurrence of Enargite (Cu3AsS4) in hydrometallurgical plants bears a number of challenges. One question lies on how Copper and Arsenic can be selectively extracted from the solid surface structure when immersed in aqueous solution. The leaching of Enargite in ambient conditions has been extensively studied; nevertheless, challenges regarding the process kinetics and surface structures enabling the extraction process remain ill-understood. Prior knowledge indicates that different conditions of pH, Eh, temperature, speciation of the aqueous phase or variations of these parameters defines the overall rate at which metals and other elements will be transferred to the solution. One aspect that the research studies have seldom addressed involves studying the main features of the surface structures formed during the leaching process at the outmost surface atomic layer. Such structures will mediate between the solid bulk and the solution to undertake subsequent stages of leaching process. The aim of this research work is to critically analyze the state of the art of Enargite electrochemistry from the mediator formation-dissolution mechanisms standpoint occurring at the mineral-solution interface. The most probable mediator species reported in the literature were found to be: Arsenolite and Sulfur (acidic media), Covellite (acidic and alkaline media) and Tenorite (alkaline media). As a result of this analysis, it was observed that the surface speciation was not in full agreement with the previous knowledge suggested to explain Enargite leaching reactions and, therefore, modified Eh-pH diagrams are presented. The acquired insights on the surface structures rising from the Enargite-aqueous solution interactions is further revised to provide new experimental protocols towards selectively separating Copper and Arsenic through hydrometallurgical paths.

Jan 1, 2014

By Philippe De Donato, Odile Barres, Mukendi Kongolo, Stoyan Gaydardzhiev, David Bastin, Jean-Marie Kanda

The adsorption patterns of potassium amylxanthate on the surface of high purity malachite subjected to prior sulfidization with NaSH have been followed and elucidated. DRIFTS spectroscopy has been used to trace the associated physicochemical alterations as well as the chemical species present on the mineral surface. Varying the collector concentration from 5.10-4 to 1.10-2 mol/L has led to different degree of surface coverage of the alkyl groups and to formation of organometallic hydrophobic complexes of CuX or CuX - X2 type. The results reveal that the CuX complex formed on the malachite surface without sulfidizing agent is more unstable and prone to dissolution-precipitation phenomena. Based upon the constructed adsorption isotherms and upon the degree of statistical coverage, different zones of mineral-reagent interactions could be distinguished. They correspond respectively to the monolayer, bi-layer and tridimensional condensation domains. In each of the identified zones mono or double layer adsorption patterns of the collector are proposed leading respectively to formation of surface compounds with different degree of hydrophobicity. The results suggest that sulfidisation remains an important prerequisite in view achieving efficient flotation of the malachite from the studied copper ore.

Jan 1, 2014

By Peter J. Nicholson

The methods of reinforcement to be discussed in this paper are all insitu methods, ones that can be used on the soil structure as it exists in the ground, and do not rely on excavation and replacement of the soil. Current practice in the United States, as well as new ideas and methods, will be discussed as they relate to slope stability, retaining walls, and to other uses such as control of mine or cavity related subsidence and to liquefaction control under existing structures. The method is based on the concept of "nailing" or reinforcing the soil in place, and thereby causing a mass of soil to act as a coherent unit. When performed properly, a true gravity structure can be constructed, one that will remain intact under both horizontal and vertical loadings and that will also resist vibrational and seismic loadings.

Jan 1, 1991

By Larry Mirabelli, Gerard J. O'Brien

"The construction of the Third Harbor Tunnel is a key element of the Central Artery TunnelProject. The tunnel is to traverse Boston Harbor directly linking South Boston to EastBoston. The tunnel is a cut and cover tunnel as opposed to a bored tunnel. The cutdimensions are 95' wide, 110' deep and approximately 4000' in overall length."

Jan 1, 1993

By Richard Campbell

Effective strata control, utilising fully encapsulated resin grouted roof bolts is dependent on the installed quality of the reinforcement elements. Resin based grouts are the main form of rock bolt anchorage in the underground coal industry in Australia and New Zealand. To be effective the system requires the mixing of the catalyst and mastic components of the resin as well as shredding of the cartridge that contains the resin. Over the past six years Solid Energy New Zealand Ltd (SENZ) has pioneered an extensive work programme quantifying the effects and extent of poor installation quality due to gloving, poor mixing and loss of encapsulation (Pastars 2003, Campbell et al 2003, Mould et al 2004, Campbell et al 2005 and Pastars & MacGregor, 2005). The One-Step Bolt (OSB), an innovative bolting solution designed and manufactured by Hilti Pty Ltd offers a self drilling, single pass bolting method that eliminates gloving, guarantees mixing quality and encapsulation performance of the installed product while not jeopardising the mechanical performance of the bolt. This paper details recent work undertaken by SENZ designed to understand and quantify the system performance of the Hilti OSB in New Zealand?s thick coal seam mining environments.

Jan 1, 2006

By S. C. Termes, P. E. Richardson, R. L. Wilfong

This paper discusses recent Federal Bureau of Mines research on the selective flocculation of various minerals with insoluble cross-linked starch xanthate (ISX). ISX is insoluble, has a shelf life of more than a year when kept cold, and has a higher molecular weight due to cross-linking than the soluble, non-cross-linked starch xanthate used in previous flocculation studies on nonsulfide minerals. ISX readily flocculates a number of sulfide mineral fines, but no silicious gangue. Floc formation, floc size, and settling rate are dependent on pH. The pH dependence, however, differs for each mineral. Bornite has been selectively flocculated from bornite-quartz mixtures, and the bornite-containing flocs were separated from the unflocculated quartz using decantation and washing procedures.

Jan 1, 1984

By S. C. Termes

This paper discusses recent Federal Bureau of Mines research on the selective flocculation of various minerals with insoluble crosslinked starch xanthate (ISX). ISX is insoluble, has a shelf life of over a year when kept cold, and has a higher molecular weight due to cross linking than the soluble noncrosslinked starch xanthate used in previous flocculation studies on nonsulfide minerals. ISX readily flocculates a number of sulfide mineral fines but not silicious gangue. Floc formation, floc size, and settling rate are strongly dependent on pH, with the pH dependence differing for each mineral. Bornite has been selectively flocculated from bornite-quartz mixtures, and the bornite-containing flocs were separated from the unflocculated quartz using decantation and washing procedures.

Jan 1, 1982

By G. E. Burpee

A COMPREHENSIVE study of insoluble residues in the productive Permian limestone in the Hobbs and Eunice fields, Lea County, N. M., has been conducted by Shell Petroleum Corp. engineers {luring the past two years. This study was prompted by the belief that the stratigraphy of the producing formation might be worked out in detail and that some relationship might be established between the permeable oil, gas, and water zones and correlatable lithologic horizons within the productive formation. As a result of the study, correlations have been established which have proved of great value to both an orderly development and corrective program.

Jan 1, 1935

"Full time inspection of drilled shafts by qualified personnel is a necessary part of construction. Detailed inspection procedures for routine inspection are provided in the Drilled Shaft Inspector’s Manual, published jointly by the DFI and ADSC: the International Association of Drilled Shaft Contractors.The use of NDT methods or other observation methods, such as probes, video camera inspection, remote shaft wall inspection devices or various calipers are not suitable substitutes for routine "topside" construction inspection as described in the Drilled Shaft Inspector’s Manual. However, these NDT and other "remote" or indirect observation methods are valuable alternatives to direct entry of personnel into drilled shaft excavations. They should be considered whenever appropriate to reduce the risks of direct entry of personnel into drilled shaft excavations.As described in the Drilled Shaft Inspector’s Manual, observations made during construction are essential for quality construction of drilled shafts. The shaft depth, diameter, plumbness, bottom conditions, reinforcement, concrete continuity, and bearing conditions are most easily checked during construction. Some of these observation methods include excavation around the shaft for relatively shallow inspection, down-hole inspection for end bearing conditions or rock sockets, and video camera devices for remote inspection. In rare circumstances, a drilled shaft can be extracted for inspection. Before concrete placement, the bottom of the shaft can also be probed by drilling or coring to determine if there are voids or soft zones in the material at the base of the shaft.The Drilled Shaft Inspector’s Manual focuses on traditional "topside" inspection for routine drilled shaft construction."

Jan 1, 2004

The Daly-Judge Tunnel, begun in 1887 to drain mine workings, is now a source of potable water for the Municipality of Park City. The water is exceptionally clean; however, when roof falls occur, suspended solids levels become too high and water from the tunnel cannot be used in the treatment plant. In 2001, the tunnel was inspected and rehabilitated to ensure that the water supply for the 2002 Winter Olympic Games would be uninterrupted. Twenty-five timber tunnel sets were removed, and 86 steel sets were installed. Timber lagging was installed or replaced over about 230 m (750 ft) of tunnel length.

Jan 1, 2006

By A. J. Bartlett

ISLAND Creek conditions are generally referred to as ideal; yet, as at all other properties, there are all known hazards of coal mining. The hardest of these hazards to combat is the human element. The basic thought in the minds of the management of these properties is to produce coal with the utmost safety, and it has impressed upon its supervisory force that it does not want a ton of coal unless it can be produced safely. This company has instituted a mine inspection department, which reports direct to the general manager, and all matters pertaining to safety come under the direction of this department. Through the medium of the inspection department, the management is kept in touch with the actual conditions existing in general at all mines. Inspections are made regularly and continuously; that is, at all times while the mines are in operation some sections of some mines are being examined. These inspections cover all active and inactive workings. Miners are con-tacted in their working places and other employees at their respective work. A thorough check is made to see that the state mining laws are complied with and that company safety rules are being observed. Night shifts receive the same attention as day shifts. All violations and dangerous practices are brought to the attention of the plant supervisory force with suggestions and recommendations; major hazards of emer-gency nature are taken up immediately with the management. Peri-odical inspections are also made of all tipples, preparation plants, dumping and hoisting equipment, to see that all machinery is properly guarded, and walkways and platforms properly fenced; conditions of equipment and mechanical defects are also reported. Reports of inspection are written in letter form and in such a manner as to give the management a picture-of the existing conditions at the time of inspection. Copies of inspection reports are forwarded; to the superintendents with the general manager's comments.

Jan 1, 1937

By Yadong Xue, Fei Wang, Hongwei Huang, Yan Sun

"Increasing attention to subway tunnel maintenance is being paid with the high speed development of urban rail transit system in China. A novel moving tunnel inspection equipment based on machine vision is developed in this paper. High resolution image acquisition system is proposed for tunnel crack and leakage inspection. The main components of this image acquisition system includes high speed CCD cameras, linear lights and high performance computer. To inspect the crack less than 0.3mm with a 3-5km/h speed in subway tunnel, we need to consider resolution and line rate of camera, pixels of cameras, range of inspection and illumination intensity of lights simultaneously. The optimization design is proposed to make the equipment more convenient for tunnel use. Entire tunnel situation can be detected and recorded in a single inspection process. This equipment has already been verified in Shanghai subway tunnel for defects inspection.1. INTRODUCTION In China, the quantity of subway tunnel has reached a large scale in recent years. Until 2014, there had been more than 2300km of subway tunnel in China which accounted for nearly three quarters of Chinese urban railway system (Zhang Chen,2015). In some metropolises like Beijing and Shanghai, most of the metro tunnels has already run over 20 years which within maintenance phase. This has brought about plenty of inspection work and maintenance work to guarantee the tunnel under the serviceability limit states. The increase of running mileage of subway tunnels in China has been displayed in Fig 1."

Jan 1, 2016

By Paul S. Fisk, Arne Fareth, Julie Frietas, Francis Lo, Fidel L. Mallonga

INTRODUCTION This report describes the inspection of parts of the New Croton Aqueduct (NCA)undertaken for the New York City Department of Environmental Protection (NYCDEP)by Parsons Brinckerhoff Quade & Douglas, Inc., (PB) in association with Montgomery Watson Engineers of New York, P.C. (MWH). Support for the inspection was provided by AFC Enterprises, Inc., under Construction Contract CRO-333, “WM-11 New Croton Aqueduct Rehabilitation and Inspection Program.” The scope of the inspection work under CRO-333 included assessing the condition of the 10.3 km (6.4 mile) long, pressurized section of NCA and inspection of shafts, head houses and blow-off structures in both the pressurized and gravity sections. The CRO-333 inspection continued investigation work begun under ContractCRO-196, which ran from 1993 to 1997. The CRO-333 inspections were conducted from November 2004 to September 2005. Background The New Croton Aqueduct was put into service in 1891 to deliver water from the Croton River Watershed in Westchester County to consumers in New York City. Figure 1 shows the location plan of Croton Water Supply System. The design flow into Jerome Park Reservoir was 12.7 m3/s (290 mgd) and into the135th Street Gate House, further south, was 10.9 m3/s (250 mgd). The NCA has been operated as a gravity conduit from Croton Lake to Gate House No. 1, just north of Jerome Park Reservoir, since its original construction. The length from Gate House No. 1to 135th Street, which includes a major siphon under the Harlem River, has been operated under pressure. Croton Lake gate house, the north end of the alignment lies at Station 4+75; Shaft 33, the south end of the alignment lies at Station 1628+05. The diameter of the tunnel is 3.2 m (10.5 ft) in the siphon and 3.7 m (12.3 ft) in the Bronx and Manhattan sections. The pressurized sections, constructed in rock, consist of a brick lining surrounded by a mortared and grouted rubble backing. Figure 2depicts a typical tunnel cross section. The objective of the shaft and tunnel inspections was to locate and document defects, such as leaks, deterioration of lining material, cracks, spalls, delaminations,

Jan 1, 2007

By O. Tranbarger

In aging tunnels, wall and roof deterioration can eventually result in defects that must be detected and repaired to maintain safe structural conditions. In investigating tunnel defect conditions, a specialized FM radar system was developed with a programmable VHF and UHF operating sweep range for optimizing the penetration and measurement capabilities. The new FM radar technology was tested in two aging brick-lined tunnels in New York City. Test results showed that FM radar signals could penetrate eight courses of water-saturated brick and that the original steel liner outside the tunnel walls was intact.

Jan 1, 1985

By Tom Shumka

Introduction ?This technique detects 100% of all gear tooth surface indications, providing comprehensive data, and has the ability to size indications accurately. ?The remarkable advantages of ECA technology, is improved inspection capabilities and significant time-savings. ?The advantage of using EMCD is its ability to size indications accurately. ?This technique does not require the gear teeth to be wiped down by hand after cleaning as in MT, LT or UT inspections. (Figure 1) ?This technique will inspect one gear tooth in 30 seconds. ?All of the data can be archived for future comparisons in an electronic report. Methodology ?This technique utilizes Eddy Current Array (ECA) as the principle inspection technique. ?What has been added are specialty scanner probes with multiple coils, a multiplexer and a software package. ?With 2 and 3D dimensional isometric displays, the defect can be seen electronically as it is on the gear tooth surface, thus, reducing the reliance on human interpretation.

May 1, 2011