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By Ronald Erdmann

Today the BOF filter dusts and sludges are mainly dumped due to their zinc contents. By typically ranging from 2 to 5 % they prevent the filter dusts and sludges from beeing recycled via the blast furnace route. Based on the different discharge kinetics of Iron and zinc during the main blowing period In a bottom stirred BOF a simple and efficient system for recovery allow zinc fractions has been developed. The obtained material Is suitable for recycling without nsc of shell formation In the blast furnace. Different subsequent development steps have been performed. By starling with a very simple lime dependent model the sludge from the BOF off gas cleaning system was collected in two different sludge channel systems. This model based an the fact that most of the scrap based zinc Is discharged from the melt within the first eight to ten minutes of the BOF process. To Improve the system a spectroscope zinc sensor was Installed at the hot section of the off gas cleaning system to get more reliable informations on the actual zinc concentation of the BOF dust. By use of the system up to 50 % of the BOF sludge can be recycled.

Jan 1, 1995

By Art Wright, Steinar L. Ellefmo, Kurt Aasly, Mike Williamson, Fredrik Søreide, Martin Ludvigsen, Michael Zylstra

Exploring for minerals on the seabed is challenging and expensive – and the ability to collect representative sub surface samples is essential. The research project MarMine led by NTNU has together with Seattle based Williamson and Associates developed and tested an ROV-based drill rig for mineral (seafloor massive sulfides and crusts) and rock sampling. The ROCS system is a single stroke drill and is simple, robust and possible to use from various larger ROVs. For the vehicle to provide a stable platform, the vertical bollard pull of the ROV and the vehicle mass are important variables. The developed drill uses a thin wall drill bit and barrel and operates at high RPM to reduce the required down weight and drilling moments. The system also contains an emergency release to be used if the core barrel is stuck. The drill is hydraulically powered with cylinders operating the tower and a rotation unit. It can rapidly be modified to provide samples from softer samples like unconsolidated material. At the Arctic Mid Ocean Ridge, a work class ROV was deployed with the drill mounted for testing at 2700 m depth in basalt rock. The recovery from the system was above 80%. Such core samples can be used for chemical analyses of metal and mineral grades, mineralogy and rock mechanical testing. The system provides a probing tool for marine mineral exploration, with low cost, low operational complexity and low risk. Proper resource estimation requires drilling deeper into the deposit, but the short core samples provided by the ROCS provide valuable a priori information planning for more extensive drilling campaigns.

Jan 1, 2017

By D. Sager

Middleburg Ferrochrome (MFC), a company in Samancor Chrome, commissioned a new ferrochrome smelter in March 2009. This is a 60 MW DC-arc furnace with a DC power supply for the smelting of Transvaal chromite ore fines. With the benefit of 12 years' experience with this technology while operating a 44 MW DC-arc furnace, MFC mitigated all known challenges and considered up-scaling risk in the new plant, which had a rapid ramp-up to full power in 02 of 2009. Good operating practices, as made possible by robust equipment selection, including a thyristor rectifier set of proven technology, and operation with optimal slag chemistry, leads to a safe and effective plant operation. With the optimized furnace design and a correctly sized power conditioning system, using only standard (static) harmonic filters and a correctly sized smoothing reactor, the arc furnace is not a 'dirty load' for the utility, staying well within IEC limits for power quality. A patented arc compensation system is installed and allows for full arc position control (to compensate for magnetic field induced arc deflection) so that a symmetrical crucible is maintained, significantly benefiting refractory life. The principal benefits gained from the MFC process is the fact that ore fines are processed, without metallurgical coke, and higher chrome recoveries are achieved compared to other smelting technologies when using a DC open arc for smelting. Keywords Samancor Chrome, Middelburg Ferrochrome, ABB, smelting, DC arc furnace, arc compensation, power factor correction, anode, harmonics, thyristor, reactor, maintenance, refractory, ores, reductants.

Jan 1, 2010

By W. Birch, G. D. Rangel-Sharp, L. Bermingham

For many years, the accepted method of Measuring the Velocity of Detonation (VOD) in blast holes has been to use an electric cable of a constant resistance per metre. Thus as the wire is consumed by the explosive in the blast hole, the change in resistance is monitored and when this data is plotted against the time period of the in hole explosion, the VOD can be calculated.

Jan 1, 2011

By John A. Clark, Danylo Oryshchyn, Casey Carney, Stephen Gerdemann, Cathy Summers, Thomas Ochs

"Limited analysis of combustion gas streams where carbon capture is not of interest is done mainly to ascertain operation parameters. Stringent regulations on acid gases and particulates promote careful flue gas analysis. Unregulated components are typically not analyzed. Typically not more than four points (two in the boiler, and one each in the flue and the stack) are sampled. A successful oxy-fuel process with carbon capture and compression is anticipated to require as many as 12 sample points with analysis for water, nitrogen, oxygen, argon, NOx, SOx, and carbon monoxide. Carbon dioxide captured for beverages produces a high value product and the cost associated with analysis is warranted. However, carbon capture for disposal must keep all costs to a minimum. This paper will compare alternative approaches for cost-effective sampling and analysis of the carbon dioxide product streams from oxy-fuel combustion, through all stages of production through compression and pipeline/vessel delivery.IntroductionAnalysis of gases in an oxy-combustion process with carbon capture is essential to the operations of the oxy-fired boiler and the subsequent collection, compression, and purification of carbon dioxide. The process is charged with pure oxygen and not-so-pure carbon in the form of coal at the front end, generating a product of mainly carbon dioxide with traces of argon, nitrogen, sulfur compounds, nitrogen compounds, oxygen, hydrogen, and mercury. It is possible that hydrogen chloride and hydrogen sulfide may also be present in trace amounts [1]. The trace components primarily come from impurities contained in coal such as water, sulfur, nitrogen, and volatile organic compounds. Coal also contains a good deal of mineral matter that is transformed into ash during combustion, becoming particulates that can complicate the analysis regimes utilizing standard analytical equipment."

Jan 1, 2010

By Ray Y. Lin, Sunil G. Warrier

"Low cost processing of metal matrix composites is an essential requirement for this class of materials to be acceptable in commercial application. In an effort to reduce the cost of processing of metal matrix composites, an infrared pressureless liquid infiltration technique has been developed. The salient features of infrared infiltration are that it is rapid, simple and a low cost process. The rapid processing capability causes very little oxide formation on the alloy resulting in both improved wetting and flow characteristics and reduced oxygen contamination in the composite. Thus, vacuum is normally not required. Using infrared inflltration, aluminum and titanium matrix composites have been prepared under an ambient argon atmosphere. Reinforcements in these composites include carbon fibers, silicon carbide Nicalon fibers and Textron's SCS fibers. Microstructural and mechanical test results indicate that completely consolidated composites with good fiber distribution, limited interfacial reaction and high mechanical properties can be manufactured by this process. IntroductionAluminum and titanium matrix composites reinforced with ceramic reinforcements are strong candidates for numerous applications in the aerospace and automotive industries. Aluminum matrix composites are commonly fabricated by either solid state vacuum hot pressing, liquid state pressure infiltration or squeeze casting [1]. Although liquid state pressure infiltration and squeeze casting has significant advantages over solid state processes, the requirement for pressure makes these composites uneconomical for large scale industrial application. Titanium matrix composites are primarily fabricated by solid state diffusion bonding [2]. Pressureless liquid infiltration can significantly reduce the cost of fabrication in both the composite systems. However, during pressureless infiltration processes, several complications concerning the wetting characteristics and chemical compatibility arise."

Jan 1, 1994

By Sneyd R. J, Walton M. C

In early 1987 Minproc acquired a license from the inventor to engineer and construct acid plants incorporating the Fattinger technology. The process offers a simple and reliable method of producing sulphuric acid from metallurgical off gases at significantly lower capital and operating costs than the more familiar contact process. The process also offers the simultaneous production of nitric acid, if the NOx content of the off gases is high enough. A development of this latter process has other applications within the minerals industry, particularly in conjunction with refractory gold ore preoxidation.

Jan 1, 1989

By John Manka

Emulsion explosives consist of an aqueous oxidizer phase, a fuel phase, and an emulsifier. The ability to use lower-cost sources for any of these raw materials presents an obvious economic advantage to emulsion manufacturers. This paper focuses on using low cost waste drain oils as the fuel phase in emulsion explosive applications. Laboratory studies showed that emulsions made from waste drain oils and agricultural ammonium nitrate prills were usable for emulsion explosives though their shear stability was weak. Customer field results proved that waste crankcase drain oil could replace half of the virgin diesel fuel in emulsion explosives to make an effective emulsion explosive product with a very low cost.

Jan 1, 2003

By Robert S. Holmes

The U. S. Army Corps of Engineers Explosive Excavation Research Office (EERO) of Livermore, California, has been engaged in research and development of excavation techniques using both nuclear and conventional explosives since 1962. Prior to July 1971, this organization was designated the U. S. Army Corps of Engineers Nuclear Cratering Group. The EERO mission is performed as part of the joint Atomic Energy Commission -Corps of Engineers nuclear excavation research pro-gram. During the period 1962-1969, the Corps executed many cratering explosions using spherical charges of up to 85 tons of nitromethane to model nuclear excavation concepts and to develop design criteria for the nuclear cratering explosions. The experience gained in these modeling tests suggested that explosive excavation using large chemical explosive charges could be applied to excavation projects as an economical substitute for traditional excavation techniques. Consequently, the Corps' research program was broadened in 1969 to include development of chemical explosive excavation as a construction tool. The term "explosive excavation" denotes the use of large buried explosive charges to produce an excavation by fracturing the material and casting it into a desired configuration. In its simplest form, this technology involves detonation of a single explosive charge buried at the proper depth to produce a crater which is roughly hyperbolic in cross section. The types of craters produced by various depths of burial are illustrated by Figure 1. Single or Multiple rows of charges are used to excavate linear cuts required for water conveyance or navigation channels. .More complex explosive excavations include small craft harbors, railroad and highway cuts, and removal of W1denvater rock barriers to navigation. While the literature indicates widespread use of large explosions in the (1) ERRO is a field activity of the Waterway Experiment Station, Vicksburg, Mississippi

Jan 1, 1971

By Paul C. Turner

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium, and titanium cost has prevented its use in non-aerospace applications including the automotive and heavy vehicle industries.

Jan 1, 2001

By G. Sachs, E. J. Ripling, S. I. Liu, J. J. Lynch

INTRODUCTION IT is a generally recognized fact that by repeated straining the fracture stress of any metal is reduced to a fraction of its value for static loading. The value of this fatigue strength depends upon numerous factors, such as the states of strain and stress, the limits of straining, and the number of repeated loadings or cycles.1.2,3 The large volume of previous investigations on fatigue is concerned entirely with large numbers of cycles, say exceeding 10,000 and up to 500,000,000. However, the changes in fracture stress and fracture strain occurring after a small number of repeated loadings have attracted little attention. Apparently the only investigations of this type are those byLudwik4,5 who subjected steel, copper, and aluminum wire to repeated torsion. In each test the torque was varied between identical values in the two directions of twisting. Depending upon the magnitude of the moment, fracturing occurred after a number of cycles, up to 10,000. The results of Ludwik's tests will be discussed later. Such torsion does not readily yield actual stress and strain values. Therefore a preliminary study was made of the effects of repeated direct stresses, i.e., tension and compression stresses. Because such tests are considerably more tedious than torsion tests, only high stresses were used in the preliminary work, yielding definite changes in metal properties after a few cycles. It was found in these tests that strains could be controlled more readily than stresses in the investigated range of high stresses. This paper, consequently, deals with the effects of strains of equal magnitude but different signs. The metal was first prestrained in static tension by a certain amount then subjected to compression to yield the same amount of strain after unloading. This loading cycle was repeated up to a maximum of seven times. After various cycles, the stress-strain curves in tension were determined, up to fracturing. As material for these tests, the aluminum alloy 24ST was selected because it exhibits a comparatively small amount of necking in the tension test. This alloy permitted, therefore, rather accurate control at the high strains necessary to produce fatigue failures at less than seven cycles. The results of this investigation appear sufficiently interesting to extend the method of attack in various directions. It is intended to study (I) the effects of cycles up to a few thousands and (2) the effects of strains of different magnitude in tension and compression, respectively. The latter variable also includes as a special case the effects of compressive strains.

Jan 1, 1948

By Anne Caroline Costacurta Polli, Jose Rojas Cáceres, Roberto Mahler de Morais, Thais Costa Silva

The technology and the knowledge about the behavior of explosives and detonation accessories allowed to create new products for different situations by the restrictions imposed by the market. In a Brazilian underground copper mine the restriction occurred in the use of high grammage Det Cord in the development heading blasts perimeter holes. Enaex Brazil has developed Densiex UG™ (Low-Density Bulk Emulsion), a water-resistant bulk gassing emulsion with a density ranging from 0.60 to 0.90 g/cm³ to replace the high grammage Det Cord in blasts. That product is pumped in the same Mobile Manufacturing Unit (MMU) as Enaex Brazil's standard underground (UG) bulk emulsion. This product has a Lower Velocity of Detonation (VOD), vibration, and detonation pressure, which contributes to a better finishing of the drift, lower impact in the support structures, and lower generation on unstable rocks in the perimeter of the drift. This case aims to summarize the results of the work on the application of the Low-Density Bulk Emulsion in perimeter holes in an underground development gallery at an underground copper mine in Brazil. During this work, 10 horizontal drift blasts were performed using the Low-Density Bulk Emulsion, which presented an average density of 0.64 g/cm³, increasing safety, a 25% reduction in overbreak, a 23% reduction in scaling time, elimination of rework, and a saving of $135,000 per year for this business partner that immediately implemented this new product in all blasts at this mine.

Jan 21, 2025

The basic make-up of the majority of currently produced bulk explosives has changed little in the last 20 years. These explosives would be described as mature in a life cycle analysis. Therefore these explosive products and the practical rules for their use are well understood and well established. In recent years there has been interest in low density explosives, predominantly due to ammonium nitrate shortages and the associated increase in the cost of explosives. In the use of low density explosives some of the practical rules for the more commonly used bulk explosives do not apply. Therefore a shift in the thinking among users is required. At a number of mines low density explosives have been trialled or are being used, utilising the practical rules that apply to bulk explosive products. This has led to poor blast results in many situations. These poor blast results have often then led to a reduction in the use of low density explosives at the mine. This reduction does not acknowledge the advantages that can be gained from this product in the area of reduced cost of mining. This paper looks at low density explosives and discusses how and why these products work. Included in the paper are some practical ideas and examples of how low density explosives can be effectively used at the mine site.

Jan 1, 2007

By H. Aaltonen, T. G. Robinson, M. Morimitsu

"The energy required to plate pure zinc can be the most significant operating cost for an operator in the production of electrolytic zinc. This paper reports on developments on low energy Outotec coated titanium anode process technology with fully amorphous coatings, MSA®, and its application to brownfield zinc electrowinning operations around the world. This technology aims to reduce the operating cost and increase productivity for zinc producers.INTRODUCTIONZinc electrowinning is an energy-intensive process using more than 3,000 kWh/t of electric energy [1-4], and the reduction of the energy consumption is one of the key issues. The high energy consumption is due to a high cell voltage during electrolysis, which is mainly caused by a high overpotential of oxygen evolution reaction on lead alloy anodes which have been widely used in commercial zinc electrowinning processes. The overpotential of oxygen evolution is 0.6 V or more and which is approximately 4 times higher on average than that of the cathodic reaction (zinc deposition) [3,4]. Therefore, the reduction of oxygen overpotential is significant to reduce the electric energy consumption, and this will become more significant with increasing demand in metal production and rising energy costs.Oxide coated titanium anodes have been widely investigated for the oxygen evolution anodes in order to replace the lead alloy anodes [5-9], because it is known that the oxygen overpotential strongly depends on the material and structure of the anode. The most typical example of such anodes is an IrO2-Ta2O5 coated titanium anode, which is usually prepared at thermal decomposition of a precursor solution containing metal salts at 450 oC or more and obtained mixed oxide coating consists of crystalline IrO2 and amorphous Ta2O5. On the other hand, one of the authors of this paper, Professor Morimitsu, Doshisha University in Japan, has developed a novel oxide coated titanium anode, MSA® [10-25]. The most specialized point of MSA® is that the catalytic coatings are prepared at low thermal decomposition temperature and amorphous IrO2 or RuO2 is contained as the components in the coatings. Such amorphous coatings have high catalytic activity for oxygen evolution compared to lead alloy or crystalline coatings. Outotec acquired the international specialized MSA® patent licensing rights from Doshisha University and has produced and commercialized the amorphous oxide coated titanium anodes. These anodes have already been utilized mainly in copper electrowinning plants worldwide and have demonstrated a significant voltage reduction, a cost-efficiency, and a long lifetime. This novel technology is also effective to zinc electrowinning process, thus this paper presents the characterization and performance of amorphous IrO2-Ta2O5 coated titanium anodes and amorphous RuO2-Ta2O5 coated titanium anodes for oxygen evolution in zinc electrowinning."

Jan 1, 2016

By K. H. Boss

In modern iron pelletizing plants fuel consumption has been optimized to such an extent that only minor savings can be expected in the future. Inspite of this fact, different process parameters were studied with a mathematical model and firing tests. The influence on fuel consumption and productivity was established. Furthermore, the adoption of simplified firing patterns was investigated, in particular for coal firing. In view of high costs of oil and natural gas, only substitution of these fuels by coal can substantially reduce production costs. In existing plants partial replacement of oil and gas can be achieved by addition of coal to the iron ore feed and by firing the pellets with pulverized coal. Two systems have been developed for the Lurgi- Dravo travelling grate process which enables coal to completely replace oil or gas. This paper describes in the first part the potentials for fuel savings available in the Lurgi-Dravo process. In the second part, different techniques for the use of coal as fuel in iron or pelletizing plants and in particular the recently developed Lurgi Multistage Coal Injection and Combustion Process (LMC) are discussed. Combined with the LMC process, a wide variety of iron ores and coals - also with high ash contents - can be used in the Lurgi-Dravo travelling grate process.

Jan 1, 1983

Whilst the fossil fuel-based power industry moves towards carbon capture and storage (CCS) or so-called 'geosequestration', the minerals industry should adapt to reap the benefits of the new technology. If CCS becomes viable, the door is open to potential key developments in mineral processing. For example, truly continuous steelmaking could at last be realised using natural or manufactured gas combined with generic melt circulation. Iron ore fines would form a thin molten layer moving countercurrent to the gaseous reductant on one side of a melt circulation loop with efficient post-combustion without deleterious effects of slag accumulation on the other. This eliminates oxygen steelmaking because carbon has no access to the circulating molten iron. Steelmaking merely requires addition of the appropriate low level of carbon and in-line impurities removal to meet product specification. Concerning non-ferrous smelting, nothing short of virtually zero gas emission will be acceptable in the future. For dolomite-hosted Zn/Pb sulfide ores, typified by those in the Carpentaria region of Northern Australia, the way forward proposed is sulfur fixation at the mine site employing the highly exothermic reaction of SO2 with dolomite, followed by encapsulation of sulfated dolomite in fused ore slag. This releases enough energy for direct ore smelting to individual metal products. However, without CCS the strategy would be unacceptable because of greenhouse gas emissions. The scheme is advocated for direct ore smelting at McArthur River. As a result, the environmental problems of disposal of flotation tailings are avoided. Also, highly energy intensive ultra-fine grinding is eliminated, as indeed froth flotation itself, with overall very significant energy savings and exceptionally high increases in metals recovery. Zinc and lead recoveries approaching 99 per cent are predicted to be entirely feasible.

Sep 13, 2010

By A. K. Sirveiya

A major concern with blasting at surface mines is generation of ground vibration, air blast, flyrock, dust & fume and their impact on nearby structures and environment. A study was conducted at a coal mine in India which produces 10 million tonne of coal and 27 million cubic meter of overburden per annum. Draglines and shovels with dumpers carry out the removal of overburden. Detonation of 100 tonnes of explosives in a blasting round is a common practice of the mine. These large sized blasts often led to complaints from the nearby inhabitants regarding ground vibrations and their affects on their houses.

Jan 1, 2005

By B Mohanty, M P. Roy, P K. Singh

"The measured response of residential structures is a critical indicator of troublesomeor potentially damaging ground vibrations. A study was conducted to evaluate theresponse of structures situated in the periphery of four open-pit coal mines in India. Although, most of the structures were at far-off distances from the present blasting sites, an attempt was made to document the response of structures to blast vibration for future applications to optimize the blast designs for the safety of the structures. The study involved a total 215 blasts, employing one-, two- and three-hole calibration study, and production blasts. The bench height varied from 7.5 m to 42 m, and boreholes loaded with emulsion and slurry explosives were 250, 260, 270 and 310 mm in diameter. The explosive detonated in a blast were between 300-198400 kg whereas in a delay it was 33-24800 kg. Up to 12 tri-axial vibration sensors were located in overburden along a linear array from 25 m to 6.5 km distance from the blasts. Altogether, 1512 blast vibration signatures were recorded. Production and specially fi red single-charge blasts allowed the determination of natural ground frequency. The fundamental frequency of the structures ranged between 3.13 to 10.6 Hz, the same as those of the ground vibrations. The amplifi cation of vibration in the structures was in the range of 1.6 to 5.6. The study details the interaction between ground vibrations and selected structures, and the means to reduce amplifi cation of vibrations in the structures and persistence of vibrations through improved blast design."

Jan 1, 2008

By G. R. Alther

Finely ground dried bentonites were compacted with a laboratory size Komarek roller compactor. Before compaction the moisture content of the bentonite was adjusted from 8-12% by adding water in a mixer. Predetermined amounts of Nat CO3 activator were dissolved in that water and added to the bentonite. Comparative rheological tests were then run with the compacted, activated bentonite versus unaltered bentonite. Compaction and activation of the bentonites improved their viscosity and water loss properties considerably, more so than extrusion and slurrying. It was concluded that, by using a compactor, bentonite reserves can be extended because low quality material can be improved without adding organic polymers. Introduction Many bentonites mined in Wyoming, South Dakota, and Montana are naturally of drilling mud quality. Those of low sodium content, and those of predominantly potassium, calcium, and magnesium exchangeable cations need altering to meet drilling mud requirements. Most foreign bentonites require sodium activation to meet drilling mud standards set by the American Petroleum Institute (API).

Jan 1, 1984

By Gordon A. Gross

Banded siliceous manganese-iron bearing sediments recognized as distinctive facies of Algoma type iron-formation constitute low grade resources of manganese in many countries. Manganiferous facies associated with oxide and carbonate facies of iron-formation have iron to manganese ratios ranging from 0.2 to 2 and commonly about one. Manganiferous facies up to 30 meters thick occurring separately or with other iron-formation facies are associated with cherts, carbonates, shales, turbidites, tuffs and lavas. Primary cherty manganiferous facies and their gondite metamorphic equivalents represent significant manganese resources and are protores for higher grade deposits derived by secondary enrichment processes.

Jan 1, 1982