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By Luben Xie, Lin Hu, Qiang Wang, Min Gan, Tao Jiang, Wenqi Li, Yi Wang, Xiaohui Fan

"The mineralization behaviors of typical fluxes are studied by investigating the microstructures with optical microscope. The results show that the reactions begin with between iron ore and lime, limestone with small particle to form primary liquid. Then coarse limestone, dolomite and serpentine take part in reaction under the action of primary liquid. Limestone is the easiest to mineralization, next dolomite, and the last is serpentine. The higher basicity and smaller fluxes size favor the mineralization process of dolomite and serpentine.IntroductionThe purposes of adding fluxes into sintering are that:(1) to increase the basicity of sinter, so as to reduce even eliminate addition fluxes into BF(blast furnace) and decrease the coke ratio of BF[1,2]. (2) to decrease the melting point of sintering mixture to ensure sintering can be carried out at a lower temperature and reduce the energy consumption. (3) to improve the qualities of sinter by forming binding phase with iron ore fines [3].Flux is another significant component for sinter besides iron ore, especially for high basicity sinter[4]. The proportion of flux is usually higher than 10% in sinter mixture(excluding return mine).There were many reports about the influence of the flux types on sintering, such as limestone, dolomite, lime and so on[5-7]. It is very important to choose suitable fluxes for iron ore sintering. Although the effect of flux size on sintering also has been researched, the mineralization behaviors of the fluxes in the sintering process has not been illuminated. The paper will study the mineralization behavior of fluxes in sintering."

Jan 1, 2011

By E. H. Chown

Scattered outliers of the Chibougamau Formation and the more continuous Mistassini and Otish Groups lie unconformably on an Archean basement abutting the Grenville Front. All the Aphebian rocks are deformed and offset by faulting related to the Front. The older Chibougamau Formation is exclusively elastic in origin, whereas the two later, time-equivalent groups include carbonatedominated (Mistassini) and elastic (Otish) sequences. Known syngenetic mineralization within these formations is limited to various radioactive showings in the Mistassini and Otish elastics, and the iron formations of the upper Mistassini Group. Three distinct types of epigenetic mineralization occur within the sedimentary rocks; pitchblende fracture fillings in all types of rocks in the Otish Group, widespread Mississippi-Valley type galenasphalerite showings at certain levels in the Mistassini Group, and chalcopyrite-pyrite bearing veins in or near argillaceous horizons of the Mistassini Group and Chibougamau Formation. The Otish elastic basin is part of a large area of the central Ungava peninsula which contains a variety of radioactive showings, the most promising being of the unconformity type, The final control for many individual showings appears to be local physico-chemical changes within faults and fracture zones. The overall structural control is in part supplied by the faulting episode related to the Grenville Front, which in turn limits the mineralization to the depth zone appropriate for open fracturing. The lead-zinc showings exhibit a strong stratigraphic control as well as close ties to secondary porosity developed by f aulting. The ore solutions were probably derived during the low grade metamorphism of the formations. Chalcopyrite- pyrite veins have provi ded the only mine production (Icon Mine) to date. They appear later than the low-grade metamorphic fluid circulation, and deposition is related to favourable structures and stratigraphy. The veins are clearly related to major faults. Thus, whereas stratigraphic settings appropriate to individual types of deposits are important, an overall structural setting may be demonstrated for a wide range of mineralizations. Detailed structural interpretations of individual showings may be the most fruitful pursuit in developing a concrete prospecting model.

Jan 1, 1984

By J. Richard Kyle

The Pb-Zn ore bodies in the Pine Point district are localized in paleo-solution structures that developed as the result of post-middle Givetian subaerial exposure of the carbonate barrier complex. Sulfides are concentrated in transgressive pale-solution structures that acted as natural bypasses between aquifers and loci for mixing of fluids of different character, one of which contained metals and the other reduced sulfur. Complex ore textures indicate rapid early sulfide precipitation followed by slower sulfide growth. Evidence for both sulfide-carbonate equilibrium and disequilibrium conditions suggest fluctuations in ore fluid composition. District and ore body metal distribution patterns may reflect the nature and movement of mineralizing fluids.

Jan 1, 1979

Two outstanding features of the world's young orogenic belts are their very consistently developed suites of volcanic rocks and, it is now recognized, the rather distinctive types of mineralization they contain. Further,it is now known that these volcanic suites exhibit evolutionary patterns, and it is beginning to appear that this evolution in style of igneous activity is accompanied by a parallel evolution in style of mineralization. Specifically,podiform chromite and stratiform pyritic copper ores of Alpine ultramafic/submarine tholeiite association progressively give way to more zincian stratiform ores associated with andesites and dacites, "porphyry copper"deposits developed in quartz dioritic to dacitic plugs, and lead-zinc stratiform ores related to increasingly pyroclastic, rbyodacitic volcanism.This "coupling" is exhibited well in the volcanic arcs - the young orogenic zones-of the SW Pacific which, with tbeir abundance of youthful and commonly unmetamorphosed materials provide an opportunity for investigating, through a petrochemical approach, the possible significance of ores in the elucidation of mechanisms of lava formation. It is suggested as a working hypothesis that in the orogenic (voleanic arc) regime ores are associated with the cale-alkaline rocks because these cale-alkaline rocks are in part generated by exhalative loss, and the ores are among the manifestations of tbat loss.

Jan 1, 1978

Contents.SummaryIntroductionSituation, climate, topographyHistorySize of depositsPrevious investigationsGeological History of AreaMap compilationHistorical summaryNature and Significance of Granitic RocksSynchronous granitesMain subsequent granitesSignificance of types of bathylithsGeological StructureNorth-south anticlineCross-foldingFormation of channelwaysHydrothermal Depth-Zoning at CobarAssociation of Ores with PorphyryOrigin of replacement porphyriesTransgressive porphyriesSummary of ore-porphyry relationshipsSource of the Copper and GoldProspecting Targets, Cobar-NymageeGeneral ApplicationBroken HillThe Bendigo FieldKalgoorlie-Coolgardie, Western AustraliaConclusions

Jan 1, 1950

By M. T. Heath

Numerous mineral deposits of somewhat limited extent and grade are associated with most of the Tertiary granitic intrusions in the Cascade Mountains of Washington. The Silver Star area in southwestern Washington is typical of many of these small, and at the present time, economically marginal mineralized areas. Small but fairly high grade deposits of copper, lead, and zinc sulfides are found within the borders of a small granodiorite stock, and in surrounding Tertiary volcanics. This paper will discuss these deposits and their genetic relationships with the intrusion.

Jan 1, 1967

By P. Berendsen

The tectonic and sedimentary environment of the Central North American Rift System (CNARS) provides all excellent setting for major mineral deposits. Major north-northeast-trending high-angle normal or reverse faults and northwest-trending transcurrent fault systems may exercise control over ore forming processes. Gabbro and basalt are the dominant igneous rock types. Carbonatite and kimberlite occur in Nebraska and Kansas. Concentrations of Cu. Ni, Co, Ti, Au. Ag and PG-minerals are known to occur in this setting. Arkosic sandstone, siltstone, shale, and minor carbonate units occur on top of the rift basalts and in flunking basins where they may reach thicknesses of 10 km (6 miles). The potential, for stratiform or unconformity-related metalliferous deposits must be considered. The rift as a whole remains, however, largely unexplored.

Jan 1, 1990

By P. Berendsen

Structures along the rift were subjected to episodic reactivation. Major north-northeast-trending high-angle normal or reverse faults and northwest-trending trans-current fault systems, may exercise control over ore-forming processes. Gabbro and basalt are the dominant igneous rock types. Carbonatite and kimberlite occur in Nebraska and Kansas. Concentrations of Cu, Ni, Co, Ti, Au, Ag and PG-minerals are known to occur in this setting Arkosic sandstone, siltstone, shale and minor carbonate units occur on top of the rift basalts and in flanking basins where they may reach thicknesses of 10 km. The potential for stratiform or unconformity-related metal liferous deposits must be considered.

Jan 1, 1986

By Johnson R. Cann

Ocean floor sulfide deposits are now known from many parts of the world mid-ocean ridge system and from some seamounts. Clearly they can be expected to occur commonly on the ocean floor. However, only two or three of the known deposits appear to approach the million-ton size, and in none of the deposits has the grade been well-defined. Can knowledge of the processes that happen within the hydrothermal plumbing below deposits help define the conditions under which large, high-grade deposits form? Here I review present knowledge of ocean-floor hydrothermal processes to attempt a first answer to this question. There are three sources of information about these processes. The solutions emerging from active systems must be compatible with patterns of alteration that underlie the volcanogenic sulfide deposits of ophiolite complexes, which are slices of ocean crust thrust onto land. Both of these types of evidence can be linked by computer modelling of the exchange of heat and metals between rocks and flowing water.

Jan 1, 1988

Although the effects of sea level changes on ore concentration processes are to some extent obvious with certain deposits, e.g. beach placer deposits, they have been largely overlooked with others such as Mississippi Valley type lead-zinc deposits. It is contended that sea level variations may have more profound effects on a wide range of deposits than has previously been appreciated. These deposits include not only placer'and residual deposits but also stratiform copper deposits, Mississippi Valley type deposits, stratiform manganese deposits and Minette type iron deposits. Sea levels in paralic basins profoundly affect the influx of 'detrital sediment, and this has to be suppressed to allow for the accumulation of thick rich deposits of coal evaporites, phosphate or metalliferous sediment. Emergence can be associated with oxidized waters, erosion, and,solution of soluble rocks. Submergence can reverse the Eh trend and can lead to preservation of ores. Both realms of surficial sedimentary environments and subsurface diagenetic environments can be affected by changes in water pressure, gas pressure (pC02), Eh, pH, and temperature as sea levels fluctuate. Even relatively small sea level changes may have profound effects. For example, there is some evidence to suggest that when the level dropped below 100 metres about 10,000 years ago, the Red Sea became isolated by the sill at Bab el Mandeb in the south, and evaporated away to leave a series of shallow lakes. The Red Sea is 1 to 2 km deep. It was at times such as this that the well-known copper-zinc mineralization developed in the Red Sea trough. Changes in sea level also affect the stability field of gas hydrates which can yield large volumes of gas leading to mass movements on the sea floor (Warnke, 1986).

Jan 1, 1987

By P. Sanchez-Mejorada

GEOLOGISTS who are acquainted with the mines of northeastern Mexico realize that the most important lead-silver replacement deposits of the province are confined to a single formation. But since the formation is several hundred meters thick, the author has determined the relative position of the lead mantos in the belief that this information will prove useful in the search for new mines. This article describes the stratigraphic location of lead-silver replacement deposits known in several mines situated in a region comprising part of the states of Coahuila and Nuevo Leon. The area studied extends for 200 km* (125 miles) from east to west and 70 km (45 miles) north to south.

Jan 1, 1958

By B. S. Butler

It is suggested that at high temperatures both sulfur and iron combine with oxygen. Iron may precipitate at the high temperatures as the oxides of iron, and sulfur also in combination with oxygen as the low solubility sulfates of barium, strontium, calcium, and potassium (alunite). At lower temperature the precipitation results from change of sulfate sulfur to sulfide sulfur, and the iron precipitates as the sulfide.

Oct 1, 1956

By I Wilkomirsky, F. Parada, R. Parra, E. Balladares

"The neutral roasting of As bearing copper concentrates is confirmed well established and promising option for the treatment of this type of complex concentrate. The AS elimination by volatilization allows subsequent treatment of the calcines produced in a conventional pyrometallurgical process, by blending this product with standard concentrates.Several tests were performed using the fluidized bed pilot plant at the University of Concepción with different types of concentrates. Calcines, fines from two hot cyclones and flue dust from the ESP were collected. These materials were characterized using QEMSCAN® and the results used for the development of a mass and energy balance which took into consideration the specific chemical transformations that occurred in the reactor.A physico-chemical/kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite. The mechanism involves solid-gas reactions between chalcocite, pyrrhotite and gaseous sulfur that without the mineralogical characterization would not have been possible to propose"

Jan 1, 2014

By S. F. Diehl

Drill cores from uranium roll-front deposits, hosted in lower Cretaceous strata, were examined from the proposed Dewey Burdock in-situ uranium recovery site in the northern part of the Edgemont uranium district, South Dakota. Uraninite (UO2), coffinite U(SiO4)0.9(OH)0.4, and doloresite (H8V6O16) occur as pore-occluding cements within the Fall River Formation in the Dewey area. In contrast, within the Lakota Formation in the Burdock area, uranium (with very little vanadium) is absorbed onto woody fragments and amorphous carbonaceous material in pressure-solution seams. Both areas have typical uranium roll-front mineralogy with 0.5 wt. % pyrite in the reduced solid phase and no pyrite in the oxidized solid phase. The groundwater at the ore zone is not oxygenated, so the uranium is relatively insoluble. Uranium in solution in ground waters is <10µg/L at Dewey and <22 µg/L at Burdock. Micromineralogic and geochemical data are being used to understand water/rock interactions, uranium distribution and movement, and as input factors for predictive reactive transport models.

Feb 27, 2013

By S. F. Diehl

Weathered mine waste consists of oxidized primary minerals and chemically unstable secondary phases that can be sources of readily soluble metals and acid rock drainage. Elevated concentrations of metals such as Cd, Cu, Fe, Mn, Ni, Pb, and Zn are observed in deionized water-based leachate solutions derived from complex sedex and Cu-Pb-Zn mine wastes. Leachate (USGS FLT) from the Elizabeth mine, a massive sulfide deposit, has a pH of 3.4 and high concentrations of Al (16700 ug/L), Cu (440 ug/L), and Zn (8620 ug/L). Leachate from the sedex Faro mine has a pH of 3.5 and high concentrations of Al (2040 ug/L), Cu (1930 ug/L), Pb (2080 ug/L), and Zn (52900 ug/L). In contrast, higher-pH leachates produced from tailings of polymetallic vein deposits have order of magnitude lower metal concentrations. These data indicate that highly soluble secondary mineral phases exist at the surface of waste material where the samples were collected. Sulfide minerals from all sites exhibit differential degrees of weathering, from dissolution etched grain rims, to rinds of secondary minerals, to skeletal remnants. These microscale mineral-dissolution textures enhance weathering and metal leachability of waste material. Besides the formation of secondary minerals, sulfide grains from dried tailings samples may be coated by amorphous Fe-Al-Si minerals that also adsorb metals such as Cu, Ni, and Zn.

Jan 1, 2011

By Ming-Feng Ye, Guang-liang Wu

The investigations on chemical composition, mineral composition, embedded figures, texture and microstructure of chrome ores were conducted systematically byvariousanalysismethodssuch aschemical analysis, XRF, SEM, and MLA 650 system. The results showed that there are 92.66% chromite and a small amount of chlorite and forsterite as the main mineral compositions, the content of quartz is very low. Elements as Cr and Fe are almost all present in chromite. The content of Cr O is 41.84% and Cr O /FeO is 2.1. The main ele- 2 3 2 3 ments in the chromite are Cr, Fe, Mg, Al, O; the main elements in the chlorite are Mg,Al,Si,OandasmallamountofFe;themainelementsintheforsteriteareMg, Si and O. On the basis of clarifying the mineralogical characteristics, to produce high-grade alloy, this ore should not be separately put into the submerged arc furnace without pretreating. However, it also seems to be difficult to separate the gangue compositions by the conventional physical upgrading methods, such as magneticseparationandgravityseparation.So,chemicalmineralprocessingshould be taken into account. (cid:1) (cid:1) (cid:1)

Mar 1, 2018

By Xiang-nan Zhu, Hao Zhang, Lin Li, Jun Qiu, Yue-xian Yu, Chun-chen Nie, Xian-jun Lyua

Waste printed circuit boards (WPCBs) are excellent metal resources. Mineralogical characteristics of different components in WPCBs were analysed in this study. Organic-enriched particles, fibreglass-enriched particles, associated particles and metal-enriched particles were obtained by density gradient method. Subsequently, the elemental composition, morphology, dissociation characteristics, functional group composition and phase composition of different components were analysed by X-ray fluorescence spectrometer (XRF), scanning electron microscopy and energy dispersive spectrometer (SEM+EDS), infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Elemental analysis results show that Cu is mainly contained in metal-enriched particles. SEM+EDS analysis results demonstrate that ideal dissociation can be achieved when the WPCBs are broken to -1 mm. Organic matter particles are enriched with carbon and oxygen elements, while fibreglass particles and associated particles mainly contain Al and Si elements, verified by XRD analysis. FT-IR results show that hydrophilic and hydrophobic groups exist widely in all components, caused by widespread organic matter. This study reveals the important properties of different components in WPCBs, which is of great significance for the subsequent separation process. Key words: Waste printed circuit boards, mineralogical analysis, elemental composition, dissociation; phase analysis, functional group composition

Jan 1, 2020

By Phillips D. N, Herbert H. K, Fletcher A. C, Lewis R. K

Quartzite is a common feedstock used for the production of silicon by reduction at high temperatures in a submerged electric arc furnace. Silica fume, formed as a by-product in this process, contains crystalline silica in the respirable fraction. The crystalline silica in the fume represents entrained quartz derived from unreacted quartzite raw material within the furnace. A knowledge of the fragmentation of quartzite feedstock, in response to thermal disaggregation in the furnace, is important in feedstock selection to help minimise (a) the amount of crystalline silica in fume, critical from an occupational health and safety perspective, and (b) impurity levels necessary to achieve the highest possible purity of product silicon. In this study, a series of quartzites has been assessed in terms of the above requirements and correlations drawn between mineralogical and chemical characteristics. Alkaline solubility correlates with grain-size and level of stored strain in the quartz matrix. Grain-size affects the surface area available for attack while stored strain enhances the chemical reactivity of the strained matrix as well as profoundly influencing the disaggregation and microfracturing characteristics of strained grains and, hence, available surface area for chemical reaction.

Jan 1, 1995

By W. Bendaikha, S. Larbi, A. Ramdane

An oolitic iron ore from Gara Djebilet, Algeria was characterized by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrosopy and the phosphorus distribution between various phases studied. Two ore types were identified – a haematite-dominated, oolitic type and a more massive, magnetite-dominated type. The haematite-dominated ore had a higher phosphorus content, up to 0.6% in the iron oxide minerals, than the magnetite-dominated type (0.3% P). Owing to the very fine-grained texture of the gangue minerals, reducing the phosphorus content to levels suitable for steelmaking (below 0.05% P) by conventiobal means would entail an energyintensive process with a high carbon footprint. Preliminary leaching test work using a sulphurous geothermal water as lixiviant, assisted by solar thermal acceleration, gave very promising results, removing 0.13% of the residual P (or 21.7% removal of total P) from the high-phosphorus oolitic ore.

Mar 14, 2024

By Slobodan Radosavljevic

The polymetallic W-Pb-Bi-Ag ore from the ?Nova jama? ore zone of the Rudnik ore field have been investigated. Contact-pneumatolytic (skarn), pneumatolytic-hydrothermal, and hydrothermal mineralization phases are defined in this ore zone. The most significant mineralization phase that gave compact ore bodies is pneumatolytic-hydrothermal phase. A relatively pure Mo-free scheelite is the only tungsten-bearing mineral. Lead minerals are mostly presented by Pb-Bi sulphosalts and much less with galena. The image analysis coupled with Energy Dispersive Spectrometry (EDS) analysis on a Scanning Electron Microscope (SEM) was applied to the characterization of a W-Pb-Bi-Ag ore as an efficient tool for mineral quantification. Results of EDS (Energy Dispersive Spectrometry) analyses gave the empirical formulae: Pb1.91Ag0.05Cu0.08Bi1.93S5 for cosalite, Pb0.98Ag0.03Cu0.05Bi1.99S4 for galenobismutite and galena Pb0.99Ag0.03S.

Jan 1, 2006