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By Junji Shibata

In a present process to treat the tungsten carbide tool waste, the wastes are roasted in air and then an alkali leaching is carried out in an autoclave. An environmentally friendly process is required to recover rare metals (Co and W) from the wastes. The effect of mechano-chemical (MC) treatment on leaching of rare metals was investigated in this study. The solvent extraction and crystallization-stripping methods were applied to separate and recover tungsten and cobalt in the leached solutions. The MC treatment for the rare metal leaching is effective to dissolve rare metals from the wastes due to the change in crystalline structure of WC and oxidation of WC with KMnO4. Cobalt ions are extracted with D2EHPA by a cation exchange reaction. Tungsten in the leachate can be extracted by TOA (tri-octyl amine) as an extractant, because tungsten species exist as a form of anionic species in acidic solution. The rare metals in organic phase are recovered as insoluble salts such as oxalates and ammonium salts in the crystallization-stripping process. Keywords:unheated oxidation, solvent extraction, crystallization-stripping, recycling

Sep 1, 2012

By R. Steven Izatt

Green chemistry principles will be discussed, and examples will be given of the use of Molecular Recognition Technology (MRT) to selectively separate specialty metals such as cobalt, nickel, bismuth, rhenium, molybdenum, indium and germanium from various primary and secondary feed streams. Recovery of these metals has numerous advantages including (i) conservation of valuable resources, (ii) prevention of environmental damage, and (iii) elimination of capital and operating expenses due to re-processing or disposal of metal-bearing streams.

By Xiangjun Zuo

This paper firstly reviewed the state of the art in the recycling of used Printed Wiring Boards (PWB), and then presented part of the authors study on the combustion of PWB powders with and without the addition of catalyst. During the combustion of PWB powders without catalyst addition, there were two obvious exothermic reactions, one at 300-380oC, the other at 450-500oC. With the addition of catalyst during PWB combustion, there were no obvious exothermic reactions, indicating that dehalogenation reactions are not exothermic: The results showed that NaHCO3 and CaCO3 were very efficient to control the emission of Br2 and C6H6, lowering 80% compared to the case without catalyst, Na2CO3 can slightly control the emission of Br2 gas but not for C6H6 gas mission, and NaOH has no any effect of the control of both gases.

Jan 1, 2009

By Melinda Bissinger, Frederic Berube

Environmental considerations are important in the aerospace industry. To that effect, several elements such as engine emission, noise and materials are identified by the industry and the society as requiring significant improvements for future and current products in order to be aligned with current expectations. In this context, the industry is addressing this opportunity by investing significantly in new engineering solutions that will meet greener targets. To this effect, the impact of material choice is significant and will make a difference in the forth coming solutions. Several opportunities to develop more efficient products, quieter aircrafts using materials and manufacturing processes that will be more respectful of environmental considerations exist. The presentation will cover those elements and provide an overview of the upcoming solutions.

Jan 1, 2010

By Guo Chen, Jin Chen, Jinhui Peng

In this study, the influences of the green evaluation variables on the characterization of microwave shaft furnaces were systematically investigated. These variables include: resource consumption, environment impact, production cost, processing time and quality of microwave shaft furnaces. A greenness evaluation index, evaluation system and evaluation model of microwave shaft furnaces were established. The analytic hierarchy process and fuzzy comprehensive evaluation were applied to the evaluation process. Resource consumption and environment impact had a statistically significant effect on the green evaluation of microwave shaft furnaces. The results indicated that green evaluation techniques can be applied effectively and efficiently to the process manufacturing of microwave shaft furnaces.

Jan 1, 2015

By R Lovel, P Fung, J Manuel, M OÆCo

The iron blast furnace is the most widely used and efficient producer of liquid iron. The integrated steel works is however under environmental pressure largely due to emissions from sintering and coking. The combustion of coke breeze during sintering contributes to greenhouse gases (eg carbon dioxide) and is the source of much of the emissions of SOx and NOx. Coke breeze, the fines produced during coking of coal, is also suffering supply issues as coke demand increases while coking capacity is constrained by environmental concerns.CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide can be sequestered into growing biomass prior to combustion. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource. Samples of pine wood flour, sawdust and red gum wood char were characterised and used in small-scale granulation and sintering tests. Red gum char granulated as well as coke and could be used to make acceptable sinter. Large-scale sinter pot test were conducted with char to produce sufficient sinter for ISO quality tests and calculate sintering performance parameters. Results showed that coke could be completely substituted by red gum char during sintering without loss of quality and with actual improvements in sintering performance. Furthermore, gas analyses made during sintering showed that there were significant reductions in SOx and NOx when char was substituted for coke. It is anticipated that the results reported here, although preliminary, will stimulate an increased effort into further research on the use of char in iron ore sintering.

Jan 1, 2004

By David Huber, John Halkyard

Deep Reach Technology, Inc. recently completed a multi-year cooperative research project for the U S Army Research Laboratory for the purposes of investigating recovery of rare earth elements from the seabed. This research led to the discovery of a potentially economical deposit in the Exclusive Economic Zone of the Cook Islands. In order to further develop this resource, Ocean Minerals LLC (OML) was formed in 2016 to explore the development of a deep-sea mining project to recover rare earth elements and scandium from the upper 10m of sediment in promising areas of the Cook Islands Exclusive Economic Zone. OML and the Cook Islands Investment Corporation signed an Agreement in 2016 giving OML exclusive rights to explore a 12000 sq km area and option rights over an additional 48,000 sq km. This poster presents the current status and activities related to this project.

Jan 1, 2017

By Louise Laverdure

Outline ?Background ?Issues and considerations ?Why do we need to innovate ?Green Mining Initiative ?Footprint reduction ?Innovation in waste management ?Ecosystem risk management ?Mine closure and rehabilitation ?The Future

May 1, 2011

Using the philosophy that 'change cannot be introduced through memos-you have to get people emotionallyinvolved', SRK's Environmental Group in South Africa is helping clients communicate their environmental management objectives more effectively through the powerful medium of interactive industrial theatre. Existing and pending environmental legislation, international pressures, and growing awareness of the environment have led South African industry to the point where responsible care, for both the environment and the health and safety of those affected by the activities of an industry, is now a focus of management policies.

Jan 1, 1995

The rising tide of environmentalism has adversely affected many mineral producers, but it has also provided them with a number of opportunities for mineral applications. These markets are as diverse as water treatment, waste disposal, and flue-gas desulphurization. Whilst legislation is forcing up the industry's environmental standards, the advent of environmental management provides an opportunity for producers to display its 'green' credentials. The picture painted of the extractive industry by environmentalists is undeservedly black, because the more efficient a producer is, the more effectively that producer conserves the very resources he exploits. The 1993 IM Forum examined these issues and how they affect the mineral producer, and this publication comprises the papers presented at that meeting.

Jan 1, 1995

Green policies have gained momentum since the 1972 Stockholm, Environment Conference. The environmental movement has influenced political initiatives both in New Zealand and abroad. Governments and international institutions have addressed local, regional and global environmental issues with varying degrees of success. New Zealand so far has not supported the United Nations' call for sustainable development in a consistent manner. New institutions and new rules for resource management mean there are opportunities to look after the land in different and more ecologically sensitive ways than has happened in the past. The increasing influence of regional councils in resource management planning will have important implications for mining and mineral exploration. These trends are discussed and possible future events outlined. Green policies have gained momentum since the 1972 Stockholm Environment Conference. Environmental issues are now global and the twentieth year Environment Conference planned for 1992 is likely to see new commitments made by world leaders and their national governments. Green politics may be the popular trend of the moment but green principles of managing the earth's resources are here to stay. There are many businessmen, many technologists, and many politicians who have hoped that the environmental movement was a passing fad and would fade into oblivion. The evidence is otherwise. Far from passing into oblivion, the environmental movement is growing rapidly. Each year brings further scientific data that indicates mankind is on a self destructive course unless we learn how to better manage the earth's natural resources. This information has contributed to a growing population of environmentally aware people. In the last 20 years there have been messages of concern about a population increase out of control and the energy crisis which focused on dwindling oil stocks. The issues are all interrelated including the present global issues of climate change and thinning ozone layers. The attention being given the messages by the United Nations and member states requires similar attention by industry. The problems have been identified; the challenge is to determine what should be done about them. Every challenge brings new opportunities and the future need not be doom and destruction. Mining is seen by some of the environmental action groups as unnecessarily destructive of the environment, but I do not see mining ceasing in the next few decades. Rather, the rules will be clearer with some areas excluded from mining, the methods of extraction will improve, the technology of processing will become more sophisticated and restoration of mining sites will be not only normal practice worldwide, but the end result may leave no hazards, may enhance the landscape and may result in acceptance of the industry by the general public. For that to happen, commitment and cooperation is required between the industry, the government, and society. As an Officer of Parliament my role is to review the system of agencies and processes established by Government for allocating, using and preserving natural resources and to report whether the system is maintaining and improving the quality of the environment. I also have a responsibility to see that the environmental planning and management carried out by public authorities is effective. That Ineans I have a keen interest in how the mining industry is administered by New Zealand public authorities, including Ministers of the Crown and district and regional councils. Today I intend to review the approach to resource management being taken by international agencies and by the New Zealand Government, and to comment on how environmental impact assessment for mineral exploration, as well as mining, may be administered in the future.

Jan 1, 1990

Green policies have gained momentum since the 1972 Stockholm Environment Conference. The environmental movement has influenced political initiatives both in New Zealand and abroad. Governments and international institutions have addressed local, regional and global environmental issues with varying degrees of success. New Zealand so far has not supported the United Nations' call for sustainable development in a,consistent manner.New institutions and new rules for resource management mean there are opportunities to look after the land in different and more ecologically sensitive ways than has happened in the past.The increasing influence of regional councils in resource management planning will have important implications for mining and mineral exploration. These trends are discussed and possible future events outlined.

Jan 1, 1990

By Thomas Schuman, Jaan Kers, Lucas N. W. Damoah, Xiangjun Zuo, Lifeng Zhang

"Rapid technological innovation has propelled the use of electronic equipment leading to the generation of more and more waste electrical and electronic equipments (WEEE). Printed wiring board (PWB) is a component made of one or more layers of insulating material with electrical conductors. To investigate an environmentally friendly process to recycle PWBs, PWB samples with and without additives were pyrolyzed. Liquid, gas and solid products were achieved with different conversion fraction. Analysis of the exhaust gases from the experiments using GC-MS and MS showed that without CaCO3 additives poisonous gases such as C6H6 and HBr were produced which were adequately controlled if CaCO3 was added.IntroductionPyrolysis is one of the best methods for treating complex mixtures of waste polymers and to recover the material and energy content. The process consists of thermal decomposition at moderate temperatures in total absence or small amount of oxygen in which the structures of polymers break down into smaller intermediate products "". The decomposition temperature of a substance is the temperature at which the substance breaks up into smaller substances or into its constituent atoms 2). Thermal treatment of PWBs were reported using DC Arc Plasma furnace 3), and fixed bed reactor 4). One drawback in dealing with thermal treatment of PWB scraps is the likely production of super-toxic halogenated dibenzodioxins and dibenzofurans from the bromine containing structures. Pyrolysis of organic materials contained in waste PWBs leads to the formation of gases, oils, and chars which can be used as chemical feedstock or fuels ""'. Dehalogenation of the pyrolysis product of electronic scraps is essential to make it commercially acceptable. It would be obviously the most advantageous solution as pyrolysis and dehalogenation are carried out simultaneously. Reported pyrolysis investigations are at experimental stage and have been carried out in vacuum, molten salt, fluidized bed, rotary kiln, entrained, stationary, and moving bed reactors 7). Comparing to the incineration and combustion of PWBs, the pyrolysis process has several characteristics: 8'"">) 1). Converting the organic solid substance into fuel gas, fuel oil and carbon-black as storage energy; 2) Emitting toxic substances such as sulfur, bromine and heavy metals in wastes; and 3) Keeping metals from being oxidized. Although many researches into the pyrolysis of PWB wastes have been reported, most of the works have been carried out using analytical pyrolysis techniques or very small batch reactors ""~'5). Also, most of the works for the pyrolysis of PWBs haves concentrated on the composition of the organic products, particularly the brominated organics. The current study is to investigate the pyrolysis of PWB powders in a small TG-DTA scale and a 50-gram tube furnace scale."

Jan 1, 2011

By C. E. M. Meskers

Electronic and Electric Equipment contains a range of components made of a wide variation of metals, plastics and other substances. Up to 60 elements can be found in complex electronic equipment: base metals, precious metals and special metals in circuit boards and batteries. Because of its amount WEEE represents a considerable metal resource with a higher special and precious metal content than found in ores. The Umicore integrated smelter and refinery recovers and supplies back to the market 17 different metals from EEE. Pre-treated materials enter state of the art, material and energy efficient metallurgical processes for environmentally sound recovery of metals and treatment of off gasses and hazardous substances. The organics in the feed function as reducing agent and alternative energy source during smelting for precious metal recovery. Lithium-ion batteries are treated using a dedicated process. As a result the environmental footprint of metals produced from EEE is much smaller than primary production.

Jan 1, 2009

By Jewel Gomes

Green rust is an important intermediate in oxidative transformation of Fe(II) phase. This unstable compound contains a mixture of ferrous and ferric hydroxides that belong to a family of minerals known as layered double hydroxides (LDH). Its general formula is [FeII(6-x) FeIIIx (OH)12]x+[Ax/n-*yH2O] x-, where A is an n-valent anion mainly Cl-, CO3-2 and SO4-2, and in which either the bivalent or the trivalent iron can be replaced for other trivalent or bivalent metal ions. It was first identified as corrosion product, later in soils as a product of interactions between microbes and metals in soils. Due to its high reactivity, it is used in the reduction of organic and inorganic compounds, As removal, and the treatment of acid mine drainage. In this paper, we described the method of electrochemical generation of green rust, its characterization by XRD, SEM and FT-IR, and its implications to electrocoagulation.

Jan 1, 2009

By Boxun Lu, Juan Wei, Kun Chen, Wanlin Wang, Lejun Zhou

"Slag system is an indispensable part during the continuous casting process, and playing various important roles like absorbing inclusions, modifying heat transfer rate, preventing oxidation of molten steel, etc. to ensure the smooth process and excellent slab quality. However most slags contains more than 8% fluorides which tend to introduce a series of environmental and health problems. This study involves the research of the removal of fluorine through the chemical composition optimization. Through the studies of CCT, DHTT, XRD and SEM, it has been successfully founded that the crystalline phase of Ca11Si4B2O22 discovered in this study shows very similar crystallization property as Cuspidine (Ca4Si2O7F2), which is the most important crystalline phase in the current fluorine bearing slags. Moreover, the optimized free/low fluorine slag shows the opportunity to replace conventional high-fluorine mold slag for casting medium carbon steels that is regarded as the bottleneck of green slag development for continuous casting.IntroductionMold flux has been widely used in continuous casting to control heat transfer, lubricate the strand, absorb inclusions, provide insulation and prevent oxidation of the molten steel[1-3]. It usually contains fluorides, like CaF2, NaF etc., which are used to control the viscosity and solidification temperature of mold fluxes [4-5]. However, the presence of fluoride leads to corrosion of equipment, serious environmental pollution (toxic volatiles and water pollution), and high processing cost of cooling water[6-7]. Therefore, the study of low or free fluorine mold flux is of interest and attracts worldwide attention.S. Y. Choi et al. [4] used B2O3 as a substitute for cuspidine in steel B2PB2) however, B2O3 content was extremely high (up to 30 w%). Other studies have investigated F-free mold flux by adding or optimizing components as MgO, Li2O, B2O3 et al[8-11]. However, most of these focused on the melting and viscosity issues or for low or ultra-low carbon steels, where crystallization tendency is not significantly strong. Very few studies regarding to the development of low/free Fluorine mold flux for casting medium carbon (MC) steels have been conducted, due to the difficulty of the crystallization and heat transfer control without the formation of cuspidine."

Jan 1, 2014

By D. P. Tripathy

A supply chain encompasses all the activities associated with the flow and transformation of goods from the raw materials stage(extraction), through to the end user. Supply chain management (SCM) is the integration of these activities through improved supply chain relationship, to achieve a sustainable competitive advantage and it rests on its ability to provide the right goods and services when and where needed. The supply chain is the vital component of any company?s value chain which links the operating processes to its supplier and customer. The globalization of business promises to offer new and unique challenges for the supply chain competencies of most firms. Challenges will also increase in the environmental aspects of supply chain often referred to as ?Green Issues?. The supply chain of mining industry comprises of the flow of material and information from the mine site, to processing and loading for transport, to the customer. However, due to recent changing environmental requirements affecting mining and mineral processing operations, increasing attention is given to developing environmental management (EM) strategies for the mineral supply chain. This paper focuses on: ? Environmental factors leading to the development of an extended environmental supply chain, ? Additional challenges presented by the extension, ? Performance measures appropriate for the extended supply chain, ? Developing a general procedure towards achieving and maintaining the green supply chain.

May 1, 2006

The Iscor Board has given its Mining Division the authority to proceed with detail engineering and design for a Heavy Minerals Project which comprises a mine in Northern Province near Gravelote, a mine in KwaZulu/Natal near Richards Bay and a central processing complex with a beneficiation plant and smelter which will be located near Richards Bay and Empangeni.

Jan 1, 1996

Mintek now offers a service for the accurate measurement and analysis of air pollution in South Africa. 'The deteriorating air quality and general degradation of the environments in industrialized and urban regions of South Africa have been of concern for more than a decade', says Mintek's Dr Johann Engelbrecht. 'The accompanying effect on health, visibility, and damage to property and the environment have prompted the public, authorities, and industry to take appropriate action. A recent study conducted by the Medical Research Council on schoolchildren in the Vaal Triangle, clearly demonstrated the relationship between the deficient quality of the air in that area, and the resultant respiratory diseases.

Jan 1, 1996

By Jean-Claude Paye

In February 1996 the OECD's Environment Policy Committee will commemorate its 25th anniversary with a fifth meeting at Ministerial level. Environment ministers will be taking stock of the progress made by OECD countries in protecting and managing the environment in that quarter-century, and sharing views on likely challenges and co-operative responses. Ministers can point to many important accomplishments. Scientific understanding and technological tools for establishing and monitoring risks to human health and the environment have improved dramatically since the early 1970s. All OECD countries now have in place comprehensive environmental legislation, supported by specialized institutions for policy design, implementation and enforcement. The results of these efforts are increasingly evident in the form of cleaner air and water, and improved protection of natural areas, notwithstanding the many complex problems that remain.

Jan 1, 1996