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By C. M. Young

BITUMINOUS coal piled in heaps or bins frequently undergoes a process of spontaneous heating as the result of the absorption of oxygen. It seems probable that the first absorption of oxygen by coal which has not previously been exposed to the air may occur as a condensation or a combination of oxygen in some form which does not result in the production of carbon dioxide, but slow combustion soon begins. The absorption of oxygen is accompanied by an increase of temperature, and this by in increased rapidity of absorption; hence the dangerous condition proceeds from bad to worse, until the kindling point is reached, unless the process is interrupted. A dangerous rise of temperature can be prevented by excluding oxygen, by increasing the bulk of coal in proportion to its surface exposed, or by circulating enough air to dissipate the heat produced. The storage of coal, in practice, varies from almost complete exclusion of oxygen, by storing under water, to such freedom of access as exists when the coal is stored in open piles. Oxygen available for absorption by coal is supplied by the air in the interstices between lumps and by additional air which may enter the pile through circulation. The size, of the coal largely affects both of these supplies; for if the fragments a re small the spaces between them constitute a small percentage of the total volume, and little oxygen will be available unless the circulation of air brings in a fresh supply, while with large fragments the percentage is relatively large; circulation also is much easier through a pile of coarse lumps. In the case f lump coal, although a large amount of air may be present, the exposed surface is comparatively small and there is little opportunity for the absorption of oxygen to so rapid as to cause dangerous heating. Attempts have been made to prevent heating by allowing a sufficient circulation of air to carry off the heat generated; obviously this method cannot be applied to fine sizes nor mixed sizes.

Jan 2, 1918

By R. A. Sullivan

I T IS one of the unwritten policies at Preston Mines that we examine closely any method or tool that will help us in our constant battle against rising costs. It is our personal conviction that most work methods can be improved. Therefore even though the job went well yesterday, it does not necessarily follow that it should be done by the same method today. With the arrival of the natural gas pipe line in the Porcupine area it was obvious that we would have to take a good look at the possibilities of using this source of fuel for plant heating. • Steam presently generated at Preston is for heating purposes only, no process steam being required. Prior to the fall of 1960, the heating plant consisted of two low pressure, coal-fired, fire-tube boilers, operating at an approximate pressure of 14 pounds per square inch. These boilers were underfed by stokers and could be operated either singly or together. ~o. 1 unit was a horizontal return tubular boiler, registered at 100 h.p. No. 2 unit was a fire-box boiler, registered at 75 h.p.

Jan 1, 1962

By C. Y. Wen, H. O. HOPMAN

l. INTRODUCTION. IN casting a thermal balance of the heat generated and absorbed in a blast-furnace treating lead-, copper- and similar non-ferrous ores, assumptions have always to be made for the values of the heat of formation of slag. ? Considering that the larger part of the charge introduced into the furnace comes out in the form of slag, the significance becomes apparent of a lack of heat-values for the singulo-silicate, which is the type of slags commonly made. The aim of the present investigation is to supply these heat-values as far as possible with the apparatus and the time available. The heats of formation of the ferrous and manganous bi-silicates have been determined by Le Chatelier; 1 those of some silicates other than iron and manganese by Tschernobaeff:2 finally Richards 3 gives a figure for a copper blast-furnace slag of known composition. The existing data and those resulting from the present investigation are assembled in Table VI. II. MATERIALS USED. The materials used in the experiments were silica, ferrous oxide, and calcium carbonate. Silica.-The silica sold in the market as chemically pure usually contains small amounts of magnesia, lime, and alumina, and is therefore not suited for the work. The pure material was obtained from clear quartz crystals from Arkansas, broken in a diamond mortar and ground in an agate mortar to pass 1 Comptes rendus, vol. cxx., p. 623 (1895); vol. cxxii., p. SO (1896). 2 Revue de Métallurgie, vol. ii., p. 729 (1905); Electrochemical and Metallurgical Industry, vol. iv., No. 2, p. 72 (Feb., 1906). 3 Electrochemical and Metallurgical Industry, vol. v., No. 7, p. 266 furls?, 1907;) ; Metallurgical Calculations, vol. iii.,.pp. 474, 475 (1908).

Jul 1, 1910

By Kampe. S. L., Baker. Andrew H., Tony Zahrah

"Experimental heats of reaction for the formation of several Al3Ti + TiB2 intermetallic composite formulations have been determined utilizing bomb calorimetry. To overcome the kinetic constraints and achieve ignition in these formulations, a boron (B)/potassium nitrate (KNO3) initiation aid was incorporated within the blended reactant compact. The heat contribution from the initiation aid was regressed to provide estimates of the heat of reaction of the nominal formulations. Powder x-ray diffraction was utilized to identify the products of the reaction and discern any differences between the predicted equilibrium products of the formulation and the actual products.IntroductionReaction synthesis is a technique for the creation of ceramics, intermetallics, and in-situ composite materials [1]. Reaction synthesis is defined by its self, propagating mechanism, where the energy liberated from a localized reaction within a green powder compact is enough to carry the bulk reaction to completion. Achieving a self, propagating state can be achieved in variations of two primary methods of initiation: uniform volumetric heating and directional propagation [2].Uniform volumetric heating involves subjecting a green compact of the unreacted formulation to uniform heating in a furnace to encourage diffusion to initiate the reaction (Figure 1a) throughout the bulk material. Directional propagation utilizes a point heat source at one section of a green compact of unreacted formulation (Figure 1b). The localized exothermic reaction at one point in the compact then initiates the reaction in the section of the compact adjacent to it and fully propagates throughout the entire compact until completion. Initiation of the localized reaction is generally associated with the melting of the constituent with the lowest melting point, with instantaneous initiation of the reaction usually occurring close to that melting point [1]. This melting point can be high in some systems of interest, such as the titanium (Ti) and boron (B) system in equation 1:"

Jan 1, 2011

By Ellsworth Spencer

Noise induced hearing loss continues to afflict workers in many occupational settings despite longstanding recognition of the problems and well-known methods of prevention and regulations. Sound levels associated with heavy construction equipment range from 80 to 120 dB(A) and power tools commonly used in construction produce sound levels up to 115 dB(A).(1) The focus of this research was to determine the noise exposures of heavy construction equipment operators while documenting the workers’ tasks, (i.e. hauling, moving, and/or pushing construction material). Time-motion studies were performed at the construction sites and were used to correlate the noise dosage with the work performed by equipment operators. The cumulative dose for the operator was then plotted with references to work tasks, to identify the tasks that caused the greatest noise exposure. Three construction sites were studied for this research located in the western Pennsylvania and eastern Ohio areas. The types of construction equipment studied included asphalt pavers, backhoes, bulldozers, compaction equipment, excavators, haul trucks, telehandlers, and wheeled loaders. The results showed that bulldozer operators consistently had the highest noise exposures, ranging from a NIOSH REL (Recommended Exposure Limit) dose of 844% to 25,836% and an OSHA PEL (Permissible Exposure Limit) dose of 139% to 1,397%.

In early June, Rio Tinto?s chief executive officer Tom Albanese said that he expected demand for iron ore, aluminum and copper to double in the next 15 years. Driven by global industrialization and urbanization, Albanese said during his company?s annual general meeting that to meet the demand in 2030, the additional supply required will be equivalent to replicating the iron ore output of Australia?s Pilbara region every five years, adding another aluminum production complex the size of Canada?s Saguenay every nine months and developing another copper mine the size of Escondida, in Chile, each year.

Jan 1, 2010

By Gerald T. Homce, Michael R. Yenchek, H. Kenneth Sacks, James C. Cawley

Accidents occur when least expected, from sources that we rarely anticipate and with outcomes that can vary greatly. Anyone who has ever been involved in an automobile accident knows, the transition from driving comfortably and safely down a highway to being involved in a potentially life-threatening situation can occur in a heartbeat. Accidents on the job are no different. The mining industry has a relatively small number of electrical injuries, compared to industries such as construction or agriculture, due to the small total employment in mining. Mining does, however, have one of the highest occupational electrocution rates of any U.S. industry, at 2.8 for every 100,000 workers per year. This is approximately four times the average for all industries. Data from the Mine Safety and Health Administration (MSHA) shows that 75 electrical fatalities occurred in the mining industry between 1990 and 1999. Of these, at least 17% involved high-reaching mobile equipment that contacted overhead power lines.

By J. Hoover

"IntroductionThis chapter will discuss the operational and maintenance aspects of a heavy media cyclone circuits as applied to coal processing and using magnetite as the media. It deals with heavy media bath separators in terms of types of media, equipment, circuits, media recovery, maintenance, and product handling. It will detail heavy media cyclone operation and supplement the previously described topics.The heavy media cyclone was first developed in the Netherlands by the Dutch State Mines in 1945. A cyclone plant was not built in North America until 1961. Traditionally, heavy media cyclones have been used to treat size fractions between 1lz in. (12 .6 mm) and 35 mesh (0.5 mm). High maintenance related to heavy media bath separators has recently prompted some plants to crush all raw coal to minus 2 in. for treatment in heavy media cyclones.The heavy media bath separators utilize only the force of gravity to make the separation between heavy and light particles. This requires lengthy retention time which can lower capacity and also is inefficient for finer particles. A heavy media cyclone utilizes centrifugal forces which are 20 to 200 times greater than the force of gravity. This means the separation between coal and the impurities occurs very quickly, therefore a low retention time is required allowing cyclones to have high tonnage capacities. Also these greater forces allow better separation for the finer particle sizes.Heavy media cyclones are now widely used to produce both metallurgical and thermal coal. Work is in progress to reduce magnetite consumption, extend wear life, increase tonnage capacity, improve separation efficiency and automatically control these cyclone circuits."

Jan 1, 1989

By T. P. Meloy

Current coal cleaning technology uses heavy media (HM) for the recovery of coal in particles larger than 1/16 of an inch. Through the use of float sink measurements of the feed and products to commercial HM unit operations, a selection function, sometimes called Tromp curve in the coal industry, can be computed. Since the selection function is a plot f the probability of a particle appearing in the float versus the particle density, the slope of the curve will be sharper at the point where the particle has a 50% chance f appearing in the float. Thus, the separation will be better. Fine-tuning a unit operation or a circuit of unit operations requires that the selection function be accurately known. By current practice, it is difficult to obtain an accurate measure of the slope because, when the selection function is plotted versus density, the data forms an S-shaped curve which lacks data points near the 505 point of the curve. This lack of sensitivity in measuring the slope means that small recovery improvements cannot be detected; thus, only large improvements are measurable. Since most engineering improvements are small when individually considered, but large when aggregated ever many small improvements, this lack of measurement sensitivity rules out the slew march toward improved efficiency. This paper presents a method of analyzing heavy media selection functions resulting in a far more effective measure of the selective function slope. Furthermore, this improved method is applied to a number of industrial coal cleaning plants for both heavy media and heavy media cyclones. Using the work of Hudy (1968), and Deurbrouck and Hudy (1972), selection functions for individual unit operations in each plant are calculated as a function f particle size as well as density.

Jan 1, 1982

By Roshan B. Bhappu, Thomas J. Lien

The DYNA WHIRLPOOL Processor (DWP) is a cylindrical dynamic heavy media vessel. It is used to beneficiate fine ore sizes from one and one-half inches in diameter down to 65-mesh. Process units available treat up to 80 tons per hour. Units can be manifolded for higher capacity plants. Finely ground magnetite and ferrosilicon are used for media. , Installed capital costs are from $4,000 to $6,000 per ton hour of feed. Operating costs are from $0.30 to $0.50 per ton of feed. The DWP is used to beneficiate metallic and non-metallic ores and coal. The OCC Vessel is a static heavy media separator used to beneficiate coarse ore up to six inches in diameter and auto scrap. Process units available treat up to 300 tons per hour.

Jan 1, 1978

By Vas P. Srinivasa

This paper examines the role of the heavy media separator in the mineral industry. Procedures used in selecting the separating vessel, developing the process flowsheet, and designing a heavy media circuit are discussed. For comparative purposes, the capital investment and operating costs of different types of operation are included.

Jan 1, 1981

By Mark Freberg

"IntroductionThis chapter is intended to provide information on the operation and maintenance of several pieces of equipment used in heavy media separation. Most heavy media separation circuits, particularly those involving bath separators can be considered as high maintenance areas. Because of this the efficient operation and maintenance of these circuits is very important if the cost per ton of material treated is to be kept to an acceptable level.Heavy media separation (HMS), is a process used to separate particles of different specific gravities. Under laboratory conditions the ideal way to separate two types of particles which have different specific gravities is to suspend them in a heavy liquid which has a specific gravity between those of the two types of particles. Those particles with the lower specific gravities will float on top of the liquid while the higher specific gravity material will sink to the bottom. Given enough time and a sufficient volume of heavy liquid this process will be essentially insensitive to the sizes of the particles involved.Heavy media separation circuits make use of the same principles described above. The material to be treated is introduced into a mixture of finely ground solids, called media, and water which takes the place of the heavy liquid; the mixture of solids and water is known as medium. The separating force can be either gravity or centrifugal force. The type of solids used as media varies but it is usually a high specific gravity material such as magnetite, galena or ferrosilicon.Heavy media separation is used extensively in the cleaning of coal and to a lesser extent as a preconcentration step in base metal and iron ore operations."

Jan 1, 1989

By Colin G. Wilson

This paper considers the heavy liquid laboratory tests used to determine the amenability of a potential ore to the heavy media process. The results of the laboratory testing are correlated to actual plant performance and establish design parameters for the heavy media process. These parameters are used in the development of the metallurgical flow sheet and in the sizing of equipment in the metallurgical plant design.

Jan 1, 1978

By E. L. Michaels

Laboratory and pilot scale tests have been made to deter- mine the utility of heavy media separation, particularly a cone type separator, as a means of recovering aluminum from shredded municipal solid waste. The effect of the method of shredding on the behavior of aluminum in a heavy media system was deter- mined. Two-stage pilot scale heavy media separations were made with size fractions of shredded refuse. Recoveries of aluminum, as well as other components of the refuse, were measured and medium losses were determined. The experimental results indicate that with certain reservations a heavy media cone system can be utilized for aluminum separation and recovery from shredded and air classified municipal solid waste. Observations made using two-stage heavy media separation in a drum unit are included. Qualitatively, the results from the two types of separators are similar.

Jan 1, 1974

By W. L. Freyberger, H. Alter, K. L. Woodruff, E. L. Michaels

Laboratory and pilot scale tests have been made to determine the utility of heavymedia separation, particularly a cone-type separator, as a means of recovering aluminum and other values from shredded municipal solid waste. The effect of the method of shredding on the behavior of aluminum in a heavy-media system was determined. Two-stage pilot-scale heavy-media separations were made with size fractions of shredded refuse. Recoveries of aluminum, as well as other components of the refuse, were measured and medium losses determined. The experimental results indicate that with certain reservations a heavy-media cone system can be utilized for aluminum separation and recovery from shredded and air-classified municipal solid waste. Observations made using two-stage heavy-media separation in a drum unit are included. Qualitatively, the results from the two types of separators are similar.

Jan 1, 1976

By Frank F. Aplan

Introduction Heavy media separation (HMS), also called dense media or float¬sink separation, is one of the newer forms of gravity concentration. Though the concept can be traced to the last century, the process has enjoyed its major growth since 1940. Heavy liquid separation is a mutation. The heavy media process is used extensively to clean coal and for the concentration of a wide variety of ores such as those of iron, lead-zinc, chrome, manganese, tin, tungsten, fluorspar, magnesite, sylvite, garnet, diamonds, gravel, etc. It may be used where ever a significant density difference occurs between two minerals, and commercial separations are typically made in the range of 1.3 to 3.8 sp gr. The particle size treated ranges downward from 6-8 in. top size. Particles greater than about 1/16-in. (10 mesh) may be treated in a "static" bath, though for reasons of separation efficiency, + 1/2 -in- feed is usually preferred. For particles less than this size, separation in a heavy media cyclone is generally used. The flowsheet of a typical heavy media process, in this case one using a ferrous medium, is shown in Fig. I. In essence, the process consists of: (1) preparation of the feed usually by wet screening to remove undesired fines, (2) heavy medium separation, and (3) removal and recovery of the medium from the separated products. Many muta¬tions of the basic scheme are possible and numerous options are possi¬ble. HMS offers the following potential advantages:12 1) Ability to make sharp separations. 2) Ability to change the specific gravity of separation quickly to meet changing conditions. 3) Ability to remove products continuously. 4) Ability to treat a broad size range of products. 5) Ease of start-up and shutdown without loss of separating efficiency. 6) Relatively low medium cost and low media losses. 7) Low operating and maintenance costs. 8) High capacity with the use of relatively little floor space. 9) Relatively low capital investment per ton of capacity. The process may be used to produce a finished concentrate, two finished concentrates, or a concentrate and a middling of differing quality, or a preconcentrate by rejection of unwanted gangue. It is an ideal method for the reprocessing of coarse waste dumps. The greatest use for the process lies in coal cleaning and in the preconcentration of ores. The relatively inexpensive heavy media process may be used advantageously to reject large quantities of coarsely crushed gangue. When used in this way, the process will allow: (1) the use of lower cost but less selective mining methods with the "overbreak" material being removed at the front end of the concentrator or preparation plant; (2) a substantial reduction in the quantity of ore that must be finely ground for subsequent mineral liberation and separa¬tion. Since comminution is often the single most expensive step in beneficiation, it is desirable to eliminate as many essentially barren pieces of rock as possible before the grinding step, (3) a decrease in overall plant capital cost per ton of concentrate since the size of the plant from the dense medium step onward will be smaller. Several general references are available,12-18 though much of the technical data on the process is widely scattered in the general litera¬ture. Heavy Liquid Separation Organic Liquids Given sufficient settling time, it is possible to make a perfect separa¬tion between two particles of differing density by placing them in a liquid whose density is intermediate between the two. This means of achieving a perfect separation has proven to be elusive because of problems in feed preparation, particle settling rates, operational considerations, and economic constraints. There are a wide variety of heavy liquids that could be used, most of them halogenated hydrocarbons, and a few typical examples are given in Table 4. These liquids are most commonly used in ore dressing for the laboratory fractionation of ore particles on the basis of specific gravity. Laboratory Separations. Using liquids typified by those given in Table 4, separations are made to develop either the standard washability curves used to estimate the response of a given sample to gravity concentration or to prepare a partition curve to evaluate the effective¬ness of a given gravity separation process or piece of equipment. A typical washability curve is given in Fig. 2.19 Such curves are generated for raw coal, e.g., by treating either the whole or various size fractions of the sample in a series of heavy liquids and analyzing the various specific gravity fractions so produced. The procedure is relatively simple for coal samples because of the ready availability of a wide variety of relatively low cost heavy liquids in the density range 1.2¬-2.0. For ores the problem is much more complicated, because only a few high density liquids, all of rather high cost, are available. Parti¬tion curves are generated in the same manner by treating the separated products in the same liquids. Greater details on the procedures to be used in heavy liquid separa¬tions are to be found in the literature (for coal, Refs. 13, 14 and 19 and for ore, Refs. 20 and 21). For testing coal, calcium and zinc chloride solutions have been used extensively in the past, though today halogenated hydrocarbons (available under the trade name Certigrav) are the preferred media. The liquids shown in Table 4 may

Jan 1, 1985

By Edward Skolnik

The concept of using fluid dense media to separate heavy ore constituents from the lighter gangue dates back to 1858, when it was patented by Sir Henry Bessemer. Its use in coal did not begin until after 1917, however, when Chance invented a process (which bears his name) in which lighter coal floats in a suspension of fine sand in water while heavier refuse sinks. Conklin used fine magnetite in suspension as a medium for floating anthracite in 1922, DuPont designed a plant employing organic liquids in 1936, and Belknap used a solution of calcium chloride (which Bessemer had suggested, among other media) in 1937. Separation of magnetic media by magnetic separators from the suspensions in which they were carried was introduced in a Butler Brothers ore concentrator pilot plant in 1937. The media first used were crushed steel and various grades of ferrosilicon. Since 1940, when American Cyanamid used magnetic separators to recover and clean magnetite in a coal washing circuit, virtually all heavy medium circuits have been of that type. As long as static baths are employed, as they are in the processes above, coal smaller than 9.5 mm or 6.4 mm cannot be cleaned economically in heavy medium. The settling velocities of the fine material are very low, and consequently the time required to separate the lighter coal from the heavier refuse becomes excessive. In addition, stray currents in the vessel and the upward velocities induced to keep media solids in suspension affect the finer solids to the degree that physical size becomes a more important factor than specific gravity.

Jan 8, 1980

By David G. Chedgy, Edward A. Zawadzki, Robert D. Stoessner

Extensive research and testing in commercial facilities has clearly demonstrated that heavy medium cyclones are the most effective process for cleaning a 0.6 x 0.15mm (28 x 100 Mesh) coal at low separating gravities, less than 1.35. This paper describes testing performed to deter- mine system characteristics at these lower gravities and the type of circuitry required to maximize performance. The results of these studies include both pilot and commercial scale tests of cleaning 0.6 x 015mm (28 x100M) coal.

Jan 1, 1988

The Sishen iron-ore-mine produces 3 pro= ducts with size gradings of 25 to 8 mm, 11 to 5 mm and 5 to 0,2 mm and has a product capacity of 20 Mtpa. Ore is produced at an average Fe content of 66,2 % Fe for the two coarser pro= ducts and an average of 65,3 % Fe for the fine ore product. Three stage crushing is practised to re= duce the run-of-mine ore to -90 mm after which it is screened into five different size frac= tions of which four are heavy media beneficiated in static baths and cyclones and the fifth frac= tion discarded to slimes dams. A final three stage crushing and screening process is employed to produce the final three Products which are homogenized by means of blen=ding systems nrinr to despatch.

Jan 1, 1987

By C. P. Broadbent

Due to growing .public awareness of environmental issues and greater sensitivity towards waste management, many countries around the world are implementing more stringent legislation governing the storage and disposal of hazardous wastes containing heavy metals such as As, Sb, Pb, Cd or Hg. These wastes can no longer be dumped without providing clear guarantees that the material concerned is environmentally safe and will not leach toxic elements to the surroundings. In the Netherlands the current dumping charge for chemical waste (i.e. worst category) is $280/t, and for industrial waste this cost reduces to $75/t. If the material can be reused there may be a small positive credit for selling it, for example discard slag as an aggregate to the construction industry. A number of (pyre)-metallurgical operations, mostly associated with the extraction of metals from sulphidic ores, produce arsenic residues in the form of As2O3 containing flue dusts and speises. If the flue dust is of high purity it can be sold, though many traditional uses are being substituted by other materials. In many cases upgrading the quality of the arsenical dusts is not possible for either technical or economic reasons. Traditional practice is to dissolve these dusts in acid prior to precipitation as ferric arsenate, which is at present classified by many countries as industrial waste and can be dumped. Recent work, however, has cast doubt on the stability of arsenates for disposal and alternative disposal routes have been investigated. Tests have shown that up to 10% (dm) As can be incorporated into "glassy" silicate slags with very low levels of arsenic leaching in the cooled product. Calcium arsenate was added to a range of synthetic and industrial slags from the system SiO2-FexOy-CaO-A12O3-AsmOn, under mildly oxidising conditions and quenched subsequently in water. It would appear that this represents an environmentally acceptable method for the disposal of many arsenical residues and there is some optimism that this method will be equally applicable to the disposal of other toxic metal residues.

Jan 1, 1994