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By P. B. Venuto, E. T. Strom, S. A. Dixon, W. F. Johnson, T. C. Vogt

Prior to assessing potential for in-situ leaching, it is advantageous to identify the nature of the probable reactants in the ore horizon, including both the uranium species and those in the gangue material. We report mineralogical data on an areally-broad suite of samples from the Westwater Canyon Member of the Jurassic Morrison Formation in the Crownpoint area of the Grants Mineral Belt. Optical microscope, electron micro-probe, X-ray diffraction, spectroscopic and wet chemical analyses were conducted. In these samples, the uranium occurs predominantly as either coffinite or uraninite. The host rock is arkosic sandstone, comprised mainly of detrital quartz and feldspar. The minerals kaolinite and chlorite are present in claystone clasts and calcite occurs as a cement. Major trace elements include molybdenum, vanadium, iron, selenium and sulfur. Carbonaceous organic material is present in the ore and is intimately associated with the uranium mineral when it is coffinite. Geochemical, pyrolytic and 13C NMR analyses indicate organic material is probably a very mature, coaly-type kerogen derived from plant components.

Jan 1, 1982

In-Situ Leaching (ISL) process plants are low cost producers for uranium deposits where the geology is suitable. In the 1970s, a three-year pilot ISL program occurred on gold ore from the Ajax Mine, Cripple Creek District, Colorado, using a chloride and iodide solution [1]. The test was halted due to poor results. With gold and silver the international ISL progress has been slow; however the potential for low capital expenditure (CAPEX) and operating expenditure (OPEX) with large low grade deposits is real. Unless the metallurgy has been demonstrated there are significant risks which could be fatal flaws to an ISL gold or silver project. The metallurgy of gold ISL projects is far from simple and it is early days with project development.

Jan 1, 2011

In-situ leaching of gold deposits has not become an option largely as a result the lack of suitability of cyanide as a lixiviant due to sluggish kinetics and high dependence on the availability of oxygen. A second problem area is the excessive cost of drilling the required number of injection and production wells needed to service a wellfield capable of maintaining any significant throughput or providing and acceptable level of gold production. Well spacing in in-situ leaching operations is limited by solution life, dissolution rate, and the need for solution control. With cyanide the life of an active solution capable of dissolving significant gold is severely limited by the availability of oxygen which cannot be readily replaced while the solution remains underground. The extremely slow gold dissolution rate also necessitates excessive contact periods in order to dissolve coarse gold.

Jan 1, 1991

By P. S. Sundar

A laboratory method for the simulation of in-situ leaching of uranium was developed under contract to the Interior Department's Bureau of Mines. Simulation tests using sulfuric acid, ammonium bicarbonate and sodium carbonate as reagents and hydrogen peroxide as oxidant were carried out with representative ores from Texas and Wyoming. The tests not only yielded recovery rates of uranium and permeability changes, but also qualitative inferences on the chemical and physical phenomena which occur underground. Leaching with basic solutions was found to be kinetic constrained and with acid solutions, equilibrium constrained. The rapid permeability changes observed when leach solutions were introduced, were probably caused by gas blockages in the packing. Precipitation of calcite or gypsum and the reaction of clay to leach solutions had slow and gradual effect on the packing permeabilities.

Jan 1, 1978

By K. L. Wiley

In-situ leaching, initiated in 1986 at San manual, was economically developed in 1989. The primary reason for this lag time between startup and viable production was the time required for technical development. The technical development pursued comprised detailed design, development, and implementation of in-situ well construction methods, formulation of suitable well pattern arrays, and the development of extensive hydrogeologic and geochemical knowledge of the mineral deposit. Since 1989, the in-situ leaching program has become a viable and cost effective method to extract copper from the supergene mineralized zone of the San Manuel deposit. The in-situ leaching methods that are currently utilized have been progressively expanded and continually developed and will became the cornerstone of copper production from the San Manuel oxide mineral deposit. This paper presents an overview of the supergene hydrogeology, current design techniques, drilling methods and well completion, pump determination and setting, solution management, and future plans for the increased extraction of copper by in-situ leaching methods at the San Manuel mine.

Jan 1, 1993

By Biao Q, Mizuta Y

Thermal constants such as thermal con- ductivity and thermal diffusivity of rock and coefficient of heat transfer of airway wall are the most important characteristic values which decide accuracy of prediction calcula- tion. However, quality of rock is not homoge- neous and water content in rock varies with location and so, a method for in-situ measure- ment of thermal constants must be taken in. The method developed by us is to measure in- situ rock temperatures at two different depths from airway wall. It is simple and we found its accuracy is good enough in the engineering Sense.

Jan 1, 1988

By R. Hogg, E. Kaya

"The presence of agglomerated particles in airborne dust in coal mines has been confirmed by SEM examination of static samples collected on substrates. In addition, the effect of agglomerated particles on the performance of cascade impactors and cyclone-type personal samplers has been studied. Simple procedures have been developed for evaluating the extent of agglomeration in air-borne dust by comparing the observed size-selectivity of the sampling devices with that expected under idealized conditions. Applications of these techniques in the laboratory and in underground mines are discussed.INTRODUCTIONAirborne dust is invariably present in mine atmospheres. Particle size is a primary factor in determining the behavior of the dust, its effects on miners' health and the effectiveness of dust control measures. Obviously, agglomeration of the dust particles can have important effects on: ""natural"" dust removal processes such as settling• the use of water sprays etc., for dust control• pulmonary deposition characteristicsIn addition, the presence of agglomerates could influence the effective toxicity of the dust. For example, ultrafine particles are often thought to be relatively unimportant in the development of respiratory ailments because of their low deposition efficiency. However, the latter could be substantially increased if such particles were present in larger agglomerates. It is by no means obvious that there should be significant agglomeration of the airborne dust in a mine atmosphere. In fact, calculations based on the classical coagulation theories indicate that, at the kinds of dust concentrations that exist even in what would be regarded as “very dusty"" atmospheres, the coagulation half-time* .should be of the order of weeks or even months. On this basis, agglomeration would be expected to be essentially negligible. On the other hand, laboratory experiments (Polat et al., 1991) have revealed very extensive agglomeration in the airborne dust released during the crushing of individual coal and mineral particles. It is postulated that such agglomeration occurs immediately at the point of dust generation. In other words, many of the fine fragments produced on fracture are never completely separated from their neighbors."

Mar 1, 1992

By R. Hogg, E. Kaya

The presence of agglomerated particles in airborne dust in coal mines has been confirmed by SEM examination of static samples collected on substrates. In addition, the effect of agglomerated particles on the performance of cascade impactors and cyclone- type personal samplers has been studied. Simple procedures have been developed for evaluating the extent of agglomeration in air-borne dust by comparing the observed size- selectivity of the sampling devices with that expected under idealized conditions. Applications of these techniques in the laboratory and in underground mines are discussed.

Jan 1, 1992

By Ben D. Thompson

Cemented Paste Backfill has proven to be of critical importance to the operation of a number of Canadian mines, primarily due to the rapid backfilling rate this method permits. In order to improve the efficiency of this backfill system (i.e. optimize binder contents, fill fence design, and the employment of two stage filling strategies) there is a requirement to better understand its geomechanical behaviour. In response, in-situ experiments have been conducted in long-hole stopes to quantify the evolution of total earth pressures and pore pressures at a series of instrumented points within both the core of the backfill and close to fill fences. The deflection of fill fences as a result of paste loading has been measured and additional instrumentation has also been employed to measure cement hydration, negative pore pressures, and blasting induced vibrations within fresh and cured paste backfill. Installing geotechnical instrumentation within an open long-hole stope can be an extremely complex procedure and this paper details the methods that have been successfully employed. Preliminary results are presented, and the pressures induced by backfill with differing binder contents, at a number of different in-stope locations are considered.

May 1, 2009

The knowledge of aggregate size under various chemical and hydrodynamic conditions is very important for selective agglomeration, flotation and water clarification processes. Traditionally, aggregate size measurements are conducted using an ex-situ technique or in a diluted suspension. In either case, the measurement occurs in an environment that does not resemble the actual conditions under which the aggregates are formed. In this study, an on-line scanning laser microscope has been used to study the coagula size of micronized coal suspensions as a function of pH, solids concentration and agitation intensity. A maximum aggregate size of 310 µ m was obtained under relatively quiescent conditions and at pH values near the iso-electric point (iep) of the coal. The aggregate size results compare well with the coagulation efficiency measurements obtained under the same pH conditions.

Jan 1, 1994

By K. Lang

A test section of the upper most lift and underlying lifts of a large scale copper heap leach operation was instrumented and monitored with advanced wireline geophysics, fiber optics and resistivity electrode arrays. Elemental Capture Spectroscopy (ESC) copper measurements, resistivity measurements from an Array Induction Tool (AIT), electrical resistivity tomography (ERT) and distributed temperature sensing (DTS) with fiber optics provided integrated near real time data about the performance of the heap. During the leaching cycle, ECS provided continuous vertical measurements of copper in the upper most and underlying lifts in the test section of the heap and was used to generate a copper recovery curve. ERT inversion modeling provided high resolution 3D resistivity measurements, which were used to evaluate moisture distribution. DTS measurements of temperature were used to track the PLS front and calculate velocity. AIT induction provided highly precise bulk resistivity measurements. In-situ samplers provided PLS chemistry at multiple points. Properly integrated monitoring data can provide the heap leach operator with information that can be used to evaluate the hydrodynamics and metallurgy of the leaching process in near real time. Problems in the heap, such as pooling, channeling, longer lag and breakthrough times, excess acid consumption, increased solution in inventory, toe saturation and slope stability can be detected in near real time with the in-situ measurements evaluated.

Feb 23, 2014

By M. U. Ozbay, D. R. Lougher

An in-situ experimental programme was carried out to improve the understanding of the rockmass and pillar behaviour in moderately deep hard-rock mines. The experiments were carried out at Impala Platinum mines and consisted of precise levelling measurements in the footwall of the reef, stress measurements in pillars, convergence measurements in the stope, and petroscope observations in pillars. The results were analyzed using a computer program in an attempt to quantify the characteristic behaviour of the rockmass as well as the pillars. The measured off-reef displacement data were found to co11fonn to the trends obtained from elastic modelling and the correlation could be improved by modelling the small pillars with reduced modulus to simulate yielding' of the pillars. The stress strain curve obtained from analyzing the in situ results, showed that a 6x 3 xl m pillar yields without significant load shedding at peak stress levels of approximately 208 MPa. The closure measurements confirmed that the mechanism of yielding is mainly that of pillars punching into the foundations. Slight to moderate sidewall fracturing and slabbing might be contributing to yielding, but to a much lesser degree than the former mechanism, as the petroscope observation revealed the existence of an intact region beyond 0,6m from the pillar sides.

Jan 1, 1995

By J. Ouellet

"ABSTRACTA brief background on in-situ testing of mine backfill, as well as pressuremeter testing is briefly described, and results from an in-situ testing on paste backfill are presented. A series of self-boring pressuremeter tests were done from the top of a backfilled stope in an underground mine. The tests were conducted along a 20-metre vertical line in the centre of the stope. Some 14 tests were performed along this depth. The instrument used was a Camkometer built by Cam Insitu, Cambridge. The instrument proved to be efficient and reliable for underground testing in a cemented paste backfill. The testing program was conducted within the planned schedule with a high success rate. The test done in this study permitted the measurement of paste backfill strength, stiffness and in-situ horizontal stress within the backfill. RésuméUn bref historique des essais in situ dans le remblai minier est présenté. L’essai pressiométrique est décrit succinctement et des résultats d’une campagne d’essai dans un remblai en pâte sont présentés. Un programme d’essais au pressiomètre auto-foreur a été réalisé à partir du sommet d’un chantier remblayé sous terre. Les essais ont été réalisés le long d’un ligne vertical d’environ 20 mètres pour un total de 14 mesures. Le Camkometer de la firme Cam Insitu de Cambridge a été utilisé. Cet instrument s’est avéré efficace et fiable pour tester le remblai en pâte cimenté sous terre. Le programme d’essai s’est déroulé à l’intérieur de l’échéancier prévu avec un taux de réussite élevé. Ces essais ont permis de déterminer la résistance, la rigidité de ce remblai ainsi que les pressions in-situ prévalant dans le remblai."

Jan 1, 2000

By James Bennett, Jinichiro Nakano, Anna Nakano

Efficiency of the chemical looping combustion technology is adversely influenced by surface properties of oxygen carrier materials during oxidation–reduction process changes at elevated temperatures. In this work, natural hematite (Fe2O3) and alumina (Al2O3) supported Cu-spinel (CuFe2O4) oxygen carrier particles were isothermally exposed to redox gas cycles (air and 10 vol% CO–90 vol% Ar) at approximately 800 °C and studied using a high temperature confocal scanning laser microscope for real time alterations in surface morphology, roughness, and particle volume. 3D topological scans from each cyclic gas exposure indicated hematite particles exhibited noticeable volume expansion in reduction and shrinkage in oxidation, corresponding to respective phase transformations. Materials surface changes during the redox gas cycles are discussed.

Mar 1, 2017

By T. W. Turk

Iron Mountain Mines, Inc., (IMMI) ore de- posits are located in the southeastern portion of the Klamath Mountains in the West Shasta copper/Zinc Mining District in Shasta County (Figure 1). The original massive sulfide ore deposits totaled 22,895,000 Mt (25 million st). The remaining ore deposits contain 12,875,000 Mt (14,183,000 st) of proven massive sulfides and 2,769,000 Mt (3,050,000 st) of proven gossan deposits. The addition of magnetite deposits and tailings (now marketable) brings the total of proven and probable reserves to 20,433,000 Mt (22,508,000 st). The massive sulfide ore bodies are generating a natural flow of acid mine water which has been slowly leaching minerals out of these deposits. This flow varies in volume, depending on rainfall, and contains variable concentrations of copper, zinc, iron and precious metals. This mine water has been treated for the past 50 years at the mine site to remove copper. The treatment process, utilizing scrap iron precipitation, continues at a production rate of approximately 54,430 Kg (120,000 pounds) of copper precipitate annually.

Jan 1, 1986

By N. B. J. Kieser

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. Platinum-group minerals (PGM) in the enriched zone at Dust Mountain occur in two separate parageneses, the first representing primary magmatic PGM and the second primary magmatic PGM that have been reduced to alloys during serpentinisation. Minerals in the first group were unaffected by hydrothermal alteration on account of their textural setting or stable chemical composition. Despite substantial alteration of the serpentinised assemblage, most evidence points to the dominant role of primary magmatic processes in determining PGM occurrence. Several base metals have nevertheless been introduced hydrothermally. With respect to surficial dispersion the single most important paragenetic factor was the reduction of sulphides to alloys, rendering them more susceptible to mechanical erosion and less so to chemical leaching. The different textural setting of Pd-group and Ir-group phases results in different dispersion characteristics, with major implications for stream sediment sampling

Apr 1, 1994

By Follington I. L

Various methods for stress measurement in the coal industry are briefly reviewed. Methods for presenting and interpretation of measured stress and displacement data are discussed with a view to assessing the mechanisms of failure. Arguments are presented for reviewing the current practices in this regard with reference to coal pillar and strata stability analyses.

Jan 1, 1991

By James C. Foley

In-situ characterizations of green state part density and sintering state have long been desired in the powder metal community. Recent advances in non-contact electromagnetic acoustic transducer (EMAT) technology have enabled in-situ monitoring of acoustic amplitude and velocity as sintering proceeds. Samples were made from elemental powders of Al (99.99%), Al (99.7%), Ag, (99.99%), Cu (99.99%) and Fe (99.9%). The powders were pressed in a uniaxial die and examined with acoustic waves for changes in velocity and amplitude during sintering. The changes in acoustic properties were correlated with mechanical properties. Evolution of a series of reverberating echoes during sintering is shown to provide information on the state of sintering, changes in sintering kinetics as well as having the potential for detection of interior flaws.

Jan 1, 2001

By J. J. Kellar

The near-infrared (NIR) (12,000-4,000 cm-1) region of the electromagnetic spectrum, between the mid-infrared and visible, has often been viewed by spectroscopists to be of limited utility. This is unfortunate, and recently the use of the NIR has increased greatly, primarily for the quantitative analysis of food and agricultural products. However, many other areas of application of NIR spectroscopy remain unexamined. In this paper a novel use of NIR in the area of flotation chemistry is demonstrated. Specifically, it is shown that NIR/Internal Reflection Spectroscopy (IRS) can be used to quantify collector adsorption reactions in-situ.

Jan 1, 1990

By D. D. L. Chung

"In-situ network composites are composites in which the filler network is formed during composite fabrication, in contrast to ex-situ networks which are formed prior to composite fabrication. A homogeneous in-situ network composite has the entire network at the same composition; a heterogeneous in-situ network composite has different parts of the network at different compositions. The homogeneous network composite is made either by the Method of Molten Filler Flow or the Method of Dissolution and Deposition; a heterogeneous network composite is made by the Method of Liquid-Phase Networking. Examples include polymermatrix and metal-matrix composites.IntroductionNetwork composites refer to composites containing a continuous three-dimensional network as the filler. These composites are attractive in their lack of delamination failure, which is usually characterised by two-dimensional composites. The filler and matrix in a network composite can be considered two interpenetrating networks. The mechanical interlocking of the networks adds to the cohesion of the composite. In cases where the filer is much better than the matrix in a certain property, the network nature of the filler makes the filler highly effective in improving that property in the composite in all directions. The property desired in the composite may be high strength, high modulus, low coefficient of thermal expansion, high thermal conductivity, or low electrical resistivity."

Jan 1, 1994