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By Lu-ming Zhao, Li Zhao, Yu Wang

In this paper, the change of crystallization rate, dendrite arm spacing and dendrite width of mold flux with various magnetic field conditions were studied by experiment. Having found that the crystallization ratio of mold flux increased from 33 to 96.6%, the dendrite arm spacing decreased from 72.47 to 38.02 lm, the dendrite width decreased from 48.47 to 27.02 lm while the magnetic field frequency (f) equaled to 8 Hz and its strength (B) increased from 0 to 30 mT. The crystallization ratio of the mold flux increased from 91.9 to 96.1%, the dendrite arm spacing decreased from 60.53 to 28.08 lm,the dendrite width decreased from 42.53 to 24.08 lm when B equaled to 20 mT and f increased from 6 to 12 Hz. However, the XRD analysis indicated that the phase types of the mold flux under the experimental conditions did not transform. Results showed that an alternating magnetic field can promote the crystallization of mold flux and refine grain structure.

Mar 1, 2018

By K. Anderson

There is a credible, cogent, and responsible argument that mining can be part of a sustainable future in countries with freely elected governments, transparent and enforceable laws, a closure plan with an adequate bond, and a small handful of other measures. This perspective, built largely upon the understanding of mining as a temporary use of the land, is coupled with a growing understanding of economic diversification as a tool to level out the ‘bust’ side of the boom and bust cycle. There are verifiable signs of progress that the sector has, at least in some venues, begun to embrace this view of ‘sustainability’ both in philosophy and practice. While laudable, there remains a conundrum not yet fully explored. It is conceivable that companies can fulfill all legal requirements, practice corporate responsibility in its broadest and most liberal interpretation, and yet leave behind, after the gates are closed and the lights turned off, a situation which is not only unsustainable, but far worse off than before mining started. Having observed this outcome, repeatedly, some critics have concluded that all mining should be stopped. Others recommend that it be vastly curtailed until regulatory regimes are re-vamped, communities fully empowered, and companies brought to heel. Yet others, including many within the industry, are looking to hold back this dark prospect with peer pressure, branding and competition for good will. In this paper, I propose to focus on this discontinuity, that gap wherein the chain of logic breaks and reasonable policies, reason-able choices, reasonable actions, may fail to deliver expected results. I suggest that any meaningful definition of post-closure sustainability must include the concept of human welfare, and increasingly, human security, over and above meeting the requirements of law, beyond retaining shareholder value and reputation, beyond discussions of subsequent land use and diversified employment. I suggest that self-determination, that ability of a people to hold for themselves the vision of their own future, and to have a sense of their power to implement it, may be both the most difficult and the single most important determinant of long-term sustainability in a community. The particulars will vary; a Canadian junior or an Australian multinational, a highly regulated state in the American west or a ‘failing state’ in Africa’s west, gold or sand and gravel. But the recommendation is the same: this must be a collective endeavor, a shared responsibility involving some combination of government, companies, communities, local and international NGOs (non-governmental organizations), each contributing in the ways most able.

Jan 1, 2004

By D. Yu, Y. Thibault, D. Paktunc

"Prereduction and flux-aided direct reduction of chromite provide significant advantages in reducing energy consumption and greenhouse gas emissions during ferrochrome production. In this investigation, a comparative evaluation of the influences of several alkali fluxes was carried out based on experimental observations supplemented by advanced material characterization and thermodynamic predictions. Direct reduction of a chromite ore with alkali fluxes at 1300°C for 1 hour produced (Cr,Fe)7C3 type alloys with Cr/Fe mass ratios from 0.7 to 2.3. Among the alkali fluxes, reduction aided by NaOH resulted in a high degree (85%) of Cr metallization with the ferrochrome alloy being Cr4.2–4.6Fe2.4–2.8C3. The formation of liquid slag, which facilitated Cr metallization, was limited by the formation of NaAlO2 between 800 and 1300°C. This, in turn, restricted the collection and transport of the charged ionic Cr species (i.e. O2–) to graphite particles. Under the conditions studied, ferrochrome particles were often small and largely unliberated, which would make the physical recovery of ferrochrome challenging. At 1400°C, the amount of liquid slag increased, enabling the growth of alloy particles. Direct reduction of chromite aided by NaOH is promising as an alternative technology to conventional flux-based smelting in electric arc furnaces. IntroductionConventional smelting processes are energyintensive (Riekkola-Vanhanen, 1999) with the energy requirements greater than 4 MWh/t (Naiker and Riley, 2006; Beukes, van Zyl, and Neizel, 2015), and the greenhouse gas emissions can be significant, exceeding 10.5 t CO2 per ton Cr in ferrochrome produced (International Chromium Development Association, 2016). These include emissions occurring on-site (smelter), emissions due to electricity production, and emissions due to upstream processes. Overall energy requirements are influenced by the degree of prereduction and smelter charge temperature. Significant reduction in electricity consumption can be realized if the charge is prereduced before feeding to the submerged arc furnace (Niayesh and Fletcher, 1986). This consideration has led to the development of several prereduction technologies, with the most important example being the Premus process. In comparison to the conventional smelting processes, this prereduction process lowers the overall energy consumption and greenhouse gas emissions by about one-third (Naiker, 2007)."

Dec 1, 2018

By Liangying Wen, Jian Xu, Dongdong Wang, Kaihui Ma, Yang Xu

Slags play an important role in blast furnace operation, and their com- positions are based on the CaO –SiO2–MgO–Al2O3 quaternary system. However, there is not a clear understanding of the effects of gangue on of the formation of FeO-bearing primary-slags process in blast furnace. In this work, the softening and dripping experiments under the blast furnace conditions are designed to explore the influences of CaO-/SiO 2-/MgO-/Al2O3 on the softening and melting properties of FeO respectively. The results indicate that additions of CaO or Al2O3 decrease the starting softening temperature and no dripping behaviors are found in comparison with the base case results when only FeO is used. On the contrary, the addition of SiO2 or MgO rises the starting and ending softening temperature, as well as the dripping temperature. The lowest maximum pressure drop is obtained in the case with addition of SiO2. According to XRD analysis results, the initial phase with CaO addition in the primary-slags should be CaOFe3O4 and that with SiO2, MgO, Al2O3 additions are fayalite (2FeOSiO2), magnesioferrite (MgOFeO), hercynite (FeO2Al2O3), respectively.

Mar 1, 2017

The impact of a methane explosion on mining operations cannot be over-emphasized. The explosion is a result of rapid combustion when a methane/air mixture is ignited by an unexpected energy release, such as a mine fire, electrical arc or sparks caused by frictions or rock falls. In most cases, an ignition of methane/air mixture could result in a deflagration other than detonation. Resulting flames and overpressure induced by a methane deflagration will harm neighboring miners and local ventilation control devices.. ,It is essential that the mechanism of an explosion and associated destructiveness be fully understood. This research seeks to predict an influence region of an incident happened within a representative underground mine geometry. The most common geometric changes in an underground coal mine are bends, regulators/doors, obstacle in airways and changes in sectional area. These geometric changes could result in an attenuation of the flame and pressure wave as a result of a methane deflagration. A study of this phenomenon could enable mine planners to have better understanding of the over-pressure redistribution due to the explosion. Both numerical and experimental work has been done in this study to ascertain a better insight of this potentially devastating event. The experimental data are also used to validate the turbulence and combustion models used in this test.

Feb 23, 2014

By Alexander I. Raitchenko

"Although one takes into account only thermal expansion usually at analysis of convection onset, the essential factors include magnetic and electric fields. If Lorentz-force originating from intercrossed electric and magnetic fields' action is directed downwards its effect strengthens gravitational action, and value of critical Rayleigh number (limit value for convection onset) must decrease; increasing of critical Rayleigh number should be observed in case of Lorentz-force directed upwards. Extent of such an influence is determined by relation of Lorentz-force to hydrostatic head in gravitational field. Competition between electromagnetic force due to nonuniformity of electroconductivity (on account of its temperature dependence) and electromagnetic buoyancy force may have ambiguous effect: both increase or decrease of critical Rayleigh numbers. Proposed conception is applicable to analysis of situations in liquid conductors and conductive gases.IntroductionStatic or dynamic situations in fluid media are determined besides properties of these media by a variety of external influences. However one correlate~ the onset of the convection and its development with influences of the minimum quantity of external causes frequently. Most known and usual factors are the gravitational and temperature fields. The number of processes includes heat generation in media volume, and theoretical analysis in these cases takes into account this interior heating together with boundary temperature conditions. But explanation of many natural and technical events is not complete and cogent within limits of thermo-gravitational terms. The whole complex of acting factors which influence convective processes in techniques and nature is greater in many cases. In particular the action of · electromagnetic nature often has not less importance than gravitation one. Stability or instability of a current layer in the plasma must be determined by non-uniformity of electroconductivity owing to non-uniformity of temperature [1]. The presence of Joule dissipation in the plasma through which the electric current flows stipulates initiation of origin of overheated instability [2]. It is known that electroconductivity of arc in the boundary zone changes sharply with radial distance [3], and this must influence its stability essentially. If the intercrossed electric current and magnetic field begin to act on an electroconductive fluid besides the non-uniform temperature field and the gravity, the conditions for the onset of the convection change radi- . cally: both the temperature field and their solutions have to be changed also. The analysis of equilibrium single-time correlation functions of fluctuations must be employed for situations with enlarged number of factors as this was in case for the Rayleigh-Benard problem where the object is a horizontal layer of liquid. This can be carried out by taking into account the detached forces' correlations [ 4, 5]"

Jan 1, 1999

By Francisco Morganti

Weight reduction is the main target of all carmakers, which results in a continuous development of new steel grades. Latest 3rdgeneration advanced high-strength steel grades (AHSS) are complex materials with special chemical compositions and multiphase microstructures. The pickling, annealing and galvanizing processes of these grades aresomewhatdifferent due to the changed chemical compositions and microstructures. Therefore, these innovative steel grades place new demands on the plant technology of pickling, annealing and galvanizing lines. The most significant challenges for the pickling process are sludge occurrence during pickling, varying pickling times, weld ability of the materials, changed visual appearance and required high surface qualities. The most important topic concerning annealing line is a precisely controlled and very flexible heating and cooling process in the furnace.One of the new requirements in galvanizing linesis the prevention of surface faults caused by bare spots, which can occur since these materials feature a higher content of alloying elements like silicon or manganese. Prevention is possible with the special pre-oxidation technologies.Due to the higher strength of the material also the mechanical equipment has to be designed differently in these lines. This paper describes the influences of the changed chemical composition and material characteristics of modern steel grades on the pickling, annealing and galvanizing process and gives an overview about the technical solutions.

Oct 30, 2017

By C. Gatschlhofer, A. Krammer, H. Raupenstrauch, T. Hochsteiner, A. Holzer, L. Wiszniewski

The rising demand for lithium-ion batteries, coupled with international climate targets, emphasises the need for circular economy and zero-waste recycling approaches. However, so far, no industrial-scaled solutions are available that fulfil global recovery targets. Therefore, a novel pyrometallurgical reactor was developed at the Chair of Thermal Processing Technology at Montanuniversitaet Leoben to avoid lithium slagging and recover volatile elements via the gas phase. Nevertheless, previous results show that several impact factors, including interfering elements or pre-treatment steps, strongly limit the recycling efficiency of black mass. To simulate the black mass and provide feedback on possible influences of pre-treatment steps, cathode material from production with additives of interfering elements was analysed regarding melting behaviour. The results show that formation of a further processable alloy was increased by almost 50% when pretreatment steps were excluded, indicating pre-treatment steps as a major influence to be considered within this specific recycling route.

Jan 1, 2023

By Sugui Tian

By means of the T6 treatment, the measurement of creep curves and microstructure observation, the influence of T6 heat treatment on the microstructure and creep properties of Ti-6Al-4V alloy is investigated. Results show that the microstructure of the forged alloy consists of the banded-like a phase and networks b phase. After sub-temperture T6 treated, the microstructure of alloy consist of the block a phase and ?networks basket? structure. Under the conditions of the applied stress of 575 MPa at 4000C, the forged alloy displays a lower creep lifetimes, after T6 treated the creep lifetimes of the alloy is enhanced to 548 h from 66 h, which is attributed to the formation of the network basket structure in which the needle-like phase are dispersedly distributed. As creep goes on, the denser dislocations in the a phase are concentrated to occur the dynamic recrystallization for refining grain. which is a main reason of the alloy displaying a better creep lifetimes and plasticity. Thereinto, the creep mechanism of the forged alloy is thought to be the slip of the straight <a> and <a+c> dislocation are activated on the prismatic planes and pyramidal planes, while the creep mechanism of T6 treated alloy is that wave-like <a+c> dislocations are activated on the pyramidal planes.

Jan 1, 2009

By Z. W. Zhang, Songsong Xu, Jinhui Li, Yun Zou, Yu Zhao

High strength low alloy (HSLA) steels with high strength, high toughness, good corrosion resistance and weldability, can be widely used in shipbuilding, automobile, construction, bridging industry, etc. The microstructure evolution and mechanical properties can be influenced by thermomechanical processing. In this study, themomechanical processing is optimized to control the matrix microstructure and nano-scale precipitates in the matrix simultaneously. It is found that the low-temperature toughness and ductility of the steels are significantly the matrix microstructure during enhancing the strength by introducing the nano-scale precipitates. The effects of alloying elements on the microstructure evolution and nano-scale precipitation are also discussed.

Jan 1, 2016

By Robert W. Bartlett

"Economic and other factors, mostly outside of metallurgy, that strongly influence applied research, development and especially successful commercial adoption of new processes for producing primary metals and other commodity materials are reviewed. These factors, which can be both positive and negative in their influence, are often too lightly regarded in the research planning stage. They include continuing imperatives that have long influenced new process development as well as more recent trends. Both are discussed. Nearly all new materials eventually become commodities--products made to standard specifications with no producer control over price. Success requires being a low cost producer on a world wide basis. Composites and other complex material assemblages are unlikely to escape this fate as they mature.INTRODUCTIONThe adoption of new processes, beginning with research and development, for primary metals and other commodity materials is particularly difficult because each new process must supplant an existing process that is already being used commercially. There are many requirements besides technical innovation and cost superiority that must be met by the new process. Consequently, few innovations make it all the way from the research laboratory to commercial success.This paper discusses some of the factors that influence success in developing new processes for primary metals and commodity materials, based on the authors experience as a research metallurgist and industrial research manager. It begins with some of the factors that are always present and constrain successful process research and development, and proceeds to current trends that are expected to continue long enough to influence processes in the year 2000. Many of these trends are contradictory in their effect on new process development, and the future remains uncertain.The prevailing importance of these trends will vary with the material, process concept and other factors intrinsic to each case. Nevertheless, an awareness of these influences can help to avoid some of the R&D pitfalls and dead ends. Such awareness is deemed to be a necessary condition to avoid failure when commercial adoption of a new process is the goal."

Jan 1, 1988

By Leandro de Almeida

Tiras e chapas de cobre e suas ligas possuem excelentes propriedades térmicas, elétricas e mecânicas simultaneamente e por isso podem ser utilizadas na fabricação de inúmeros produtos através de processos de conformação. Determinadas características devem ser analisadas na chapa antes mesmo do processo de manufatura, visando eliminar possíveis falhas durante as etapas de produção. Especificamente para o processo de repuxo profundo, faz-se necessário avaliar a possível formação de orelha e o possível afinamento da espessura da chapa durante a conformação. Sendo assim, o levantamento dos coeficientes de anisotropia planar ?r e o de anisotropia normal r são essenciais para se obter bons resultados nos processos de conformação. O presente estudo tem como objetivo avaliar a influência da deformação (e) na obtenção dos coeficientes ?r e r na liga UNS C22000, utilizada especificamente para a produção de projéteis A norma ASTM E 517 que apresenta a metodologia para se determinar esses coeficientes não especifica claramente qual e a ser utilizada. Os resultados alcançados não demonstram diferenças significativas com relação a e utilizada nos ensaios, ou seja, os coeficientes obtidos utilizando 0,10, 0,15 e 0,20 de deformação são os mesmos.

Aug 17, 2017

By Rodrigo Martins Barbosa

A água é utilizada em processos industriais desde o começo da era industrial. Sua utilização é variada, desde como matéria prima, até como utilidades. Muito se discute a respeito da qualidade da água para descarte e seus possíveis danos ambientais, mas é importante mostrar que, além disso, existe um impacto financeiro ao trabalharmos com a má qualidade da água industrial. Este trabalho propõe demonstrar a influência da qualidade da água nos processos industriais, através da avaliação do resultado da instalação de um filtro de água na tubulação de entrada de um trocador de calor.

Aug 17, 2017

By Fabiana Fonseca de Morais

A sinterização é um dos mais importantes e mais antigos processos de aglomeração da indústria metalúrgica. Entender a realidade atual do processo de sinterização e as qualidades requeridas para o sínter é primeiro passo para o desenvolvimento de equipamentos ou processo. Este trabalho visa entender o impacto das diferentes características de minério e resíduos empregados em uma sinterização, seu comportamento na qualidade do sínter e a sugestão de equipamentos para amenizar problemas encontrados. Parâmetros como CaO/SiO2, SiO2, Al2O3 e MgO são avaliados para entender a tendência do mercado e o efeito na qualidade final do sínter. A correta avaliação das necessidades da planta para otimização dos equipamentos a matéria-prima disponível se faz necessário para o melhor resultado no alto-forno. A granulometria da matéria-prima também é um ponto importante a ser analisado. O sinter feed tradicionalmente possui uma maior fração entre 0,7 e 6 mm, uma fração menor entre 0,2 e 0,7 mm e um conteúdo de ultrafino (&lt;0,150 mm) limitado a 15%. Estudos identificam uma tendência do sinter feed com maior conteúdo de sílica e o consequente aumento da utilização de ultrafinos. Como resposta ao incremento de ultrafinos na sinterização as grandes siderúrgicas já estão investindo em equipamentos que minimizem grandes perdas de produtividade, como a instalação do misturador intensivo, utilizado em projetos da Pau Wurth. Outra solução inclui a instalação de uma mini-sinterização dedicada para receber este material mais fino e resíduos. O sínter produzido poderá ser adicionado diretamente no forno e/ou ser utilizado como nuclueante na sinterização grande para aumento de sua produtividade.

Aug 16, 2017

By Sergio Castro

Los modelos geotécnicos disponibles suelen estar basados en las litologías existentes, sin considerar el impacto de las soluciones hidrotermales en las rocas y, por tanto, en la estabilidad de los taludes de un tajo abierto. El estudio de caso presentado en este artículo muestra que realizar una zonificación en términos de los tipos de alteración hidrotermal es muchas veces necesario; pero también que ello debe acompañarse de investigaciones geotécnicas adicionales y un análisis de la estabilidad física de taludes, con el fin de lograr un rediseño basado en la variabilidad de la resistencia de la roca en cada tipo de alteración, ya que el efecto puede haber sido tan intenso que la roca termina transformándose en un suelo residual.

Jun 30, 2020

By Daniel Asunción García Ramos

El presente texto señala la influencia del quebracho como agente tensoactivo que evita el problema causado por el azufre a través de concentrados, cuyas especies mineralógicas predominantes son: esfarelita, pirita, incrementándose la extracción de metales. En este sentido, este método hidrometalúrgico permite que los concentrados que tienen plomo y arsénico en su composición, sean neutralizados para neutralizarlos como sulfatos sólidos, mientras que los sulfuros de zinc y de cobre pasan a la solución acuosa en estado iónico para ser recuperados posteriormente por electrodeposición.

Dec 1, 2015

By Gilberto Yanarico Apaza

"El presente texto señala las pautas necesarias para realizar una evaluación técnica integral de la influencia del collar de bolas para las operaciones de molienda, afectando al desgaste de los revestimientos de los molinos convencionales. Para la determinación del collar de bolas es necesario realizar los análisis granulométricos con la finalidad de obtener el F80 y el P80 de las muestras obtenidas en la alimentación y producto de los molinos, definir el índice de trabajo (Wi) y consumo de energía. Asimismo, se debe considerar el porcentaje de la velocidad crítica, las dimensiones de los molinos, la densidad de los medios de molienda (bolas), el porcentaje de la carga de bolas, las características geométricas de las bolas para molienda y el diámetro real de bolas, que influye de forma inversamente proporcional en la tasa específica del consumo observada."

Jul 1, 2015

By César Augusto Martín Hilser Vicuña

El "Punto de fluencia” es el contenido de humedad crítico a partir del cual un mineral concentrado sufre “liquefacción”, es decir, libera la humedad como agua libre al ser sometido a las sacudidas propias de una travesía por mar. En esta perspectiva, el presente texto correlaciona la influencia que tiene el proceso de producción de los concentrados en el punto de fluencia a través de los siguientes factores: granulometría, efecto de los reactivos de flotación y la mineralogía. De forma que al conocer los factores que influyen notablemente en el valor de la humedad límite de transporte, se evita los riesgos de que la carga sufra licuefacción durante su transporte por mar.

Sep 14, 2009

By Fabio Da Costa Garcia Filho

O uso de resíduos de vidro como aditivo mineral finamente moído, em substituição parcial de cimento e agregados é uma direção promissora para a reciclagem. Este trabalho teve como objetivo analisar a influência de resíduos do processo de corte de vidro em argamassa adesiva, como substituição parcial de cimento e agregado miúdo. O vidro em pó foi utilizado em percentuais de 10, 15 e 20% em peso em substituição ao cimento Portland e, em outro momento, em substituição ao miúdo agregado. Verificou-se que a substituição refletiu positivamente sobre a resistência à adesão da argamassa, com o aumento da temperatura de cura.

Oct 30, 2017

By Dyego Irineu Silva de Almeida

O presente trabalho teve como objetivo analisar os efeitos dos ciclos de tratamento térmico de recozimento, normalização e esferoidização nas características microestruturais do aço SAE 8620. O aço SAE 8620 é amplamente utilizado na fabricação de engrenagens, pinos e peças onde há exigência de dureza superficial, obtida pelo processo de cementação ou carbonitretação. O aço SAE 8620 é empregado na construção de mecanismos onde a resistência ao desgaste é propriedade mais importante. Para essa aplicação, aços com baixo teor de carbono produzem um núcleo tenaz e os tratamentos termoquímicos conferem as características superficiais necessárias. O espécime original foi caracterizado através dos procedimentos necessários para visualização da microestrutura, bem como as amostras provenientes dos tratamentos térmicos. Sabe-se que o estudo metalográfico de um material é de grande importância para a identificação de suas propriedades, haja vista que essas propriedades estão diretamente relacionadas com a microestrutura que o material possui. Concluiremos que os diferentes ciclos de tratamento térmico, influenciam diretamente nas microestruturas das peças tratadas termicamente, como também na propriedades mecânicas.

Oct 30, 2017