Search Documents

By R. J. Mitchell

"Centrifuge modelling of earth structures is a well-proven technique for evaluating the performance of prototype structures using physical models. The applications of this technique have increased dramatically during the last decade such that even the modelling of dynamic responses in structures has been accomplished.This paper presents the first model test results used to design a mine backfill. The models were tested using a 3 m radius 30 g-tonne geotechnical centrifuge which was constructed at Queen's University specifically for model studies on mine backfill stability and subsidence. The models represent the first production blast-hole stope to be mined at Westmin Resources Ltd. 's H. ~ Mine on Vancouver Island. This paper includes photographs of:model failures in the centrifuge and correlations of model test results with analyses based on unconfined and triaxial test data.IntroductionDuring the feasibility study and development stages for the H.W. Mine, Westmin Resources Ltd. conducted a comprehensive rock mechanics and backfill engineering program. The results of these studies indicated the need for assurance of backfill stability during pillar recovery on the initial blast-hole mining block. The cemented tailings backfill had to be free standing for heights up to 25 m and the potential for surcharge loading from a weak hanging wall zone, the potential for fill block sliding down-dip and the potential for seismic loading had to be considered in the design of the fill strength. The basic questions to be answered were: what cement content is required and will the resulting backfill costs be economic relative to the proposed mining method and sequence? Figure I shows a typical cross-section through the first mining block . The up-dip stope is to be mined first and backfilled with cemented tailings . The down-dip stope would then be mined and filled. Depending on ground conditions encountered, the complete intervening pillar could be recovered and the void backfilled with uncemented tailings or it could be recovered in small sections by exposing limited back and wall areas, backfilling with waste rock and I or cemented tailings . This latter method is commonly referred to as the Avoca method"

Jan 1, 1987

By R. J. Mitchell

"The use of hydraulically delivered classified tailings sands to provide ground support in large mining operations is still widespread despite recent developments of alternate backfilling methods and materials. The major disadvantages of the use of hydraulic fill are the costs and risks associated with slurry delivery. The main risk is that of bulkhead failure resulting from sand liquefaction due to insufficient operational control or due to dynamic loading from earthquake or rockburst. That risk may be eliminated by the pouring of a stiff cemented sand plug in the base of each stope prior to continuous fill pouring in that stope. An additional advantage of cemented plugs is that massive bulkheads are not needed. Instead, a temporary (removable and reusable) bulkhead can be used for plug forming.Physical model studies of fill pressures on a temporary bulkhead were carried out in a 3 m radius centrifuge facility. Fill pouring in-flight was carried out in order to model prototype stress paths. The results indicate that the average bulkhead pressure is likely to be less than 10 kPa under normal operating conditions and less than 20 kPa under the poorest anticipated operating conditions which include smooth walls, high slimes content and high water-content slurries. A portable bulkhead consisting of a central core and a surrounding sealing bladder was modelled and found to be effective. The use of different sizes of cores allowed the stress distribution adjacent to these bulkheads to be evaluated."

Jan 1, 1992

By Richard Schmidt, Lijun Deng, Mohamed Abdelaziz, Weidong Li

Helical piles are widely used as a foundation supporting a variety of different structures. Understanding the axial behaviour of helical piles is required to confirm the engineering design. Helical pile research is often conducted in the field, but this method can be prohibitively expensive in some cases. Geotechnical centrifuge modeling offers an alternative method for the helical pile research and practice. A series of axial load tests of helical piles installed into cohesive soils were conducted on the geotechnical centrifuge at the University of Alberta. The objective was to investigate the effects of inter-helix spacing and soil strength on the axial behaviour of helical piles. Four types of aluminum model helical piles including one single-helix pile and three double-helix piles with various inter-helix spacing ratios were tested. Both compressive and tensile loading tests were conducted. All model piles were instrumented with multiple strain gauge stations. The clay had an undrained shear strength of approximately 50 kPa and 120 kPa. The test results indicate that there is a transitional failure mode between the two widely recognized failure modes, i.e., individual plate bearing and cylindrical shearing. The shaft adhesion was significantly reduced by the helix. Axial capacities were comparable to the field test results.

By J. Gniel, L. King, C. Gaudin, C. O’Loughlin

"This paper presents some recent advancements in centrifuge modelling, which enable the installation of displacement piles to be performed in-flight while measuring ground responses. Details and results are provided from a series of experiments where 21 full-displacement piles were installed into a sample of consolidated kaolin clay at 40g. The piles were pushed into the sample at a constant rate of penetration, with installation reaction loads and pore pressures measured. Insight into the installation effects of the full-displacement piles was obtained by undertaking in-situ testing pre- and postinstallation of piles. The findings show that centrifuge testing has the potential to play an important role in furthering the current understanding of displacement pile behaviour and installation effects.INTRODUCTIONDisplacement piles and displacement ground improvement columns cause soil to undergo significant distortion and shearing during installation, which alters the soil properties. It is essential to consider these changes in soil properties to estimate the behaviour of pile foundations with higher degree of accuracy. However, the installation effects of displacement piles are widely considered as one of the most difficult geotechnical mechanisms to model, both analytically and numerically, and experimental data is needed to advance the current state of knowledge.Theories, analytical and semi-analytical, have been developed to describe the displacement pile installation process. Randolph et al. (1979) applied the cylindrical Cavity Expansion Method (CEM) to model the installation of a displacement pile in a fine grained cohesive soil. However, cylindrical CEM only considers the field variables in radial coordinates, and hence the soil-pile interface can only be modelled as a frictionless material. Baligh (1985) introduced the Strain Path Method (SPM), which assumes soil flows around the tip of a displacement pile. SPM was shown to model the stress and strain fields, particularly within close proximity to the pile, more accurately compared to the cylindrical CEM. While these methods account for the installation effects of a displacement pile and can be used to estimate a resulting ultimate bearing capacity, they are unable to describe the load-settlement behaviour of such piles. With the added complexity of group effects, existing analytical methods do not provide a means to accurately calculate the ground response to the installation of a group of displacement piles in a cohesive soil.The advancement of computational power, numerical techniques and constitutive models has improved the accuracy of numerical analysis, particularly in regard to modelling pile installation. However, even with advanced techniques, Finite Element Method (FEM) suffers a number of disadvantages due to the large deformations, which results in mesh distortion and tangling. Mesh-free methods such as Discrete Element Method (DEM), Smoothed Particle Hydrodynamics (SPH) and Material Point Method (MPM) are the next generation of computational techniques that are able to deal with large deformation problems. However, these advanced techniques are computationally expensive, complex and yet to be incorporated into commercial packages. Such methods are considered to still be in the development stage and are yet to provide a complete solution to pile installation problems."

Jan 1, 1900

By M. J. DeJong, R. J. Mair, S. Ritter, G. Giardina

"For urban tunneling projects it is essential to predict and prevent building damage. Although various case studies and experiments have shown that buildings considerably modify greenfield soil movements, widely accepted damage assessment methods neglect this soil-structure interaction and simplify structures as linear elastic beams. This paper summarizes an experimental investigation of the response of more realistic structures to tunneling-induced deformations. Small scale structural models with façade openings and brittle material properties were 3D printed and tested in a geotechnical centrifuge. Soil and structure displacement data were obtained by image-based measurement. Results demonstrate that structures notably mitigate differential greenfield ground displacements. It is also shown that maximum soil settlements, horizontal soil displacements beneath the structure and structural damage in the form of cracking significantly depend on the position of the structure in the settlement profile. The results provide a basis from which to predict building settlement response with greater certainty. INTRODUCTION With continuing population growth and increasing urbanization expected in the next decades, there is an urgent need for a next generation of infrastructure. It is likely that a large part of this infrastructure will be underground. Such creation of urban underground space frequently involves the excavation of shallow tunnels in close proximity to existing structures and utilities. For example, along the Crossrail project in London more than 1,200 structures are located within a possible influence area of the tunnel construction (Torp-Petersen and Black 2001). The assessment of building damage plays a vital role throughout the planning, design and construction stage of urban tunneling projects. However, while predictions of tunneling-induced deformations in the greenfield can generally be made with some confidence, much uncertainty exists about how structures interact with ground movements arising from tunnel construction."

Jan 1, 2016

By Shinji Sassa, Naoki Takahashi, Eiji Kohama, Wakaki Tsuda, Hidenori Takahashi, Ikuo Towhata, Yoshiyuki Morikawa

"Abstract Deep mixing method has been employed increasingly in recent years as a countermeasure against subsoil liquefaction. Column-type solidification, however, has been thought to have little effect as a liquefaction countermeasure, because the shear deformation of unimproved soil between the columns cannot be reduced. In recent years, experimental results have been reported that imply that solidified columns can reduce the shear deformation of unimproved soil around them. A new arrangement has been proposed to mitigate lateral flow induced by liquefaction. In this study, a series of dynamic centrifuge model tests was conducted to verify the lateral flow resistance of stabilized columns. The results indicate that stabilized columns can reduce the lateral flow of liquefied ground if the column displacement and the column head rotation are restricted. This paper concludes that it is important to restrict the displacement and the rotation of the column head by surface improvement to mitigate the lateral flow of liquefied ground.INTRODUCTIONDeep mixing method has been employed increasingly in recent years as a countermeasure against subsoil liquefaction. The solidified body formed by the deep mixing method is usually block or lattice shape, composed of solidified columns that overlap each other horizontally. Lattice-type solidification has been shown to be effective as a liquefaction countermeasure despite the presence of unimproved soil inside the lattice wall, because the shear deformation of the interior soil is restrained by the wall (Suzuki et al., 1989). On the other hand, it has been thought that column-type solidification cannot reduce shear deformation of unimproved soil around columns, because the displacement of a solidified column is less restricted than that of a lattice wall. Column-type solidification has been reported to have little effect as a liquefaction countermeasure, but to be superior in terms of construction cost and applicability around existing underground structures (Koga et al., 1986). However, there are experimental results implying that solidified columns have reduced the shear deformation of unimproved soil and mitigated its liquefaction (Yasuda et al., 2003; Tanaka et al., 2003). Yamamoto et al. (2006) conducted dynamic analyses of ground improved with lattice- and column-type solidification. Their results showed that column-type solidification with an improvement ratio of more than 35% reduces excess pore water pressure generated by earthquakes. Furthermore, the new column arrangement shown in Figure 1(a) has been proposed to mitigate lateral flow induced by liquefaction. It was developed and has been verified using dynamic model testing in a 1 g field (Takahashi et al., 2010a; 2010b; 2013; Towhata et al., 2010). The stabilized columns in this configuration interrupt lateral flow in any direction, unlike those placed in square and triangular arrangements."

Jan 1, 2014

By André R. Laplante

"This presentation reviews three continuous centrifuge separators, the Falcon-C, Kelsey Jig and Multi-Gravity Separator, two units with possible synergies with centrifuges, the In-Line Pressure Jig and InLine Leach Reactor, and two centrifuge prototypes, the continuous Knelson and the Altair Jig. Typical applications, potential problems, promising synergies and general concentration mechanisms are discussed. A general discussion on the sources of information, the nature of the fluidization water flow, test work for potential centrifuge separations and the early life cycle of new technology, using centrifuge separators as an example, follows. ResumeCette présentation fait le point sur trois appareils de séparation centrifuge, le Falcon-C, bac oscillant Kelsey et Multi-Gravity Separator; deux appareils qui présentent des synergies possibles avec les centrifuges, le bac oscillant In-Line Pressure Jig et le système InLine Leach Reactor; et deux prototypes centrifuges, le Knelson continu et le bac oscillant Altair. On y présente des applications typiques, les problèmes d’opération les plus usuels, les synergies les plus intéressantes. On discute également des sources d’information disponibles pour le minérallurgiste, de l’impact du mode d’ addition de l’eau de fluidisation, de la démarche expérimentale a faire avant d’installer un centrifuge, et du cycle de développement de nouveaux équipements, en utilisant les centrifuges comme exemple.IntroductionGravity separation has undergone a renewal in the past 20 years, much of it attributed to centrifuge units. The semi-batch Knelson Concentrator has probably received the most exposure, but it is rather because of the shear number of units sold than the width and breath of its applicability. It excels at recovery very dense minerals in very small concentrations, and has become a workhorse of the gold industry. Falcon’s Super-Bowl comes a distant second, with very similar applications. A number of copycats are available, and are generically identified as “Knelsons.” This presentation will not address these units explicitly, but as possible synergies."

Jan 1, 2000

By Scott Rodibaugh

El presente trabajo describe las aplicaciones representativas de la PPC (pressure-powered centrifugue) en minería, diseño básico, función y la experiencia de aplicación de OEM de motores. Asimismo se detallará ejemplos de desempeño de campo de la PPC como experiencias en un sistema hidráulico de camión minero, un motor diésel de camión minero y una trituradora de mineral que lleva el circuito de lubricación. De otro lado, se abordan los métodos de análisis de laboratorio para detectar los rasgos clave del fluido y evaluar la condición del contaminante.

Feb 1, 2017

By JOHN H. HUDSON

Ceramic clays of the Prairie Provinces range in age from Lower Cretaceous to Pleistocene and Recent. Two significant ceramic clay horizons are the Paleocene Willo wbunch Member of the Ravenscrag Formation in Southern Saskatchewan and the Upper Cretaceous Whitemud Formation, which is found in Saskatchewan and Alberta. The Willowbunch Member is worked at one locale in Saskatchewan; the Whitemud Formation is worked at several locales in Saskatchewan and Alberta. Bentonite operations are found at Morden in Manitoba, Rosalind and Onoway in Alberta, and Wilcox in Saskatchewan.

Jan 1, 1984

By LUKE O. LINDOE

A major clay products industry in the Medicine Hat area since before 1910 has maintained a continued interest in the clays of the Cypress Hills. For the first forty years the materials used were local red-burning Cretaceous and Pleistocene clays and sands and high-quality stoneware clays of the Whitemud Formation at Eastend, Saskatchewan. Recently a much broader spectrum of raw materials has been brought into use. Including the exposures of the Eagle Butte structure, the Cypress Hills present a 1200 m section of clay-like sediments. Of this 1200 m about 94 per cent, the high montmorillonite shales of the Upper Cretaceous, can be considered useless, or nearly so; the remaining six per cent, all fresh-water beds, presents a wide variety of potentially useful materials. The development of these clay resources is complicated by deep surface creep on the south flank of the Cypress Hills, by largescale slumping on the north flank and by a structural complex in the Eagle Butte area.

Jan 1, 1984

By D. A. Garland, A. D. Jackson

"Alanx ceramic/metal composites are proprietary products developed by Lanxide Corporation who joined with Alcan to form Alanx Products L.P. in 1988. Alanx ceramic/metal composites are composed of silicon carbide in a combined alumina and metallic aluminum matrix. In laboratory slurry wear tests conducted by Alanx ceramic/metal composites have shown to perform well against other wear resistant materials. At the Kidd Creek Concentrator Alanx CG896 ceramic/metal composite was tested in two pumping applications, the primary cyclone feed pumps and the filter feed pumps. In both instances the wear rates of the parts made of Alanx CG896 were far less than the gum rubber parts traditionally used. As of year to date September 1992 the unit cost to repair primary cyclone pump parts has dropped 58% from 1991 figures. For the filter feed pumps the unit cost to maintain the pumps has dropped by 33% as compared to 1990 figures. The total savings represented by implementation of Alanx wear parts, based on projected year end unit costs for 1992, as compared to 1991 costs for primary cyclone feed pumps and 1990 figures for filter feed pumps, is $166,753. INTRODUCTIONAt the Kidd Creek Concentrator the cost to maintain the primary cyclone feed pumps and the filter feed pumps was a constant concern. Rubber wear part consumption was quite high and the manpower required was considerable. For 1991 the total cost to maintain five primary cyclone pumps was $244,062. The cost to maintain the filter feed pumps in 1990 was $72,076. A wear material was needed that would increase the time between repairs and that would increase the reliability of these pumps between scheduled shut downs."

Jan 1, 1993

By Gary K. Elliott

Many industrial processes generate hot waste gases which contain particulate pollutants. Conventional clean-up techniques suffer limitations either because collection efficiency is low or because the gas must be cooled before treatment. thereby increasing costs and preventing energy recovery. The application of increasingly stringent environmental legislation to the non-ferrous metallurgical industry is presently illustrating these conventional technology limitations. Low density ceramic media allow filtration to ta,ke place at 'high temperatures and are now rapidly becoming accepted In many industries. This paper reviews experiences with a proprietary low density ceramic filter element. CerafH. It includes consideration of the structure, composition. typical operating and case studies with particular reference to non-ferrous metallurgical furnace applications.

Jan 1, 1992

By Gary K. Elliott

Many industrial processes generate hot waste gases which contain particulate pollutants. Conventional clean-up techniques suffer limitations either because collection efficiency is low or because the gas must be cooled before treatment. thereby increasing costs and preventing energy recovery. The application of increasingly stringent environmental legislation to the non- ferrous metallurgical industry Is presently illustrating these conventional technology limitations. Low density ceramic media allow filtration to take place at high temperatures and are now rapidly becoming accepted in many industries. This paper reviews experiences with a proprietary low density ceramic filter element, Cerafill. It includes consideration of the structure, composition. typical operating and case studies with particular reference to non-ferrous metallurgical furnace applications.

Jan 1, 1992

By J G. Brady

This paper discusses the ceramic products used in the construction industry in Canada, as well as the main raw materials used in their manufacture. The products include the! following: (1) clay prorlucts -such as facing brick (glazed and unglazed), common brick, facing tile (glazed and un-glazed), terra cotta, load-bearing tile, non-load-bearing tile, structural clay floor tile, quarry tile, drain tile, sew-er pipe, conduits .and flue liners -which are made mainly from domes-tic common clays and shales and from domestic or imported stoneware clays and low-grade fire clays; (2) floor and wall tiles of the whiteware type, which are produced from ingredients such as kaolin, ball clay, feldspar, nepheline syenite, talc, pvro-phyllite and wollastonite; (3) glass products -the major ones being sheet glass, plate glass and mineral wool (glass wool, and rock or slag wool) -which are made from such materials as silica sand, soda ash, salt cake, feldsspar, nepheline syenite, dolomitic limestone, high-calcium limestone. borax and (for rock and slag wool) various rocks or slags;

Jan 1, 1963

By B. M. Burchfiel

CALIFORNIA possesses such an abundance of ceramic materials other than clays, that she is quite independent of other states and foreign countries so far as these materials are concerned. Certain users import some feldspar, silica, and allied minerals, but they do so from choice and not necessity. Production is largely for home consumption, so the total volume of ceramic materials produced is comparatively small. Many small deposits of the materials here under discussion are worked by individuals, and their output sold to individual grinding companies or users. The data given here shall be confined to the larger deposits and developments because they give a truer picture of typical deposits, operations, and materials.

Jan 1, 1936

By Ann M. Hagni

"Ceramic matrix composites are inorganic materials that are particularly resistant to heat and abrasion. A magnesia (MgO) and aluminum nitride (AlN) based composite is formed by exposing a magnesia preform to a metallic alloy block in a nitrogen atmosphere at 950°C. The metallic alloy, which is composed primarily of aluminum, is wicked into the preform. Aluminum nitride matrix is grown between MgO particles as the wicked metallic aluminum reacts with nitrogen. Unused metallic alloy, remnant metallic alloy (carcass), and composite produced after 8 hours, 50 hours, and 225 hours of processing are characterized mineralogically. Reflected light microscopy, transmitted light microscopy, scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction techniques reveal that in addition to anhedral to euhedral AhNi, AbSbSr, and Al crystallizing in the metallic alloy carcass, AIN and (Al,Si)N have formed as well. Nitride rings and nodules in the carcass may hinder AIN growth in the composite. Fine-grained residual AhNi and AhShSr are dispersed throughout the composite matrix. The nitride matrix is composed of AIN and (Al,Si)N. Rim replacement of MgO by spine! occurs in the composite. Aluminum nitrides in the metallic carcass cathodoluminesce deep violet-blue, unlike non-luminescent AIN in the composite matrix. This distinction in cathodoluminescence suggests a different mode of formation for composite AIN than for carcass AIN. Phase interpretations and textural characterizations deduced from the implementation of sophisticated mineralogical techniques have contributed to the understanding, and will aid in the improvement, of MgO/ AlN-based ceramic matrix compositeprocessing."

Jan 1, 1999

By E. A. Chavarriaga, L. J. Jaramillo, O. J. Restrepo

"This paper presents the results of the manufacturing ceramic pigments with spinel structure, using methods of synthesis of low temperature. In this work we obtained spinel structures type by the methods of Self-combustion, Coprecipitation, Microemulsion, Gel citrate and Pechini. These methods become an attractive alternative to traditional method (ceramic method), since we can work at a lower temperature, reducing manufacturing costs, lower fuel consumption, less wear on equipment and other environmental and economic implications. Also it is possible to have control over features such as stoichiometry, morphology of the products, reaction times and structures. The products obtained by these routes will be used in the manufacture of ceramic pigments and characterized using different techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-VIS spectrophotometry.IntroductionSpinels are ternary oxides AB204, where A and B are cations occupying tetrahedral and octahedral positions respectively. These oxides exhibit interesting electrical, magnetic and catalytic properties [1-4], depending on its nature, charging and intrinsic distribution of ions [5].The most widely used method to prepare spinels has been through solid state reaction, which consists of mixed oxides at high temperatures [6, 7]. In the last years, there have been a strong tendency to use chemical routes for the synthesis of crystalline ceramic particles at low temperatures [8,9]. Unconventional methods currently employed for the synthesis of complex oxides are Gel citrate method, Pechini, Spontaneous combustion, Microemulsion and Coprecipitation. Pechini method [10, 11], based on polymeric precursors, does not require high temperatures and allows stoichiometric control for greater reproducibility. This method involves the formation of a polymeric resin between a metal quelate and polyhydroxy acid of alcohol by polyestirification.Coprecipitation is important for many environmental problems related to water resources, including acid mine drainage, migration of radionuclides in waste repositories dirty, transport of contaminant metals in the industry, metal concentrations in aqueous systems and the technology of wastewater treatment. The coprecipitation process can vary in each case; the partition in the solid phase can be carried out by surface adsorption, ion exchange, surface precipitation, occlusion and formation of solid solution. The formation of solid solution is the result of structural incorporation of the marker in structural support sites resulting in a minor component in the solid solution with the host phase that has a very low solubility of pure solid [12]. Synthesis by gel citrate method allows the use of a route to obtain ceramic pigments from a very simple experimental system in which the stoichiometric control, the size and shape of the particles and the purity of the phases obtained can be controlled more accurately [13]."

Jan 1, 2012

By Lane Mitchell

A ceramic product or processed material is a solid composed of materials which have been subjected to heat above 875°F. The raw materials, which are blended together (or in some cases used singly), are selected and utilized for various reasons such as ease of fabrication, aid to processing, to yield desired properties after processing, lack or controllable degree of toxicity or hazard, availability, cost, and perhaps other considerations. Almost all solid inorganic, some organic, and some liquid and gaseous materials have the potential to be used individually in some ceramic product. There are several fundamental functions to be fulfilled in every ceramic product and a number of secondary functions are desirable in specified products. These functions are generally met by the most widely occurring minerals and rocks of the earth and their debris. This fact characterizes ceramics as a field utilizing the raw materials most available to man. Of course, specified products utilize synthetics, organics, and rare inorganics to produce desired results. Any solid nonmetallic product processed by subjection to temperature above a red heat may be called a ceramic product. Widely used construction materials and units, domestic utensils and units, industrial parts to facilitate manufacture, technical components, and aesthetic creations are very often of a ceramic nature because of the durability, inertness, hardness, ease of fabrication, cost, and availability of the ingredients. Often, organics or metals cannot meet desired specifications for some of these products. The rocks and minerals and mineral debris of the earth are largely siliceous. Oxygen and silicon comprise roughly 75% of the earth's crust with aluminum, iron, calcium, and the alkalies following in abundance. Silica ( SiO, ) and silicates can be melted to form glasses. Alumina (A1,0,), present in a mineral com- pound, gives greater durability, hardness, and strength, but lessens the glass-forming property. Iron, calcium, and the other alkalies flux silica and reduce melting points. Thus, sand, which is generally almost pure SiO,, and clay, which is generally hydrated alumina silicate, are the most widely used of all ceramic raw materials-principally because of the glass-forming propensities of silicates. In ceramic formulations, clay is generally a refractory filler or skeletal material, having in the raw state a plasticity derived from its colloidal grain size and its water-loving nature. On the other hand, silica sand is a glass former or nonplastic filler. Clay and silica sand in pure forms are quite refractory, i.e., not easily melted. Clay, although siliceous, is less of a glass former than pure silica and is more refractory. Natural contaminants, such as iron oxide or limestone, adulterate many clays and some sands. These contaminants act as fluxes and reduce the fusion points of the mineral or blends. Glass is made from silica sand by fluxing the sand with strong bases, usually soda ash and limestone. Red building bricks are hard and durable because the sand and clay have been partially fused with help of natural iron oxide serving as a flux. The iron oxide per- forms a dual function, serving as a pigment as well as a flux. In a blend of clay and sand and iron oxide, the sand is more susceptible to fusion than is the clay. Although silica sand and clay are the most widely used raw materials in most ceramic products, many other minerals, and some non- minerals are utilized in products where these materials can produce or aid in achieving desired results. Limestone and dolomite, feldspars, pigmentary minerals, refractory oxides or carbides, and special property producers can

Jan 1, 1975

By Lane Mitchell

A ceramic product or processed material is a solid composed of materials which have been subjected to heat above 468.3°C (875°F). The raw materials, which are blended together (or in some cases used singly), are selected and utilized for various reasons such as ease of fabrication, aid to processing, to yield desired properties after processing, lack or controllable degree of toxicity or hazard, availability, cost, and perhaps other considerations. Almost all solid inorganic, some organic, and some liquid and gaseous materials have the potential to be used individually in some ceramic product. There are several fundamental functions to be fulfilled in every ceramic product and a number of secondary functions are desirable in specified products. These functions are generally met by the most widely occurring minerals and rocks of the earth and their debris. This fact characterizes ceramics as a field utilizing the raw materials most available to man. Of course, specified products utilize synthetics, organics, and rare inorganics to produce desired results. Any solid nonmetallic product processed by subjection to temperature above a red heat may be called a ceramic product. Widely used construction materials and units, domestic utensils and units, industrial parts to facilitate manufacture, technical components, and aesthetic creations are very often of a ceramic nature because of their durability, inertness, hardness, ease of fabrication, cost, and availability of the ingredients. Often, organics or metals cannot meet desired specifications for some of these products. The rocks and minerals and mineral debris of the earth are largely siliceous. Oxygen and silicon comprise roughly 75% of the earth's crust with aluminum, iron, calcium, and the alkalies following in abundance. Silica (SiO2) and silicates can be melted to form glasses. Alumina (A1203), present in a mineral compound, gives greater durability, hardness, and strength, but lessens the glass-forming property. Iron, calcium, and the other alkalies flux silica and reduce melting points. Thus sand, which is generally almost pure SiO2, and clay, which is generally hydrated alumina silicate, are the most widely used of all ceramic raw materials-principally because of the glass-forming propensities of silicates. In ceramic formulations, clay is generally a refractory filler or skeletal material, having in the raw state a plasticity derived from its colloidal grain size and its water-loving nature. On the other hand, silica sand is a glass former or nonplastic filler. Clay and silica sand in pure forms are quite refractory, i.e., not easily melted. Clay, although siliceous, is less of a glass former than pure silica and is more refractory. Natural contaminants, such as iron oxide or limestone, adulterate many clays and some sands. These contaminants act as fluxes and reduce the fusion points of the mineral or blends. Glass is made from silica sand by fluxing the sand with strong bases, usually soda ash and limestone. Red building bricks are hard and durable because the sand and clay have been partially fused with help of natural iron oxide serving as a flux. The iron oxide performs a dual function, serving as a pigment as well as a flux. In a blend of clay and sand and iron oxide, the sand is more susceptible to fusion than is the clay. Although silica sand and clay are the most widely used raw materials in most ceramic products, many other minerals, and some nonminerals are utilized in products where these materials can produce or aid in achieving desired results. Limestone and dolomite, feldspars, pigmentary minerals, refractory oxides or carbides, and special property producers can

Jan 1, 1983

By R. S. Kalyoncu

Materials demands by the advancing process technologies, desire for higher performance and durability, and improved efficiency in combustion processes, such as applications in heat engines, heat exchanges, and batteries have added to the driving force fueling R&D efforts for the development of components with the combined characteristics of metals and non-metals. These new materials involve refined and specialized microstructures that can lead to improvements in the performance characteristics and durability new technological applications require. Fabrication and sintering methods, once believed to be sufficient, alone, have been found to be inadequate in the manufacture of such advanced components. Realization of the importance of the starting powders has led to efforts to produce materials of ultrahigh purity and ultrafine particle size with very narrow particle size distributions. Such powder characteristics are essential for the fabrication of components with high density and with the desired mechanical, electrical, or magnetic properties called for by the specific application. Novel ultrafine and ultrapure powder preparation techniques are discussed and effects of impurities on the powder characteristics, particle size and morphology, sintering behavior and properties of the finished product are elucidated.

Jan 1, 1992