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By Chinmay Shingote, Robert Visintainer, Renjie Ke, Jaikrishnan R. Kadambi, John Furlan

Hydrocyclone separators are widely used in various industrial applications in the oil and mining industries to sort, classify, and separate solid particles or liquid droplets within liquid suspensions, which are considered to be multiphase systems. Numerous valuable studies have been conducted in recent years to investigate the flow fields inside hydrocyclones. However, much of the information regarding the performance of cyclones in the literature has limitations and much of it cannot be considered as completely applicable to most real-world applications; many of the studies investigated the flow fields within extremely simplified hydraulic designs that are not representative of the complex geometries or large sizes which are typical in industry. Therefore, in this study, the two-phase flow system inside the actual hydraulic geometry of a milling circuit hydrocyclone is explored with the aid of both computational and experimental techniques (particle image velocimetry (PIV)). More specifically, the flow field with an air core has been investigated. In addition, the air-liquid two phases flow in a hydrocyclone might cause some challenges on both the computational and experimental sides. Two turbulence models are utilized in the numerical calculations: the Reynolds stress model and large eddy simulation. The computational studies are mainly focused on the local flow behavior and the prediction of the dimensions and shape of the air core. Different section planes of hydrocyclone are selected as planes of interest and divided into several fields of view (FOV) for PIV measurements. Two-dimensional experimental velocity vector maps are obtained in each of the fields of view. The computational results are validated globally using pressure and flow rate readings at the boundaries and locally by comparison to the PIV velocity vector maps and profiles.

By J. R. Kadambi, C. Shingote, J. Furlan, R. Ke

"Hydrocyclone separators are widely used in various industrial applications in the oil and mining industries to sort, classify and separate solid particles or liquid droplets within liquid suspensions, which are considered to be multi-phase systems. Numerous valuable studies have been conducted in recent years to investigate the flow fields inside hydrocyclones. However, much of the information regarding the performance of cyclones in the literature has limitations, based in some part on the respective current-available theoretical models, and much of it cannot be considered as completely applicable to most real-world applications; many of the studies investigated the flow fields within extremely simplified hydraulic designs that are not representative of the complex geometries or large sizes which are typical in industry. Therefore, in this study, the two phase flow system inside the actual hydraulic geometry of a milling circuit hydrocyclone was explored with the aid of both computational and experimental techniques (Particle Image Velocimetry). In this study, the flow field with an air core has been investigated; in essence, the research was a two-phase problem, which caused some challenges on both the computational and experimental sides. Two turbulence models were used in the numerical calculations: the Reynolds Stress Model and Large Eddy Simulation. The computational studies are mainly focused on the prediction of the dimensions and shape of the air core. Different section planes of the hydrocyclone were selected as planes of interest and then were divided into several fields of view (FOV) for PIV measurements. Two dimensional experimental velocity vector maps were obtained in each of the fields of view. The computational results were validated globally using pressure and flow rate readings at the boundaries and locally by comparison to the PIV velocity vector maps and profiles. Keywords: Computational fluid dynamics (CFD); Hydrocyclone; Particle image velocimetry (PIV); Reynolds Stress Model (RSM); Large Eddy Simulation (LES). INTRODUCTION A hydrocyclone is a device used to separate a solid-liquid, liquid-liquid, solid-gas, or liquid-gas suspensions into at least two separate density or particle size components. Hence, the flow field of the hydrocyclone is generally considered a multi-phases flow system. Application of hydrocyclones have been used in numerous industries including oil, drilling, metal working, and mineral processing since 1891, when E. Bretney obtained the first patent for the predecessor design of all contemporary hydrocyclones. A modern hydrocyclone typically consists a cylindrical section at the top where the liquid is being fed tangentially, and a conical chamber attached to the bottom of the cylindrical section, as shown in Figure 1. The characteristics of the feed stream that is injected into the cylindrical chamber play a significant role in hydrocyclone operation. The inlet is tangential relative to the cylindrical chamber and hence causes a centripetal force in the flow field which is considered as the primary separation mechanism."

Jan 1, 2017

By Xin Wang, He Shao, Wenpu Li, Yiyi Zheng, Xi Chen, Yurong Gao

This study utilized experimental and numerical simulation methods to investigate and analyze the atomization characteristics of three internal air–water mixed atomizers under different operating conditions. By comparing the research results, the effective dust control working parameters for the application of the selected atomizer in the engineering field were determined. Firstly, the atomization characteristics of the three atomizers were studied using a customized experimental system. The results indicated that nozzle 2 had a wide atomization range, a small atomization distance, and small droplet size; nozzle 3 had a narrow atomization range, large droplet size, and fast atomization speed; and nozzle 1 not only had a large atomization range but also could produce droplets of dry mist size with fast atomization speed, meeting the dust reduction requirements of the Majiliang Coal Preparation Plant. Secondly, Fluent software was used to simulate the atomization process and particle size distribution of the three internal mixed atomizers, determining the working conditions of the atomizers, the required number of atomizers, and the application angle of the atomizers in the internal mixed dust removal system. Finally, the atomized dust control system was applied on-site, achieving a total dust removal efficiency of 90.72% and a respirable dust removal efficiency of 89.75%.

Mar 9, 2024

By S Sineva, E Jak, M Shevchenko, D Shishin

This study represents a part of comprehensive research aimed at integrating nickel into a thermodynamic database constantly developed at Pyrosearch. The behaviour of Ni in calcium-ferrite slags is considered. An integrated approach combining experimental and thermodynamic modelling methods has been employed to predict phase equilibria in the NiO-CaO-FeO-Fe2O3 system under oxidising conditions and in equilibrium with the metal FeNi phase. The compositions of liquid slags and coexisting solid solutions have been determined through the analysis of equilibrated and quenched samples by electron probe microanalysis technique (EPMA). The research results are presented in the form of liquidus projections on the corresponding phase diagrams, considering both oxidising and reducing conditions. The solubility of Ni in spinel, dicalcium ferrite and calcium oxide as well as solubility of Fe and Ca in Ni monoxide, have been examined under several atmospheric conditions. Additionally, the compositions of the NiO-FeO monoxide in equilibrium with metal phase have been studied. The experimental data not only support the outcomes of thermodynamic modelling but also validate the parameters of the applied thermodynamic models, thus confirming the reliability and accuracy of the integrated approach.

Aug 21, 2024

By M. Faure

The experiment with backfill at Harmony was mainly an attempt to improve the ground conditions in a particularly tricky section of the mine. A deslimed tailings system was selected for financial reasons, ease of installation, ease of operation and its low level of mechanization. The design of the system has three aspects: firstly, to define the parameters of the backfill material itself; secondly, to design a reliable plant which could consistently produce the desired material in sufficient quantities; and, thirdly, to design a fill distribution system for maximum reliability in the shaft, minimum pipe line velocity, pressure and cost in the horizontal sections and consistency and reliability at the delivery end. The system was successfully constructed and commissioned in a short space of time at a relatively low cost. It has now reached its full potential, and very encouraging results have been achieved with regard to cost savings, ground conditions, ventilation and accident statistics.

Jan 1, 1988

By F. C. Langenberg

IT is the purpose of this paper to present a limited amount of experimental data obtained on the Charpy impact machine. Several concrete examples will be given showing the relation existing between the results obtained upon the Charpy impact machine and the behavior of the parts tested when in service. Although it is pointed out by G. Charpy and A. Cornu-Thenard1 that it is first necessary to determine a satisfactory working process before studying the correlation between the results of these tests and the behavior of the parts tested in service, this ideal course cannot be strictly adhered to. If a certain part repeatedly fails in service and the available tests give no indication of its cause, advantage must be taken of any possible means that will solve the problem; therefore, even though the reliability of the results obtained by the Charpy impact machine have been questioned by many, it was necessary to use this instrument without giving careful consideration to its possible sources of error. It would seem that the conclusions arrived at by Charpy and Cornu-Thénard justify the assumption that the precision obtained by this machine is comparable to that obtained by, the other more common forms of testing. The second general conclusion arrived at by them, namely, that the impact test upon notching does not offer any direct correlation to the ordinary tests, is also borne out by many hundred determinations made in the laboratories at Watertown Arsenal. This statement, however, should be qualified as follows: Other ordinary tests include the static tensile test from bars taken in a longitudinal .direction and the Brinell hardness. The author agrees that no law is yet known for the computation of the energy absorbed in the rupture of bars of the same material but of different dimensions. Although Charpy and Cornu-Thénard do not refer in their valuable article to the use of the Charpy machine in industrial practice, it should be stated that this instrument has been in constant use in the laboratory at Watertown Arsenal for several

Jan 8, 1919

By S. J. Jung

Determining the correct combination of mix components and water for high-density paste backfills with the transport and deposition properties necessary in a mining operation is a difficult task. Rheologic properties cannot be determined without conducting full-scale pumping tests, and data from existing tests are very limited. The following presents the findings of investigations undertaken to determine if paste backfill rheology can be determined using existing techniques and which mix and system variables have the greatest influence on transport pressure loss. Data from lab-oratory-scale pumping tests were used to produce a rheologic model of flow behavior for comparison, and a statistical analysis was conducted to determine the most significant factors affecting transport pressure loss.

Jan 1, 1994

By R. A. Campbell

The electric smelting of five lowgrade Canadian manganese ores has been investigated at the Mines Branch, Department of Mines and Technical Surveys, Ottawa. Ferromanganese, silkomanganese, and spiegeleisen were produced 1by special smelting processes from these ores since the latter were too low grade to be treated by conventional smelting methods. In one case the results were considered to be sufficiently promising to justify the construction of a pilot plant, by the Company concerned, for the further development of the process.

Jan 1, 1956

By Jeffery L. Kohler

The research and development of a pattern recognition system which can predict incipient failures and safety hazards in the mine power network is described. An examination of mine electrical safety hazards revealed they are often related to the electrical equipment down-time experienced on mine sections. Based on this, a method is proposed that can improve both production and safety, without compromising either. Equipment failure modes are examined to illustrate how the ultimate failure can be predicted for enough in advance to allow a convenient and safe repair, followed by a discussion of actual monitoring system performance. Finally, the paper is concluded by projections of the system's utility to industry.

Jan 1, 1977

By Vitor Orlando Ferreira

The efficiency of an apparatus which uses a forced lubrication system, as well as the useful life of its components, is strongly related to the degree of contamination of lubricating oil. The presence of contaminants and the degradation of the oil itself cause it to release substances that fouling of the wall of the pipes. The cleaning and dialysis of the oil pipes, besides prolonging the life of the lubricant reduces wear of the components. There are several methods of cleaning in pipes, the problem is that some have abrasive characteristics, which could damage some types pipes. Among the non-abrasive methods stand the Flushing and Air scouring. Flushing uses the lubricating oil which circulates in temperatures alternating and high speeds, for generating turbulence to perform washing. The Air scouring method uses oil and filtered compressed air, injected into pipe, to generating higher flow, causing the power supply unit with fluid can work with lower power consumption and higher speeds, removing fouling of the pipe. The objective of this research is to evaluate the Reynolds number to correlate with the efficiency of cleaning the pipe. The method applied was the Air scouring and it was verified that the qualitative effects may occur when compared to Flushing. After testing, it was found that the chosen method brings significant changes in flow, and this flow regime varies considerably increasing the Reynolds number.

Jul 31, 2018

By O. Salami, G. Xu

Fire accident is one of the most classic safety concerns in underground mines both in the USA and abroad. It may occur from pool fires due to leakages in hose or pipes, vehicle fires, or fires in tires and conveyor belts in the underground mines. It may also result from the storage of flammable materials such as gasoline, diesel, and explosives in the underground. When fire occurs in an underground mine, it releases heat, smoke, and other toxic gases such as carbon monoxide, and methane to the surrounding thereby making life unbearable to the miners. Furthermore, smoke greatly impact visibility in the underground which makes evacuation even more onerous and challenging. To this end, a thorough investigation of fire behavior and spread of toxic gases in a practical underground mine is imperative to develop a reliable emergency evacuation plan in an event of fire disaster in the underground mine. The objective of this study is to investigate temperature variation and CO spread along mine airways by conducting full-scale fire experiment in the underground mine. The results presented from this study are crucial to developing evacuation plans in underground mines. In addition, the findings from this study could be used to validate existing evacuation models.

Mar 2, 2022

By Frederick C. Trutt, Jeffery L. Kohler, Joseph Sottile

Condition-based maintenance (CBM) of industrial equipment is generally recognized as being the most cost-effective means for improving equipment availability. However, prerequisite to successful implementation of CBM is a reliable detector of failing components. One such detector, termed the effective negative-sequence impedance, had previously been identified as an indicator of induction motor stator winding degradation. However, a limitation of this detector is that it does not change in a predicable manner under certain motor operating conditions. This paper presents an experimental investigation of an improved technique for on-line detection of induction motor stator winding degradation. The paper begins with a brief description of the detectors, followed by a detailed description of the experimental setup, the experiments conducted, and results.

By Neel Gupta, Brijes Mishra

Coal mining activity disturbs the natural equilibrium of in situ stress state such that the induced stresses deform the surrounding rock mass. Although the installation of roof supports typically prevents rock deformation, rock mass failure may still occur in bolted roof. The erratic failure of rock mass after few days to months and years of excavation is the result of time-dependent deformation of roof rock under constant surrounding stresses. In the current research, the triaxial laboratory creep experiments proved that Marcellus shale exhibits time-dependent deformation under constant stress that was smaller than the failure strength. However, unlike conventional experimental results, the time-dependent deformation did not depend on the level of constant stress. The often-neglected initial state of specimens and intrinsic heterogeneity highly influenced the time-dependent failure of Marcellus shale.

Jul 27, 2021

By Adel M. Hanna, Ibrahim M. Mashhour

"Collapsible soil is known as one of the difficult soils, which possesses considerable strength when it is dry and significantly reduced when inundated. In practice, in case of a thick layer, pile foundations are often used to penetrate the collapsible soil to firm soil/rock strata. Inundation of collapsible soil is accompanied by a large and sudden settlement, which may significantly increase the negative skin friction and accordingly the drag loads on the pile’s shaft. Inundation may take place from the running surface-water or raising the groundwater. In case of surface water, the amount of settlement varies, depending on the extent of the wetted zone and the degree of saturation in the soil, while rising groundwater will produce full saturation in the ground and accordingly larger settlement.In the literature, there is lack of reports dealing with the prediction of the drag load on piles in collapsible soils subjected to inundation. This is due to the complexity of modeling collapsible soil analytically. Alternatively; the results of a sophisticated experimental investigation may guide the researcher to develop a model to predict the drag load on these piles.This paper presents the results of a small-scale experimental investigation tailored to measure the soil collapse during inundation and the associated drag load on an endbearing pile’s shaft. Based on the results of the present investigation, the effect of the soil collapse potential and the pressure acting on the soil during inundation on negative skin friction is presented.INTRODUCTIONCollapsible soil is a metastable material, traditionally defined as unsaturated soils that experiences a radical rearrangement of particles and significant reduction of volume upon wetting with or without loading (Bara 1976; Houston et al., 1988). A wide range of soils fall into the category of collapsible soil, including naturally existing types of soils such as: Alluvial flood plains, mud flows, residual soils, colluvial deposits, fans, aeolian or wind-blow deposits sands and silts (loess), volcanic tuffs, gypsum, dispersive clays, loose cemented sands , sodium rich montmorillonite clays (Clemence and Finbarr 1981).Soil wetting and soil saturation may take place as a result of urbanization or natural causes, such as: groundwater level rise, landscape irrigation, broken water pipelines or sewer lines, poor surface drainage, groundwater recharge, cut/fill construction, and moisture increase due to capillary rise. The severity of the outcome depends heavily on the so called collapse potential of the soil, which depends mainly on; soil type, compaction effort, initial water content and stress level at soaking (Houston and Houston, 1997; Ayadat and Hanna, 2007)."

Jan 1, 2015

By Yong Yuan, Wenhao Xiao, Luc Taerwe

"The static shear stiffness of an immersion joint subjected to combined compression and shear forces is investigated by experiments in a test set-up. To explore the performance of the immersion joint, the compression-shear loads, which are applied on a specimen according to test protocol, are determined based on real design situation. In this test, the main focus is on the steel shear keys and the rubber sealing. For the applied loading schemes, different levels of axial force, corresponding to the water depth of the joint, are considered as well as the changing amplitudes of the shear force. The force-displacement curve is obtained and the hysteresis is observed during the whole test. The joint‘s static shear stiffness is calculated, showing to increase linearly with respect to the magnitude of the axial force. Moreover, it is found that the rubber sealing has a significant influence on the shear behavior of the joint. INTRODUCTION An immersion joint is the connecting part between two adjacent elements of an immersed tunnel. Compared to that of the bulk elements, the stiffness of the immersion joint is relatively small. When it is subjected to shear actions, whether resulting from vertical foundation settlement or horizontal earthquake movements, shear-resistance of the joint is the main concern for a safe and reliable water-proof design. A flexible immersion joint, which normally consists of a rubber seal and shear keys installed at an element end is a common solution in practice. The way in which the shear keys and the rubber seal behave in the joint together is of vital importance to a comprehensive understanding of the shear behavior of the joint. However, in literature very few experiments on the shear behavior of immersed joints are available although the flexible joints are applied in practice for more than 50 years already. O. Kiyomiya (2004) carried out both a 3-dimensional experiment and a finite element analysis for a new type of flexible joint referred to as the Crown Seal. The results indicated that this new type of joint can be applied in practice because of the effective reduction of lateral deformation. A linear model was found in the paper of Anastasopoulos et al. (2007) to describe the behavior of the shear keys, which consider that the stiffness of the shear keys tends to infinity. R.S. van Oorsouw (2008) discussed the shear capacity of concrete shear keys in segmental joints, by analyzing the influences of reinforcement and friction force between shear keys."

Jan 1, 2016

By A. Ghirian

Once cemented paste backfill (CPB) is transferred and placed into a mine stope, various coupled mechanisms will take place in the CPB material or structure. It will be subjected to strong coupled thermal (T), hydraulic (H), mechanical (M), and chemical (C) processes. Field studies have shown that the in-situ properties and performance of CPB differ from those obtained in the laboratory. This is mainly due to effects of the aforementioned coupled THMC mechanisms or processes. For a reliable and cost-effective design of a CPB structure and barricade, it is crucial to have a proper understanding of the THMC behaviour and evolution of CPB. Also, it is important to consider the effect of coupled THMC factors (e.g., self-weight pressure, drained/undrained and thermal conditions, pore pressure) while curing the CPB specimens. For this purpose, a laboratory setup is developed to investigate the properties of CPB materials. The setup is capable of curing CPB specimens (10 cm in diameter and 20 cm in height) under controlled vertical pressure (curing under stress) and various coupled THMC conditions, while continuously monitoring the evolution of total stress, pore pressure, suction, temperature, water drainage, chemical composition of the pore water and vertical deformation. Once the required curing time is achieved, the specimen can be extracted and then subjected to experimental tests of interest, such as those that determine the Unconfined Compressive Strength (UCS), shear strength parameters, saturated hydraulic conductivity and thermal properties. In this paper, we describe the developed experimental setup and present some results of the THMC behaviour of CPB under various curing stresses and rates of backfilling. The obtained results show that the THMC properties of CPB are strongly coupled due to several mechanisms, such as self-weight pressure, heat of hydration and suction development as a result of self-desiccation. The findings can assist researchers and practitioners to better understand THMC behaviour and thus design more cost-effective CPB structures.

Aug 1, 2013

By G. Laird, N. B. Gray, N. Lawson

"Photographic, video, laser, hot film and conductivity methods are used in the experimental study of gas-liquid flows. A discussion of their capabilities and limitations are given in this paper illustrating the wide range of phenomena that can be studied. Most of these methods are limited to physical models at room temperature with transparent fluids, although they can be extended for use with opaque and hot fluids. A number of these techniques have been used by the GKW CRC in studies on industrial plants and their usage is increasing although a number of technical difficulties still need to be overcome. An in-depth discussion of the laser doppler anemometry (LDA) and particle image velocimetry (PIV) methods is given with experimental results on the flow field of an air plume in water based on advanced development of the techniques and studies carried out at the GKW CRC. The LDA method provides high resolution data on the velocity profiles, while the PIV method provides an overall view of the complex flow structure occurring at the gas-liquid regions. These two methods complement each other in providing experimental data for validating numerical models and exploring the complexities of multi phase flows.IntroductionThe injection of gases into melts is an important operation in the metallurgical industry. It is used in converters, anode furnaces, blast furnaces, ladles, bath smelters, zinc fumers and many other smelting processes. In many of these processes, the gas is injected into a molten bath resulting in the formation of bubbles that promote reaction, mixing, alloying and heat transfer. The study of gas-liquid systems presents enormous challenges to the researcher due to the complexity of the mathematical and physical modelling which require innovative numerical and experimental skills."

Jan 1, 1996

By WenCai Li, Yong Ren, Shuai Niu, Xin Hong

"Temperature measurement is very important in metal smelting process. Many devices are used to realize non-contact temperature measurements. Compared to conventional thermocouple, infrared temperature measurement has it's unique advantages. However, using an infrared temperature measurement at the top of the furnace can not obtain the desired optical signal because of disturbance from slag layer, high-temperature gases and other effects. A real time thermometry system with dual-wavelength radiation was presented to get optical signal emitted from molten metal through bottom-blowing nozzle. Taking into account the advantages and disadvantages of bottom-blowing devices, a MHP (Multiple Hole Plug) bottom-blowing device was used, through which the optical signal was transferred to the infrared thermometer by use of optical fiber. After conversion and analysis in real-time, the result was displayed and recorded in computer. After calibration, it could be a good predictor of temperature trend in a metallurgical process. IntroductionAt the refining stage of steelmaking, in order to achieve predetermined chemical composition and temperature, high-temperature molten steel is refined in a furnace such as converter. Because the refining process involved with chemical components and reaction velocities in the furnace rely on the temperature of steel, it is necessary to know the temperature accurately in real time during the process. And temperature measurement is also helpful for the end-point judgment. The temperature in the refining process changes quickly, for instance, in a converter, 300t molten steel is processed in only about half an hour.At present, traditional way of temperature measurement is using a thermocouple probe mounted on a lifter called a sub-lance. The thermocouple is immersed in molten steel and its temperature is measured during the short period until the thermocouple is fused. Accurate and reliable temperature can be obtained by this method, but in consideration of the discontinuous measurement and the costs, missing the end-point temperature may sometimes occur.According to the above background, a method in which a temperature-sensing element such as a thermocouple is immersed directly in molten steel is not suitable for the continuous temperature measurement because materials having such stability are not available. Therefore, radiation thermometry is promising. There have been some reports on radiation thermometry through an observation nozzle through the bottom or side of a refining furnace [1, 2]."

Jan 1, 2014

By T Duff

This paper describes results from small scale tests conducted to determine the distribution of pressure on target plates when subjected to loading due to the detonation of a buried mine in various media. The tests are conducted by using saturated sand, dry sand, and water as the loading media. Different stand-off distances are investigated. Kolsky bars and pressure sensors are used to determine the free-field pressure - time profile of the output of the charge at any location on the vehicle bottom. For verification of the pressure results at certain distances, the specific impulse measured by utilizing different size round plates are employed. In order to investigate the loading mechanisms, high speed cameras are applied. The small-scale test results can be scaled to full scale by using verified scaling laws.

Jan 1, 2014

By C Zschiesche, alam, A Abadias Llamas, A K

An integrated experimental and thermodynamic modelling study of the phase equilibria in the FeOFeO1.5- SbO1.5-SiO2 system in equilibrium with liquid Sb and Sb-Ag metal has been undertaken to develop thermodynamic model of the Na-Si-Fe-O slag system with S-Sn-Sb-Pb-As minor elements based on the experimental investigation of the selected sub-systems. New experimental phase equilibria data at 575–1600°C were obtained for this system using high-temperature equilibration of synthetic mixtures with predetermined compositions in sealed silica ampoules, Fe3O4 basket in sealed silica ampoule, or Re foils, a rapid quenching technique, and electron probe X-ray microanalysis of the equilibrated phase compositions. Experimental results on phase equilibria in the Fe-Sb-Si-O+Sb metal system obtained helped to produce initial set of model parameters in the slag. The primary phase fields of quartz/tridymite/cristobalite (SiO2), 2 high-SiO2 immiscible liquids, olivine (Fe2SiO4), wustite (FeO1+x), spinel (Fe3O4), schafarzikite (FeSb2O4) and valentinite/ senarmontite (Sb2O3) were identified in the binary Sb2O3-FeO, Sb2O3-SiO2 and ternary FeO-Sb2O3- SiO2 systems. Further refinement, particularly the distribution of excess Gibbs energy among the ‘FeO’-Sb2O3-SiO2 and ‘FeO1.5’-Sb2O3-SiO2 interactions, required the study at more oxidising conditions. Oxygen potential was increased using an inert metal (Ag) rather than using the gas flow due to the high volatility of Sb-containing gaseous species. Liquid Ag-Sb alloys with low concentrations of Sb of a few percent were used. At these conditions, the concentration of AgO0.5 in slag was below 1 mol per cent, which had a small effect on observed phase equilibria in the system. In addition, important information on the solubility of silver in slags is produced, which can be valuable when treating electronic recycling materials or primary silver-containing ores through the Pb process. Two main areas were addressed: the spinel-tridymite boundary (40–70 per cent SiO2 in slag) and spinel liquidus near 15 per cent SiO2 in slag. This allowed to deconvolute the separate contributions of the FeO-Sb2O3(-SiO2) and Fe2O3-Sb2O3(-SiO2) systems.

Jun 17, 2024