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By Mahmut Altiner

Magnesium is listed as a key critical raw material in a report by the European Commission that evaluated raw materials based on supply risk versus economic importance [1]. It has extraordinary properties, such as nontoxicity, inertness, high melting point, stability, low weight, chemical resistance, electrical insulation, optical transparency, corrosion-resistant behavior and refractory nature. It is widely used in the areas of agriculture; the environment, for antibacterial and water-purification purposes; electronics; automotive; drug delivery; ceramics; construction, as filler in brick; and concrete production, in the forms of magnesium oxychloride and magnesium oxysulfate. Magnesium oxide (MgO) particles can be produced through the calcination of magnesite ore at different calcination conditions depending on the desired quality of the product, classified as fused (2,800 °C), dead-burned (>1,400 °C), hard-burned (1,000–1,400 °C), or light-burned MgO (700–1,000 °C) [2]. However, the global availability of magnesite ore is limited.

By Mahmut Altiner

This study aimed to produce magnesium oxide (MgO) particles with different properties from dolomite ore using an experimental procedure comprising four stages: sample preparation (S1), HCl leaching (S2), precipitation (S3), and calcination (S4). Three different base sources (NaOH, KOH, and NH4OH) were used as precipitant in the third stage to obtain magnesium hydroxide [Mg(OH)2] from a leachate solution, which was obtained in the second stage. Next, Mg(OH)2 particles generated by different alkali sources were calcined at various temperatures from 600–1000 °C for different durations (1–5 h). The effect of these base types on the properties of each product was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), atomic force microscopy (AFM), and wet chemical analyses. The experimental results indicated that each product was identified as periclase (MgO) mineral, which was produced with a specific surface area (SSA) of 4.49–44.54 m2 /g depending on the production conditions. The surface roughness of the MgO particles increased with increasing calcination temperature. SEM analyses showed that MgO particles produced at a temperature of 600 or 800 °C were amorphous, indicating that the process was not influenced by the base type, but MgO crystals were smooth when the calcination temperature was 1000 °C. Finally, it was determined from all experimental findings that MgO particles produced via the addition of NaOH have superior properties (such as higher SSA and lower surface roughness) compared with MgO particles produced with KOH or NH4OH as the alkali source. These properties led to great improvement of its usability in industry.

By Jinliang Zhang, Jian Pan, Deqing Zhu

"Limestone and burnt magnesite were added to vary MgO content and basicity (CaO/SiO2 ratio) of pellets for investigating their influences on the properties of specularite pellets. At fixed MgO content, the addition of limestone does not affect on the properties of green balls significantly. The addition of burnt magnesite has obvious influence on the quality of green balls, especially on the thermal shock temperature. Without burnt magnesite, the thermal shock temperatures are about 400°C, and, the thermal shock temperature increases to 600~630°C by adding burnt magnesite. For preheated pellets, when the burnt magnesite is added, the compressive strength will be decreased. For roasted pellets without burnt magnesite, the calcium additives can form binding phase of calcium-ferrite, and suitable liquid phase will improve recrystallization of hematite, but excessive liquid will destroy the structure of pellets, so the compressive strength of pellet increases firstly and then decreases. When adding burnt magnesite, the compressive strength will increase as the basicity increases. When the basicity is more than 0.2, the compressive strength of the pellets various MgO content and basicity is above 2500N/pellet and then MgO-bearing fluxes can be added to prepare pellets with good high temperature properties.IntroductionWith the rapid development of the steel industry in China, oxidized pellets, possessing good mechanical and metallurgical properties, are becoming indispensable burdens for blast furnace ironmaking [1-3]. However, this has resulted in the shortage of domestic iron concentrates, so many Chinese steel plants begin to use imported hematite concentrate to prepare pellets. Compared with magnetite pellets, the hematite pellets require high roasting temperature and narrow roasting temperature range (1300–1350°C) and possess low compressive strength [4,5].1"

Jan 1, 2012

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014

By Mark Jolly, Nasim Soleimanian

"During the last 20 years CFD (Computational Fluid Dynamics) has been used as a tool to aid furnace designers and manufacturers to improve energy efficiency and effectiveness of glass furnaces. However as the models are maturing the effect of feeding equipment used to push the raw material into the furnace has not been included in the process models. This paper investigates the effects of batch pattern in the melt space caused by charging equipment on the energy efficiency of the furnace focusing on the melting zone. A simple batch patterns sensitivity study has been performed using purpose built software (Glass Furnace Model-GFM). It is concluded that in order to further reduce the energy consumption of the furnace it is necessary to model the batch charging process in more detail to find more opportunities for improvement.Introduction Glass manufacturing is a conservative industry which applies to all the four major segments (float glass, container glass, fiberglass, and specialty glasses). Risks due to the high capital investment, very long service life of the furnaces, and the demand for high performance and quality from the outset translates into evolutionary progress rather than revolutionary. The main problem facing glass manufacturers are the financial cost of manufacture, its impact on the environment, and mounting pressure imposed by the authorities for greener manufacturing and reduction in emissions.The main energy intensive activities involved in continuous glass manufacturing are: the need for high temperature to create and maintain the viscous flow, homogenisation of glass melt (melt residence time), and maintaining the two to achieve continuous output of glass at the right quality. The high temperature and long duration of homogenisation has resulted in the design oflarge furnaces, which have high energy consumption, low specific performance, and high C02 emissions. As an example in the container glass sector the most efficient furnace has a specific primary energy consumption of 3.8 GJ /tonne of glass at a level of 50% cullet in the batch. Even very small improvements in efficiency by optimising operation would have a high impact [1-14]. Given the conservative nature of the industry and the costs involved in experimental data gathering, CFD modeling of the process has been used extensively during last two decades to not only improve our understanding of the process but also as a tool in predicting possible optimisation windows, e.g. Glass Furnace Model ( GFM), a commercially available piece of software that has been developed to optimise furnace operation."

Jan 1, 2013

By William Brinkman, Mark Jolly, Nasim Soleimanian, Karl Dearn, Oliver Brinkman

"Glass manufacturing is a heat intensive process. There is a direct correlation between the batch distribution techniques and the furnace energy consumption, productivity, and quality of the glass manufactured. All four major segments (float, container, fibre, and specialty glasses) would benefit from using an optimised batch distribution technique where possible. Oscillating batch chargers (OBC) have been in use since the early 70s, despite their superior batch shape, coverage, and in turn positive effects on the energy consumption and productivity of the furnace they are almost exclusively used in container glass manufacturing. The OBC’s main difference compared with other charging methods is its ability to directly influence the batch initial velocity. This paper reports on results achieved in CFD models (GFM) used to study effect of the machine on the overall energy consumption in the doghouse and the melt space.IntroductionGlass manufacturing can be divided to four major segments float glass, container glass, fiberglass, and specialty glasses. The financial cost of manufacture, its impact on the environment, lack of standardisation and mounting pressure imposed by the authorities for reduction in emissions means that the industry and its suppliers are utilising CFD modelling in order to tackle these challenges. The need for high temperature to create and maintain the viscous flow, homogenisation of the glass melt, and maintenance of the process to allow continuous output of glass of the right quality are the contributors to the energy intensive activities that are involved in continuous glass manufacturing. This in turn has resulted in design of large container glass furnaces which have high energy consumption, low specific performance, and high CO2 emissions where the most efficient furnaces in the container glass sector have a specific primary energy consumption of 3.8 GJ /tonne of glass at a level of 50% cullet in the batch making even very small improvements in efficiency by operation optimisation a value adding activity [1-14].The theoretical calculated energy required to melt glass is 2 to 3 times less than the energy actually used to melt glass as a result of glass melt passing a zone 5 to 8 times before leaving the tank.[8]. This causes contamination as the result of mixing between the completely molten glass free from bubbles returning to the batch area where there is freshly molten non-homogeneous glass, still containing very large numbers of bubbles and un-molten batch. At high temperature some components are dissolved rather than melted. Given that an un-molten batch is a good thermal insulator, it can be transported a long way into the furnace, increasing the need for homogenization which also increases the glass residence time of glass melt. This is why large unbroken strings of batch should be avoided, as should an overall blanket without gaps."

Jan 1, 2014

By Monica R. Garcia, Antonio Alberto S. Correia, Paulo J. Venda Oliveira

"The aim of this paper is to analyze the creep behavior of a Portuguese soft soil stabilized with binders in one-dimensional conditions, based on oedometer creep tests. The study focuses on the analysis of the effect of the binder content and binder type on the creep behavior of a stabilized soil. The results show that the best binder type for this soil, in terms of creep behavior, is composed of Portland cement and fly ash with a dry weight proportion of 75/25, as this promotes the development of secondary pozzolanic reactions. The results also show the decrease in the secondary compression index with the increment of the binder content, since it promotes an increase in the cementation bonds between soil particles. The general analysis of the results shows a clear dependence on C??and qu, until values of qu of 1500 kPa; after that this relationship is negligible.INTRODUCTIONThe geotechnical structures (such as embankments, dams and buildings) built on organic soils exhibit notable creep deformations, which increase the maintenance and exploitation costs and can even compromise their functioning. To attenuate the creep effects of the soft ground, some improvement techniques are frequently used, such as preloading or reinforcing the soil foundations with vertical rigid inclusions, like concrete piles, stone columns or deep mixing columns (DMCs). However, the installation of DMCs in the soft ground induces (via the arching effect) a transfer of stresses from the soft soil to the DMCs, which causes an increase in the creep settlement on the DMCs (Venda Oliveira et al. 2011).Notwithstanding the fact that the creep behavior of clays has been the object of several studies (Leroueil et al. 1985; Mesri and Castro 1987; among others), the study of the creep behavior of soil-binder admixtures has been practically ignored by the scientific community. The few studies on this theme have revealed that a stabilized soil’s creep behavior is dependent on: the type of binder (Venda Oliveira et al. 2013), the binder content (Correia 2011; Bobet et al. 2011; and Venda Oliveira et al. 2013), the stress level applied during the creep phase (Venda Oliveira et al. 2013), the organic matter content of the natural soil (Venda Oliveira et al. 2012; 2014), and the curing conditions (humidity, vertical stress applied during curing, and curing time) (Correia 2011; Venda Oliveira et al. 2012).The aim of this paper is to contribute to a better understanding of the creep behavior of a soil-binder admixture, by examining the results of oedometer creep tests. The study focuses on the analysis of the effect of the binder content and binder type on the creep behavior of a stabilized soil. Additionally, the creep behavior is correlated with the effective vertical yield stress and the unconfined compressive strength (UCS)."

Jan 1, 2015

By D. J. Sweet, B. Seymour, T. M. Emery, M. Armatys, J. P. Bourgeois, W. Johnson

The Spokane Mining Research Division (SMRD) of the National Institute for Occupational Safety and Health (NIOSH) has partnered with a narrow vein, hard rock underground mine to research the effects of the binder content on the elasticity and post-peak ductility of cemented hydraulic backfill (CHB). This is part of a larger study to enhance the long-term integrity of ground support in underground mines. As mining advances deeper and stresses increase, CHB mix designs will benefit if they can be modified to handle higher levels of strain which are induced by an increased stope closure, typically affected by a reduction in stope width and increased mining depth, or through dynamic loading resulting from a local seismic event. This portion of the research examined the impact of reductions in binder and their impact on Young’s modulus, peak strength, and post-peak ductility.

Mar 2, 2022

By C. Guo

The Mildred Lake Settling Basin (MLSB) is the largest disposal site for mature fine tailings (MFT) at the Syncrude Canada Ltd oil sands plant. Over the past years (since 1997), there has been a marked change in the consolidation behaviour of MFT in the MLSB, which is attributed to microbial activity. Methane-producing microorganisms, known as methanogens, have become very active, and large amounts of biogas (mainly methane) have been produced. In certain regions within the MLSB, gas bubbles are released to the water surface of the tailings pond. Continued field monitoring of the MLSB has provided convincing evidence of the rapid densification process (rapid water drainage from the tailings). This phenomenon contradicts the consolidation models for MFT developed over the past 20 years. The above phenomenon has also been reported at the oil sands tailings ponds operated by Suncor Energy Ltd. in Fort McMurray. This rapid densification has caused pumping challenges in the transfer of fine tailings from the Mildred Lake Settling Basin for the creation of composite tailings. The rapid densification of the MFT may also have potential positive effects in accelerating the reclamation of the oil sands fine tailings. A field and laboratory research program is underway to study the mechanism leading to the rapid densification phenomenon. Systematic field investigations were performed to determine the distribution and characteristics of the rapidly densified MFT. Gas bubble distribution on the water surface was mapped to determine the zones of different biological activities in the pond. These field investigations provided solid ground for further experimental and theoretical research. A number of small-scale column tests were carried out to observe the gas evolution and to measure the changes of some geotechnical parameters under different microbial activity. Also, a series of gassy MFT densification tests are being conducted to study the mechanism of the rapid densification of the MFT under microbiological activity. A review and discussion of the research program is given and some preliminary research results are presented in the paper.

Apr 1, 2005

By Lorenzo Reyes-Bozo, Ronaldo Herrera-Urbina, Pablo Higueras, Alex Godoy-Faúndez

"The copper mining industry in Chile and perhaps in other countries as well is faced with the challenge to implement the best practices in order to achieve a sustainable and more environment-friendly growth. Relationships between mining industry and society have been historically complex due to its environmental impacts. Whereas the ore grade has declined continuously, this has involved an intensive energy and water consumption thus increasing operational costs at different stages of the concentration process. In the case of copper sulphide ore concentration, froth flotation is the main technology used worldwide. The amount of the different chemical reagents used in flotation plants (i.e., collectors, depressants, frothers and modifiers) affects significantly production costs and has a negative effect on the environment as well. The objective of this research work was to evaluate the use of biosolids and their main components (i.e., glucose, proteins and humic substances) as more environment-friendly flotation collectors for chalcopyrite and molybdenite. For this purpose, microflotation tests were conducted in a modified Hallimond tube. In addition, FTIR and zeta potential experiments were performed to investigate the interaction of biosolids with these sulphide minerals. Biosolids and their main components may interact through physical and chemical ways due to different affinities with such sulphide minerals as chalcopyrite, pyrite and molybdenite, which are present in copper sulphide ores. In alkaline pHs, biosolids and their main components make the zeta potential of the sulphide minerals investigated more negative. These results may provide important information concerning the behavior of the main sulphide minerals in the concentration of copper sulphide ores at industrial scale, wherein mill processes could affect their surfaces properties. Therefore, biosolids and their main components may open an opportunity to be used in copper sulphide flotation plants to partially replace conventional reagents, which are more hazardous and less environment-friendly."

Jan 1, 2014

By A. W. Khair, M. Ahmad, L. D. Gehl

"This paper presents an analysis of the dynamics of bit wear on the productivity of the continuous miners. Two field surveys have been carried out. The first survey was to assess the impact of bit wear on productivity and production cost. The second survey was to study the wear characteristics of the cutting tool (i.e. magnitude, forms, and mechanisms of bit wear). Primary factors affecting bit wear is identified and laboratory experiments were carried out to study the effects of some of these primary factors on wear in detail. Results indicate that bit wear has a significant effect on the productivity of the continuous miners. Furthermore under the severe geologic conditions (i.e. cutting rock partings and roof and floor rocks) bit wear not only hampers the productivity, but also increases the production cost due to a higher number of bit consumption. This study also indicated that bit wear accelerates beyond 20% of the conical height loss which corresponds to 7% of the weight loss. This increase rate of wear is an indicative of higher abrasion between bit body and cutting material, resulting in a more dusty environment.IntroductionThe high demand for coal production has increased the need for mechanized coal cutting in underground coal mines. Continuous miners have been used in the United States of America for nearly four decades and now presently more than 2000 are in operation. Almost half of the underground coal production of the country is by continuous miners. Today, competition in the coal industry has increased, due mainly to market conditions and legal restrictions, thus placing an emphasis on production, efficiency, and safety. The use of continuous miners has resulted in the generation of respirable coal dust which causes black lung in mine workers. On the other hand, bit wear presents a serious problem as it affects productivity and economy.Much research in the put has been done on energy requirements and mechanism of energy dissipation for ideal rock fragmentation in the cutting process. Recently, dust hazards in underground coal mines as a result of coal cutting has been a great concern to mining engineers as well as environmentalist of the country. In past, much emphasize has been given to fragmentation mechanics (Khair et al, 1989), dust generation due to regrinding (Khair and Xu, 1991) and dust generation due to bit wear (Khair, Xu. and Ahmad, 1992). These studies concluded that dust concentration increased considerably after a bit weight loss of 7% and thereafter the bit should be replaced. Thus, legal restriction by the Mine Health and Safety Administration for the respirable dust concentration in underground might be a factor deciding the level or rate of production using continuous miners. While efforts in research are on reducing dust generation, it is also important and relevant to study bit wear in more detail.Bit wear is affected by three major groups of parameters: (1) machine operating parameters, (2) insitu conditions and (3) properties of rock. Again, past studies have shown that depth of cut, material of tool, position of water jet and velocity of the rotating drum are very important machine operating parameters. The content of the rock/coal material is important as bit wear is usually due to abrasion or adhesion. Diffusive wear becomes dominant only when the temperature exceeds the sensitive range i.e critical temperature. Mechanical tools have indicated that a rise in temperature is a function of drum velocity, properties of cutting material (rock or coal) and properties of tool. Bit wear due to chemical reaction and oxidation art almost negligible in coal cutting."

Nov 1, 1995

By A. W. Khair

This paper presents an analysis of the dynamics of bit wear on the productivity of the continuous miners. Two field surveys have been carried out. The first survey was to assess the impact of bit wear on productivity and production cost. The second survey was to study the wear characteristics of the cutting tool (i.e. magnitude, forms, and mechanisms of bit wear). Primary factors affecting bit wear is identified and laboratory experiments were carried out to study the effects of some of these primary factors on wear in detail. Results indicate that bit wear has a significant effect on the productivity of the continuous miners. Furthermore under the severe geologic conditions (i.e. cutting rock partings and roof and floor rocks) bit wear not only hampers the productivity, but also increases the production cost due to a higher number of bit consumption. This study also indicated that bit wear accelerates beyond 20% of the conical height loss which corresponds to 7% of the weight loss. This increase rate of wear is an indicative of higher abrasion between bit body and cutting material, resulting in a dustier environment.

Jan 1, 1993

By G. Titichoca

Modification of the blasting process considers that any increase in the energy consumption generates greater benefits if done in the later stages (associated with a larger decrease in energy consumption). Therefore, although the blasting cost is doubled, generating a greater proportion of fines in addition to a weaker ore (because with greater loads and appropriate distribution of explosives a greater number of internal cracks is generated), the reduction of the unit cost that occurs in the grinding stages (SAG and ball mills) generates a positive balance in the overall size reduction process. Codelco Chile, Division Andina, has developed an extensive experimental plan to evaluate the concept of blasting modification applying greater energy. This was implemented in two stages, each including a specific mine sector: La Union and Don Luis. This paper reviews the experience of implementing such blasting modifications at the La Union mine and its impact on the design concepts and the operation of the SAG mill plant

Jan 1, 2007

By P D. Katsabanis, S Kim

A number of small scale fragmentation tests have been conducted to analyze the effects of blasting effort on the grindability of granite, granodiorite, limestone and iron ore. Powder factors were modified, post-blast fragments were screened and drop weight tests were conducted on fragments of different sizes to deliver a variety of specific impact energies. The fragmentation from the drop weight tests has been analyzed to examine the effect of impact energy and powder factor on size reduction. A consistent effect of blasting on the various fractions of the fragmentation distribution has been obtained for all rocks used. The effect of powder factor on the impact fracturing of the rocks has been expressed in a convenient relationship between progeny size, impact energy and powder factor used in obtaining the primary fragmentation. It is clear that explosives consumption affects downstream size reduction; depending on the rock, the effect can be substantial at coarser final sizes but very small in the case of grinding to small final sizes. Differences from the expected trend can be attributed to changes in blast design. As an example, the effect of in-hole collision of detonation waves is analyzed.

Jan 1, 2011

By Rennie Kaunda, David Streeter, John Kemeny

This paper describes a field/laboratory study that was conducted in cooperation with a mine in Arizona. The primary purpose of the study was to investigate the effect of blasting energy on the crushability and grindability of the post-blast rock fragments. The crushability and grindability of the rock fragments were evaluated through laboratory comminution tests. A secondary purpose of the study was to investigate different laboratory methods for estimating the comminution properties of the rock fragments. In particular, a number of standard rock mechanics tests were conducted and compared with the comminution test results. Finally, the study was used to evaluate new technologies for estimating insitu rock mass strength and for assessing post-blast fragmentation. To estimate in-situ rock mass strength, the specific energy of drilling (SE) was calculated during blast hole drilling utilizing a continuous drill monitoring system. Post-blast fragmentation was estimated using the Split image processing system. Results from the study support the idea that increases in blast energy can enhance crushing and grinding. Also, several simple rock mechanics tests were found to correlate well with the results from standard comminution tests, which could prove to be useful in practice.

Jan 1, 2003

"Large scale open pit mining and quarrying operations dictate safe and reliable pit wall stability. The current approach of employing the particle velocity-scaled charge distance approach to estimate and minimize damage to residential structures is considered inadequate to protect rock slopes. This study utilizes close-in blasting vibration data as input to an advanced 2D numerical code to study its applicability to serve as a predictive tool in terms of blast-induced rock slope failure. Two tri-axial accelerometer stations, consisting of high-frequency and high-amplitude (20 kHz, 100g) sensors, located within ~100m of the blast, but at two different bench levels, were used to monitor a production blasting in a quarry. The production blast consisted of double-decked explosive loads in 155 mm (6 in) diameter holes, with an inter-deck delay of 42 ms, and each deck consisting of 130 kg (285 lb) of emulsionexplosive. The blasting vibration data obtained at the two bench levels were critically analyzed, and thevibration results served as input to the numerical model consisting of a single rock block with a 45 degree persistent joint plane but with specified strength properties, significantly different from that of the intact rock. The model was able to characterise progressive accumulation of damage in the form of micro-cracks along the joint surface as a function of the vibration load from successive explosive decks. The results showed that such a numerical model can serve as a very good diagnostic and predictive tool, when backed up by careful vibration monitoring and further supported by detailed slope monitoring."

Jan 1, 2017

By B Mohanty, A Siamaki, K Esmaeili

Large scale open pit mining and quarrying operations dictate safe and reliable pit wall stability. The current approach of employing the particle velocity-scaled charge distance approach to estimate and minimize damage to residential structures is considered inadequate to protect rock slopes. This study utilizes close-in blasting vibration data as input to an advanced 2D numerical code to study its applicability to serve as a predictive tool in terms of blast-induced rock slope failure. Two tri-axial accelerometer stations, consisting of high-frequency and high-amplitude (20 kHz, 100g) sensors, located within ~100m of the blast, but at two different bench levels, were used to monitor production blasts in a limestone quarry. The production blast consisted of double-decked explosive loads in 125 mm (5 in) diameter holes, with an inter-deck delay of 42 ms, and each deck consisting of 130 kg (285 lb) of emulsion explosive. The blasting vibration data obtained at the two bench levels were critically analyzed, and the vibration results served as input to the numerical model consisting of a single rock block with a 45 degree persistent joint plane but with specified strength properties, significantly different from that of the intact rock. The model was able to characterise progressive accumulation of damage in the form of microcracks along the joint surface as a function of the relatively low vibration load from successive explosive decks. The results showed that such a numerical model can serve as a very good diagnostic and predictive tool, when backed up by careful vibration monitoring and further supported by detailed slope monitoring.

Jan 1, 2017

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By S. Moussa

The formation of boron-doped nickel aluminides Ni3AI, (76 at. % Ni) from elemental powders by reaction synthesis using reactive sintering was studied. The process involves the mixing of elemental powders of nickel and aluminium with various wt % of boron up to 1 wt % boron. Nickel and Aluminium powders were mixed in the correct proportion to form the intended boron-doped nickel aluminide intermetallic. XRD, SEMI EDS, Image analysis and Archimedes principle; were used to study the effect of Boron addition on the final microstructure, bulk density, average grain size of as reactively-sintered nickel aluminides (boron-doped), compared with no boron addition. The results showed that at greater boron content than 0.3 wt %, a two-phase non-equilibrium microstructure of consisting of NiAI phase in NiJAI matrix was formed that have been primarily retained even after heat treatment for 5 hours at 1000 °C. Boron was present in solid-solution within both the NiAI and the Ni3AI (in greater amounts) phases.

Jan 1, 2001

By J. A. Bowers

THIS investigation of the effect of bottom shape and life on slag volume was carried out in two Lectromelt top-charge furnaces whose rated capacity is 1000 lb per hour. Unfortunately, just as the work [ ] was started, our steel tonnage was reduced approximately one half, therefore we did not accumulate enough data from which to draw any definite conclusions. Furthermore, the life of the linings in these furnaces was greatly decreased by intermittent operation, which was a further handicap in making a study of this kind. The weight of the heats from which the data were taken varied 1200 lb but all the information was corrected to the standard weight charge for these furnaces of 4500 lb. Almost all the heats were plain carbon; a few contained a small percentage of added copper.

Jan 1, 1947