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By C. Hsu

Underground coal gasification (UCG) is becoming more popular as the reserves of good quality, mineable coal are starting to diminish, and yet the global energy demand from coal is still increasing. The purpose of this research project was to investigate cavity formation within a coal block due to the combustion reactions in the context of UCG. The cavity plays a pivotal role in the UCG process, as it is essentially the gasification reactor. Cavity formation in an in situ gasification process using the forward combustion linking method (FCL) had been investigated, and a laboratory model was created to simulate the process. The experiment was performed by drilling a U-shaped tunnel into a coal block, which was then combusted internally with air that was fed through an injection hole. A heating element (at approximately 500°C) was used to supply the required heat for combustion at the base of the injection well. The coal blocks were analysed using micro-focus X-ray tomography. The tomography results showed that the coal tended to crack along the bedding plane after a short duration of combustion, due to either the formation of clinker or the expansion of swelling vitrinite along the horizontal tunnel. The deposit was thicker at the base of the injection well compared to the base of the production well; this may have been caused by the turbulence of the air flow and the relatively high oxygen concentration at the base of the injection well. A comparison of the results with work by Daggupati et al. (2010) showed the same trend, despite the slightly different methodology applied.

Jan 1, 2014

By İbrahim Çınar, Hakan Özşen

Mine workers in heavy and dangerous work are under several physical risk factors, for example temperature, humidity, noise, vibration, lighting and air velocity. Thermal comfort includes parameters such as air temperature, air humidity, air flow rate, radiant heat, metabolic rate and garment insulation. In this study, thermal comfort conditions were evaluated using thermal comfort indices defined as predicted mean vote (PMV) and predicted percentage dissatisfied (PPD) which were determined by measurements taken from an underground coal mine for approximately 100 days. Although the metabolic rate (light work) was kept at 2 met, it was found that predicted mean vote ranged between − 2.58 and 1.68. The predicted percentage dissatisfied index was found to reach 95%. According to the results, it can be seen that thermal comfort may have negative effects on occupational health and safety. The change in thermal comfort index values in the Soma Underground Coal Mine was investigated in detail and the reasons for the changes were determined. Furthermore, determining the optimal working environment for the mine workers was also an aim of this study.

By İbrahim Çınar, Hakan Özşen

Mine workers in heavy and dangerous work are under several physical risk factors, for example temperature, humidity, noise, vibration, lighting and air velocity. Thermal comfort includes parameters such as air temperature, air humidity, air flow rate, radiant heat, metabolic rate and garment insulation. In this study, thermal comfort conditions were evaluated using thermal comfort indices defined as predicted mean vote (PMV) and predicted percentage dissatisfied (PPD) which were determined by measurements taken from an underground coal mine for approximately 100 days. Although the metabolic rate (light work) was kept at 2 met, it was found that predicted mean vote ranged between − 2.58 and 1.68. The predicted percentage dissatisfied index was found to reach 95%. According to the results, it can be seen that thermal comfort may have negative effects on occupational health and safety. The change in thermal comfort index values in the Soma Underground Coal Mine was investigated in detail and the reasons for the changes were determined. Furthermore, determining the optimal working environment for the mine workers was also an aim of this study.

By Qiang Zhong, Bin Xu, Qian Li, Wei Gao, Yongbin Yang, Yaxuan Wang

Lump coal with high volatility is used for providing heat and reductive gas, and ensuring permeability in COREX. However, it is apt to be pulverized in transport and storage process. Therefore, comprehensive utilization of the pulverized coal to produce coal briquettes with appropriate binders is significant, among which the molasses binder cannot meet the technological requirements. In this paper, coal tar pitch binder and BJ additive were used in briquetting and carbonizing process of coal powder. The results showed that BJ effectively activated cold state cohesiveness of the pitch and make it bond the coke particles to a firm briquette at room temperature .Carbonizations of coal and coal tar pitch achieved obvious constriction and formed a carbonized skeleton. The drop resistance of wet briquettes reached over 50 times/1meter. When cured at 1000 °C for 1h under nitrogen atmosphere, the compressive strength of carbonized briquettes came to 6.43 Mpa.

Jan 1, 2016

By M. Hakan Morcali, Onuralp Yücel, Haldun Gürcan, Serdar Aktas, Semih Özbey, Alper Keskin

"This work presents a method for the precipitation of cobalt sulfate by alcohols, specifically ethanol and methanol. The effect of the initial concentration of cobalt, the volumetric ratio of alcohol to cobalt sulfate solution, the addition of sulfuric acid and ammonia, and the effects of common ions on the precipitation percentage were investigated. The performances of ethanol and methanol were compared in terms of the precipitation percentage of cobalt sulfate, and explanations for different performances are offered. In the sulfate-based solution, the alcohol was shown to displace water ligands from the first coordination sphere of the cobalt(II) cations, which led to the precipitation of the cobalt ions as cobalt sulfate heptahydrate. SEM analysis revealed that the particle sizes of the powders produced by this method are smaller than those of commercially available cobalt sulfate. The scientific literature contains no data on the solubility of cobalt sulfate in ethanol. In this study, the solubility product constant (Ksp) for cobalt sulfate was experimentally calculated to be approximately 1.15 x 10-5.IntroductionCobalt sulfate, which is one of the most important compounds of cobalt, is used in the electroplating and electrochemical industries. The addition of cobalt sulfate to nickel-plating baths makes the treated metals brighter, harder, smoother and more ductile (Armstrong et al., 1988). It is also used as a desiccant for lithographic inks, varnishes, paints and linoleum, as well as in storage batteries, e.g., nickel-cadmium (Ni-Cd) and lithium-ion (Li-ion) rechargeable batteries (Kang et al., 2010). Cobalt sulfate is employed as a coloring agent in ceramics, enamels and glazes to prevent discoloration and as a copigment for the decoration of porcelain. In addition, cobalt sulfate has been used in animal feeds as a mineral supplement (Budavari et al., 1996; Kirk and Othmer, 1999).In the past, brewers used cobalt sulfate to prolong the life of beer foam (Kesteloot et al., 1968). Ranchers have dosed livestock with cobalt sulfate or used fertilizer enriched with this mineral to ensure that their animals obtained sufficient amounts of the trace mineral, which is essential to the production of vitamin B12. Cobalt sulfate has also been used in veterinary medication to prevent and treat cobalt deficiency in ruminants, which causes a reduction in feed intake and body weight, accompanied by emaciation, anemia and debility.Cobalt sulfate is a water-soluble bivalent cobalt salt. Cobalt sulfate heptahydrate dehydrates entirely at 420° C, and the dehydrated salt forms red monoclinic crystals."

Jan 1, 2015

By Prasad Kopparthi, Narasimha Mangadoddy, Balraju Vadlakonda, A. K. Mukhurjee

"Column flotation (CF) is widely using equipment in mineral processing since many years. ERT technique facilitates non-invasive and nonintrusive visualization of different parameters in a column flotation. The hydrodynamic investigation of two-phase and three-phase are studied using electrical resistance tomography (ERT) coupled with pressure transducers in laboratory column flotation. Bubble size distribution, bubble rise velocity and gas and solids hold-up hydrodynamic parameters are extensively used for column flotation design and performance evaluation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas holdup and its radial distribution has been analyzed for both two-phase and three phase flows. Influence of solid particles on gas hold-up and its complete elucidation of dispersion in the column are assessed. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, were employed to explore the parameter study in two phase flow in column flotation.Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the `inside' flow behaviour of gas-liquid two-phase and gas–liquid–solid three-phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is being widely used in mineral processing industries in last few decades. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker and Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena et al., 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on the performance of column flotation (Finch and Dobby, 1991)."

Jan 1, 2018

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

Results of flotation process combined with atmospheric leaching and high pressure leaching for recovery of copper from low-grade silicate-copper ore have been presented in this study. The low-grade copper ore contains a small amount of copper (0.42 mass %), iron (4.6 mass %), and silicon (38.3 mass%) and among many other metals (Al, Ca, K, Mg, Na, Ti and S). The main mineralogical constituents of the copper ore are calcium aluminosilicate (Ca(Al2Si2O8), amesite (Mg2Al2SiO5(OH)4) and gypsum (CaSO4×H2O), and quartz (SiO2) as resulted from the alteration of an igneous rock. This study has shown that about 92 % of copper can be recovered with a maximum copper grade of 4.2 mass% in a froth after 15 minutes of flotation at pH 8.5 when used potassium amyl xanthate as a collector, MIBC and Dow-froth 250 as frothers and calcium hydroxide as a pH adjuster. The images of bubbles in the cell during flotation process were recorded using a high-speed camera. The froth concentrate with average copper grade of 2.0 mass% was further processed by atmospheric leaching with a solution of sulphuric acid and hydrochloric acid, respectively and high pressure leaching with sulphuric acid solution. As a result, leaching rate of copper reached about 60 % in an atmospheric leaching with sulphuric and hydrochloric acid respectively, whereas the rate can reach more than 70 % by autoclave leaching at high pressure under the controlled condition. A process to recover of copper from its low-grade ore can be developed by optimization of flotation combined with acid leaching.

Jan 1, 2014

By Ali Ekrem Aritan

In this study, the vibration exposure of excavator operators working regularly in 25 different natural-stone quarries was measured. In addition, the relationship between vibration exposure and rock properties was investigated. Gloved and ungloved vibration measurements were performed and revealed that antivibration gloves reduce excavator operators’ vibration exposure by 7.10 to 25.95 percent. Samples from each quarry were characterized with rock mechanics tests. The correlations between the hand-arm vibration measurements and the natural stone’s physical-mechanical properties, such as uniaxial compressive strength, Shore hardness, Knoop hardness, apparent density and total porosity were determined to be more than 70 percent. One finding of the study was that the health risk in excavators cannot be reduced sufficiently by the sole use of antivibration gloves. Furthermore, the excavation of any rock with a Knoop hardness above 121 is associated with an 81 percent risk of hand-arm vibration. To increase awareness of the danger of vibration exposure for natural-stone miners, training programs should be provided, and technical and operational changes should be implemented.

By Ali Ekrem Aritan

Exposure to hand-arm vibration (HAV) among the labor force in the mining industry can result in permanent vibration diseases such as behavioral disorders, visual impairment, osteoporosis, pain (mostly in the hands, wrists, and shoulders), circulatory system disorders, and malnutrition. In this study, the vibration exposure of excavator operators working regularly in 25 different natural stone quarries was measured. In addition, the relationship between vibration exposure and rock properties was investigated. Gloved and ungloved vibration measurements were performed and revealed that antivibration gloves reduce excavator operators’ vibration exposure by 7.10–25.95%. Samples from each quarry were characterized with rock mechanics tests. The correlations between the hand-arm vibration measurements and the natural stone physical–mechanical properties (uniaxial compressive strength, Shore hardness, Knoop hardness, apparent density and total porosity) were determined to be over 70%. One finding of the study was that the health risk in excavators cannot be reduced sufficiently by the sole use of antivibration gloves. Furthermore, the excavation of any rock with a Knoop hardness above 121 is associated with an 81% risk of HAV. To increase awareness of the danger of vibration exposure for natural stone miners, training programs should be provided, and technical and operational changes should be implemented.

By Ali Ekrem Aritan

Exposure to hand-arm vibration (HAV) among the labor force in the mining industry can result in permanent vibration diseases such as behavioral disorders, visual impairment, osteoporosis, pain (mostly in the hands, wrists, and shoulders), circulatory system disorders, and malnutrition. In this study, the vibration exposure of excavator operators working regularly in 25 different natural stone quarries was measured. In addition, the relationship between vibration exposure and rock properties was investigated. Gloved and ungloved vibration measurements were performed and revealed that antivibration gloves reduce excavator operators’ vibration exposure by 7.10–25.95%. Samples from each quarry were characterized with rock mechanics tests. The correlations between the hand-arm vibration measurements and the natural stone physical–mechanical properties (uniaxial compressive strength, Shore hardness, Knoop hardness, apparent density and total porosity) were determined to be over 70%. One finding of the study was that the health risk in excavators cannot be reduced sufficiently by the sole use of antivibration gloves. Furthermore, the excavation of any rock with a Knoop hardness above 121 is associated with an 81% risk of HAV. To increase awareness of the danger of vibration exposure for natural stone miners, training programs should be provided, and technical and operational changes should be implemented.

By Qing-Xun Low

Ni current collector has excellent electronic conductivity and mechanica, properties. However, nicke, cannot be used in H2S-containing syngas SOFCs due to sulfur poisoning and coking. Copper coated nicke, is prepared by electrochemica, deposition. XRD, SEM, and EDX techniques are used to characterize the samples. After high temperature treatment in syngas containing, the coated samples exhibit high resistance of coke formation and sulfur corrosion compared to pure nickel. Therefore, copper coated nicke, is a promising anode current collector for H2S-containing syngas SOFCs.

Jan 1, 2010

By R. R. Odle

A laboratory and pilot-scale investigation of direct smelting of copper concentrates was conducted to determine the effect of concentrate analysis and the degree of roasting on the yield and quality of copper produced in a subsequent smelting step. A stoichiometric :mOdel of direct smelting is presented which predicts the? quantity of copper; slag, and white metal' prOduced'and the distribution of copper in these phases as a function? of the concentrate '(calcine) analysis.

Jan 1, 1983

By J. Partyka

Respirable dust produced during blasting operations in underground mines exhibits both diffusion and convection properties of the airflow. However, the application of the mathematical model presently used to calculate the change in time in the concentration of blasting pollutants is mostly limited to a single drift and cannot be easily utilized for blasts taking place in stopes. This paper discusses an analytical solution based on considerations that enable us to reliably identify the initial condition. Such an approach may be used for any blasting area regardless of its position, its size, or the ventilation system in use during blasting. In addition, a test procedure using field data is established to determined those parameters not measured directly. As well, equations are derived to find the diffusion coefficient, and the position and size of a dust source from the field data. Mathematical considerations The convection-diffusion problem, for a one-dimensional case, is described by the following partial differential equation (PDE): ct. = Dcxx - Vcx + source - sink(1) where C = the concentration of a pollutant T = time V = the mean air velocity in x-direction D = the diffusion coefficient X = distance away from the pollutant source source = any additional pollutant source specified by an initial value problem sink = decay of a pollutant inside the region specified by the boundary conditions. Respirable dust produced during blasting is best considered as an initial value problem (IVP). To derive a mathematical model, the following assumptions are made: •At time zero (t = 0), the dust source is at point x = 0 of an infinite drift. •The problem is considered a one-dimensional case. •The mean velocity of air and the diffusion coefficient are constant. •There is no source or sink of dust other than specified at point x = 0 and time t = 0. We have to solve the following problem [PDE ct=Dcxx-Vcx-m<x...m;0<t<m(2)] ICc(x,0)=f(x)t=0, the initial condition Where c = dust concentration in mg/m3 V= the average mean velocity in a drift in m/s t= time in s D= the diffusion coefficient in m2 /S x = distance coordinate in m. We observe that in problem (2), we have moved the boundaries to[ -m and +m] in order to have an initial-value problem. We introduce new coordinates, s = t and z =x - Vt. To rewrite the PDE in terms of (z, s), we use the chain rule ct = czzt + csst = -Vcz + cs cx = czzx = cz cxx = (cz)x = czz. We now substitute our computed ct, cx. and cxx into the PDE to get new IVP in terms of z and s :

Jan 1, 1991

By E. Yigit

In the flotation process the physical factors such as agitation intensity air flow rate and pulp solid concentration are very important parameters affecting grades and recoveries of the products. The flotation tests were performed on the samples of Bigadic colemanite ore to investigate these factors at different agitation intensities ranging from 1000 rpm to 1400 rpm and air flow rates from 1000 cm3 ? min-1 to 2000 cm3 ? min-1 with 2 L and 4 L cells using Denver laboratory flotation machine. The tested collectors were Cytec Aero 825, Aero 848N and their mixtures. Agitation intensity and air flow rises resulted in more floated material although sometimes being not selective. These effects can be attributed to powerful collisions between air bubbles and mineral particles. The first observation was the effect of pulp solid concentration on the floatability of minerals, while the flotation in 2 L cell (0.125 g.L-1 solid concentration) at 1000 rpm (0.176 wattcm-3), and with 1000 cm3.min-1 air flow rate was possible, the flotation in 4 L cell (0.0625 g.L-1 solid concentration at 1000 rpm. (0.176 wattcm-3) and with 1000 cm3 ? min-1 air flow rate was not possible. However at 4 L cell after increasing agitation intensity to 1200 rpm (0.201 wattcm-3) keeping 1000 cm3 ? min-1 air flow rate, flotation was possible again. This shows that these factors such as agitation intensity have some critical role on flotation. Another interesting observation was on the selective effect of pulp solid concentration. In the flotation with 1 L cell at different agitation intensities, collector Aero 848N was selective against calcite, while in the flotation with 2 L cell at different agitation intensities the same collector Aero 848N was selective against colemanite.

Jan 1, 2014

By Steven J. Knoll, Theodore J. Williams, Douglas F. Scott

Highly stressed rock in stopes continues to be a primary safety risk for miners in underground mines because it can result in failures of ground that lead to both injuries and death. Spokane Research Laboratory personnel investigated electromagnetic (EM) emissions in a deep underground mine in an effort to determine if these emissions could be used as indicators of impending catastrophic ground failure. Results suggest that (1) there is no increase in the number of EM emissions prior to recorded seismic activity, (2) some EM signals are generated during blasting, (3) interference from mine electrical sources mask seismic-generated EM signals, (4) EM emissions do not give enough warning (compared to seismic monitoring) to permit miners to leave a stope, (5) the distance an EM signal can travel in the rock is between 18 and 40 m, and (6) current data acquisition systems do not differentiate between EM signals generated from seismic activity and random mine electrical noise. These results preclude monitoring EM emissions as precursors of impending catastrophic ground failure.

By A. Juganda, F. WILSON, H. PINHEIRO, N. SANDOVAL, J. F. Brune, G. E. Bogin Jr.

To evaluate methane explosion hazards in longwall coal mines, a CFD model was developed along with a 1/40th-scale, optically accessible model of an underground longwall coal mining section. In this project, CFD models assisted in the design of the physical model to ensure specifications were met for accurately representing the scaling physics as well as to assist in narrowing the experimental matrix and identifying key locations for sensor placement to measure velocity, pressure, and gas concentrations. This research will help develop strategies for methane monitoring that prevent methane ignitions and explosions in longwall coal operations.

Aug 15, 2022

By A. Juganda, F. WILSON, G.E. BOGIN, H. PINHEIRO, N. SANDOVAL, J.F. BRUNE

To evaluate methane explosion hazards in underground longwall coal mines, researchers at the Colorado School of Mines developed a computational fluid dynamics (CFD) model along with a 1/40th-scale, optically accessible, physical model of a longwall mining section. In this project, CFD models assisted in the design of the physical model to ensure specifications were met to accurately represent the scaling physics as well as to assist in narrowing the experimental matrix and identifying key locations for sensor placement to measure velocity, pressure and gas concentrations. This research will help develop strategies for methane monitoring to prevent methane ignitions and explosions in longwall coal operations.

Dec 1, 2022

By Wendy M. Brunner

A 70% excess of mesothelioma, an asbestos-related cancer, has been reported among men in northeastern Minnesota, where iron mining has been the major industry. The Minnesota Department of Health has studied iron miners who developed mesothelioma to identify possible sources of asbestos exposure. A database of all Minnesota residents diagnosed with mesothelioma between 1988 and 1996 was linked to a database of approximately 72,000 current and former Minnesota iron-mining employees to identify cases who had ever worked in the mining industry. The job histories of the cases were examined to determine if any of their jobs could have involved exposure to commercial asbestos. Seventeen individuals diagnosed with mesothelioma in Minnesota between 1988 and 1996 were found to have worked in the iron mining industry. Of the 15 for whom adequate work histories were available, 14 had identifiable sources of exposure to commercial asbestos in jobs held both inside and outside of the mining industry. The time between employment in these asbestosexposed occupations and the diagnosis of mesothelioma is consistent with the 20 or more year latency period that has been observed in other studies of this cancer. © 2007 Elsevier Inc. All rights reserved. Keywords: Mesothelioma; Asbestos; Iron miners; Taconite; Epidemiology; Case series

Jan 1, 2007

By J. de Korte, Z. Loubser

"SynopsisThe aim of a blending stockpile is to minimize the natural variation in properties of a material. Two simulation models were written, for coneshell and chevcon stacking, and used to investigate the influence of different stockpile parameters on blending efficiency. The coneshell model is used to show that blending efficiency is highly sensitive to stacked height, with lower output variances observed for higher capacities. Output variance in both models also decreased when the stacker movement increment was decreased. For chevcon stacking, increasing stacker speed significantly increases the blending efficiencies. Increasing the length of the blending tail also reduces output variation, but this parameter would need to be weighed against the accompanying decrease in buffer capacity.IntroductionEven in the most uniform deposit of materials in nature, material properties will vary. The degree of variation can be measured, and usually resembles a normal distribution. The aim of blending and homogenization operations is to minimize the standard deviation of this normal distribution (De Wet, 1994). In general, the reduction in variation will result in a more efficient and cost-effective downstream process. Cement plants need a precise blend of raw materials to ensure desired kiln performance; boilers used in power generation are optimized for fuels of a constant specification; and even though the separation density in a coal washing plant can be adjusted, a constant product quality cannot be produced from highly variable feed (Denny and Harper, 1962). The process efficiency, product quality, and environmental compliance depend on consistency of characteristics in the material fed (Kumral, 2005) Many industries involved in"

Jan 1, 2015

By H. F. Moore

AT PRESENT, I am connected with an investigation of the so-called fatigue of metals under stress. So far we have studied the more fundamental and simple case of the repeated stress, without the additional complexity of impact, which might bring in other factors. We feel that this investigation, which has been in active progress for a little over a year, has shown more conclusively than has been shown before that steel under repeated applications of stress, reversed from positive to negative, will not fail below some fairly clearly defined limiting stress that,, so far we can see, does not bear any definite relation to the ordinary elastic limit, being as large as the elastic limit in some cases and about one-half the elastic limit in others. I might be asked, first, what is fatigue. The old view is summed up "in the word "crystallization." The idea was that under repeated stress the material changed its crystalline structure. I do not know of any evidence in favor of the theory that metals materially change their crystalline structure under repeated stress. The crystals are broken under repeated stress. The second theory, advanced by Bauschinger, the German scientist, is that under repeated stress some inherent property of the material changes its elastic limit; it is an inherent property of the material, possibly some property of the amorphous cement between the crystal. The third view is that all fatigue of metals is the result of the spread of damage from little localized overstresses. I do not feel justified in stating my positive belief in the third view as against the second, but I have yet to run across a case of failure of steel or other metal, either in the laboratory or in service, that could not be explained by the gradual spread of damage from some nucleus. We have found, for example, that it is possible to subject a homogeneous steel, like Armco iron or a 0.90 per cent. carbon steel, that hag been thoroughly annealed, to one hundred million reversals f stress as high as the elastic limit of the steel with no sign of failure. We stopped the test at one hundred million because the machines Were required for other work. Forty-five days, continuous running at 1500 revolutions a minute is required to produce one hundred million repetitions. On the other hand, a complex structured steel, like a chrome-nickel steel that

Jan 6, 1921