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By Majid Sarkari, Hossein Atashi, Farhad Fazlollahi

"The aim of this research work was to prepare the efficient catalyst to purify pollutant output gases such as SO2 , NO2 and CO. This catalyst, lanthanum cobaltat (LaCo03) was prepared by the proper method in the analysis laboratory of Tabriz Oil .The first materials were chosen through calcination operation and temperatures of operation related to the Tamman temperature, therefore the basis for the first material of catalyst was nitrate and aqueous and since we had no availability to lanthanum nitrate, lanthanum oxide was used to prepare the nitrate one. Before all else, the first materials of catalyst were mixed together with the equal mole proportions and then, at the lower and upper temperatures of Tanunan temperature, calcination operation was carried out. To determine the molecular structure, the XRD analysis was utilized and specified that prepared lanthanum cobaltat was sixth aqueous and had the crystal structure type Triclinic.IntroductionLaCo03 has presented a vast interest because of its special electrical, magnetic and catalytic properties [1-4]. The catalyst LaCo03 can be prepared by means of several methods such as spray drying, freeze drying and also co-precipitation [5-12]. Some methods including hydrothermal, sol gel and citrate [13] This material usually has been synthesized by ceramic method and certainly the high temperature for the calcination operation. [14]. Lanthanum catalysts have been researched because of having such an active state [15]. One of the unique properties of this catalyst is the simultaneous conversion of pollutant elements. Nowadays CO oxidation has important applications in environment protection, such as indoor air cleaning and automotive exhaust treatment. LaCoO3 is one of the most important catalysts for CO oxidation."

Jan 1, 2013

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Jan 1, 1938

By George Koenig

I have been granted the outstanding privilege... and pleasure to introduce you this evening to the Grand-Duchy of Luxembourg and to tell you in a few words how this country came into existence, how it managed to survive and what role it nowadays plays in the International Community. Luxembourg, situated between Belgium, Germany and Prance is a small, a very small country... just a dot on a map. After all, it is only a matter of 62 miles from top to bottom and 37 miles across at it's widest... barely covering some thousand square miles... so be careful about stepping on the accelerator... you might be in and out without having realized it... which would be a real shame as the Grand-Duchy enjoys a fairly unique geographical feature in so far as it provides the visitor with an outstanding variety of scenery concentrated in a minute spot.

Jan 1, 1987

By G. D. Tranter

THE importance of ladle and teeming practice and its relationship to the yield and quality of the product has focused considerable attention on this phase of open-hearth operation. Inherently bad steel cannot be perfected by manipulation during teeming, but through the proper handling of "off heats" serious losses, which in many cases arise, can be greatly minimized. Conversely, good steel can be ruined as a result of poor workmanship in the -pit, and rendered unsuitable for application to orders where exacting surface and physical requirements are essential. Sufficient evidence has been secured to warrant careful investigation of pit operations when an abnormal number of basic defects develop in the semifinished product or are found on the inspection table. This paper is written from the standpoint .of the problems involved in making satisfactory ingots for sheet rolling. Furthermore, since rimming steel is almost universally used for manufacture of sheet, the data presented herein refer particularly to that type of steel. Going back some 30 years in open-hearth .history, the word "pit" properly described the hole into which the ladle was lowered to receive the metal tapped from the furnace. The working space was necessarily limited, and the disposal of slag and metal overflowing the ladle or lost because of breakouts presented a serious problem. The equipment, of course, was rather crude in the light of present-day development. Often no ladle stands were provided, the ladle being hung on the crane beneath the runner. When delayed taps occurred, the ladle was often held in position for many hours, thus tying up pit operations and causing delays to adjacent furnaces. Because of crowded conditions, slag thimbles were not used and a network of cast-steel triangles and old tapping bars, placed before the heat was tapped, was the means for removing slag from the hole. Furnaces of different capacities were used

Jan 1, 1935

By G. D. Tranter

THE importance of ladle and teeming practice and its relationship to the yield and quality of the product has focused considerable attention on this phase of open-hearth operation. Inherently bad steel cannot be perfected by manipulation during teeming, but through the proper handling of "off heats" serious losses, which in many cases arise, can be greatly minimized. Conversely, good steel can be ruined as a result of poor workmanship in the pit, and rendered unsuitable for application to orders where exacting surface and physical requirements are essential. Sufficient evidence has been secured to warrant careful investigation of pit operations when an abnormal number of basic defects develop in the semifinished product or are found on the inspection table. This paper is written from the standpoint of the problems involved in making satisfactory ingots for sheet rolling. Furthermore, since rimming steel is almost universally used for manufacture of sheet, the data presented herein refer particularly to that type of steel. Going back some 30 years in open-hearth history, the word "pit" properly described the hole into which the ladle was lowered to receive the metal tapped from the furnace. The working space was necessarily limited, and the disposal of slag and metal overflowing the ladle or lost because of breakouts presented a serious problem. The equipment, of course, was rather crude in the light of present-day development. Often no ladle stands were provided, the ladle being hung on the crane beneath the runner. When delayed taps occurred, the ladle was often held in position for many hours, thus tying tip pit operations and causing delays to adjacent furnaces. Because of crowded conditions, slag thimbles were not used and a network of cast-steel triangles and old tapping bars, placed before the heat was tapped, was the means for removing slag from the hole. Furnaces of different capacities were used

Jan 1, 1935

By Jörg Thomasberger

Delivering liquid steel to a steel processing unit at right temperature is an important criterion for high production steel shops, but it is surprising how little attention has been paid in the past to manage this vital phase in the steelmaking process-the steel in transit. The ladle running costs, both directly and indirectly, contribute significantly to the cost of steelmaking and should be an area of concern to any high production steel plant. Here we are talking not only of refractory costs or preheating fuel costs, but also cost of extra heating in ladle furnace, additional process delays incurred in delivering steel at right temperature to downstream unit in case proper care is not exercised at upstream unit, and occasional costs of ladle breakout due to inability to judge the residual life of the ladle. This paper emphasizes the need of a comprehensive ladle management system, an aspect which has not been properly addressed in the operations of a steel plant, in improving the productivity of a steel melt shop. Starting with review of present status and the attempts at implementation of ladle tracking in steel melt shop automation system, it looks at components of an exhaustive Ladle Management System (LMS), and finally gives an idea of benefits that will accrue from implementation of such a system in a steel melt shop.

Aug 17, 2017

By P. Chris Pistorius

An example is presented to illustrate the joint effect of local reaction equilibria and mass transfer limitations, for reactions during ladle refining of steel. The example relies on some of the kinetic principles that David Robertson has employed to quantify many metallurgical processes. In calcium treatment of alumina inclusions in aluminum-killed steels, solid CaS forms as an intermediate reaction product. During subsequent reaction, CaS disappears and calcium aluminate forms; at the same time, aluminum and sulfur dissolve in the steel. Kinetic analysis shows that the rate of this reaction is not limited by mass transfer of dissolved aluminum and sulfur away from the reacting inclusions. The reaction rate is likely limited by transport of dissolved calcium. This example also illustrates the use of FactSage macros for kinetic modeling.

Jan 1, 2014

By C R. Fountain, W R. Cannings

The zinc-lead-silver mineral resource at Lady Loretta ranks amongst the worldÆs richest when measured in terms of in situ metal grades. However, the project remains undeveloped 28 years after its discovery in 1969. The primary obstacle to development has been the fine and complex grain structure of its ores, which make flotation concentration inefficient even with fine grinding. The size and remote location of the deposit have also hindered exploitation. BUKA planned to directly fume the volatile target metals from the ore when it acquired the project. Intensive, post-acquisition modeling showed the innovative processing route to be uneconomic, notwithstanding high metals recovery and low waste content in fume product. Progressive modifications and supplements to the underlying fuming process enhanced economics and resulted in a new mine-to-metal processing route for zinc-lead-silver ores. The proprietary, three-stage BUKA Zinc Process offers technical, economic and environmental advantages. It is expected to find widespread application in the treatment of ores and residues. However, neither continued R&D nor application to Lady LorettaÆs currently delineated resource can be justified under prevailing market conditions. The objectives and results of each step in the process development sequence are outlined with reference to their impact on the commercial viability of the Lady Loretta project.

Jan 1, 1998

By Jean-Guy Levaque, Robert Ethier, Ron J. Elliot

This paper presents data gathered during a comprehensive study on the impact of improvements to fragmentation in a major Limestone quarrying operation. The full impacts of gains in fragmentation are tracked through the mucking, crushing, and grinding phases of the operation.

Jan 1, 1999

By Charles H. Snow

In vol. xxxviii. (1889) of the American Journal of Science, under the heading " Pseudomorphs of Native Copper after Azurite from Grant County, New Mexico," Mr. W. S. Yeates describes a most interesting mineral form. His account is, that a material having the appearance of native copper, but brittle and much lighter than native copper (its specific gravity being but 4.15), was submitted to him by the United States National Museum for examination. The substance was reported to him as occurring in masses, varying in weight from one ounce to seventy pounds, and composed of tabular crystals, variously grouped. The specimens, when submitted, ex hibited on the outride a covering of clay; and they were subse quently found to consist of particles of the same clay, intimately mixed with others of native copper, producing the aspect, without the weight, of pure copper. The forms of the azurite crystals, found at Bisbee, Arizona, having been suggested by the specimens, actual goniometer-measurements were made; and the two crystallizations were thus proved to be identical. To these statements I may be permitted to add some further in formation, derived from personal examination, and illustrated with a suite of characteristic specimens collected by myself (Fig. 2).* Grant County, New Mexico, in which these specimens were found, is a region noted for variety of mineral species. The sixth edition of Dana's Mineralogy mentions many of the silver, copper, and lead minerals, and also turquois, aragonite, wulfenite, barite, fluorite, vanadinite, etc. I have noticed also green and red garnet, molybdenite, native alum, smithsonite, bornite, etc., some of which presented peculiar modes of occurrence. The green garnet, for instance, was in masses formed of separate crystals, each of pea-size and not unlike that vegetable in tint and smooth opaqueness. The crystallization was

Jan 1, 1893

By F. H. McDowell

The increasing interest in the subject of electrical separation warrants the addition to what has already been written of a few lines covering the practical workings of the Tilly Foster mill under the direction of Mr. E. S. Moffat, General Manager. Since my last paper was presented to the Institute, Mr. S. P. Tomkins, the superintendent, has had thrust upon him for solution several problems complicated by the introduction of new conditions. 1. The richer portion of the lean ore dump, and that nearest the railroad track, having been worked up in 1890, the handling of the balance, including a largely increased amount of rock, could only be accomplished at an increased cost. 2. The tailings had accumulated close about the mill to such an extent that arrangements had to be perfected to move them further away.

Jan 1, 1893

By William P. Mason

FoR reasons unnecessary to enter into here, I was called upon to contradict the statement that " closed metallic vessels, partly filled with water and heated, do not become shattered by violent explosion, but simply rupture by over-pressure;" and the following experimental results were obtained in support of my position : A piece of drawn brass tubing (telescope-tubing) 1 1/2 inches in diameter and 15 inches long was closed at both ends by screwing on heavy caps of bronze. Before closing the second end the vessel was half filled with river water, the cap was then screwed on, and the closed vessel was supported upon two iron anvils, and heated in the interval between the supports by a large Bunsen lamp. The resulting explosion (which was doe to over-pressure only and not to any more occult cause) was exceedingly violent. No small damage was done to the room in which the experiment was undertaken; and the noise was like that of a cannon. Those of the pieces which could be recovered are shown in Fig. 1. Upon examining the wreck, it was noticed that one of the heavy bronze end-caps had preserved its circular section and still contained that portion of the barrel of the tube which had been screwed into it, while the other end-cap contained no portion of the tube, and was moreover sprung into a shape more or less elliptical, as if from excessive lateral strain. It was also observed that the large pieces of the shattered boiler predominated towards the end which had been closed by the un-sprung end-cap. The reasonable explanation, in view of the facts, was, that over-pressure had caused the boiler to yield through the screw-threads at A B, Fig. 2, and the righthand end-cap had blown off, thus leaving the boiler half filled with water, greatly super-heated for the new (atmospheric) pressure to which it was suddenly reduced; that this water had consequently sprung instantly into steam with dynamite effect, shattering the tube and springing the remaining end-cap. The large pieces would be expected at the open end of the boiler, as at that point the "tamping "would have been that of the atmosphere only. This explanation assumes a rupture to have been caused by gradually increased pres-

Jan 1, 1893

By William P. Blake

In my short " Contribution to the Early History of the Industry of Phosphate of Lime in the United States,"* mention is made of the erection by Dr. Emmons and myself of a magnetic machine for the removal of iron-ore from the so-called "red sand," a granular form of apatite. At the time of writing, it was not possible to refer to my diary and notes, and the general statements were made from recollection. The subject seems to have special interest at this time, by reason of the many forms of machines now being introduced and patented for similar purposes; and, having received letters of in quiry for further details, I have availed myself of the opportunity, when recently at home for a few days, to refer to the original notes and records made by me in 1852, when living at Crown Point and Moriah, on Lake Champlain. The machine mentioned in my former communication mas pur chased of Ransom Cook, of Vermont. It arrived, and was un loaded from the boat and taken part way up to the nine, on October 18,1852. The weight was 1400 pounds and the cost $1200. It was constructed, not with permanent magnets but with electro-mag nets. It was set up and first turned by hand on October 28th, using twelve battery-cups or cells, the connections being made with wires in small cups of quicksilver. The magnets were not sufficiently strong, and the machine did not work well. More batteries were sent for, arid the machine was started with steam-power on Novem ber 6th. The ore was dried in kilns, then put through a coffee-mill crusher or grinder, and then fed upon the leather belt which carried it under the magnets. Many experimental runs were made, and some diffi culties were overcome, before December 21st, when the record states that the machine was working pretty well, using 24 cells and giving a product of from 3 to 5 tons a day of granular phosphate. The ori-

Jan 1, 1893

By Harvey S

After considerable experience in connection with the magnetic iron-ores at the South, especially in the Cranberry district of western North Carolina and eastern Tennessee, the writer was led into a thorough investigation of the magnetic separation of iron-ores, and, from this investigation, has gradually been developed a separating machine which it is the purpose of this paper to explain. Numerous United States patents have been issued upon machines for magnetic separation. Since the original patents date back to 1849, it is not possible to-day to establish broad claims upon the principles of electro-magnets as applied in such machines. Among these inventions there are certain types of separators which have very marked practical advantages over the others; and these successful machines, while varying radically from each other in their proportions and arrangements, are all based upon a principle originally explained in a patent which was granted in 1870, and which has now expired by limitation. The problem of practically separating iron-ores, as found in the mines, is very different from the separation of a purely magnetic substance from a purely non-magnetic one, since the crystals of magnetite, scattered through the ore-bearing rock, and sometimes collected in masses, are of very different sizes. The average size of the particles may be definitely ascertained for each mine, and the crushing- and screening-machinery may be adapted thereto, but there will still be a large percentage of very fine crystals which, in the crushing for the average, will not be broken apart from the gangue. If these mixed particles are thrown into the heads they carry gangue with them, and if thrown into the tails they occasion a loss of ironore. There are two methods for preventing such loss. One is, to crush all the material to the size of the finest particles, which means, of course, a large crushing-plant, heavy wear and tear, and excessive cost for repairs, and the production of only a very fine-grained concentrate which our blast-furnace managers, to say the least, do not

Jan 1, 1893

By C. A. Stetefeldt

The iron-ore deposits worked by this Company occur in lenses 200 to 1000 feet long and 5 to 80 feet wide, and stand at an angle of from 65' to 75, with a vertical height of 250 to 500 feet, other lenses occurring below. A number of the deposits were first worked as open pits, which in some cases were carried to the depth of 150 feet, when, owing to the weakness of the walls, underground mining was adopted. While the ore was being removed from the open pit, shafts mere in several instances sunk into the foot-wall, the intention being to mine the ore with breast-stopes of an approximate height of 20 feet, followed by underhand-stopes of the same height, leaving floors between of the necessary thickness to support the walls, or to effect the removal of the ore by means of what is known as the stall system. As the work progressed, however, it was found that the walls (which are of chlorite) were too weak to permit the working of breast-stopes 20 feet high, there being frequent heavy falls of ground from the hanging and, in some instances, from the foot. The plan of following breast-stopes with underhand-stopes was, therefore, abandoned. By working breast-stopes only, but little more than one-half of the ore could be removed, and that only at an excessive cost, the ore being so hard that power-drills with 3 1/8-inch pistons . and 6-inch stroke, working under 60 pounds of compressed air, are able to drill but 8 feet in ten hours as a yearly average, while from 6 inches to 2 feet is a common result of ten hours' drilling. It was plain that some other system of mining must be adopted, and it was proposed to sink by levels of 75 feet, carrying in the cross-cuts from the shafts and working out the ore each way from the shaft from foot to hanging, and from 15 to 20 feet in height. When this has been done, drift-sets consisting of caps and legs are set up the whole length of the opening and connected with the cross-cut; the necessary openings for ladder-ways and chutes or mills are timbered from

Jan 1, 1893

By John E. Lens

Minutes after the Friday afternoon October 16, 2009 announcement that the 80 year old Lake Champlain Bridge was closed to traffic out of concern for public safety, emergency detour planning started at VTrans and NYSDoT. The closure severed a cross-lake link between Addison, VT and Crown Point, NY, which created a 76 mile detour and significant hardship for commuters, farmers working on both sides of Lake Champlain, and businesses relying on both traffic and employees commuting between Vermont and New York. Rehabilitating the bridge was determined to be economically and technically unfeasible and the design of a replacement bridge was accelerated for a spring 2010 construction start. In the meantime, a temporary ferry alternative was to be rushed into service beside the original bridge by February 2, 2010. This paper presents the case history of the fast-tracked ferry dock design and construction on the Vermont side. Twin 300-foot-long pile supported approach spans, a loading slip system and ice deflectors were designed, fabricated and constructed in 90 days in the fall/winter of 2009-2010. This chronicles the project from initial concepts through the extraordinary cooperation between state and federal agencies, and near round-the-clock winter construction on Lake Champlain. This project and its companion project on the New York shore succeeded by virtue of exceptional cooperation between seasoned regulatory, design, and construction participants and warrant this case-history presentation of the Vermont project to share within the industry as an example of overcoming extraordinary challenges.

Jan 1, 2011

By D Johnston

Within the first full year of BarrickÆs Cowal Gold Mine operation, the Lake Cowal Foundation Limited (LCF) has already been delivering results consistent with its goal to protect and enhance the natural environment of Lake Cowal and its catchment area. The LCF is a non-profit Environmental Trust established in June 2000 in conjunction with the development consent process for the construction of BarrickÆs Cowal Gold Mine. Its primary goal is to protect and enhance Lake Cowal, a nationally significant ephemeral wetland located 350 km west of Sydney, New South Wales, Australia. Significant concentrations of water birds visit the lake and the Australian Heritage Commission listed Lake Cowal on the Register of the National Estate in 1992. The LCF is managed by a Board of Directors from representative member organisations including the Total Environment Centre, National Parks Association, Nature Conservation Council and Barrick Australia Limited. Although largely funded by Barrick, the Foundation also attracts external funding and works in partnership with a diverse range of other groups and organisations, beyond the mine fence. The total value of currently approved projects is estimated to be in excess of $7.1 million, which includes æin-kindÆ contributions made by the local community and in particular the Lachlan Catchment Management Authority (LCMA) and local farmers. To date, LCF has been involved with the development and implementation of 30 projects with a total of 34 project partners. LCF has worked with over 60 landholders to improve Lake Cowal and its catchment, with 6180 ha of land now being managed for conservation or sustainable farming in the local area. Many landholders have been, or are involved in property planning or participating in other training opportunities. Sustainability of LCF programs and outcomes will be assured by commitments to projects within four key themes: conservation, research and research support, sustainable farming and community education and training. The LCF works independently from the mining company and has no responsibility for the environmental management within the mining lease. It is about capitalising resources generated by the mine to enhance environmental outcomes in the wider Lake Cowal catchment area by working collaboratively with the local community, industry and government authorities to ensure the long-term protection of a unique wetland ecosystem affected by landscape scale degradation.

Jan 1, 2007

By Timothy M. Bruner, William J. Maloney

Faced with rapid growth that strained their current water supply capabilities, the Somerset Water Service in Somerset, KY decided to construct a new intake structure on the shore of Lake Cumberland. With an existing intake structure within 200', very hard limestone geology with calcite geodes, and lake level fluctuations as high as 50 ' ,this project posed many challenges. The following paper discusses how mechanical excavation techniques were used to overcome these obstacles.

Jan 1, 2001

By Jason Morrison

The Norwegian Lake Tap Method was successfully used to tap into the side of Lake Dorothy 36.5 m (120') below the lake surface. The lake tap allows water to flowinto an access tunnel from the lake lowering the water elevation below its natural out-fall. When the lake reaches a predetermined elevation below the outfall, a 1.5 m (60?) valve in the tunnel will be shut and discharge from Lake Dorothy will stop temporarily allowing construction of a dam located 2.9 km (1.8 miles) downstream at Bart Lake. The lake tap and tunnel were one phase of the $64 million Lake Dorothy Hydroelectric Project, owned and operated by Alaska Electric Light & Power Company (AEL&P), a private utility located in Juneau, AK. The Lake Dorothy portal site and tunnel are located approximately 25.7 km (16 miles) southeast of Juneau, AK, in the remote Tongass National Forest at an elevation of 701 m (2,300') above sea level in the mountains above the Taku Inlet. Thirty degree snow covered mountainsides and limited access by helicopter were just two of the many factors which challenged this unique project. The lake tap and tunnel development consisted of 250 m (820') of horizontal tun-nel, averaging 3.6 m x 3.6 m (12' × 12'), excavated using conventional drill and blast methods in highly competent Granodiorite and Tonalite rock, placement of one 3.9 m (13') long concrete plug, or bulkhead, located at the tunnel midpoint, and one 3 m (10') diameter lake tap into the side of Lake Dorothy. This paper will provide an analysis of the logistical and engineering challenges involved in the development of one of only a handful of lake taps in North America. AEL&P and contractor J. S. Redpath Corporation worked together to complete this critical project phase safely and on schedule, in a location accessible only by helicopter and plagued by constantly changing, harsh weather conditions. A strict schedule had to be maintained to ensure the timely operation of the downstream dam and power plant.

By Jan Mehren, Arild Neby

Underwater Tunnel Piercing or Lake Tap, often also called the Norwegian Method, will in many projects be an important part of the hydro electric development scheme. The very last blasting round in the Lake Dorothy Lake Tap Tunnel, which penetrated into the lake at a depth of 120 ft (36 m), was such a key step in constructing the Lake Dorothy Hydroelectric Project. A lake tap project is multidisciplinary. Besides the pure blasting and construction technique aspect, engineering geological and geometric considerations that aim to optimize the tunnel alignment making a lake tap possible at minimized risk are of significant importance. Output data from numerical model analysis of the hydrodynamics resulting from the blasting is vital for the final adjustments to the geometrical layout. The planning of monitoring systems for the surveillance of hydrodynamic impact on valves and pipes as well as control with water levels and air pressures prior to and during the blasting, are all additional crucial elements in the design. More than 600 lake taps have been successfully performed in Norway since the 1890`s. The technique, which deserves to be called well proven, has been applied mostly in the hydropower sector but over the last 20 years also for shore approaches in the oil and gas industry. The demand for this technique seems to be ever more growing.

Jan 1, 2009