Search Documents

By N. Behnood

"This paper describes how material selection, quality assurance, and failure investigation play important roles in the efficiency and safety of mining and metallurgical operations.INTRODUCTION Material selection, quality assurance, and failure investigation are all complementary elements of materials engineering in the application of materials technology for failure prevention. Based on commodity price increase of 300% between 2002 to 2013 [1] and increased cost ofcapital projects and operation, equipment failure, which in some cases causes complete shutdown of the operation, becomes a vital importance in mining and metallurgical plants. The following sections present a number of examples from many failure cases experienced by the author during his three decades of work as a materials engineer in the mining industry."

Jan 1, 2015

By Jewel A. G. Gomes

Electrocoagulation (EC) has been performed with Al-Fe electrode system with changing polarity for the removal of arsenic from water. The removal process has been studied using ICP-AES and Anodic Stripping Voltammetry with a wide range of arsenic concentration (1-1000 ppm) at various pH (4-10) and residence times (1-60 min). Electrochemically generated by-products have been analyzed using XRD, FTIR, XPS, SEM/EDS and Mössbauer Spectroscopy. Results revealed expected crystalline iron oxides (magnetite (Fe3O4), lepidocrocite (FeO(OH)), iron oxide (FeO)) and aluminum oxides (bayerite (Al(OH)3), diaspore (AlO(OH)), mansfieldite (AlAsO4?2(H2O)), as well as some interaction between the phases. The amorphous or ultra-fine particular phase was also found in the floc. The substitution of Fe3+ ions by Al3+ ions in the solid surface has been observed, indicating an alternative removal mechanism of arsenic in these metal hydroxides and oxyhydroxides by providing larger surface area for arsenic adsorption via retarding the crystalline formation of iron oxides.

Jan 1, 2006

By W. H. Hodgson, A. R. Preston

"Improved rail production techniques provide new options for the rail user. Steelmaking improvements offer tighter composition control, lower oxide and sulphide counts, greater control of segregates and freedom from hydrogen problem s. New ultrasonic, laser and eddy current equipment gives printout information on surf ace flatness, straightness and internal condition. These have come along at a time when dramatic changes have occurred on the rail heat treatment scene. Rails can now be deep hardened on or offline in ways which should eventually result in a complete rewrite of the world's specifications. Rails of simple composition can be produced in the hardness range 2801400 BHN as required. The rail user can choose the hardness within this range according to requirement without the necessity for any step changes in the process routes.It is suggested that this is the pattern f or the next decade.IntroductionRails have been the subject of very slow improvement over many years but developments gathered momentum in the early seventies. Recent improvements in quality and properties have provided dramatic increases in rail life under the more severe service situations. Rail profile grinding, lubrication and other track improvements have greatly added to expectations of even longer life. All of this, coupled to even newer mill heat treatment developments, tilt both technical and economic advantages away from tradition to the point where specifications will need to be rewritten so that railroads can take full advantage of these new products."

Jan 1, 1988

By Xiaobing Yang, Animesh Jha, Greg Doughty

"Successful use of inert anodes should reduce the CO2 footprint in aluminum production. The search for a “holy grail” inert anode for metal electro-winning from constituent oxides using molten salt bath as an electrolytic medium is continuing. In this article we demonstrate the engineering approaches for the fabrication of intermetallic anodes, based on a quaternary Al-Ti-Cu-M (M:Ni, Fe) system for primary aluminium production. In particular, we examine the microstructural and electrochemical properties of alloys, based on the quaternary compositions. We explain the aspects of phase stability under anodic potential, which leads to the loss of anodic materials in the temperature range of 850-1050oC. The results are analysed in the context of oxidation reaction and formation of oxide layers which readily dissolve in the cryolite melt and prevent passivation. The paper also describes the conditions under which the reduction of aluminium at the graphite cathode occurs which also strongly depends on the molten salt chemistry for the nucleation of molten aluminium at the cathode.1. IntroductionOxygen-evolving inert anodes are an alternative to the conventional consumable carbon anodes for the production of primary aluminium. In this paper the materials selection criteria chosen for the engineering of anode is based on the understanding of the thermodynamic stabilities of aluminide intermetallic phases, some of which are formed and remained stable in fluoride melts. For example, the formation Al3Ti dispersed in aluminium metal via molten-fluoride flux reaction is well known in the context of aluminium casting and grain refining [1-3]. It is for this reason in our research we concentrated on the engineering of stable intermetallic phase mixture in the Al-Ti-Cu ternary system, shown in Figure 1 [4]. In this figure two compositions in the Al3-0.5zTi1-0.5zCuz family are shown with the substitution of 7 atomic % and 11 atomic % copper. However initial investigations showed that these two compositions were unsuitable due to the formation of low-temperature liquid (~540oC) and intermetallic phase, Al2Cu along the Al-Cu binary edge during solidification. The Al2Cu phase segregated along the boundaries of Al3Ti and Al5Ti2Cu, and dissolved away when electrolysis was carried out using these anodes above 800oC. The presence of consequential porosity in the anode material increased the corrosion of the alloy through local heating due to high current density at 0.8 A cm-2. The early tests were carried out with cryolite melts, shown in Figure 2, having 3 weight percent of Al2O3 in the bath at 850oC."

Jan 1, 2010

By David J. Dunn

Materials related problems at mines can be big ones - like a newly completed 1 -m (3.5ft) water pipeline burst during initial filling, grinding ball consumption at double the typical norms on startup of a new semiautogenous grinding (SAG) mill circuit or 30 open-pit haul trucks in the shop for new bed liners after less than a year’s service. Materials engineering provides solutions to these kinds of equipment problems by selecting good materials and designs, by trouble-shooting service failures and by maintaining high quality in vendor-furnished materials and components. Materials with good properties, correctly made and fabricated, correctly installed in mining and processing equipment, produce ore and final products reliably and efficiently. Materials engineering, applied during design phases, specification writing, and receipt and installation of materials, ensures that equipment will have the best possible shot at performing up to expectations. Good calls on materials properties - specifying state-of-art materials produced by competent manufacturers - help mine managers to reduce downtime and mining and processing costs. Materials that are improperly made or specified can make a mining operation less efficient or, possibly, uneconomical.

Jan 1, 1992

By G. Delagrammatikas, M. Karmis, J. Mastoris

The evaluation of raw materials in terms of quality profile, mineralogical character and mechanical properties is of great importance to the cement industry. The variability of their chemistry and structure is among the decisive design parameters in the choice of any mining, handling and preblending systems. Furthermore, clinker and cement production require sound estimates of the above parameters, to help produce some appropriate and realistic raw mix configurations and achieve minimum standard deviation of the major components. This paper addresses this subject from the perspective of a cement producer and presents the principles of a methodology aimed at optimizing mine planning and process design. Finally, results from case studies on actual sedimentary deposits currently in operation are discussed.

Jan 1, 2002

By Thomas G. Goonan

Copper production through smelting generates large volumes of material flows. As copper contained in ore becomes copper contained in concentrate to be fed into the smelting process, it leaves behind an altered landscape, sometimes mine waste, and always mill tailings. Copper concentrate, fluxing materials, fuels, oxygen, recyclables, scrap and water are in-puts to the process. Dust (recycled),gases — containing carbon dioxide(CO2) (dissipated) and sulfur dioxide (SO2) (mostly collected, transformed and sold) and slag (discarded or sold) — are among the significant process outputs. This article reports estimates of the flows of these input/output materials for a particular set of smelters studied in some countries. They include Chile (Altonorte, Caletones, Chagres, Chuquicamata, LasVentanas and Potrerillos), Japan(Naoshima, Onahama, Saganoseki,Tamano and Toyo), the United States(Garfield — Fig. 1 — Miami and Hayden) and Europe (Glogow I, Glogow II, Huelva, Norddeutscheand Ronnskar).

Jan 1, 2005

By Ree Llewellyn

"It has been estimated conservatively that the costs of wear damage and friction in the Canadian mining and mineral processing industry amount to over one billion dollars per year. These are mainly incurred through the repair or replacement of worn parts and production losses from related equipment downtime. The selection and application of the most appropriate wear protection components and systems, can thus have a very significant influence on productivity, profitability and global competitiveness.Details are presented of the wide diversity of materials used to counteract the varied and often complex wear attack mechanisms that occur in surface mining. The majority are various forms of steels and irons with generally very high hardness. However, they also include relatively soft elastomers and polymeric products.The main characteristics and applications of the different classes are reviewed. Case studies record significant performance improvements achieved through more judicious selections. Finally, some new developments which reduce maintenance charges by substantially increasing wear component life, are described."

Jan 1, 1996

By Andrukaitis. E.

The increasing use of electronic equipment by the Canadian Forces has increased the importance of electric power. A power source that is packed with energy and yet light, small and durable is the common request of military users. However, this needs to be achieved while also addressing the requirements of safety, reliability and low temperature performance. The potential use of fuel cells in a military environment has become a possibility in several areas in the 21st century. Some examples of power source requirements and the materials related R&D required to give better, higher energy power systems in the future will be discussed.

Jan 1, 2005

By G. T. van Rooyen

Materials for Winding Plant Components By Prof. G. T. van Rooyen (ScD) (MIT). Materials for critical applications such as winding plant components are reviewed in terms of the basic requirements which have to be complied with. It is shown that tensile testing alone is not sufficient and that impact testing also is necessary if the incidence of brittle fracture is to be avoided. As a criterion it is suggested that the brittle transition temperature (B.T.T.) determined by impact testing should in all cases be well below the lowest anticipated service temperature. A number of steels were evaluated by impact testing and it is shown that a small ferrite grain size, obtained either by chemical means such as by the use of appropriate alloying elements in the steel or by means of a quenching heat treatment, is effective in attaining a Iow B.T.T. The speed of strain aging as well as the influence of strain aging on the B.T.T. was also evaluated. On the basis of the results obtained it is recommended that steels for critical applications must conform to an appropriate grade and class of steel according to BS 4360 specification. It is further recommended that such steels be exempted from the customary six-monthly heat treatment prescribed by the Mines and Work Act, Regulation 16,18.

WMC Limited, owner/operator of Olympic Dam, the worldÆs largest underground uranium mine and the fourth largest underground copper mine has now completed an expansion that has been classed as a benchmark in the mining industry. To achieve a production increase from 3.4 to 9.25 Mtpa from an underground mining operation in two years was a major challenge, it was essential to review the overall materials handling system from æthe face to the stockpileÆ. The challenge was two-fold:How to deliver 30 000 tonne of ore per day to the processing plant, from a single underground mine? To provide the processing plant with a consistent metallurgical feed. This paper traces the transformation from the old to the new materials handling system at Olympic Dam.

Jan 1, 2000

By E. C. Speers

The Ray Mines Division has a long and illustrious history beginning in 1911, as one of the early underground block caving copper mining operations. The tonnage mined from the beginning of operations, increased from about 8, 000 TPD in the early years to the present daily tonnage of 22, 500 tons, mined by open pit methods. The Ray basic milling practice has been relatively unchanged since 1927 when the sulphide-flotation process was introduced at Ray. The leach-precipitation-flotation process introduced in 1956 has been the only major process change. The change from underground to open pit' mining was accompanied by a renewed drilling and exploration program which developed large tonnages of low grade copper ores both in the porphyry and the diabase. The ore bodies as outlined were of such a grade and size that it soon became apparent that economical operations could not be developed with the lower tonnage rate. Also that in order to develop these newly proven ores, it would be necessary to move the Ray crushing plant, the Ray. supporting shops, offices, a substantial part of the Ray townsite, and would also involve the rerouting of Mineral Creek, a typical Arizona stream which is dry most of the year but can flow as high, as 8, 000 second feet in the rainy season. This paper describes those changes in flow sheet made necessary both by the increased tonnage .and the requirement to move as much of the crushing facilities from the Ray area as practical in order to free the mine for the extension of its physical limits.

Jan 1, 1961

Depressed prices for minerals will force the mining industry to became more efficient. The continuous conveying of pit product is one area in which savings can be made. Conveyors are available, or can be adapted to provide the flexibility and reliability required. Each conveying system will need to be custom designed to suit the particular requirements of the mine. The Australian mining industry must take the initiative and accept the challenge of the new technology.

Jan 1, 1986

By B. C. Litzinger

Minerações Brasileiras Reunidas S.A. - MBR is a brazilian iron ore mining company geared for the export market. It is controlled by Companhia Auxiliar de Empresas de Minerações - CAEMI through its subsidiary Empreendimentos Brasi leiros de Minerações - EBM which holds 51% in MBR and is formed by CAEMI, the six major japanese steelmills and five japanese trading companies, Universe Tankships, Inc., and Indústria e Comércio de Minérios S.A. - ICOMI. The remaining 49% of MBR's capital are held by St. John del Rey Mining Company, a subsidiary of The Hanna Mining Company. MBR iron ore reserves exceed 1.5 billion tons of high grade ore distributed in 36 deposits located in the so-called IRON QUADRANGLE in the State of Minas Gerais. The Aguas Claras Mine is the largest presently known and highest grade deposit owned by MBR. Other mines such as Pico, Mutuca and Jangada are in operation at a combined rate of production of about 2 to 2. 5 million tons per year. The project consists of mine, railroad and marine terminal (slide). The Aguas Claras deposit, which is located about six kilometers southeast of Belo Horizonte the Capital of Minas Gerais, was selected for initial development. The Sistema Regional Centro of the Rede Ferroviária Federal, through its 6th Division known as the "Central " is responsible for the transportation of MBR ore, and provided the necessary railway construction to connect Mine and Terminal. The Terminal is located on Guaiba Island near the entrance to Sepetiba Bay, at about 120 kilometers west of Rio de Janeiro.

Jan 1, 1974

By G. Sperlins

"IntroductionBrenda Mines Ltd. is a low-grade open-pit mining and milling operation located near Peachland, B.C. Brought into production in late 1969, the plant treats an average of 30,000 tons per day of an ore that contains 0.130% copper and 0.030% molybdenum.The operation is divided into six areas of responsibility, namely the mine, mill, plant, accounting, industrial relations and purchasing /stores departments.The purchasing and warehousing area handled in excess of 11,000 items valued at $31,000,000 in 198J. Over and above this, the warehousing area issued in excess of 74,000 line items valued at $15,000,000 during that same period.Materials Management- DefinitionWhat is meant by the term ""Materials Management""? Reference to the dictionary will reveal that a material is ""that of which anything is composed or may be constructed; the tools, instruments, implements', etc. for doing something"". Management is defined as ""the act, or manner of managing; the skillful use of means to accomplish a purpose"". Presumably combining these words defines materials management.Of greater importance are the materials managers who will carry out the function. At Brenda Mines Ltd., all employees and suppliers contribute to the materials management function. Each has a specialized knowledge of the materials used in his field. Each has a different view concerning the use and description of the same material. The key is to focus this knowledge so as to make the materials management system useful to everyone."

Jan 1, 1982

By G. J. Benard

In the 1970’s, several plants have been built and others are in the design stage which use solvent extraction for recovery of copper from acid leach solutions. Other plants are presently being built for the recovery of nickel and cobalt from laterite ores by prereduction and ammonia leaching. A review will be given on the materials of construction for these leaching and solvent extraction processes. Many plants have factors in common which permit selection with a greater degree of accuracy. Based on pilot plant corrosion data, effective use of materials of construction includes proper selection of materials, substitution of lower cost plastics for alloys, and selection of materials resistant against chloride stress corrosion cracking.

Jan 1, 1974

By John A. Riddle

Some of the pitfalls and problems in selecting and applying corrosion-resistant materials in uranium plants are discussed, together with some suggested solutions. Includes some cost data.

Jan 1, 1979

By Morris A. Steinberg

Because of the broad scope of my topic I will discuss my subject from the point of view of a present status of the metallic materials that are used in structures and will dwell primarily on those structures related to high- performance aerospace systems. Thus, I can best portray the status of these structural materials as related to existing transportation systems, delineating some of the highlights of alloy development, fabrication, and properties obtained. I shall point out what are, in my opinion, the needed solutions to pressing unsolved metallurgical problems connected with certain selected metals: aluminum alloys, beryllium, titanium, steels, superalloys, refractory metals and some metal-matrix composites. Aluminum Alloys For a number of years a series of strong aluminum alloys used for airframes has had an important bearing on the development of minimum- weight, highly efficient structures. Among these alloys are such familiar ones as 2024-T3, 2014-T6, 7075-T6, 7079-T6 and 7178-T6. A review of the development and use of strong aluminum alloys in aircraft structures indicates that before about 25 years ago there was very little application of products other than forgings in the high-strength tempers produced by precipitation heat treating to T6- or T8-type tempers. 1 As stated by Dix in 1944, "There has been a gradual evolution in engineering viewpoint regarding the mechanical characteristics which are required in a structural material suitable for aircraft. Formerly, emphasis was placed on a generous spread between yield and tensile strengths, on elongation, on impact strength and on resistance to corrosion. Aircraft structural engineers still differ widely as to the importance which they attach to these proper tie.” 2 It is fair to say that this evolution is still taking place, that the problem is much the same in 1970 as in 1944 - except that strength levels have advanced some - and the question remains as to how far we can go in that direction. In the meantime, a new group of alloys has received acceptance and widespread use. The first alloy of this group, 7075-T6, was formally introduced by Dix's 1944 paper. The drastic changes that have taken place in the size and configuration of components employed in air-

Jan 1, 1971

By X. K. Lan

The greater demand for high-quality large-diameter crystals has led to the robust idea of a free- flying solar-powered furnace satellite, whereby the buoyancy-driven convection effects are almost nonexistent, and diffusion-controlled crystal growth with minimal radial segregation is promoted. In the proposed solar furnace, a paraboloid of revolution imaging concentrator is used to focus the sun's radiation onto an-ampoule which holds the solid charge to be processed. The charge will start melting in the vicinity of the focal point, after which it is translated in order for the melt to resolidify as a single crystal. A ray-trace method has been developed to determine the incident concentrated solar heat flux on the ampoule surface for a perfectly-aligned configuration with an incoming columnated beam. A transient 2- dimensional conduction problem with phase change is formulated, which is solved using the commercial code FIDAP. Results highlighting the feasibility of growing GaAs, Ge and Si crystals with diameters of the order of 20 cm using the solar furnace satellite concept are presented. The transient temperature fields within various charge materials are quantified.

Jan 1, 1994

By Arthur E. Morris

Process modeling software is used extensively in process engineering, but there is a notable lack of affordable software for educational uses. This paper describes two educationally oriented software programs for thermochemical modeling of processes involving metals, minerals, and ceramic materials. Both programs run as Excel@ spreadsheet files. The first is FREED, a thermodynamic database program containing datafiles for 2500 species. It contains the entire U. S. Bureau of Mines and most of the U. S. Geological Survey database, plus data for scores of other species drawn from various sources. Several modules are available for manipulating and viewing the data. The second program is THERBAL, for making thermodynamic calculations using FREED data. Equilibrium calculations can be made for systems with non-ideal solutions, for a specified set of pressure, temperature, and input amounts of reactants. An optional heat balance is also calculated. The results are displayed as tables or charts in Excel worksheets. Examples of the use of THERBAL will be given for the reforming of natural gas for DRI production, DRI production, and EAF steelmaking. Some observations will be made on its use in the classroom. The development of FREED and THERBAL was initially carried out at the Department of Metallurgical Engineering, University of Missouri - Rolla as part of a project to preserve and enhance the Bureau of Mines database. The current versions were developed privately by the authors.

Jan 1, 2002