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By Xiaolin Cheng, A. J. Sinclair

"Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeo chemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:<equation>where all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemico-mineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By Waldemar Lingren

CONTENTS. PART I.-GENERAL FEATURES. [ ]

Jan 1, 1902

In south-eastern King Island, sediments and lavas of possible Upper Proterozoic to Lower Cambrian age have been intruded by Lower Carboniferous granitic rocks.Within the contact aureole of the Bold Head adamellite north of Grassy the sediments and lavas have been metamorphosed to hornblende hornfels facies grade. The thermal gradient within the contact aureole was small, as the hornfelses exhibit no mineral zoning over a distance of 700 ft from the adamellite.Skarns occur both within the adamellite near its contact with the country rocks, and within the country rocks as partial replacements of three dolomitic limestone horizons. The latter type, the exoskarns, commonly have an andradite-salite mineralogy and carry economic concentrations of scheelite. These resulted from the replacement of carbonate beds due to both diffusion and infiltration metasomatism. Silica, tungsten, minor sulphides, and water were introduced from the adamellite, while aluminium and iron diffused from the enclosing pelitic sediments. Calcium released during marble replacement countered the loss of iron and aluminium in the pelitic hornfelses transforming them to diopside-rich rocks.Endoskarns within the adamellite are the result of two way diffusion across the contact; calcium, aluminium, and iron diffused from sediment to adamellite as silica, potassium, sodium, and water diffused from adamellite to the sediments. From estimates of the lithostatic pressure and mole fraction of CO2, the mineral assemblages of the hornfelses imply that the temperature of metamorphism lay between 530&#176; and 710&#176;C. This temperature range is in good agreement with minimum temperatures, between 610&#176; and 710&#176;C, for the recrystallization of the marbles of the contact aureole, calculated from the determinations of the solid solution of the magnesite molecule in calcite.

Jan 1, 1971

In 1939 at the annual meeting of the Australasian Association for the Advancement of Science, held at Canberra, a paper was contributed by E. de C: Clarke and H. A. Ellist in which a plea was made for more &quot;facts&quot; concerning metasomatism near ore-bodies in Western Australia. From time to time writers here, and in other parts of the world, have discussed the alterations in wall rocks of various reefs and lodes, but little has yet been attempted in the matter of accumulation of quantitative data, both chemical and mineralogical, and in the correlation and comparative study of this data. Such a detailed comparative study is needed to determine the economic value of a practical application of our accumulated knowledge of the phenomena of metasomatism.When in 1939 the opportunity offered for an examination of the core from 4 bores recently put down by the Big Bell Mines Ltd., to explore the ore-body of the Corinthian G.M. 10 miles N.W. of Southern Cross, Western Australia it was hoped that some small beginnings might be made of an accumulation of comparative and quantitative data regarding the metasomatism of the wall rock immediately adjacent to this ore-body.By the courtesy of the Big Bell Mines Ltd., the core from the 4 bores was delivered to Survey Headquarters, Perth;in the middle of June, 1939 and copies of assay plans of part of the underground workings at Corinthian, and of the results of assays of the bore cores, were also supplied by the management of the above company.It was not, however, until March, 1940, that it was &apos;found possible to investigate the core. At that time the writer&apos;s colleague, Mr. R. S. Matheson, conducted a: megascopic examination of all the bores and selected material from two of these for possible future chemical analyses. Late in 1940 the writer commenced a microscopic petrological examination of this material.AIM OF THE INVESTIGATIONThe object of the petrological part of this investigation was to determine whether from a megascopic and microscopic examination of the core, any evidence could be obtained indicating changes, in mineralogical composition...

Jan 1, 1942

By C. H. Bucknam, S. A. Wilson, G. E. McClelland

The Meteoric Water Mobility Procedure (MWMP) was developed in the State of Nevada during the 1980’s as part of their mine waste characterization programs. During the 1990’s the Waste Subcommittee of the Nevada Mining Association (NvMA) contacted ASTM Subcommittee E01.02 on Ores, Concentrates and Related Metallurgical Materials to undertake a standardization program for the method. A cooperative program was developed in conjunction with the Acid Drainage Technology Metal Mining Sector (ADTI-MMS)Prediction Committee, which involved eight of the NvMA labs performing duplicate leaching tests on two test materials: a coarse fraction of the USGS Hard Rock Mine Waste standard and a typical spoils sample from a heap leach operation undergoing closure in Nevada. Solutions for metals analysis were preserved and sent to the USGS Laboratories in Denver to determine the reproducibility and repeatability of the leaching. The history of the method and reference material and the results of the interlaboratory testing and statistical analyses will be presented.

Jan 1, 2003

Alcoa of Australia&apos;s Western Australian bauxite mining operations in the Darling Ranges, south east of Perth, present major challenges in the control of air blast. The close proximity of rural communities and the face profile make the traditional methods of air blast control difficult. An extensive blast noise monitoring programme has been established. The develop- ment of a computerised blast noise prediction model and the establishment of a radiosonde weather balloon facility have reduced blast induced complaints by a factor of ten. The meteorological factors affecting blast noise transmission are discussed and examples are given of adverse weather condit- ions for the south west region of Western Australia.

Jan 1, 1982

Alcoa of Australia&apos;s Western Australian bauxite mining operations in the Darling Ranges, southeast of Perth, present major challenges in the control of air blast. The close proximity of rural communities and the face profile make the traditional methods of air blast control difficult.An extensive blast noise monitoring programme has been established. The development of a computerised blast noise prediction model and the establishment of a radiosonde weather balloon facility have reduced blast induced complaints by a factor of ten.The meteorological factors affecting blast noise transmission are discussed and examples are given of adverse weather conditions for the southwest region of Western Australia.

Jan 1, 1983

By Allan B. Tanner

The effects of radon in drillholes on gamma-ray logs have been described by L. S. Hilpert and C. M. Bunker1 Since these effects may cause drastic error in the evaluation of uranium deposits, it is useful to know the conditions under which significant amounts of radon tend to accumulate in drill- holes. In the studies described here, atmospheric conditions were found to dominate in the control of the behavior of radon in drillholes in the vicinity of a uranium orebody. The site of the investigation was in McKinley County, New Mexico, about 12 miles north of Grants. Drillholes of 4 ¼ -in. diam, on 25-ft and 100- ft centers, penetrate ore in dry rock at a depth of about 100 ft. A geologic log of the drillhole of primary interest is shown in Fig. 1. Gamma-ray logs revealed three zones of ore-grade mineralization in the Todilto limestone. A 6-ft zone, the lowest of the three, assayed 0.20 pct U3O8 by chemical analysis. The limestone ores in this area contain disseminated uraninite and some yellow and orange secondary minerals.

Jan 7, 1959

1.Assessment of methane content in coal. Given a naturally low methane content in 11 Coal Seam and the fact that the areas of the 11 Seam adjacent to the tunnelway were degassing for a very, very long time due to previous development and mining, it is conservatively estimated that the remaining in -situ methane is less than 0.5m3/tonne. 2. Continuous miner cutting rate based on the past practice. The best loading rate recorded at the past operations of Smoky River Coal was 45 seconds for a 8 tonnes shuttle car. Using these records, the maximum peak loading rate potential at the face is calculated at 0.178 tonnes per one second or 10.67 tonnes per one minute. 3. Methane release at the face. ?The actual face methane liberation, conservatively assumed at 40% of the total in situ content: 0.20 m3/tonne ?The peak cutting rate: 0.178 t/sec ?The maximum (peak) face methane release: 0.20*0.178 = 0.036 m3/sec

May 1, 2003

By W. P. Yant

THIS paper presents evidence of the general occurrence of methane in a large number of the coal fields of the United States and substantiates the apparent unnecessary differences in the ventilation requirements and codes in the various states, as was brought to the attention of the Committee on Mine Ventilation of the American Institute of Mining and Metallurgical Engineers at its Pittsburgh meeting in October, 1925, by J. A. Garcia.1 The data in his report have been compiled from the files of the Gas Laboratory of the Pittsburgh Experiment Station of the Bureau of Mines and represent samples collected throughout the various states and submitted for analysis by its engineers, also by mine operators and State mining departments, since 1911. Several thousand analyses were available but most of them were rejected because they represented abnormal conditions, undefined place of sampling, special investigations, or duplications in the same mine. Only those samples were included which, without reasonable doubt, were ascertained to fall within three major classes, namely, main return, air splits, and face and rooms of live workings. In the case of air splits, and face and room samples, only the one which contained the highest percentage of methane found in a given mine was taken.

Jan 1, 1927

By Pramod C. Thakur

Introduction Methane is contained under pressure within the fractures and adsorbed on the surface of the coal seams and adjacent strata. It is released into the mine atmosphere during mining of the seam creating explosive gas-air mixtures. Large volumes of air, sometimes as high as 20 tons of air for each ton of coal mined, are circulated constantly to dilute and carry away methane from coal mines. Removal of methane from solid coal, wherever high methane emissions occur, has been discussed by Spindler and Poundstone (1960) and Thakur and Davis (1977). Methane control in longwall gobs is much more complicated. As longwall mining progresses, the overburden continually subsides, and the immediate roof caves behind the roof supports. Even the underlying strata heave and open up communication channels feeding gas to the longwall gobs. The pressure of gas in the underlying and overlying strata is usually higher than the ambient air pressure in the mine. Thus the mine workings become natural pressure sinks, into which gas flows from the entire disturbed zone. Winter (1975) defines this zone as the "gas emission space". Depending on the number of gas-bearing zones in the gas emission space and their gas contents, the total methane emission from longwall gobs could vary from a few to more than one hundred cubic meters of gas per ton of mined coal. Hence the ventilation of longwall faces demands a large quantity of air. This ventilation need is further enhanced by high air losses specially on caving faces (with no stowing of the gobs). The old system of longwall ventilation, the &apos;U&apos; pattern, where all the air was brought down one gate road and exited through the other gate road, loses large quantities of air through gobs giving a high methane concentration at the return end of the face. The &apos;Y&apos; ventilation pattern where intake air is brought down both head and tail gate roads relieves the situation to some extent but, on most longwalls, some kind of methane control is still needed. With the onset of longwall mining in Europe several decades ago, the initial work on methane control on longwall has naturally been done there. The basic principle of methane control has always been, and still remains, some means of "bypassing methane from the gas emission space without letting it mix with the mine air". In most cases the bypassing mechanism is either a strategically located borehole or a roadway. A successful methane control program depends on the following basic premises: a. Determination of the geometry of the gas emission space and location of gas bearing horizons therein. b. Estimation of the rate of methane influx into the longwall gob. c. A scheme to bypass the gas in the most economic and efficient manner and thus prevent it from entering the mine atmosphere. In successful methane drainage programs a high proportion, usually between 50 and 70 percent, of the total gas emissions in a working district is removed before it can enter the mine airways. Advantages of methane drainage can be summarized as: 1. Generally reduced methane levels in the mine leading to increased safety and productivity. 2. Reduced air requirements and corresponding savings in ventilation horsepower. 3. Faster rate of advance for development headings and economy in the size of headings. 4. Possible use of mine gas as an additional source of fuel. The purpose of this paper is to briefly review the geometry of gas emission space and methane influx therein and discuss more successful European and U.S. longwall gob gas control techniques.

Jan 1, 1981

By Fred N. Kissell, Jon C. Volkwein

In This Chapter [How inert gas works to prevent methane explosions How inert gas is generated and delivered at highwall mines Volume and quality requirements for inert gas at highwall mines How an inert gas system is operated and Precautions to take during mining to prevent methane explosions] This chapter discusses a method, originally developed by Volkwein and Ulery [1993], to prevent methane explosions during highwall mining. In highwall mining, a horizontal auger or a mining machine enters the coal seam from a surface mine pit at the bottom of a highwall, and the coal is mined out from a series of parallel holes. Explosions can be prevented by injecting inert gas into each hole as it is mined. Coal near the surface has lost most of its methane gas over time. However, in recent years, surface mining has been used for deeper reserves of coal. This trend toward mining deeper reserves has increased the chance of encountering methane, and methane explosions at highwall mining operations have resulted in injuries. HOW INERT GAS WORKS TO PREVENT METHANE EXPLOSIONS A methane explosion requires the presence of sufficient amounts of both methane and oxygen, as well as an ignition source. If the methane cannot be reduced and the ignition source cannot be eliminated, then explosions may be prevented by adding an inert gas, which contains little to no oxygen, to the mixture [FWQA 1970]. Just how much inert gas must be added depends on the mining rate, as well as the composition of the inert gas. An explosibility diagram can be used to show whether a methane mixture is explosive after inert gas is added [Zabetakis et al. 1959] (Figure 10–1). This diagram indicates that gas mixtures fall into one of three range categories—explosive, explosive when mixed with air, and nonexplosive—depending on the percentage of methane and percentage of “effective inert.” Effective inert is calculated from the percentage of “excess nitrogen”3 and percentage of carbon dioxide in the mixture.

Jan 6, 2006

By H. John Head, Fred N. Kissell

In This Chapter [Gas reports from around the world Regulations for gassy mines in the United States Differences between metal/nonmetal mines and coal mines Monitoring for methane and taking action Diluting methane with additional ventilation Eliminating ignition sources What experienced mine operators say about methane control and Looking for methane when starting a new mine or expanding an existing mine] This chapter gives guidelines for preventing methane gas explosions during metal and nonmetal mine development and subsequent production operations.3 Emphasis is placed on recognizing the differences between coal mines, where the potential for methane hazards is relatively well understood, and metal/nonmetal mines, where methane may accumulate unexpectedly. Also, interviews with experienced mine operators add much to a complete understanding of what must be done to address methane problems in metal/nonmetal mines. METHANE GAS IN METAL/NONMETAL MINES Gas reports from around the world. The presence of methane gas in metal/nonmetal mines around the world is more common than one might imagine [Edwards and Durucan 1991]. For example: • The former Soviet republics have occurrences of methane and hydrogen in apatite, gold, and diamond ores, where solid or liquid bitumen occurs in the rock. • Scandinavian iron ore deposits include methane and other hydrocarbons in boreholes that intersect pitch and asphalt within the deposits, and methane and nitrogen in boreholes and fissures in arsenic and sulfide ores.

Jan 6, 2006

By Joseph Cervik

INTRODUCTION Common methods of controlling gob gas in U.S. mines are by means of ventilation of gob areas and gas drainage through surface boreholes. Costs of drilling surface gob holes increase as deeper coal- beds are mined. Where gob holes cannot be drilled because of topography, ventilation is the only means of control. Even then, sufficient air may not be available to dilute methane in the bleeder entries to acceptable levels. Thus, new methods of gob gas control need to be developed that are independent of surface topography, and of the mine ventilation system, and less costly than present systems. Except for slight variations in procedures and equipment, Great Britain, West Germany, France, Belguim, Poland, and Czechoslovakia use a common methane control method that is different from the system generally used in the United States. This Bureau of Mines paper reviews European mining methods, mining conditions, and methane control technology and discusses their applicability to U.S. mines.

Jan 1, 1981

By Joseph Cervik

Common methods of controlling gob gas in U.S. nines are by means of ventilation of gob areas and gas drainage through surf ace boreholes. Costs of drilling surface gob holes increase as deeper coalbeds are mined. Where gob holes cannot be drilled because of topography, ventilation is the only means of control. Even then, sufficient air may not be available to dilute methane in the bleeder entries to acceptable levels. Thus, new methods of gob gas control need to be developed that are independent of surface topography, and of the mine ventilation system, and less costly than present systems. Except for slight variations in procedures and equipment, Great Britain, West Germany, France, Belguim, Poland, and Czechoslovakia use a common methane control method that is different from the system generally used in the United States, This Bureau of Mines paper reviews European mining methods, mining conditions, and methane control technology and discusses their applicability to U.S. mines.

Jan 1, 1979

By Maurice Deul

This bulletin summarizes the work conducted under the Bureau of Mines methane control research program during the years 1964 to 1979. This research effort was directed toward improving existing methods and developing alternative methods of reducing the explosion hazard during mining. The research was performed in three general areas: (1) basic factors that control the emission of methane into coal mines, (2) methane control during mining, and (3) methane drainage in advance of mining. Topics discussed in this bulletin include the magnitude of the methane problem; the equipment and instruments developed; the geological, chemical and physical parameters that control the movement of methane in coalbeds; the direct method of determining gas content; the estimates of gas content from adsorption data; and methane drainage, through shafts, through horizontal boreholes, through vertical boreholes, or through slant holes. Improvements in ventilation, control of methane in gob areas, and water infusion are also discussed, as is the potential use of coalbed methane as a supplement to natural gas supplies. This bulletin provides a comprehensive source of information on the accomplishments of the Bureau&apos;s methane control research program, on the technology developed, and on the direction of further research.

Jan 1, 1986

By Joseph Cervik

The mined coal bed and surrounding strata are both sources of methane which must be control led during mining. During developmental mining, the mined coalbed is the primary methane source; during retreat longwall mining, the primary methane source is the overlying strata. Underground technology is being developed to control both sources. This technology involves drilling long horizontal drainage holes into the mined coal bed and relatively short holes (less than 152 m or 500 feet) into the overlying strata. Because of the large volumes of methane that flow from such drainage holes and the limited ventilation available for in-mine dilution, underground pipelines are used to transport the drained gas to the surface. Large- scale in-mine degasification demonstrations showed reductions in methane flow of up to 70% during developmental mining.

Jan 1, 1981

By Griffiths L, Marshall P

fhis paper describes investigations into drainage of gas from the solid to control outbursts. Initial studies conducted on drainage of shear zones showed that, given enough time, these can be successfully drained. Once drained, they can be intersected and driven through without any activity of outbursts. The results of programme of investigations to determine parameters for drainage from the solid show that gas flow rates from the Bulli Seam on the average are about 2 litres/min/metre length of borehole. But when shear zones are intersected, the flow rates could be as high as 8 litres/min/ metre length of hole. Shear zones can be picked up from pressure measurements 50 - 60 m away and this could give sufficient time to drill through these zones and drain them in advance. Systematic drainage of Bulli Seam at West Cliff Colliery could eliminate or reduce frequency of outbursts considerably. At present drainage holes are being drilled systematically in the seam, with drainage installations on the surface. Gas purity of 80% methane is being delivered at the surface plant.

Jan 1, 1980

By Pramod C. Thakur

Methane drainage by cross-measure boreholes on retreat longwall faces can be a viable alternative to the vertical gob degas boreholes under favorable circumstances. The research was done in a mine working Pittsburgh Coal seam in Northern West Virginia under U.S.B.M. Co-operative Agreement No. 14-09-0050-3252. The study was the first application of this technique to Pittsburgh coal seam. A total of fourteen, small diameter, inclined boreholes were drilled over a retreat longwall panel from gate roads, to intersect the overlying coal seams. All boreholes were manifolded to a pipeline and the gob gas was extracted by an exhaust fan on surface. The methane capture ratio was poor at 7 to 18% at various stages of the longwall panel. A vertical gob degas borehole captured an additional 20% gas. Poor results were due to premature failures of the cross-measure boreholes leading to air leakage. For better performance the boreholes should be drilled from a point 30 to 45 m from longwall pillar over the largest chain pillar, the standpipe should be grouted for at least 6 m, and the entry containing boreholes and the pipeline must be supported to ensure access for maintenance, and optimization of methane capture. Coursing the ventilation air around longwall such that it forces methane-migration towards cross-measure boreholes can further improve methane capture. The optimum vertical inclination is 45° ± 10°.

Jan 1, 1983

By J. Cervik, P. C. Thakur, S. D. Lauer

Methane drainage by cross-measure boreholes on retreat longwall faces can be a viable alternative to the vertical gob degas boreholes under favorable circumstances. The research was done in a mine working Pittsburgh coal seam in northern West Virginia under USBM Cooperative Agreement No. 14-09-0050-3252. The study was the first application of this technique to Pittsburgh coal seam. A total of 14 small diameter, inclined boreholes were drilled over a retreat longwall panel from gate roads, to intersect the overlying coal seams. All boreholes were manifolded to a pipeline and the gob gas was extracted by a surface exhaust fan. The methane capture ratio was poor at 7% to 18% at various stages of the longwall panel. A vertical gob degas borehole captured an additional 20% gas. Poor results were due to premature failures of the cross-measure boreholes leading to air leakage. For better performance, the boreholes should be drilled from a point 30 to 45 m (98 to 148 ft) from longwall pillar over the largest chain pillar. The standpipe should be grouted for at least 6 m (20 ft), and the entry containing boreholes and the pipeline must be supported to ensure access for maintenance and optimization of methane capture. Coursing the ventilation air around longwall such that it forces methane migration toward cross-measure boreholes can further improve methane capture. The optimum vertical inclination is 45º ± 10º.

Jan 1, 1986